共查询到19条相似文献,搜索用时 93 毫秒
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研究了四氮杂杯[2]芳烃[2]三嗪的合成及其叠氮化。以三聚氯氰和间苯二胺(摩尔比>2∶1)为原料,碳酸钾为缚酸剂,四氢呋喃为溶剂,在冰浴条件下合成中间体N,N’-二(4,6-二氯-1,3,5-均三嗪-2-基)-1,3-苯二胺,产率为85.8%;该中间体和间苯二胺(摩尔比为1∶1)丙酮为溶剂,在室温条件下反应,生成四氮杂杯[2]芳烃[2]三嗪,产率为45.5%;四氮杂杯[2]芳烃[2]三嗪和叠氮钠在40~50℃条件下反应生成四氮杂杯[2]-1,5-芳烃[2]-2-叠氮基-1,3,5-三嗪产率为90.0%。产物通过元素分析、红外光谱和氢谱的表征,其结构得到了确定。 相似文献
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综述了近20年来典型的DNA-分子光开关钌(Ⅱ)多吡啶类配合物[Ru(phen)2(dppz)]2+在实验和理论上的研究进展与应用.阐明了该配合物的结构特征及其与DNA的作用机理、作用模式以及在一些相关热点问题上的争议,同时还介绍了该配合物在DNA-结构识别及定量分析等方面的重要应用.基于此,还对DNA-分子光开关钌配合物的开发作了展望. 相似文献
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阴极射线显示器用蓝粉一直是限制彩色显示器发光效率和亮度的重要因素之一,这一问题也 同样存在于FED显示器件中。本文报导了最新研制的一种新型蓝色荧光粉Sr_5(PO_4)_3Cl: EU~(2+), 具有发光亮度较高,色纯度好,对阴极不易产生污染的特点。 相似文献
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报道了一种新型尾式卟啉化合物5-(4-叔丁氧基苯基)-10、15、20-三苯基卟啉[H2(t-BuPTPP)]及其Ni(bpy)^2 配合物的合成,并通过元素分析、红外光谱、核磁共振氢谱及紫外可见光谱等对其结构进行了表征。 相似文献
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运用TDDFT方法,分子光开关钌配合物[Ru(phen)2(phehat)]^2+的UV—Vis光谱得以计算和理论解释。计算表明在水溶液环境下对钌配合物进行计算,实验结果和计算结果一致。而且,溶液条件下计算的UV-Vis光谱的结果能较好的指认该配合物实验光谱的^1MLCT和^1LLCT性质。 相似文献
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Xue-Wen Liu Ji-Ling Lu Yuan-Dao Chen Lin Li Da-Shun Zhang 《Inorganic chemistry communications》2010,13(3):449-451
A novel ruthenium(II) complex, [Ru(bpy)2pzip]2+ has been synthesized and characterized. The DNA-binding properties of this complex have been studied by spectroscopic and viscosity measurements. The results indicated that the complex [Ru(bpy)2pzip]2+ bound to double-stranded DNA in an intercalation mode. In the presence of Co2+, the emission of DNA–[Ru(bpy)2pzip]2+ can be quenched. And when EDTA was added, the emission was recovered. The experiment results show that [Ru(bpy)2pzip]2+ exhibited the “on–off–on” properties of molecular “light switch”. 相似文献
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《Inorganic chemistry communications》2003,6(6):773-775
A novel dinuclear ruthenium(II) complex [(bpy)2Ru(bdptb)Ru(bpy)2]4+ (bpy=2,2′-bipyridyl; bdptb=2,2′-bis(5,6-diphenyl-1,2,4-triazin-3-yl)-4,4′-bipyridine) has been synthesized and characterized. The DNA-binding behaviors of this complex have been studied by viscosity, absorption and circular dichroism (CD) spectra. It has firstly been found that the dinuclear ruthenium(II) complex display the enantiopreferential DNA-binding after equilibrium dialysis. 相似文献
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采用溶剂热法,用4-羧基吡啶和醋酸镍,合成了一个新的化合物[Ni(C6H4O2N)2(H2O)2],配合物中HC6H4O2N为4-羧基吡啶,并通过单晶体衍射测定了其结构.结构测定表明,该标题配合物属三斜晶系,空间群Pī,晶胞参数为a=6.3070(10)A.,b=6.9310(11)A.,c=9.2770(14)A.;α=96.313(2)°,β=105.189(2)°,γ=113.359(3)°,V=348.67(9)A.3,Z=1,Dc=1.786 g·cm-3,F(000)=194,μ=1.439 mm-1,λ(MoKα)=0.71073A.,Mr=374.98. 最终偏差因子(对I>2σ(I)的衍射点)R1=0.0783,ωR2=0.2055,对全部衍射点R1=0.0819,ωR2=0.2104,ω-1=[s2(F0)2+(0.1832P)2+ 0.0000P],P=(F02+2Fc2)/3.配合物分子中,中心离子Ni(Ⅱ) 采用六配位,6个配原子中,4个氧原子分别来自4个配位水,2个氮分别来自2个4-羧基吡啶,形成一个稍变形的具有对称中心的八面体结构.邻近配合物分子间通过4-羧基吡啶和配位水之间大量的氢键堆积成无限三维网状结构. 相似文献
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A novel technique for controllable assembly of [Ru(bpy)2ITATP]3+/2+ (where bpy = 2,2′-bipyridine, ITATP = isatino[1,2-b]-1,4,8,9-tetraazatriphenylene) on an ITO electrode in the absence and presence of calf thymus DNA is proposed. The [Ru(bpy)2ITATP]3+/2+ and double stranded DNA is assembled onto the ITO electrode using repetitive voltammetric sweeping. The assembly is confirmed by ex situ cyclic voltammetry and the fluorescence microscopy. A pair of diffusion-controlled waves and prewaves for [Ru(bpy)2ITATP]3+/2+ is observed in the voltammetric sweeping process. The formal potential of the prewaves is found to be much negative than that of the diffusion-controlled waves. The controllable assembly of [Ru(bpy)2ITATP]3+/2+ on the ITO surface is accelerated by DNA and affected by ionic strength. With this DNA-prompted electrochemical technique, a multifunctional biomolecular film containing surface-confined redox center of controllable thickness is fabricated. 相似文献
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以2-氨皋嘧啶缩水杨醛席夫碱和硝酸铜为原料,在常温下,用甲醇和水为溶剂合成了配合物[Cu(2,Ap)2(NO3)2](2-Ap=2,氨基嘧啶)。通过红外光潜、元素分析、X-射线单品衍射对它进行了结构解析和表征,并系统研究了配合物的结构特点。 相似文献
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A series of five ruthenium(II) polypyridyl complexes [Ru(bpy)2(N--N)]Cl2 was tested against human HT-29 and MCF-7 cancer cell lines. Cellular uptake efficiency and cytotoxicity were found to increase with the size of the aromatic surface area of the N--N ligand. The most active compound carrying the dppn ligand exhibits a low micromolar IC(50) value against both cell lines comparable to that of cisplatin under similar conditions. Continuous measurement of oxygen consumption, extracellular acidification rate, and impedance of the cell layer with a chip-based sensor system upon exposure to the complexes showed only small changes for the first two parameters throughout the series. A significant and irreversible decrease in impedance was, however, found for the dppn compound. This suggests that its biological activity is related to modifications in cell morphology or cell-cell and cell-matrix contacts. 相似文献