Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation)

The effects of biodiesel (rapeseed methyl ester, RME) and different diesel/RME blends on the diesel engine NO_x emissions, smoke, fuel consumption, engine efficiency, cylinder pressure and net heat release rate are analysed and presented. The combustion of RME as pure fuel or blended with diesel in an unmodified engine results in advanced combustion, reduced ignition delay and increased heat release rate in the initial uncontrolled premixed combustion phase. The increased in-cylinder pressure and temperature lead to increased NO_x emissions while the more advanced combustion assists in the reduction of smoke compared to pure diesel combustion. The lower calorific value of RME results in increased fuel consumption but the engine thermal efficiency is not affected significantly. When similar percentages (% by volume) of exhaust gas recirculation (EGR) are used in the cases of diesel and RME, NO_x emissions are reduced to similar values, but the smoke emissions are significantly lower in the case of RME. The retardation of the injection timing in the case of pure RME and 50/50 (by volume) blend with diesel results in further reduction of NO_x at a cost of small increases of smoke and fuel consumption.     

Effects of Fischer-Tropsch diesel fuel on combustion and emissions of direct injection diesel engine

Effects of Fischer-Tropsch (F-T) diesel fuel on the combustion and emission characteristics of a single-cylinder direct injection diesel engine under different fuel delivery advance angles were investigated. The experimental results show that F-T diesel fuel exhibits shorter ignition delay, lower peak values of premixed burning rate, lower combustion pressure and pressure rise rate, and higher peak value of diffusion burning rate than conventional diesel fuel when the engine remains unmodified. In addition, the unmodified engine with F-T diesel fuel has lower brake specific fuel consumption and higher effective thermal efficiency, and presents lower HC, CO, NO _x and smoke emissions than conventional diesel fuel. When fuel delivery advance angle is retarded by 3 crank angle degrees, the combustion duration is obviously shortened; the peak values of premixed burning rate, the combustion pressure and pressure rise rate are further reduced; and the peak value of diffusion burning rate is further increased for F-T diesel fuel operation. Moreover, the retardation of fuel delivery advance angle results in a further significant reduction in NO _x emissions with no penalty on specific fuel consumption and with much less penalty on HC, CO and smoke emissions. __________ Translated from Chinese Internal Combustion Engine Engineering, 2007, 28(2): 19–23 [译自: 内燃机工程]     

Remarkable improvement of NOx–PM trade-off in a diesel engine by means of bioethanol and EGR

In order to realize a premixed compression ignition (PCI) engine, the effects of bioethanol–gas oil blends and exhaust gas recirculation (EGR) on PM–NO_x trade-off have been investigated focusing on ignition delay, premixed combustion, diffusion combustion, smoke, NO_x and thermal efficiency. The present experiment was done by increasing the ethanol blend ratio and ethanol and by increasing the EGR ratio in a single cylinder direct injection diesel engine. It is found that a remarkable improvement in PM–NO_x trade-off can be achieved by promoting the premixing based on the ethanol blend fuel having low evaporation temperature, large latent heat and low cetane number as well, in addition, based on a marked elongation of ignition delay due to the low cetane number fuel and the low oxygen intake charge. As a result, very low levels of NO_x and PM, which satisfies the 2009 emission standards imposed on heavy duty diesel engines in Japan, were achieved without deterioration of brake thermal efficiency in the PCI engine fuelled with the 50% ethanol blend diesel fuel and the high EGR ratio. It is noticed that smoke can be reduced even by increasing the EGR ratio under the highly premixed condition.     

Investigation on a diesel engine fueled with hydrogen-compressed natural gas and Kusum seed biodiesel: Performance,combustion, and emission approach

The objective of the present study is to evaluate the performance, combustion, and emission characteristics of a compression-ignition engine using hydrogen-compressed natural gas (HCNG)-enriched Kusum seed biodiesel blend (KSOBD20). The flow rate of HCNG was set at 5, 10, and 15 liters per minute (lpm), and the injection pressure was varied in the range of 180–240 bar. Brake thermal efficiency (BTE) and brake-specific fuel consumption (BSFC) were improved when HCNG was added to the KSOBD20. Combustion characteristics, namely, cylinder pressure (CP) and net heat release rate (NHRR), were also improved. Emissions of carbon monoxide (CO), hydrocarbons (HC), and smoke were also reduced, with the exception of nitrogen oxides (NO_x). The higher injection pressure (240 bar) had a positive effect on operating characteristics. At an injection pressure of 240 bar, for KSOB20 + 15 lpm HCNG, the highest BTE and the lowest BSFC were found to be 32.09% and 0.227 kg/kWh, respectively. Also, the CP and NHRR were 69.34 bar and 66.04 J/deg. CO, HC, and smoke levels were finally reduced to 0.013%, 47 ppm, and 9%, respectively, with increased NO_x levels of 1623 ppm. For optimum results in terms of engine characteristics, the fuel combination KSOBD20 + 15 lpm HCNG at fuel injection pressure 240 bar is recommended. Thus, HCNG-enriched KSOBD20 can be used as an alternative fuel in diesel engines without requiring any modifications to increase performance and reduce emissions.     

Emission and performance estimation in hydrogen injection strategies on diesel engines

Recently, the increasing demand for energy requires the use of alternative fuels, especially in fossil fueled power systems. As a promising alternative fuel for next-generation diesel engines that utilize fossil fuel, hydrogen fuel is one step ahead due to its positive properties. In this study, the effects of hydrogen on the performance of a diesel engine have been numerically investigated with respect to different injection ratios and timings. The numerical results of the study for 25% load conditions on a single-cylinder, four-stroke diesel engine have been validated against experimental data taken from literature and good agreement has been observed for pressure results. Emission parameters such as NO_x, CO and performance parameters such as cylinder temperature, pressure, power, thermal efficiency and IMEP are presented comparatively.The results of numerical analyses show that the maximum pressure, temperature and heat release rate are observed with injection ratio of H15 and early injection timing (20° CA BTDC). Besides that, engine power, thermal efficiency and IMEP are greatly improved with increasing injection ratio and early injection timing. Although combustion chamber performance parameters improve with rising the hydrogen injection ratio, higher NO_x emissions have also been detected as a negative side effect. Furthermore, while early injection timing increases diesel engine performance, it also causes an increase in NO_x emissions. Therefore, precise determination of injection timing together with the optimum amount of hydrogen has revealed that it brings crucial improvement in engine performance and emissions.     

Influence of advanced injection timing on the performance and emissions of CI engine fueled with ethanol‐blended diesel fuel

Ethanol has been considered as an alternative fuel for diesel engines. On the other hand, injection timing is a major parameter that sensitively affects the engine performance and emissions. Therefore, in this study, the influence of advanced injection timing on the engine performance and exhaust emissions of a single cylinder, naturally aspirated, four stroke, direct injection diesel engine has been experimentally investigated when using ethanol‐blended diesel fuel from 0 to 15% with an increment of 5%. The original injection timing of the engine is 27° crank angle (CA) before top dead center (BTDC). The tests were conducted at three different injection timings (27, 30 and 33° CA BTDC) for 30 Nm constant load at 1800 rpm. The experimental results showed that brake‐specific energy consumption (BSEC), brake‐specific fuel consumption (BSFC), NO_x and CO₂ emissions increased as brake‐thermal efficiency (BTE), smoke, CO and HC emissions decreased with increasing amount of ethanol in the fuel mixture. Comparing the results with those of original injection timing, NO_x emissions increased and smoke, HC and CO emissions decreased for all test fuels at the advanced injection timings. For BSEC, BSFC and BTE, advanced injection timings gave negative results for all test conditions. Copyright © 2008 John Wiley & Sons, Ltd.     

Effects of split injection proportion and the second injection timings on the combustion and emissions of a dual fuel SI engine with split hydrogen direct injection

In this paper, a new kind of injection mode, split hydrogen direct injection, was presented for a dual fuel SI engine. Six different first injection proportions (IP1) and five different second injection timings were applied at the condition of excess air ratio of 1, first injection timing of 300°CA BTDC, low speed, low load conditions and the Minimum spark advance for Best Torque (MBT) on a dual fuel SI engine with hydrogen direct injection (HDI) plus port fuel injection (PFI). The result showed that, split hydrogen direct injection can achieve a higher brake thermal efficiency and lower emissions compared with single HDI. In comparison with single HDI, the split hydrogen direct injection can form a controlled stratified condition of hydrogen which could make the combustion more complete and faster. By adding an early spray to form a more homogeneous mixture, the split hydrogen direct injection not only can help to form a flame kernel to make the combustion stable, but also can speed up the combustion rate through the whole combustion process, which can improve the brake thermal efficiency. By split hydrogen direct injection, the torque reaches the highest when the first injection proportion is 33%, which improves by 1.13% on average than that of single HDI. With the delay of second injection timing, the torque increases first and then decreases. With the increase of first injection proportion, the best second injection timing is advanced. Furthermore, by forming a more homogeneous mixture, the split hydrogen direct injection can reduce the quenching distance to reduce the HC emission and reduce the maximum temperature to reduce the NO_X. The split hydrogen direct injection can reduce the HC emission by 35.8%, the NO_X emissions by 7.3% than that of single HDI.     

Performance, emissions and heat release characteristics of direct injection diesel engine operating on diesel oil emulsion

Emulsions of diesel and water are often promoted as being able to overcome the difficulty of simultaneously reducing emissions of both oxidises of nitrogen (NO_x) and particulate matter from diesel engines. In this paper we present measurements of the performance and NO_x and hydrocarbon emissions of a diesel engine operating on a typical diesel oil emulsion and examine through the use of heat release analysis differences found during its combustion relative to standard diesel in the same engine. While producing similar or greater thermal efficiency and improved NO_x and hydrocarbon emission outcomes, use of the emulsion also results in an increase in brake specific fuel consumption. Use of the emulsion is also shown to result in a retarded fuel injection, but smaller ignition delay for the same engine timing. As a result of these changes, cylinder pressures and temperatures are lower.     

A nonlinear regression based multi-objective optimization of parameters based on experimental data from an IC engine fueled with biodiesel blends

This study reports the results of an experimental investigation of the performance of an IC engine fueled with a Karanja biodiesel blends, followed by multi-objective optimization with respect to engine emissions and fuel economy, in order to determine the optimum biodiesel blend and injection timings complying with Bharat Stage II emission norms. Nonlinear regression has been used to regress the experimentally obtained data to predict the brake thermal efficiency, NO_x, HC and smoke emissions based on injection timing, blend ratio and power output. To acquire the data, experimental studies have been conducted on a single cylinder, constant speed (1500 rpm), direct injection diesel engine under variable load conditions and injection timings for neat diesel and various Karanja biodiesel blends (5%, 10%, 15%, 20%, 50% and 100%). Retarding the injection timing for neat Karanja biodiesel resulted in an improved efficiency and lower HC emissions. A tradeoff relationship between the NO_x and smoke emissions is observed, which makes it difficult to determine the optimum blend ratio. The functional relationship developed between the correlating variables using nonlinear regression is able to predict the performance and emission characteristics with a correlation coefficient (R) in the range of 0.95-0.99 and very low root mean square errors. The outputs obtained using these functions are used to evaluate the multi-objective function of optimization process in the 0-20% blend range. The overall optimum is found to be 13% biodiesel-diesel blend with an injection timing of 24°bTDC, when equal weightage is given to emissions and efficiency.     

Study of methane enrichment in a biogas fuelled HCCI engine

Biogas has been a promising alternative fuel for IC engines. However, its CO₂ content reduces calorific value and ignitability. The CO₂ fraction of raw biogas can be separated out by various techniques, which are collectively called methane enrichment. The present study explores the effect of methane enrichment on the output parameters of a Homogeneous Charge Compression Ignition (HCCI) engine. A single cylinder CI engine is altered for this purpose. Biogas (CH₄ + CO₂) is supplied along with air. Diethyl Ether (DEE) is used as the secondary fuel to initiate auto-ignition. The effects of injecting DEE at the inlet port and upstream in the intake manifold are also compared. Performance, emission and combustion characteristics such as brake thermal efficiency, equivalence ratio, HC, CO, CO₂, NO_x and smoke emissions, start and duration of combustion, in-cylinder pressure and maximum heat release rate are compared for operation with raw biogas (50% methane) and methane enriched biogas (100% methane) for various biogas flow rates and engine torques. Results show that methane enrichment enhances brake thermal efficiency by up to 2% compared to raw biogas. Methane enrichment advances and speeds up combustion. HC, CO and CO₂ emissions, maximum cylinder pressure and maximum heat release rate are also improved with methane enrichment. Ultra-low NO_x and smoke emissions can be obtained using raw biogas as well as methane enriched biogas. Low biogas flow rates provide better brake thermal efficiency and HC emissions. Manifold injection of DEE enhances brake thermal efficiency by up to 2% compared to port injection by virtue of greater mixture homogeneity.     

Investigation on combustion and emission characteristics of hydrogen-enriched dual-fuel engine operated under waste frying oil biodiesel

Using nonedible waste frying oil (WFO) as biodiesel and hydrogen in the mix composition may partly replace significant quantities of diesel fuel and help reduce fossil fuel reliance. The combination of diesel fuel, waste-fired biodiesel, and hydrogen gas can improve the performance, combustion, and emissions of single-fuel and dual-fuel diesel engines. This may lead to a novel alternative fuel mix pattern and modification for diesel engines, which is the research gap. Although there has been some research on waste-fired biodiesel and hydrogen gas-powered dual-fuel engines with the goal of partly replacing fossil fuels to a larger degree, there has been very little progress in this area. As a result, the current research effort focuses on using diesel fuel (100%, 30%, and 60%), waste-fired biodiesel (at 100%, 70%, and 40%), and hydrogen gas as fuel sources (5 and 10 liters per minute [LPM]). According to the current experiment, it was perceived in both dual-fuel and single-fuel modes. Under duel-fuel mode, the engine results for WFOB70D30 + H10 fuel blend had higher 4.2% (brake thermal efficiency [BTE]), 19.72% (oxides of nitrogen [NO_x]), and 9.09% (ignition delay [ID]) with a minimal range of (in-cylinder pressure, MFB, volumetric efficiency and heat release rate [HRR]) and a dropped rate of 4.34% (brake-specific energy consumption [BSEC]), 33.33% (carbon monoxide [CO]), 39.28% (hydrocarbons [HC]), 9.43% (smoke), and 6.97% (combustion duration [CD]) related to diesel fuel at peak load. However, single-fuel powered diesel engines provide minimal performance for the WFOB40D60 fuel blend with (11.32% lower BTE and 2.04% higher BSEC) and minimal rate of combustion (lower cylinder pressure, 2.12% minimal CD, 14.72% higher ID, minimal HRR combustion, volumetric efficiency, and MFB). Emitted fewer emissions (9.09% less CO, 4.87% less HC, 0.92% higher NO_x, and 1.69% more smoke) than diesel fuel at peak load. Therefore, it was concluded that adding 10 LPM of hydrogen gas to the biodiesel under a dual-fuel condition leads to better combustion, better performance, and less pollution than the single-fuel mode of operation.     

Effects of variable O2 concentrations and injection pressures on the combustion and emissions characteristics of the petro-diesel and hydrotreated vegetable oil-based fuels under the simulated diesel engine condition

This experimental research investigates the effects of variable O₂ concentrations and injection pressures on the combustion and emissions characteristics of the diesel (B7) and the hydrotreated vegetable oil (HVO)-based fuels. The O₂ concentrations included 21%, 15% and 10% O₂, while the injection pressures were 80 and 120 MPa. The experimental fuels were the diesel fuel (B7), the neat HVO, the 20%, 50% and 80% HVO (by mass fraction) blended with the diesel. The experiments were carried out in a rapid compression-expansion machine (RCEM) under the direct injection (DI) diesel combustion condition. The analysis was undertaken using the two-color method. The experimental results indicated that the ignition delay, the heat release rate, the flame temperature, the soot density-KL factor, the NO_x and soot-out emissions were inversely correlated to the HVO fraction in the blend. In addition, the findings revealed the similar flame profiles in which the higher flame temperature region and the darker KL density were concentrated around the spray flame upstream, regardless of the HVO mixing ratio. Besides, the decrease in the O₂ concentration resulted in the lower heat release rate, integral heat release, flame temperature, KL factor and NO_x emissions but the longer ignition delay and higher soot concentration, with the highest soot concentration observed under the 15% O₂ environment. Nevertheless, the higher pressure differential (i.e. between the injection pressure and the ambient pressure) contributed to the shorter ignition delay, higher heat release rate, early peak of the flame temperature, wider combustion area, faster soot oxidation rate and higher NO_x production.     

预喷正时对柴油机燃烧与排放影响的试验研究

通过台架试验,分析对比柴油机各参数随预喷正时的变化,研究多次喷射预喷正时对柴油机燃烧和排放性能的影响。试验表明,预喷正时决定缸内燃烧的放热始点和放热率,影响缸内的燃烧温度、爆发压力、NOx排放和碳烟的生成,预喷正时为20°时,爆发压力最大;预喷正时为35°时,热效率最高,油耗率和烟度最低;预喷正时为45°时,NOx排放最小。综合分析选择预喷正时40°作为折中优化方案,降低发动机油耗和NOx、碳烟排放,同时提高发动机的热效率。     

Characteristics and energy distribution of modulated multi-pulse injection modes based diesel HCCI combustion and their effects on engine thermal efficiency and emissions

Cycle fuel energy distribution and combustion characteristics of early in-cylinder diesel homogenous charge compression ignition (HCCI) combustion organized by modulated multi-pulse injection modes are studied by the engine test. It is found that heat loss due to unburned fuel droplets and CO emission can be decreased effectively by injection mode regulation, and thermal efficiency can be potentially increased by 4%–12%. From the analyses of combustion process, it is also found that diesel HCCI combustion is a process with a finite reaction rate and is very sensitive to injection timing and injection mode. At injection timing of −90°CA ATDC, extra low NO_x emissions can be obtained along with high thermal efficiency. __________ Translated from Transactions of CSICE, 2006, 24(6): 385–393 [译自: 内燃机学报]     

Experimental study of combustion and emission characteristics of ethanol fuelled port injected homogeneous charge compression ignition (HCCI) combustion engine

The homogeneous charge compression ignition (HCCI) is an alternative combustion concept for in reciprocating engines. The HCCI combustion engine offers significant benefits in terms of its high efficiency and ultra low emissions. In this investigation, port injection technique is used for preparing homogeneous charge. The combustion and emission characteristics of a HCCI engine fuelled with ethanol were investigated on a modified two-cylinder, four-stroke engine. The experiment is conducted with varying intake air temperature (120–150 °C) and at different air–fuel ratios, for which stable HCCI combustion is achieved. In-cylinder pressure, heat release analysis and exhaust emission measurements were employed for combustion diagnostics. In this study, effect of intake air temperature on combustion parameters, thermal efficiency, combustion efficiency and emissions in HCCI combustion engine is analyzed and discussed in detail. The experimental results indicate that the air–fuel ratio and intake air temperature have significant effect on the maximum in-cylinder pressure and its position, gas exchange efficiency, thermal efficiency, combustion efficiency, maximum rate of pressure rise and the heat release rate. Results show that for all stable operation points, NO_x emissions are lower than 10 ppm however HC and CO emissions are higher.     

A study on the performance and emission of a diesel engine fueled with Jatropha biodiesel oil and its blends

Biodiesel either in neat form or as a mixture with diesel fuel is widely investigated to solve the twin problem of depletion of fossil fuels and environmental degradation. The main objective of the present study is to compare performance, emission and combustion characteristics of biodiesel derived from non edible Jatropha oil in a dual fuel diesel engine with base line results of diesel fuel. The performance parameters evaluated were: brake thermal efficiency, brake specific fuel consumption, power output. As a part of combustion study, in-cylinder pressure, rate of pressure rise and heat release rates were evaluated. The emission parameters such as carbon monoxide, carbon dioxide, un-burnt hydrocarbon, oxides of nitrogen and smoke opacity with the different fuels were also measured and compared with base line results. The different properties of Jatropha oil after transestrification were within acceptable limits of standards as set by many countries. The brake thermal efficiency of Jatropha methyl ester and its blends with diesel were lower than diesel and brake specific energy consumption was found to be higher. However, HC, CO and CO₂ and smoke were found to be lower with Jatropha biodiesel fuel. NO_x emissions on Jatropha biodiesel and its blend were higher than Diesel. The results from the experiments suggest that biodiesel derived from non edible oil like Jatropha could be a good substitute to diesel fuel in diesel engine in the near future as far as decentralized energy production is concerned. In view of comparable engine performance and reduction in most of the engine emissions, it can be concluded and biodiesel derived from Jatropha and its blends could be used in a conventional diesel engine without any modification.     

Optimization of hydrogen-enriched diesel/n-Amyl alcohol-fueled engine to meet emission standards through varying nozzle opening pressure and static injection timing

Important injection parameters such as fuel injection timing (FIT) and fuel injection pressure (FIP) on different piston bowl geometries substantially impact the performance, emissions, and combustion characteristics of a common rail direct injection engine. The aim of this study deals with the effects of piston bowl geometry (hemispherical bowl [HSB], troded bowl [TRB], and re-entrant bowl [REB]), FIP (200, 220, and 240 bar), and variable FIT (20, 24, and 28°bTDC) with hydrogen-diesel/1-pentanol (B20) (80% diesel and 20% pentanol) with a constant flow rate of hydrogen at 12 Lpm. Furthermore, to decrease emission standards and energy consumption, biodiesel and hydrogen are the ideal substitutes for conventional fuels. REB outperforms HSB and TRB in terms of brake thermal efficiency (5.67%) and hydrocarbon (8% reduction), increasing the FIP at full load (240 bar). However, with the increase in the FIP in the REB, a slight reduction in nitrogen oxide (NO_x) emissions (2%) is observed. With an increase in FIP in the case of REB, net heat release rate, peak pressure (in-cylinder), and rate of pressure rise all rise significantly by 3.4%, 4.2%, and 2.3%. NO_x emissions are marginally enhanced with higher FIP and advanced FIT. It is found that changing the piston shape and FIP simultaneously is a potential alternative for improving engine performance and lowering emissions.     

An experimental investigation on DI diesel engine with hydrogen fuel

The internal combustion engines have already become an indispensable and integral part of our present day life style, particularly in the transportation and agricultural sectors [Nagalingam B. Properties of hydrogen. In: Proceedings of the summer school of hydrogen energy, IIT Madras, 1984]. Unfortunately the survival of these engines has, of late, been threatened due to the problems of fuel crisis and environmental pollution. Therefore, to sustain the present growth rate of civilization, a nondepletable, clean fuel must be expeditiously sought. Hydrogen exactly caters to the specified needs. Hydrogen, even though “renewable” and “clean burning”, does give rise to some undesirable combustion problems in an engine operation, such as backfire, pre-ignition, knocking and rapid rate of pressure rise [Srinivasa Rao P. Utilization of hydrogen in a dual fueled engine. In: Proceedings of the summer school of hydrogen energy, IIT Madras, 1984; Siebers DL. Hydrogen combustion under diesel engine conditions. Hydrogen Energy 1998;23:363–71]. The present investigation compares the performance and emission characteristics of a DI diesel engine with gaseous hydrogen as a fuel inducted by means of carburation technique and timed port injection technique (TPI) along with diesel as a source of ignition [Swain N, Design and testing of dedicated hydrogen-fueled engine. SAE 961077, 1996]. In the present study the specific energy consumption, NO_x emission and the exhaust gas temperature increased by 6%, 8% and 14%, respectively, and brake thermal efficiency and smoke level reduced by 5% and 8%, respectively, using carburation technique compared to baseline diesel. But in the TPI technique, the specific energy consumption, exhaust gas temperature and smoke level reduced by 15%, 45% and 18%, respectively. The brake thermal efficiency and NO_x increased by 17% and 34%, respectively, compared to baseline diesel. The emissions such as HC, CO, and CO₂ is very low in both carburation and TPI techniques compared baseline diesel.     

Direct injection of hydrogen main fuel and diesel pilot fuel in a retrofitted single-cylinder compression ignition engine

Up to 90% hydrogen energy fraction was achieved in a hydrogen diesel dual-fuel direct injection (H2DDI) light-duty single-cylinder compression ignition engine. An automotive-size inline single-cylinder diesel engine was modified to install an additional hydrogen direct injector. The engine was operated at a constant speed of 2000 revolutions per minute and fixed combustion phasing of ?10 crank angle degrees before top dead centre (°CA bTDC) while evaluating the power output, efficiency, combustion and engine-out emissions. A parametric study was conducted at an intermediate load with 20–90% hydrogen energy fraction and 180-0 °CA bTDC injection timing. High indicated mean effective pressure (IMEP) of up to 943 kPa and 57.2% indicated efficiency was achieved at 90% hydrogen energy fraction, at the expense of NO_x emissions. The hydrogen injection timing directly controls the mixture condition and combustion mode. Early hydrogen injection timings exhibited premixed combustion behaviour while late injection timings produced mixing-controlled combustion, with an intermediate point reached at 40 °CA bTDC hydrogen injection timing. At 90% hydrogen energy fraction, the earlier injection timing leads to higher IMEP/efficiency but the NO_x increase is inevitable due to enhanced premixed combustion. To keep the NO_x increase minimal and achieve the same combustion phasing of a diesel baseline, the 40 °CA bTDC hydrogen injection timing shows the best performance at which 85.9% CO₂ reduction and 13.3% IMEP/efficiency increase are achieved.