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1.
M. Bremont W. Brockmann M. F. Guimon G. Pfister-guillouzo 《The Journal of Adhesion》2013,89(1-4):147-168
The durability properties of bonded lap shear joints made from an epoxy/dicyandiamide adhesive and hot-dipped galvanized (G2F) or electroplated-phosphated (EZ2) steel have been investigated. The degradation mechanisms have been studied after three accelerated ageing tests: the “cataplasme humide” (“C.H.T.”), immersion (“I.T.”), and salt spray (“S.S.T.”) tests. X-ray photoelectron spectroscopy (XPS) analysis of fracture surfaces after ageing have shown that anodic dissolution of the zinc-coating is responsible for debonding in all cases and that intergranular corrosion phenomena account for poorer performances of the hot-dipped galvanized substrate during “C.H.T.” and “I.T.” Silane coupling agents were successfully used as primers on both substrates to increase the hydrolytic stability of the metal/adhesive interface. XPS results indicate that both the interfacial dissolution of the phosphate coating of EZ2 and intergranular corrosion of G2F are delayed for silane-primed specimens. The observed improvements do not appear to depend on the nature of the silane coupling agents. Alkylsilanes have been found to perform as well as silanes having a group capable of reacting with the epoxy/dicyandiamide system. Additional tests were carried out in view of the possible application of organosilane reagents as additives in corrosion-protective oils. Good durability properties have been obtained by priming the metal coupons with a standard oil/silane mixture prior to bonding. When corrosion was the controlling degradation mechanism as is the case during the salt spray test, silane treated specimens did not generally perform better than control specimens. 相似文献
2.
The durability properties of bonded lap shear joints made from an epoxy/dicyandiamide adhesive and zinc metal coupons have been investigated. The metal coupons were anodized in sodium hydroxide solutions before bonding. The influence of the anodizing conditions on the morphology and composition of the oxide layers has been studied using SEM and TEM imaging analyses as well as X-ray photoelectron spectroscopy. The hydrolytic stability of the bonded joints has been assessed by storing the joints in water at 70 °C or 90 °C for periods of time up to 5 weeks. Polypropylene has been used as a model adhesive to study the influence of mechanical interlocking effects on the performance of the bonded joints. Depending on the anodizing conditions, the improved durability properties have been attributed either to „mechanical interlocking effects“ or to the higher hydrolytic stability of the oxide layers generated during the anodizing treatment.
Some of the results gained from the anodization of zinc have been extrapolated to hot-dipped galvanized steel. Bonded joints made from hot-dipped galvanized coupons anodized under smooth conditions (2% NaOH) displayed residual shear strengths of up to 70% higher than specimens simply degreased after immersion test. The generation of stable oxide layers as well as the suppression of intergranular corrosion phenomena at the metal/adhesive interface can explain the improved durability properties. 相似文献
Some of the results gained from the anodization of zinc have been extrapolated to hot-dipped galvanized steel. Bonded joints made from hot-dipped galvanized coupons anodized under smooth conditions (2% NaOH) displayed residual shear strengths of up to 70% higher than specimens simply degreased after immersion test. The generation of stable oxide layers as well as the suppression of intergranular corrosion phenomena at the metal/adhesive interface can explain the improved durability properties. 相似文献
3.
Robert T. Foister 《The Journal of Adhesion》1987,24(2):279-313
Galvanized substrate morphology, oxide layer chemistry, bond failure modes, failure loci, and bondline corrosion have been investigated for adhesive bonds to galvanized steel. Significant differences in surface morphology were observed between the relatively smooth surfaces of “hot-dipped” substrates and the considerably rougher texture of “electroplated” substrates. The hot-dipped substrates were also chemically heterogeneous, with significant amounts of Al, Mg, Ca, and Pb, in addition to Zn, constituting the surface layer. For electroplated substrates, on the other hand, Zn was the major constituent. It was concluded that, for a given adhesive, low strengths and poor bond durability generally correlated with the minimum surface roughness and maximum chemical heterogeneity of the hot-dipped substrates. Higher strengths, and better durability, on the other hand, were observed for electroplated substrates, which showed the greater roughness, as well as chemically the more uniform surface.
Significantly, ESCA spectroscopy of fracture surfaces of unaged samples established that failure loci for both one and two-part epoxy adhesives included the oxide layer of the substrate. This was true for both hot-dipped, as well as electroplated substrates. For aged samples, scanning electron microscopy and X-ray diffraction analysis of failure surface identified zinc-based corrosion products present in the original bond area. 相似文献
Significantly, ESCA spectroscopy of fracture surfaces of unaged samples established that failure loci for both one and two-part epoxy adhesives included the oxide layer of the substrate. This was true for both hot-dipped, as well as electroplated substrates. For aged samples, scanning electron microscopy and X-ray diffraction analysis of failure surface identified zinc-based corrosion products present in the original bond area. 相似文献
4.
In this article we describe the application of X-ray photoelectron spectroscopy to epoxy/dicyandiamide laminates on zinc galvanized steel which were aged under different environmental conditions involving high humidity and temperatures.
X-ray photoelectron microscopy allows us to identify the distribution of chemical elements with a lateral resolution of 10μm. Areas selected in the microscopy mode were then analyzed in the spectroscopy mode in order to get information on the local chemical composition.
We compared the spectroscopic features of the aged but freshly delaminated surfaces of samples stored under ambient conditions at room temperature with samples exposed to the “Kataplasmann” and the “KWT” test, respectively. Furthermore, a comparison was made with a model sample which was prepared in vacuum and on which the curing process was investigated.
Though there is no substantial loss in the lap-shear strength of the samples, we find drastic spectroscopic changes in the Kataplasma and KWT treated samples compared with the sample kept at room temperature. We conclude that the chemical changes induced by these tests cause an internal interphase boundary between the epoxy/metal interface and the bulk adhesive along which delamination occurs. Comparison with the behavior of the water-vapor-treated model sample gives evidence that hydrolysis is the main reaction in these tests.
The results described here complement our former study.1 相似文献
X-ray photoelectron microscopy allows us to identify the distribution of chemical elements with a lateral resolution of 10μm. Areas selected in the microscopy mode were then analyzed in the spectroscopy mode in order to get information on the local chemical composition.
We compared the spectroscopic features of the aged but freshly delaminated surfaces of samples stored under ambient conditions at room temperature with samples exposed to the “Kataplasmann” and the “KWT” test, respectively. Furthermore, a comparison was made with a model sample which was prepared in vacuum and on which the curing process was investigated.
Though there is no substantial loss in the lap-shear strength of the samples, we find drastic spectroscopic changes in the Kataplasma and KWT treated samples compared with the sample kept at room temperature. We conclude that the chemical changes induced by these tests cause an internal interphase boundary between the epoxy/metal interface and the bulk adhesive along which delamination occurs. Comparison with the behavior of the water-vapor-treated model sample gives evidence that hydrolysis is the main reaction in these tests.
The results described here complement our former study.1 相似文献
5.
The durability properties of bonded lap shear joints made from an epoxy/dicyandiamide adhesive and zinc, zinc-coated steel, two different aluminium alloys or cold-rolled steel metal coupons have been investigated. The influence of the dicyandiamide content of the adhesive on the durability properties-has been assessed by salt spray testing or by storing the joints in water at 70°C or 90°C for periods of time up to five weeks. The degradation products formed during ageing of the epoxy adhesive in water have been investigated using high performance liquid chromatography (HPLC) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFT). The degradation mechanisms of aluminium/epoxy bonded joints have been thoroughly studied using X-ray photoelectron spectroscopy.
The performances of the bonded joints under a pure corrosive environment have been found to be little influenced by the quantity of dicyandiamide in the adhesive. When the bonded joints were aged in hot water, the stability of the interface toward an excess of dicyandiamide directly followed the sensitivity of the oxide layer at high pH values. Optimal durability properties without peel strength losses of the adhesive were aehieved both with zinc and aluminium-coated substrates by reducing the quantity of dicyandiamide in the epoxy adhesive by 20% (the initial dicyandiamide content in the commercial adhesive being ca. 9%, with respect to the epoxy resin). 相似文献
The performances of the bonded joints under a pure corrosive environment have been found to be little influenced by the quantity of dicyandiamide in the adhesive. When the bonded joints were aged in hot water, the stability of the interface toward an excess of dicyandiamide directly followed the sensitivity of the oxide layer at high pH values. Optimal durability properties without peel strength losses of the adhesive were aehieved both with zinc and aluminium-coated substrates by reducing the quantity of dicyandiamide in the epoxy adhesive by 20% (the initial dicyandiamide content in the commercial adhesive being ca. 9%, with respect to the epoxy resin). 相似文献
6.
During a program to develop new structural adhesives that would meet the processing requirements of the current automotive “high heat” bake cycles, substantial differences in performance were noted between the “standard” cold rolled steel (CRS) of SAE1008 and certain Drawing Quality steels (DQSK).
In parallel tests, certain DQSK test specimens (bonded with 200°C heat cycle) failed consistently in the interfacial region, while the CRS samples failed center of bond.
The surface characteristics of the steels and failed adhesive specimens were examined with ESCA, AUGER, and ISS spectroscopic methods. The metal failure surfaces of the DQSK samples were shown to contain relatively high levels of silicon and oxygen, and smaller amounts of boron, with a lower concentration of iron, as compared to CRS which shows iron surface with minor contaminations.
In subsequent testing, with other samples of DQSK SAE1008, this effect was not observed. These samples did not exhibit the same levels of contamination. It is suggested that certain DQSK processes may involve processing steps that are detrimental to the surface properties of the rolled sheet stock. 相似文献
In parallel tests, certain DQSK test specimens (bonded with 200°C heat cycle) failed consistently in the interfacial region, while the CRS samples failed center of bond.
The surface characteristics of the steels and failed adhesive specimens were examined with ESCA, AUGER, and ISS spectroscopic methods. The metal failure surfaces of the DQSK samples were shown to contain relatively high levels of silicon and oxygen, and smaller amounts of boron, with a lower concentration of iron, as compared to CRS which shows iron surface with minor contaminations.
In subsequent testing, with other samples of DQSK SAE1008, this effect was not observed. These samples did not exhibit the same levels of contamination. It is suggested that certain DQSK processes may involve processing steps that are detrimental to the surface properties of the rolled sheet stock. 相似文献
7.
The performance of eight organofunctional silane coupling agents as adhesion promoters for the bonding of aluminium with two 121°C and two 177°C curing structural film adhesives was investigated and compared to the chromic acid (FPL) etch pre-treatment process and two non-chemical pretreatments. Aspects considered were shear strength of joints at ambient and elevated temperatures and durability, as judged by the wedge test.
The epoxy silane, γ-glycidoxypropyltrimethoxy silane, was found to be a very efficient adhesion promoter with all film adhesives evaluated. The cationic styryl silane, a neutral diamine monohydrochloride, showed promise with two adhesive systems. Four other neutral silanes were less effective.
Performance of amine functional silanes was mixed. Although the shear strength of joints with the primary amine silane at its natural pH of ∼10.3 was relatively good, durability was poor. However, good durability was obtained if the primer was first adjusted to pH 8 with hydrochloric acid, but not if acetic or phosphoric acids were used. Diamine silane was not an effective adhesion promoter at either its natural pH or when acidified with hydrochloric acid. 相似文献
The epoxy silane, γ-glycidoxypropyltrimethoxy silane, was found to be a very efficient adhesion promoter with all film adhesives evaluated. The cationic styryl silane, a neutral diamine monohydrochloride, showed promise with two adhesive systems. Four other neutral silanes were less effective.
Performance of amine functional silanes was mixed. Although the shear strength of joints with the primary amine silane at its natural pH of ∼10.3 was relatively good, durability was poor. However, good durability was obtained if the primer was first adjusted to pH 8 with hydrochloric acid, but not if acetic or phosphoric acids were used. Diamine silane was not an effective adhesion promoter at either its natural pH or when acidified with hydrochloric acid. 相似文献
8.
《The Journal of Adhesion》1969,1(2):88-91
“lssledovaniya v oblasti poverkhnostnykh sil” (“Research on surface forces”) B. V. Deryagin, editor. Nauka Publ., Moscow 1967.544 pp. Rubles 3.00.
G. D. Andreevskaya, “Vysokoprochnye Orientirovannye Steklo-plastiki” (“High-strength Oriented Glass-Plastics”). Nauka Publ., Moscow 1966. 370 pp., Rubles 2.12.
A. D. Zimon, “Adgeziya pyli i poroshkov” (“Adhesion of dust and powders”) Khimiya Publ., Moscow 1967.372 pp. Rubles. 1.51.
J. J. Bikerman, “The Science of Adhesive Joints”. Academic Press, New York 1968.349 pages. $16.00. 相似文献
G. D. Andreevskaya, “Vysokoprochnye Orientirovannye Steklo-plastiki” (“High-strength Oriented Glass-Plastics”). Nauka Publ., Moscow 1966. 370 pp., Rubles 2.12.
A. D. Zimon, “Adgeziya pyli i poroshkov” (“Adhesion of dust and powders”) Khimiya Publ., Moscow 1967.372 pp. Rubles. 1.51.
J. J. Bikerman, “The Science of Adhesive Joints”. Academic Press, New York 1968.349 pages. $16.00. 相似文献
9.
Initial (i.e., unaged) adhesion, as well as adhesion after seven day, 60°C water immersion and six week scab corrosion accelerated environmental exposures, has been assessed for five different one and two-part epoxy adhesives, bonded to three different types of galvanized steel substrates. We have shown that adhesion, as measured by lap shear strength, is specific to the galvanized substrate type. In general, for a given adhesive, adhesion to “hot-dipped” galvanized substrates is harder to achieve and maintain under accelerated environmental exposure than is adhesion to “electroplated” galvanized. Also, for a given type of galvanized steel, the one-part epoxies evaluated generally showed higher initial strengths, as well as better strength retention under environmental exposure than did the two-part epoxies. 相似文献
10.
The interface in aluminium bonded structures can be revealed by ultramicrotomy and subsequently studied by transmission electron microscopy. By these means, the more usual surface pretreatments encountered, have been characterised in depth.
A similar examination has been effected following exposure of bonded joints (floating roller peel specimens) to 85% relative humidity at 70°C. Although a drop in peel performance is noted over the exposure time, interfacial examination reveals little damage to the adhesive or adherend. Possible mechanisms for bond strength reduction are discussed: subtle undermining of the alumina film and disruption of physico-chemical bonds across the interface. Both are initiated by moisture reaching the alumina film, either passing along the interface itself or travelling through the adhesive matrix. Also considered are the effects of surface pretreatment and “oxide” penetration, by the adhesive, on durability.
The effect of priming the adherend surface prior to bonding, using a heavily strontium chromate filled adhesive primer, is mentioned and its possible influence on durability is briefly discussed. 相似文献
A similar examination has been effected following exposure of bonded joints (floating roller peel specimens) to 85% relative humidity at 70°C. Although a drop in peel performance is noted over the exposure time, interfacial examination reveals little damage to the adhesive or adherend. Possible mechanisms for bond strength reduction are discussed: subtle undermining of the alumina film and disruption of physico-chemical bonds across the interface. Both are initiated by moisture reaching the alumina film, either passing along the interface itself or travelling through the adhesive matrix. Also considered are the effects of surface pretreatment and “oxide” penetration, by the adhesive, on durability.
The effect of priming the adherend surface prior to bonding, using a heavily strontium chromate filled adhesive primer, is mentioned and its possible influence on durability is briefly discussed. 相似文献
11.
Walter J. Thomas Mohamed A. El-Sawy Edward W. Palmer 《Chemical Engineering Communications》1982,16(1):53-78
Two published theoretical models are examined and applied to experimental results for absorption and desorption. The system used was CO2/H2O and studies were made for liquid film flow down inclined planes. Experimental results give “Reduced” values of mass ransfer rates.
Interferometric studies give interfacial concentration, penetration and film depths, and take-up of carbon dioxide. In the case of desorption the interferograms are distorted by “deflections.”
All the experimental values for absorption and desorption differ from those calculated from theoretical models.
Desorption is not a mirror image of absorption, and it is approximately 75% of the transfer rate of absorption over a wide operating range.
A comparison is made of the behaviour of static pools and flowing liquid films. 相似文献
Interferometric studies give interfacial concentration, penetration and film depths, and take-up of carbon dioxide. In the case of desorption the interferograms are distorted by “deflections.”
All the experimental values for absorption and desorption differ from those calculated from theoretical models.
Desorption is not a mirror image of absorption, and it is approximately 75% of the transfer rate of absorption over a wide operating range.
A comparison is made of the behaviour of static pools and flowing liquid films. 相似文献
12.
In drying problem, particularly for drying foodstuff, modelling is very difficult. Many physical effects have to be taken into account for mass transfer ; then mass transfer coefficient varies
In different models unknown functions must be estimated. It is particularly the case in simple models of drying using average values of water content, where the mass transfer varies versus mean water content in falling rate period. On the other hand in the “diffusion model” we have the same problem concerning the diffusion coefficient which must be also estimated
The method we propose in this paper for these two models : simple and “diffusion model” of drying consists from measurements of temperature and water content of the product to search a numerical approach of the unknown function. This method uses optimization techniques on computer and least squares criterion between model values and experimental data
Results are given for the “diffusion model” applied to shelled corn drying to find the diffusion coefficient and for a simple 11107 del applied to plum drying to find the mass transfer coefficient. 相似文献
In different models unknown functions must be estimated. It is particularly the case in simple models of drying using average values of water content, where the mass transfer varies versus mean water content in falling rate period. On the other hand in the “diffusion model” we have the same problem concerning the diffusion coefficient which must be also estimated
The method we propose in this paper for these two models : simple and “diffusion model” of drying consists from measurements of temperature and water content of the product to search a numerical approach of the unknown function. This method uses optimization techniques on computer and least squares criterion between model values and experimental data
Results are given for the “diffusion model” applied to shelled corn drying to find the diffusion coefficient and for a simple 11107 del applied to plum drying to find the mass transfer coefficient. 相似文献
13.
A. L. Berlad 《Drying Technology》1985,3(1):123-147
The three publications reviewed herein deal with the complex of hazards which may derive from the agricultural and commercial handling of combustible particulate and gaseous materials. The principal thrusts of each book differ substantially from those of the other two. This review first attempts to consider the essential combustion processes which underlie the hazards of common concern in all three works. Each of the three books is then considered on an individual basis. The three publications are designated Books (1)- (3) respectively and are listed below:
(1) “User Guide to Fire and Explosion Hazards in the Drying of Particulate Materials.” 1977. Institution of Chemical Engineers. Warwick Printing Company Limited, England.
(2) “Prevention of Grain Elevator and Mill Explosions.” 1982. NAS-NRC Publication NUB 367-2. National Academy Press, Washington, D. C.
(3) “Guidelines for the Investigation of Grain Dust Explosions.” 1983. NAS-NRC Publication NMAB 367-4, National Academy Press, Washington, D. C. 相似文献
(1) “User Guide to Fire and Explosion Hazards in the Drying of Particulate Materials.” 1977. Institution of Chemical Engineers. Warwick Printing Company Limited, England.
(2) “Prevention of Grain Elevator and Mill Explosions.” 1982. NAS-NRC Publication NUB 367-2. National Academy Press, Washington, D. C.
(3) “Guidelines for the Investigation of Grain Dust Explosions.” 1983. NAS-NRC Publication NMAB 367-4, National Academy Press, Washington, D. C. 相似文献
14.
In this paper, three types of protective silane films, methyltrimethoxysilane (MTMS), vinyltrimethoxysilane (VTMS) and dodecyltrimethoxysilane (DTMS) were prepared on aluminum alloys AA 2024-T3 by electrodeposition technique. The Reflection-Absorption Fourier Transform IR (FTRA-IR) measurements showed that, the silane films were successfully deposited through chemical bonding between silane agents and Al alloys. Electrochemical impedance spectroscopy (EIS) tests indicated that in comparison with those by conventional “dip-coating” method, silane films electrochemically prepared at cathodic potentials exhibited obviously higher corrosion resistances. “Critical potential” was all observed for each silane system. Silane films prepared at this potential performed the highest corrosion resistance. The scanning electron microscopy (SEM) images indicated a potential dependence of surface morphology of silane films. The highest compactness was obtained at the “critical potential”. Due to the presence of long hydrophobic dodecyl chain in bone structure, DTMS films displayed the highest barrier properties. 相似文献
15.
《The Journal of Adhesion》2007,83(1):1-14
The durability of epoxy-aluminium joints that use a homopolymerised epoxy resin was studied, and the effects of relative humidity, temperature, and salt concentration were analysed. The adhesive properties were measured by lap-shear tests, and the water uptake of the epoxy resin was determined by gravimetric measurements. Ageing and degradation effects on the epoxy resin and on the aluminium substrates were also analysed.
The homopolymerised epoxy resin absorbs little water (1.5 wt%) because of its nonpolar network structure. The water uptake is enhanced by increasing relative humidity and temperature; however, the joint strength remains constant because of epoxy plasticization. A saline environment is damaging to the adhesive joints, because of metal corrosion, but was not significantly harmful to the epoxy resin, because of a lower diffusion coefficient of salt water. The Tg decrease of the epoxy adhesive due to water absorption depends only on the amount of absorbed water and is independent of the hydrothermal ageing conditions. 相似文献
The homopolymerised epoxy resin absorbs little water (1.5 wt%) because of its nonpolar network structure. The water uptake is enhanced by increasing relative humidity and temperature; however, the joint strength remains constant because of epoxy plasticization. A saline environment is damaging to the adhesive joints, because of metal corrosion, but was not significantly harmful to the epoxy resin, because of a lower diffusion coefficient of salt water. The Tg decrease of the epoxy adhesive due to water absorption depends only on the amount of absorbed water and is independent of the hydrothermal ageing conditions. 相似文献
16.
This paper deals with the sublimation of large bodies, or “objects”, made up from a pure substance in a bubbling gas fluidized bed of considerably smaller particles, or “fines”. The influence of such parameters as the gas velocity, the bed temperature, the size and the adsorption capacity of the fines has been investigated.
The results obtained clearly show that the rate of sublimation in fluidized beds is far higher than in air alone. It increases with increasing bed temperature, decreasing particle size, increasing powder mass capacity, and roughly varies as a parabolic function of time. It has also been observed that the temperature difference between the bed and the object surface, or “temperature depression”, depends on the fines characteristics as well as on bed temperature, but is independent of gas velocity when good solid mixing conditions are achieved.
Bed-to-object heat and mass transfer coefficients have been deduced from data points and attempts have been made to provide a reasonable theory to account for them. After a complete examination, the idea of interpreting transport phenomena based on a well-adapted “surface renewal model” has been proposed. 相似文献
The results obtained clearly show that the rate of sublimation in fluidized beds is far higher than in air alone. It increases with increasing bed temperature, decreasing particle size, increasing powder mass capacity, and roughly varies as a parabolic function of time. It has also been observed that the temperature difference between the bed and the object surface, or “temperature depression”, depends on the fines characteristics as well as on bed temperature, but is independent of gas velocity when good solid mixing conditions are achieved.
Bed-to-object heat and mass transfer coefficients have been deduced from data points and attempts have been made to provide a reasonable theory to account for them. After a complete examination, the idea of interpreting transport phenomena based on a well-adapted “surface renewal model” has been proposed. 相似文献
17.
Within the “International Collaborative Programme on Organosilane Adhesion Promoters” (ICOSAP), scientists from the U.S. and Europe contributed to the understanding of an organosilane primer process, based on an aqueous solution of γ-glycidoxypropyl trimethoxysilane (γ-GPS), used currently for aerospace repair purposes. Parameters such as temperature of cure, ageing time, and concentration of the aqueous solution have been investigated, and this work reviews the effect that each variable has on the process, and the resulting integrity of the GPS/aluminium interface. The aim of the work was to provide a more environmentally friendly replacement for pretreatments containing Cr(VI) that are currently used, such as chromic acid anodising and acid etching employed for the structural adhesive bonding of aluminium.
The formation of covalent interfacial bonding is shown to be a function of the hydrolysis and condensation of the silane molecules in solution as well as the type of solvent used. The curing temperature of the aqueous film on the aluminium is also shown to have an effect on the chemistry of the resulting primer film and its efficacy as an adhesion promoter. All these parameters must be optimised to obtain durability that matches that obtained by a phosphoric acid anodising pretreatment. This work reports on the various studies performed towards this aim carried out within the remit of the ICOSAP initiative, with a particular emphasis on the interfacial chemistry between γ-GPS and the aluminium substrate, and indicates the manner in which the results point the way towards a viable, environmentally friendly pretreatment for the adhesive bonding of aluminium for aerospaceapplications. 相似文献
The formation of covalent interfacial bonding is shown to be a function of the hydrolysis and condensation of the silane molecules in solution as well as the type of solvent used. The curing temperature of the aqueous film on the aluminium is also shown to have an effect on the chemistry of the resulting primer film and its efficacy as an adhesion promoter. All these parameters must be optimised to obtain durability that matches that obtained by a phosphoric acid anodising pretreatment. This work reports on the various studies performed towards this aim carried out within the remit of the ICOSAP initiative, with a particular emphasis on the interfacial chemistry between γ-GPS and the aluminium substrate, and indicates the manner in which the results point the way towards a viable, environmentally friendly pretreatment for the adhesive bonding of aluminium for aerospaceapplications. 相似文献
18.
A mechanical test method for the studies of high-temperature anaerobic adhesives has been established, based on fracture mechanics, by modifying the standard test method of collar and pin test. Linear Elastic Fracture Mechanics approach was applied to the establishment of the relationship between adhesive fracture surface energy “R”, fracture load and crack length. Hence, from the joints containing a given artificial flaw the adhesive fracture surface energy can be determined; alternatively, from the strength of the joints without artificial flaws the inherent flaw size “ai” can be calculated to account for the decrease of joint strength.
The experimental techniques were applied to examine the mechanical behaviour of the joint system based on high temperature anaerobic adhesives. It was found that the joints cured at room-temperature had higher adhesive fracture surface energy but lower joint strength than the joints postcured at high temperatures. The “ai” data explained this interesting phenomenon. The joints cured at room-temperature had extraordinarily large “ai”, which was found to be formed by the uncured adhesive near the edges of the joints and the adhesive further cured in the postcure processes to reduce the “ai”. Also, the growth of intrinsic flaw was found to be responsible for the deterioration of the joints in a short-term, high-temperature ageing process. 相似文献
The experimental techniques were applied to examine the mechanical behaviour of the joint system based on high temperature anaerobic adhesives. It was found that the joints cured at room-temperature had higher adhesive fracture surface energy but lower joint strength than the joints postcured at high temperatures. The “ai” data explained this interesting phenomenon. The joints cured at room-temperature had extraordinarily large “ai”, which was found to be formed by the uncured adhesive near the edges of the joints and the adhesive further cured in the postcure processes to reduce the “ai”. Also, the growth of intrinsic flaw was found to be responsible for the deterioration of the joints in a short-term, high-temperature ageing process. 相似文献
19.
Mazen A. Shalabi 《Chemical Engineering Communications》1989,76(1):169-178
Kinetic data with pore diffusion limitation on methanol synthesis were generated by extending the “UCKRON-I” kinetic rate expression. The best fit model and the extended “true” model were compared using their respective rates to simulate temperature profiles in a non-isothermal plug flow tubular reactor.
The objective of this work was to add pore diffusion resistance to the UCKRON-1 kinetic rate for methanol synthesis (Berty, et al. 1983). Kinetic modeling of the data with 5% experimental error added, showed the best model to be that developed from a previous kinetic model (Shalabi, et al. 1983) with apparent activation energy approximately one-half the activation energy at no pore diffusion.
Methods used in this work to determine and evaluate pore diffusion parameters can be utilized for other reaction systems where pore diffusion may play a role in reaction rate.
Temperature profiles estimated from reactor simulation studies showed good argeement between ideal and predicted models for temperature. 相似文献
The objective of this work was to add pore diffusion resistance to the UCKRON-1 kinetic rate for methanol synthesis (Berty, et al. 1983). Kinetic modeling of the data with 5% experimental error added, showed the best model to be that developed from a previous kinetic model (Shalabi, et al. 1983) with apparent activation energy approximately one-half the activation energy at no pore diffusion.
Methods used in this work to determine and evaluate pore diffusion parameters can be utilized for other reaction systems where pore diffusion may play a role in reaction rate.
Temperature profiles estimated from reactor simulation studies showed good argeement between ideal and predicted models for temperature. 相似文献
20.
The model equations in the relaxation form for the multicomponent kinetics of isothermal and non-isothermal adsorption, taking into account all major distinctive features of the interphase heat and mass exchange inside porous grains and at their surface (see points 1 to 4 below) for P (“pore”) and S (“solid”) models of mass transfer within porous grains of the adsorbent, have been obtained.
First for isothermal and non-isothermal kinetics in the mixed kinetics region of mass and heat exchange in the absence natural mutual diffusion and natural thermal-diffusion the essential influence effective mutual diffusion and effective thermal-diffusion is shown.
Recommendations on the use of model equations of adsorption kinetics for describing isothermal and non-isothermal adsorption dynamics of multicomponent mixtures in the inner-diffusion and mixed (outer- and inner-diffusion) kinetic region of heat and mass exchange are made. 相似文献
First for isothermal and non-isothermal kinetics in the mixed kinetics region of mass and heat exchange in the absence natural mutual diffusion and natural thermal-diffusion the essential influence effective mutual diffusion and effective thermal-diffusion is shown.
Recommendations on the use of model equations of adsorption kinetics for describing isothermal and non-isothermal adsorption dynamics of multicomponent mixtures in the inner-diffusion and mixed (outer- and inner-diffusion) kinetic region of heat and mass exchange are made. 相似文献