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常大山 《精细与专用化学品》2020,28(6):39-42
综述了国内外异丁烷脱氢制备异丁烯工艺的研究进展,包括FBD-4工艺、Oleflex工艺、Catofin工艺、Star工艺、Linde工艺和ADHO工艺等,提出了未来发展的建议。 相似文献
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采用严格模拟计算的方法,对液化天然气分离过程的现有常规蒸馏工艺与热耦蒸馏工艺、侧线提馏工艺、双效蒸馏工艺和热集成工艺进行了模拟,并比较了其能量消耗。模拟计算结果显示,复杂蒸馏工艺都比常规蒸馏工艺减少了能耗和操作成本。其中,热耦蒸馏工艺可比常规蒸馏工艺节能21.4%,侧线提馏工艺节约13.3%,双效蒸馏工艺可节约34.7%,热集成工艺节约则达37.6%左右,表明新工艺在此分离过程中都有较好的应用前景,尤以多效蒸馏和热耦蒸馏最有优势。 相似文献
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以新疆伊犁新天煤化工有限责任公司20亿m3/a煤制天然气项目净化工艺方案的选择为例,介绍了NHD工艺和低温甲醇洗工艺的技术特点;对比分析了低温甲醇洗工艺之鲁奇工艺、林德工艺和大连理工大学工艺的技术特点。结果表明:①大型煤化工项目净化工艺宜首选低温甲醇洗工艺;②从投资、能耗、环保等方面综合考虑,林德工艺在低温甲醇洗工艺中具有一定的优势。 相似文献
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介绍了Fenton氧化法的基本反应原理,综述了传统Fenton氧化工艺、微电解-Fenton氧化工艺、Fenton流化床氧化工艺、UV-Fenton氧化工艺、电Fenton氧化工艺的主要工艺形式及其在难降解工业废水中的应用,并总结各种Fenton氧化工艺的特点及工艺选择原则。 相似文献
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水源微污染问题日益加剧,加上常规工艺的局限性,迫使人们研究和开发新的净水工艺.组合工艺由于其突出的整体优势,备受青睐.该文重点介绍了一些典型的组合工艺在微污染水源水处理中的研究和应用,主要有:含活性炭的组合工艺、生化组合工艺、膜法组合工艺、臭氧氧化组合工艺、光催化组合工艺. 相似文献
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A model is developed for the sedimentation from a suspension of two particle species of unequal densities and of different sizes. The composition and the thickness of various layers in the sediments are predicted using graphical and analytical methods. The model predictions were in excellent agreement with experimental results, when the particle size ratio was ≥ 108. When size ratio of the particles was 2.60 and 4.31 the agreement occurred in about 50 percent of the cases. 相似文献
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P. P. Budnikoff 《Journal of the American Ceramic Society》1924,7(11):817-820
The different analytical methods proposed for the evaluation of gypsum have been subjected to an experimental test. A combination method, consisting of a fusion with KHCO3 and determination of CaO by KMnO4 titration, the SO3 by Andrews method of titration of BaCrO4 has been found to give very reliable results with the least consumption of time. 相似文献
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提出了有双官能团酸相对分子质量调节剂存在时己内酰胺水解聚合过程动力学模型 ,并进行了实验验证 .对不同温度下聚合产物组成和各影响因素对数均聚合度的影响进行了模拟 .结果表明 ,数均聚合度随进料中水、氨基己酸及相对分子质量调节剂浓度的增加而减小 ,其中水的浓度影响较显著 ,且在考察浓度范围内相对分子质量调节剂浓度 [R]0 ≤ 0 0 0 68mol·kg- 1 时数均聚合度基本不变 ,而 [R]0 >0 0 0 68mol·kg- 1 时数均聚合度则显著减小 .无氨基己酸及相对分子质量调节剂时数均聚合度亦随水浓度增加而减小 . 相似文献
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面对日益激烈的市场竞争,摩托车油箱外观质量越来越成为影响销售的因素之一。文章介绍了改进工艺后的油箱涂装,该涂装体系提高了油箱外观的丰满度,降低了油箱涂装的生产成本。 相似文献
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A novel technique serves to monitor instantaneous rates of loss of a volatile solute from a suspended drop during drying. A highly sensitive electron capture detector is used to monitor concentrations of SF6 released into a flowing gas stream from a suspended, drying drop. Simultaneously, the appearance and morphological development of the drop are monitored with a video camera. This provides the wherewithal of relating instantaneous rates of loss of the volatile solute to particular events during the development of particle morphology.
Initial experiments have been carried out with drops of aqueous solutions of glucose, sucrose, maltodextrin and coffee extract. The results clearly display the onset of the volatiles-retentive selective diffusion phenomenon. There is also substantial loss of the volatile component later in the drying process, when the drops undergo repeated ex ansion, bursting and cratering due to the formation of internaf bubbles. These experiments appear to be the first quantitative demonstration of major losses accompanying changes in drop morphology. 相似文献
Initial experiments have been carried out with drops of aqueous solutions of glucose, sucrose, maltodextrin and coffee extract. The results clearly display the onset of the volatiles-retentive selective diffusion phenomenon. There is also substantial loss of the volatile component later in the drying process, when the drops undergo repeated ex ansion, bursting and cratering due to the formation of internaf bubbles. These experiments appear to be the first quantitative demonstration of major losses accompanying changes in drop morphology. 相似文献
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直链烷烃氯磺酰化反应的光催化动力学研究 总被引:3,自引:1,他引:3
本系统采用氯气和二氧化硫作为气相原料,C18-17直链烷烃为液相原料,在光作用下进行气相氯磺酰化反应。由于该反应过程机理复杂,本研究采秀工程研究方法,对过程进行合理简化,导得该反应的动力学速率模型,并采用非线性多响应常微分模型的参数估计方法求得模型参数。模型计算值与实验结果能较好吻合,该模型可用于反应器的设计计算。 相似文献
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气化工艺特性对IGCC效率的影响 总被引:1,自引:1,他引:1
影响煤气化联合循环总效率的五个主要因素为煤转化率、燃气轮机循环,蒸汽循环,热旁路比率和发电效率。其中以煤转化率影响最大,它将包括产品气的显热和剩余蒸汽。在任何气化装置中气化炉是最主要单元并极大地影响气化性能。为改善气化效率,所有第二代气化方法均已引入加压操作。本文讨论了高温操作、生严能力放大、负荷跟踪能力、加煤方式、气化剂和煤气净化,同时提出仍待开发的某些值得注意的问题。 相似文献
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Experiments were carried out to find the effects of dissolved gas pressure,liquid flow rateand nozzle geometry on the bubble generation when saturated water was depressurized through anozzle.A new method,high speed camera system was developed to measure the generated microbubblesdynamically.On the basis of the laws of ideal gas and solution,theoretical generated gas flow ratewas deduced,while the Smoluchowski′s equation was applied to describe the kinetics of bubblenucleation.It was found that the size distribution of nucleated bubbles was of skewed distribution.An explanation to this phenomenon was made and the Gamma function distribution was employedfor mathematical simulation.The results show good agreement between the experimental data and thepredictions by proposed model. 相似文献
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硫酸钠盐结晶对混凝土破坏的影响 总被引:8,自引:2,他引:8
研究了Na2SO4盐结晶对干湿循环作用下混凝土剥蚀破坏、膨胀率和强度的影响,以及降温作用下Na2SO4溶液体积膨胀率和结晶压的变化.结果表明:Na2SO4盐结晶产生的混凝土膨胀和剥蚀破坏随着盐浓度和干湿循环次数的增加明显增大,且超过一定循环次数后,经干燥后的混凝土非但不收缩,反而继续膨胀.在降温作用下,Na2SO4溶液盐结晶体积膨胀率和结晶压随着盐浓度增加显著增大,且开始出现膨胀和结晶压的温度也提高,其产生的盐结晶压可超过7MPa,足以引起混凝土破坏. 相似文献
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An expression to predict the values of the latent heat of vaporization of pure compounds at their normal boiling point has been developed. A knowledge of the critical temperature, critical pressure, normal boiling point and acentric factor of the compound coupled with the use of generalized correlations for second virial coefficient and liquid molar volume allows to obtain good estimates, particularly for alcohols and ketones. Results for 71 various substances are compared with experimental values and with the results of eight other equations available in the literature. The possibility of using the calculated heats of vaporization at the normal boiling point to estimate values at other temperatures is discussed. 相似文献