共查询到19条相似文献,搜索用时 109 毫秒
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综述了微波辐射下五种淀粉接枝共聚高吸水树脂的制备研究进展,包括淀粉接枝丙烯腈类高吸水树脂、淀粉接枝丙烯酸类高吸水树脂、淀粉接枝多元单体类高吸水树脂、淀粉系列互穿网络高吸水树脂、无机复合淀粉接枝高吸水树脂等;指出了微波辐射制备淀粉接枝共聚高吸水树脂的研究中,几个需要加强的研究方向:加强理论研究与实践研究的相互促进,开发新型无机矿物复合淀粉接枝共聚高吸水树脂等。 相似文献
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GG-g-PAA/SH高吸水性树脂的制备与缓释性能研究 总被引:2,自引:2,他引:0
以天然瓜尔胶(GG)、丙烯酸(AA)和腐植酸钠(SH)为原料,过硫酸铵为引发剂,N,N’-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合法制备了环境友好的多功能瓜尔胶接枝聚丙烯酸/腐植酸钠(GG-g—PAA/SH)高吸水性树脂。考察了腐植酸钠含量对树脂吸水性能的影响,评价了树脂在沙土中的实际保水性能、反复溶胀性能和腐植酸钠肥料缓释性能。结果表明,在体系中引入廉价的腐植酸钠,不但降低生产成本,还能提高树脂的吸水能力,当腐植酸钠含量为15wt%时,高吸水性树脂吸蒸馏水和生理盐水的倍率分别为532g/g和62g/g。在沙土中加入高吸水性树脂能显著提高其保水性能,30d后仍能保持13%的水分。此外,GG-g-PAA/SH高吸水性树脂还具有较优的反复溶胀性能和腐植酸钠肥料缓释功能,可用作兼具吸水、保水和缓释性能的新型节水材料。 相似文献
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Haiwang Wang Tianbo Zhao Xinfang Wei Huaihe Song Fengyan Li Xin Xu Jian Qi Ce Miao Shuai Zhang Man Zhang Qing Chen Yin Lin 《Carbon》2011,(2):357-363
An easy method is described for fabricating carbon sheets with nanostructures using sucrose as a carbon precursor and a layered superabsorbent polymer (LSAP) as a structure-directing agent. The method is based on the interaction of the three-dimensional polymer networks of the LSAP with a sucrose solution in the hydrogel cells. The synthesis scheme consists of: (a) preparation of the LSAP, (b) preparation of layered hydrogels by immersing the LSAP in the sucrose solution for 2 days, (c) carbonization of the layered hydrogels containing the sucrose solution. The synthesized carbon sheets show different microstructures including petal-like, regular and interleaved types, which can be controlled by simply adjusting the initial concentration of the sucrose solution in the hydrogel cells. Moreover, a formation mechanism for the carbon sheets is proposed. 相似文献
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实验采用乳液聚合法合成了一系列单体组成和吸水倍率不同的高吸水树脂。选取部分吸水树脂与苯乙烯、表面活性剂组成聚合体系,用过氧化苯甲酰引发进行原位共混聚合,制备了遇水崩解型聚苯乙烯。同时,考察了吸水树脂的种类、添加量、吸水倍率和聚苯乙烯的摩尔质量对材料崩解性的影响。研究发现:吸水树脂添加量越大,吸水倍率越高,聚苯乙烯摩尔质量越小,越有利于材料的崩解。当吸水树脂中含有强亲水性基团时,虽然其吸水倍率没有显著提高,但却能明显改善共混物的崩解性。 相似文献
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新型多功能腐植酸基农林保水生态治理剂 总被引:1,自引:0,他引:1
论述了新型多功能腐植酸基农林保水生态治理剂研制开发的意义,提出了保水剂在农林业应用中存在的问题及目前的研究方向,并介绍了新型多功能腐植酸基农林保水生态治理剂的特点、效果及项目实施的可行性。 相似文献
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Zhanxin Jing Guangcheng Zhang Xiao‐Feng Sun Xuetao Shi Weimin Sun 《Polymer Composites》2014,35(8):1516-1528
A novel superabsorbent was prepared by the copolymerization reaction between multiwalled carbon nanotubes (MWCNTs)–xylan composite and poly(methacrylic acid) (PMAA) in the presence of N,N′‐methylenebisacrylamide as cross‐linker and the redox initiation system (NH)4S2O8‐anhydrous Na2SO3 as initiator for adsorbing methylene blue (MB) from aqueous solution. First, covalent modification of MWCNTs with a natural polymer xylan was achieved by the nucleophilic substitution reaction. The obtained xylan modified MWCNTs–xylan composite was characterized by transmission electron microscope, Fourier transform infrared spectroscopy, X‐ray photoelectron spectrometer, and thermal gravimetric analysis. The results indicated that the hydroxyl groups of xylan participated in the formation of MWCNTs–xylan composite, and MWCNTs–xylan composite contained 32% xylan and about four molecule chains of xylan were grafted onto 5,000 carbon atoms of MWCNTs sidewalls. Subsequently, a novel superabsorbent based on MWCNTs–xylan composite and PMAA was prepared and characterized by Fourier transform infrared spectroscopy, scanning electron microscope, and swelling test. The results proved that superabsorbent was successfully prepared by copolymerization reaction and found that the superabsorbent evidently presented three‐dimensional network structure. Swelling process of superabsorbent complied with the Fick's law. Adsorption property of superabsorbent for MB was also systematically studied by investigating these parameters, such as superabsorbent dosage, initial MB concentration, contact time, ion strength, and pH. The superabsorbent presented a higher adsorption capacity and removal rate for MB. The adsorption data were fitted by Langmuir, Freundlich isotherm models, and four adsorption kinetic models. Freundlich isotherm model better fitted the equilibrium data than Langmuir, and adsorption kinetics could be well described by pseudo‐second‐order kinetic and intraparticle diffusion. These results indicated that the superabsorbent can be used as an efficient absorbent for removal of MB from aqueous solution. POLYM. COMPOS., 35:1516–1528, 2014. © 2013 Society of Plastics Engineers 相似文献
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环境矿物/高分子复合高吸水树脂的研究进展 总被引:1,自引:0,他引:1
从环境友好和可持续发展的角度出发,着眼于制备复合型综合性能优异的高吸水树脂,综述了几种环境矿物/高分子复合高吸水树脂的制备及性能等方面的最新进展。 相似文献