Carrier Transportation Mechanism of the $hbox{TaN}/ hbox{HfO}_{2}/hbox{IL}/hbox{Si}$ Structure With Silicon Surface Fluorine Implantation

In this paper, the current transportation mechanism of HfO₂ gate dielectrics with a TaN metal gate and silicon surface fluorine implantation is investigated. Based on the experimental results of the temperature dependence of gate leakage current and Fowler-Nordheim tunneling characteristics at 77 K, we have extracted the current transport mechanisms and energy band diagrams for TaN/HfO₂/IL/Si structures with fluorine incorporation, respectively. In particular, we have obtained the following physical quantities: 1) fluorinated and as-deposited interfacial layer (IL)/Si barrier heights (or conduction band offsets) at 3.2 and 2.7 eV; 2) TaN/fluorinated and as-deposited HfO₂ barrier heights at 2.6 and 1.9 eV; and 3) effective trapping levels at 1.25 eV (under both gate and substrate injections) below the HfOF conduction band and at 1.04 eV (under gate injection) and 1.11 eV (under substrate injection) below the HfO₂ conduction band, which contributes to Frenkel-Poole conduction.     

A dynamic threshold voltage MOSFET (DTMOS) for very low voltageoperation

A new mode of operation for Silicon-On-Insulator (SOI) MOSFET is experimentally investigated. This mode gives rise to a Dynamic Threshold voltage MOSFET (DTMOS). DTMOS threshold voltage drops as gate voltage is raised, resulting in a much higher current drive than regular MOSFET at low V_dd. On the other hand, V_t is high at V_gs =0, thus the leakage current is low. Suitability of this device for ultra low voltage operation is demonstrated by ring oscillator performance down to V_dd=0.5 V     

A study on the physical mechanism in the recovery of gatecapacitance to Cox in implanted polysilicon MOSstructures

The anomalous CV characteristics of MOS capacitor structures with implanted n⁺ polysilicon gate and p-type silicon substrate are studied through physical device simulation and experimental characterization over a wide range of frequencies and temperatures ranging from 100 to 250 K. It is shown that this anomalous CV behavior can be fully explained by the depletion of electrons and the formation of a hole inversion layer in the polysilicon gate due to energy band bending. The use of transistor structures for characterizing the polysilicon gate electrode is proposed. The results suggest thermal generation rather than impact ionization to be the dominant physical mechanism in supplying holes required by the inversion layer at the polysilicon-SiO₂ interface. This result also implies that hot-hole injection from the polysilicon gate into the SiO ₂ gate dielectric should not present a serious problem in device reliability     

Fully depleted CMOS/SOI device design guidelines for low-powerapplications

We report the fully depleted (FD) CMOS/SOI device design guidelines for low-power applications. Optimal technology, device and circuit parameters are derived and compared with bulk CMOS based design. The differences and similarities are summarized. Device design guidelines using devices with L=0.1 μm for FDSOI low-power applications are presented using an empirical drain saturation current model fitted to experimental data. The model is verified in the deep-submicron regime by two-dimensional (2-D) simulation. For L=0.1 μm FDSOI low-power technology, optimum speed and lower-power occurs at V_dd=3V_th and V_dd=1.5 V_th, respectively. Optimum buried oxide thickness is found to be between 300 and 400 nm for low-power applications. Optimum transistor sizing is when the driver device capacitance is 0.3 times the total load capacitance. Similarly optimum gate oxide thickness is when the driver device gate capacitance is 0.2-0.6 times the total load capacitance for performance and 0.1-0.2 for low-power, respectively. Finally optimum stage ratio for driving large loads is around 2-4 for both high-performance and low-power     

Gate current and oxide reliability in p+ poly MOScapacitors with poly-Si and poly-Ge0.3Si0.7 gatematerial

Fowler-Nordheim (FN) tunnel current and oxide reliability of PRiLOS capacitors with a p⁺ polycrystalline silicon (poly-Si) and polycrystalline germanium-silicon (poly-Ge_0.3Si_0.7 ) gate on 5.6-nm thick gate oxides have been compared. It is shown that the FN current depends on the gate material and the bias polarity. The tunneling barrier heights, φ_B, have been determined from FN-plots. The larger barrier height for negative bias, compared to positive bias, suggests that electron injection takes place from the valence band of the gate. This barrier height for the GeSi gate is 0.4 eV lower than for the Si gate due to the higher valence band edge position. Charge-to-breakdown (Q_bd) measurements show improved oxide reliability of the GeSi gate on of PMOS capacitors with 5.6 nm thick gate oxide. We confirm that workfunction engineering in deep submicron MOS technologies using poly-GeSi gates is possible without limiting effects of the gate currents and oxide reliability     

Dynamic threshold-voltage MOSFET (DTMOS) for ultra-low voltage VLSI

In this paper, we propose a novel operation of a MOSFET that is suitable for ultra-low voltage (0.6 V and below) VLSI circuits. Experimental demonstration was carried out in a Silicon-On-Insulator (SOI) technology. In this device, the threshold voltage of the device is a function of its gate voltage, i.e., as the gate voltage increases the threshold voltage (V_t) drops resulting in a much higher current drive than standard MOSFET for low-power supply voltages. On the other hand, V_t is high at V_gs=0, therefore the leakage current is low. We provide extensive experimental results and two-dimensional (2-D) device and mixed-mode simulations to analyze this device and compare its performance with a standard MOSFET. These results verify excellent inverter dc characteristics down to V_dd=0.2 V, and good ring oscillator performance down to 0.3 V for Dynamic Threshold-Voltage MOSFET (DTMOS)     

Characteristics of Self-Aligned Gate-First Ge p- and n-Channel MOSFETs Using CVD HfO2 Gate Dielectric and Si Surface Passivation

The electrical properties of p- and n-MOS devices fabricated on germanium with metal-organic chemical-vapor-deposition HfO₂ as gate dielectric and silicon passivation (SP) as surface treatment are extensively investigated. Surface treatment prior to high-K deposition is critical to achieve small gate leakage currents as well as small equivalent oxide thicknesses. The SP provides improved interface quality compared to the treatment of surface nitridation, particularly for the gate stacks on p-type substrate. Both Ge p- and n-MOSFETs with HfO₂ gate dielectrics are demonstrated with SP. The measured hole mobility is 82% higher than that of the universal SiO₂/Si system at high electric field (~0.6 MV/cm), and about 61% improvement in peak electron mobility of Ge n-channel MOSFET over the CVD HfO₂ /Si system was achieved. Finally, bias temperature-instability (BTI) degradation of Ge MOSFETs is characterized in comparison with the silicon control devices. Less negative BTI degradation is observed in the Ge SP p-MOSFET than the silicon control devices due to the larger valence-band offset, while larger positive BTI degradation in the Ge SP n-MOSFET than the silicon control is characterized probably due to the low-processing temperature during the device fabrication     

Power Optimization for SRAM and Its Scaling

With technology scaling, there is a strong demand for smaller cell size, higher speed, and lower power in SRAMs. In addition, there are severe constraints for reliable read-and-write operations in the presence of increasing random variations that significantly degrade the noise margin. To understand these tradeoffs clearly and find a power-delay optimal solution for scaled SRAM, sequential quadratic programming is applied for optimizing 6-T SRAM for the first time. The use of analytical device models for transistor currents and formulate all the cell-operation requirements as constraints in an optimization problem. Our results suggest that, for optimal SRAM cell design, neither the supply voltage (V_dd) nor the gate length (L_g) scales, due to the need for an adequate noise margin amid leakage and threshold variability and relatively low dynamic activity of SRAM. This is true even with technology scaling. The cell area continues to scale despite the nonscaling gate length (L_g) with only a 7% area overhead at the 22-nm technology node as compared to simple scaling, at which point a 3-D structure is needed to continue the area-scaling trend. The suppression of gate leakage helps to reduce the power in ultralow-power SRAM, where subthreshold leakage is minimized at the cost of increase in cell area     

Simulation of a high performance MOSFET with a quantum wirestructure incorporating a periodically bent Si-SiO2 interface

A MOSFET using a serrated quantum wire structure that produces one-dimensional electron confinement shows excellent subthreshold characteristics and enhanced drive capability compared to a conventional MOSFET with a flat Si-SiO₂ interface. We studied the quantum wire structure with its periodically bent Si-SiO₂ interface using simulations. The potential in the convex regions of the silicon is 0.34 V higher than that in the concave ones when the bending angle is 90°, the bending period is 100 nm, substrate doping is 3.0×10 ¹⁷ cm^-3, and a gate voltage is 0.1 V. Because of this increase in potential in the convex regions, electrons are confined in a narrow width of 13 nm in the convex regions. This 1-D electron confinement effect by the bent Si-SiO₂ interface is clearly observed at low gate voltage and is reduced as the gate voltage becomes higher. Due to the confinement effect, drain current in the MOSFET with this quantum wire structure is 270 times higher than that of a MOSFET with a flat Si-SiO₂ interface at a gate voltage of 0.05 V. In addition, the short-channel effect is more effectively suppressed in this MOSFET than in a conventional MOSFET     

Quantization effects in inversion layers of PMOSFETs on Si (100)substrates

The 2-D hole gas distributions within inversion layers of PMOSFETs have been evaluated by solving the coupled Schrodinger equation and Poisson equation self-consistently based on the effective mass approximation with the light hole and heavy hole subbands taken into account. The threshold voltage shift resulting from the carrier redistribution due to quantization effects is found to be more significant for PMOSFETs than NMOSFETs on (110) Si substrates. For a certain substrate doping concentration the threshold voltage shift from the classical value due to quantization effects is found to be a combination of substrate band bending and oxide potential differences between the classical and the quantum mechanical models     

Polarity dependent gate tunneling currents in dual-gate CMOSFETs

Polarity dependence of the gate tunneling current in dual-gate CMOSFETs is studied over a gate oxide range of 2-6 nm. It is shown that, when measured in accumulation, the I_g versus V_g characteristics for the p⁺/pMOSFET are essentially identical to those for the n⁺/nMOSFET; however, when measured in inversion, the p⁺/pMOSFET exhibits much lower gate current for the same |V_g|. This polarity dependence is explained by the difference in the supply of the tunneling electrons. The carrier transport processes in p⁺/pMOSFET biased in inversion are discussed in detail. Three tunneling processes are considered: (1) valence band hole tunneling from the Si substrate; (2) valence band electron tunneling from the p⁺-polysilicon gate; and (3) conduction band electron tunneling from the p⁺-polysilicon gate. The results indicate that all three contribute to the gate tunneling current in an inverted p⁺/pMOSFET, with one of them dominating in a certain voltage range     

On the gate capacitance limits of nanoscale DG and FD SOI MOSFETs

An analytical total gate capacitance C/sub G/ model for symmetric double-gate (DG) and fully depleted silicon-on-insulator (FD/SOI) MOSFETs of arbitrary Si film is developed and demonstrated. The model accounts for the effects of carrier-energy quantization and inversion-layer screening and is verified via self-consistent numerical solutions of the Poisson and Schro/spl uml/dinger equations. Results provide good physical insight regarding C/sub G/ degradation due to quantization and screening governed by device structure and/or transverse electric field for nanoscale DG and FD/SOI MOSFETs. Two limits of C/sub G/ at ON-state are then derived when the silicon film t/sub Si/ approaches zero and infinity. The effect of inversion-layer screening on C/sub G/, which is significant for ultrathin Si-film DG MOSFETs, is quantitatively defined for the first time. The insightful results show that the two-dimensional screening length for DG MOSFETs is independent of the doping density and much shorter than the bulk Debye length as a result of strong structural confinement.     

Characterization and profile optimization of SiGe pFETs onsilicon-on-sapphire

We present the details of the fabrication, electrical characterization, and profile optimization of a SiGe pFET on silicon-on-sapphire (SOS) technology. The results show that the SiGe pFETs have higher low-field mobility (μ_eff), transconductance (g_m), and cutoff frequency (f_T) than a comparable Si pFET. At low temperature (85 K), a secondary peak is observed in the linear g_m of the SiGe pFETs and is attributed to hole confinement in the SiGe channel. The effect of reducing the SOS film thickness on the mobility and short-channel performance is studied. A low-frequency noise study shows significant improvement in the SiGe pPETs over comparable Si pFETs, and is attributed to a lower sampling of interface trap density caused by the band offset at the oxide interface due to SiGe. Drain Induced Back Channel Inversion (DIBCI) is shown to occur in short gate length devices, resulting in high off-state leakage current through conduction at the back silicon-sapphire interface. The paper also discusses important optimization issues in the design of 0.25-μm gate length SiGe pFETs. A novel structure is proposed which optimizes the threshold voltage, maximizes hole confinement gate voltage range and cutoff frequency, while at the same time minimizing DIBCI to make the design usable to gate lengths as short as 0.25 μm     

Characterization of soft breakdown in thin oxide NMOSFETs based onthe analysis of the substrate current

We have investigated the properties of soft breakdown (SBO) in thin oxide (4.5 nm) nMOSFETs with measurements of the gate and substrate leakage currents using the carrier separation technique. We have observed that, at lower gate voltages, the level of the substrate current exhibits a plateau. We propose that the observed plateau is due to the Shockley-Hall-Read (SHR) generation of hole-electron pairs in the space charge region and at the Si-SiO₂ interface. At higher voltages, the substrate current steeply increases with voltage, due to a tunneling mechanism, trap-assisted or due to a localized effective thinning of the oxide, from the substrate valence band to the gate conduction band, which becomes possible for gate voltages higher than the threshold voltage. The proposed interpretation Is consistent with the results of measurements performed at different operating conditions, in the presence of light and in the case of substrate reverse bias. The presented results are also useful for characterizing the performance of MOSFETs after SBD     

Vertical InAs Nanowire Wrap Gate Transistors on Si Substrates

We report on InAs enhancement-mode field-effect transistors integrated directly on Si substrates. The transistors consist of vertical InAs nanowires, grown on Si substrates without the use of metal seed particles, and they are processed with a 50-nm-long metal wrap gate and high-$kappa$ gate dielectric. Device characteristics showing enhancement-mode operation are reported. The output characteristics are asymmetric due to the band alignment and band bending at the InAs/Si interface. The implemented transistor geometry can therefore also serve as a test structure for investigating the InAs/Si heterointerface. From temperature-dependent measurements, we deduce an activation energy of about 200 meV for the InAs/Si conduction band offset.      

HfO2 Gate Dielectrics for Future Generation of CMOS Device Application

The material and electrical properties of HfO2 high-k gate dielectric are reported.In the first part,the band alignment of HfO2 and (HfO2)x(Al2O3)1-x to (100)Si substrate and their thermal stability are studied by X-ray photoelectron spectroscopy and TEM.The energy gap of (HfO2)x(Al2O3)1-x,the valence band offset,and the conduction band offset between (HfO2)x(Al2O3)1-x and the Si substrate as functions of x are obtained based on the XPS results.Our XPS results also demonstrate that both the thermal stability and the resistance to oxygen diffusion of HfO2 are improved by adding Al to form Hf aluminates.In the second part,a thermally stable and high quality HfN/HfO2 gate stack is reported.Negligible changes in equivalent oxide thickness (EOT),gate leakage,and work function (close to Si mid-gap) of HfN/HfO2 gate stack are demonstrated even after 1000℃ post-metal annealing(PMA),which is attributed to the superior oxygen diffusion barrier of HfN as well as the thermal stability of the HfN/HfO2 interface.Therefore,even without surface nitridation prior to HfO2 deposition,the EOT of HfN/HfO2 gate stack has been successfully scaled down to less than 1nm after 1000℃ PMA with excellent leakage and long-term reliability.The last part demonstrates a novel replacement gate process employing a HfN dummy gate and sub-1nm EOT HfO2 gate dielectric.The excellent thermal stability of the HfN/HfO2 gate stack enables its use in high temperature CMOS processes.The replacement of HfN with other metal gate materials with work functions adequate for n- and p-MOS is facilitated by a high etch selectivity of HfN with respect to HfO2,without any degradation to the EOT,gate leakage,or TDDB characteristics of HfO2.     

Effect of gate impurity concentration on inversion-layer mobility in MOSFETs with ultrathin gate oxide layer

In this paper, the influence of poly-Si-gate impurity concentration, N/sub poly/, on inversion-layer electron mobility is experimentally investigated in MOSFETs with ultrathin gate oxide layer. The split capacitance-voltage C-V method is modified to directly measure an effective mobility, paying attention to both 1) accurate current-voltage I-V and capacitance-voltage (C-V) measurements with high gate leakage current and 2) correct surface carrier density, N/sub s/, estimation at a finite drain bias. It is demonstrated that the mobility in ultrathin gate oxides becomes low significantly for highly doped gate, strongly suggesting the contribution of remote Coulomb scattering due to the gate impurities, which is quantitatively discriminated from that of Coulomb scattering due to substrate impurities and interface states. It is also found that the mobility lowering becomes significant rapidly at T/sub ox/ of 1.5 nm or less. The mobility-lowering component is weakly dependent on N/sub s/, irrespective of N/sub poly/, which cannot be fully explained by the existing theoretical models of remote impurity scattering.     

HfO2 Gate Dielectrics for Future Generation of CMOS Device Application

Introduction High- k gate dielectrics have been extensivelystudied as alternates to conventional gate oxide( Si O2 ) due to the aggressive downscaling of Si O2thickness in CMOS devices,and hence the exces-sive gate leakage.Hf O2 has emerged as one...