共查询到20条相似文献，搜索用时 15 毫秒
1.
Pavel A. Levkin Frantisek Svec Jean M. J. Fréchet 《Advanced functional materials》2009,19(12):1993-1998
Here, a facile and inexpensive approach to superhydrophobic polymer coatings is presented. The method involves the in situ polymerization of common monomers in the presence of a porogenic solvent to afford superhydrophobic surfaces with the desired combination of micro‐ and nanoscale roughness. The method is applicable to a variety of substrates and is not limited to small areas or flat surfaces. The polymerized material can be ground into a superhydrophobic powder, which, once applied to a surface, renders it superhydrophobic. The morphology of the porous polymer structure can be efficiently controlled by composition of the polymerization mixture, while surface chemistry can be adjusted by photografting. Morphology control is used to reduce the globule size of the porous architecture from micro down to nanoscale thereby affording a transparent material. The influence of both surface chemistry as well as the length scale of surface roughness on the superhydrophobicity is discussed. 相似文献
2.
Hyeongjeong Kim Yunji Lee Sungjune Jung Hyomin Lee 《Advanced functional materials》2024,34(34):2470196
3.
Ziyi Dai Ge Chen Sen Ding Jing Lin Shunbo Li Yi Xu Bingpu Zhou 《Advanced functional materials》2021,31(7):2008574
Flexible superhydrophobic surfaces have recently attracted extensive interest not only in the field of burgeoning flexible electronics, but also for the practicability toward various situations. Herein, a cost-effective and environment-friendly approach is demonstrated to realize the durable, flexible, and superhydrophobic film with optical transparency. Without sophisticated facilities, the essential hierarchical architecture to render a low-adhesive surface is achieved via magnetic field-assisted polydimethylsiloxane microcilia, followed with the swelling process to decorate nanoscaled particles with excellent robustness. This tight connection between the microcilia and decorated nanoparticles renders the mechanical robustness with resistance to ultrasonic treatment, sandpaper abrasion, and high-speed water impact. The film further exhibits outstanding stabilities when exposed to organic contamination, hot water, and chemical corrosions. Water repellency is well preserved when the film is under various mechanical deformations including cyclic stretching, bending, and squeezing. For practical demonstrations, the film is applied as the protective film for touch screen owing to the intrinsic optical transmittance, or serves as the water-proof covers for sorts of complex/curved surfaces. These stated features reveal the convincing potential of the methodology to be applied for the circumstances where simultaneous addressing of robustness, flexibility, and adaptability is highly appreciated. 相似文献
4.
5.
Stefanie N. Guntari Aaron C. H. Khin Edgar H. H. Wong Tor K. Goh Anton Blencowe Frank Caruso Greg G. Qiao 《Advanced functional materials》2013,23(41):5159-5166
The continuous assembly of polymers (CAP) is used to fabricate tailored nanocoatings on a wide variety of substrates. Ring‐opening metathesis polymerization (ROMP) is used to mediate the CAP process (CAPROMP) to assemble specifically designed macromolecules into nanoengineered crosslinked films. Different films composed of single or multiple macromolecules are used to tune the surface wetting characteristics on various planar substrates, including porous substrates such as filter paper and cotton, and non‐porous subtrates such as aluminium foil and glass. By judicious selection of the macromolecules, these substrates, which are hydrophilic in nature, can be rendered (super)hydrophobic. The robustness of the ROMP catalysts and the reinitiation ability of the CAPROMP approach allow the production of layered multicomponent amphiphilic films with on‐demand switchable wettability. Such functional nanocoatings can be potentially applied as self‐cleaning surfaces, as waterproof woven fabrics, and for the next generation of microelectronic devices. 相似文献
6.
Michael Q. Hovish Florian Hilt Nicholas Rolston Qiran Xiao Reinhold H. Dauskardt 《Advanced functional materials》2019,29(19)
A method for the deposition and functionalization of a nanostructured organotitanate thin film, which imparts superhydrophilicity to a surface with a one‐step, open‐air process, is described. Extreme wetting (Θ < 5°) is achieved through synergistic contributions from both nanoscale roughness, visible light absorption caused by nonmetal dopants, and oxygen vacancies and surface activation by reactive plasma species. To test the efficacy of this material as an antifog coating, glass is coated and subjected to aggressive changes in humidity. Under both fogging and defrosting conditions, the superhydrophilic coating achieves a high degree of transparency, showing nearly two orders of magnitude improvement over the bare glass. The measured adhesion of the superhydrophilic coating is 5.9 J m?2, nearly double that of the solution‐processed control. The reliability of the coating is further validated by demonstrating scratch‐resistance. Additionally, the incorporation of organic matter into the molecular structure of the coating disrupts long‐range crystallinity from developing. This structural and subsequent chemical analysis of the coating reveals that inorganic and organic species are intimately connected at the nanoscale via alkyl and alkoxy bridges. The amorphous organotitanate material is distinct from conventional TiO2, which requires high temperature crystallization and extensive UV irradiation to display similar superhydrophilic qualities. 相似文献
7.
Zhongxue Tang Meijin He Ruixin Bian Zhongfeng Duan Kang Luan Jiexin Hou Binbin Hu Lei Jiang Huan Liu 《Advanced functional materials》2019,29(30)
Superwettable solid surfaces have attracted substantial research interest due to their outstanding performance. Various approaches have been developed for preparing superwettable surfaces via constructing a highly textured surface roughness and/or altering the surface free energy. Here, a facile dewetting strategy is proposed to produce multiple superwettabilities on copper hydroxide nanofiber arrays (Cu(OH)2‐NFAs) by controlling the localized state of low‐energy silicone oil. It is proposed that both the capillary forces along each nanofiber and the evaporation of the octane solvent contribute to the localization of the silicone oil in the NFAs. By varying the concentration of the silicone oil, its localized state changes from a scattered discontinuous distribution to a continuous thin/thick film, which leads to variations in the surface energy and surface roughness. Consequently, Cu(OH)2‐NFAs with superhydrophilicity, superhydrophobicity with both high and low adhesion, and super slippery properties are prepared. Notably, a very small amount of silicone oil can alter the surface wettability of the Cu(OH)2‐NFAs from superhydrophilic to superhydrophobic, which is attributable to the migration of silicone oil to the top of the nanofibers during the dewetting process. These results will provide new insights on the facile fabrication of functional surfaces with multiple superwettabilities. 相似文献
8.
Gang Wu Jinliang An Xiu‐Zhi Tang Yong Xiang Jinglei Yang 《Advanced functional materials》2014,24(43):6751-6761
Numerous microencapsulation techniques have been developed to encase various chemicals, for which specific processing parameters are required to address the widely differing features of the encapsulated materials. Microencapsulation of reactive agents is a powerful technique that has been extensively applied to self‐healing materials. However, the poor solvent compatibility and insufficient thermal stability of microcapsules continue to pose challenges for long‐term storage, processing, and service in practical applications. Here, an easily modifiable and highly versatile method is reported for preparing various chemicals filled poly(urea‐formaldehyde) microcapsules that exhibit superior tightness against solvents and heat and that possess widely tunable, repetitiously self‐restorable, and solvent‐proof superhydrophobicity. In addition, the low‐cost fabrication of biomimetic multifunctional smart coatings is demonstrated for self‐healing anticorrosion and self‐cleaning antifouling applications by directly dispersing the superhydrophobic microcapsules into and onto a polymer matrix. The methodology presented in this study should inspire the development of multifunctional intelligent materials for applications in related fields. 相似文献
9.
Biomimetics: A Versatile Approach towards Multifunctional Robust Microcapsules with Tunable,Restorable, and Solvent‐Proof Superhydrophobicity for Self‐Healing and Self‐Cleaning Coatings (Adv. Funct. Mater. 43/2014) 
下载免费PDF全文
下载免费PDF全文 Gang Wu Jinliang An Xiu‐Zhi Tang Yong Xiang Jinglei Yang 《Advanced functional materials》2014,24(43):6734-6734
10.
Yifan Si Chuxin Li Jinlian Hu Chengqi Zhang Zhichao Dong 《Advanced functional materials》2023,33(32):2301017
Microfluidics and bioinspired superwetting materials, as two crucial branches of scientific research, are entering their golden age of development. As an emerging interdisciplinary subject of these two fields, bioinspired superwetting open microfluidics is triggering technological revolutions in many disciplines, including rapid medical diagnosis, biochemical analysis, liquid manipulation, 3D printing, etc. However, this new research area has yet to attract extensive attention. So, a timely review is necessary to organize the development process, summarize current achievements, and discuss the challenges or chances for the ongoing scientific trend. In this review, the evolution from closed to open microfluidics is combed first. Then, three typical bioinspired superwetting systems are introduced emphatically. Based on this, the bioinspired superwetting open microfluidics is divided into different categories according to the bionic objects as the focus of this study. Taking natural phenomena as the entry point, the research from the underlying mechanism to the application is systematically discussed and summarized. Several emerging applications are also mentioned. Finally, some views on major problems, existing challenges, and developing trends are briefly put forward in this field to guide future research. 相似文献
11.
Weihao Pan Qiulin Wang Jun Ma Wen Xu Jing Sun Xin Liu Jinlong Song 《Advanced functional materials》2023,33(31):2302311
Many solar-power and wind-power devices in the world urgently demand self-cleaning and de-icing surfaces to ensure stable power generation. However, existing superhydrophobic surfaces and slippery liquid-infused porous surfaces with self-cleaning and de-icing functions are difficult to apply due to various defects. Herein, a novel solid-like slippery coating (SSC) is developed by constructing a smooth epoxy resin surface embedded with oil-stored silica nanoparticles. The SSC has excellent water-slippery capability to various water-based liquids with low to super-high viscosity, excellent durability and robustness, high hardness, strong adhesive strength to substrate, good optical transparency, and easy fabrication processes. This SSC also has remarkable non-sticking, self-cleaning, and de-icing performances, showing promising practical applications in solar and wind power. 相似文献
12.
Jinlong Song Fusheng Guan Weihao Pan Ziai Liu Jing Sun Siying Ling Xu Deng Yuwen Sun 《Advanced functional materials》2020,30(16)
Self‐propelled autonomous devices have huge application prospects in the field of environmental protection and energy. Nonetheless, the requirement of special chemicals or external electric and thermal energy limits their practical application. Here, a green self‐propelling method based on Laplace pressure originated from water droplets is reported. First, a triangle‐shaped miniboat composed of a superhydrophobic plate with an inclined superhydrophilic pore is fabricated. Water droplets put on superhydrophilic pore pass through the pore and form a jellyfish‐like jet, which further propels the miniboat to move spontaneously and directionally. The propelling distance, propelling time, and instantaneous propelling velocity of the miniboat is greatly affected by the pore size and the initial water droplet volume. Then, two types of devices are designed and installed on the miniboat to successively provide small water droplets from the reservoir or rain to realize the continuous and long‐distance self‐propelled motion. Moreover, a spindle‐shaped miniboat with two or four symmetrical and inclined pores is designed. Under propelling by the torque, the spontaneous and continuous rotation motion is also achieved. This finding will open a new avenue for a wide range of applications ranging from a detecting minirobot on the water surface to a power generation device from rain. 相似文献
13.
Maxime Paven Regina Fuchs Taro Yakabe Doris Vollmer Michael Kappl Akiko N. Itakura Hans‐Jürgen Butt 《Advanced functional materials》2016,26(27):4914-4922
Surfaces with self‐cleaning properties are desirable for many applications. Conceptually, super liquid‐repellent surfaces are required to be highly porous on the nano‐ or micrometer scale, which inherently makes them mechanically weak. Optimizing the balance of mechanical strength and liquid repellency is a core aspect toward applications. However, quantitative mechanical testing of porous, super liquid‐repellent surfaces is challenging due to their high surface roughness at different length scales and low stress tolerance. For this reason, mechanical testing is often performed qualitatively. Here, the mechanical responses of soot‐templated super liquid‐repellent surfaces are studied qualitatively by pencil and finger scratching and quantitatively by atomic force microscopy, colloidal probe force measurements, and nanoindentation. In particular, colloidal probe force measurements cover the relevant force and length scales. The effective elastic modulus, the plastic work Wplastic and the effective adhesive work Wadhesive are quantified. By combining quantitative information from force measurements with measurements of surface wetting properties, it is shown that mechanical strength can be balanced against low wettability by tuning the reaction parameters. 相似文献
14.
Chao Li Mathew Boban Sarah A. Snyder Sai P. R. Kobaku Gibum Kwon Geeta Mehta Anish Tuteja 《Advanced functional materials》2016,26(33):6121-6131
In this work, a facile methodology is discussed, involving fluoro‐silanization followed by oxygen plasma etching, for the fabrication of surfaces with extreme wettabilities, i.e., surfaces that display all four possible combinations of wettabilities with water and different oils: hydrophobic–oleophilic, hydrophilic–oleophobic, omniphobic, and omniphilic. Open‐channel, paper‐based microfluidic devices fabricated using these surfaces with extreme wettabilities allow for the localization, manipulation, and transport of virtually all high‐ and low‐surface tension liquids. This in turn expands the utility of paper‐based microfluidic devices to a range of applications never before considered. These include, as demonstrated here, continuous oil–water separation, liquid–liquid extraction, open‐channel microfluidic emulsification, microparticle fabrication, and precise measurement of mixtures' composition. Finally, the biocompatibility of the developed microfluidic devices and their utility for cell patterning are demonstrated. 相似文献
15.
Rong Wang Chongling Cheng Huiyun Wang Qi Tao Dayang Wang 《Advanced functional materials》2023,33(35):2301085
In this study, poly(vinyl sulfonate) (PVS)–capped surfaces are constructed on the polyelectrolyte multilayers (PEMs) of poly(diallyldimethylammonium chloride) and poly(styrene sulfonate) via electrostatic assembly. The water wetting behavior on the resulting PVS-capped PEMs is meticulously correlated with the number of surface sulfonate groups with the aid of sum frequency generation spectroscopy and quartz crystal microbalance. It is found that when the molecular packing density of surface sulfonate groups is adjusted to be comparable to the maximal packing density of spheres in two dimensions (≈0.9), the PVS capping is able to effectively adsorb water molecules from the surrounding to form hydrogen-bonded networks, which not only promote complete surface wetting by water in air but also diminish surface affinity to adhesion of ice, oil and wax deposited atop. As a result, the PVS-capped PEMs are able to fulfil all the self-cleaning functions proposed for superhydrophilic surfaces including anti-fogging, anti-icing, anti-grease, anti-smudge, anti-graffiti, and anti-wax. After being coated with the self-cleaning PVS-capped PEMs, conventional stainless steel meshes are able to perform oil-water separation without prior water wetting. 相似文献
16.
Mengchun Wu Benhua Ma Tiezheng Pan Shanshan Chen Junqi Sun 《Advanced functional materials》2016,26(4):569-576
Colored cotton fabrics with satisfactory color fastness as well as durable antibacterial and self‐healing superhydrophobic properties are fabricated via a convenient solution‐dipping method that involves the sequential deposition of branched poly(ethylenimine) (PEI), silver nanoparticles (AgNPs), and fluorinated decyl polyhedral oligomeric silsesquioxane (F‐POSS) on cotton fabrics. The deposited AgNPs with tunable surface plasmon resonance endow the cotton fabrics with abundant color and and antibacterial ability. However, in general, water‐soluble AgNPs cannot be firmly deposited onto cotton fabrics to endure the laundering process. The integration of self‐healing superhydrophobicity into the cotton fabrics by depositing F‐POSS/AgNP/PEI films significantly enhances the color fastness of the AgNPs against laundry and mechanical abrasion, while retaining the antibacterial property of the AgNPs. The F‐POSS/AgNP/PEI‐coated cotton fabric accommodates an abundance of F‐POSS, which autonomically migrates to the cotton surface to repetitively restore its damaged superhydrophobicity. The self‐healing superhydrophobicity of the F‐POSS/AgNPs/PEI‐coated cotton fabric guarantees long‐term protection of the underlying AgNPs against laundry and abrasion and allows the cotton fabric to be cleaned by simple rinsing with water. 相似文献
17.
Desmond van den Berg Dalal Asker Jungchul Kim Ho-Young Kim Joanna Aizenberg Benjamin Hatton 《Advanced functional materials》2024,34(32):2315957
Microbial contamination of hospital surfaces is a major contributor to infectious disease transmission. This work demonstrates that superhydrophobic (Cassie-Baxter) micro post topographies can significantly reduce cell attachment compared to flat controls. For ordered micro post arrays (post diameters 0.3 to 150 µm), the attachment of four pathogens (Pseudomonas aeruginosa, Staphylococcus aureus, Escherichia coli, and Candida albicans) from discrete contaminant droplets upon short-term contact (15 s to 30 min) are assessed. There is a 3-4-log decrease in microbial attachment when reducing the micro posts diameters from 150 to 0.3 µm for all strains, with large posts (>20 µm) exhibiting similar attachment rates to flat controls. The critical, maximum feature size to prevent attachment can be tuned depending on the ratio of the cell size to post diameter. Two potential mechanisms are discussed for this size effect. First, application of the random sequential adsorption model shows that this relative post/cell size effect may be due to a reduced probability of attachment, which is theorized to be the dominant mechanism. Alternatively, a physical model is suggested for bacterial cell “pull-off” due to surface tension forces during droplet dewetting. This work may be important for the design of non-wetting antimicrobial surfaces within healthcare environments. 相似文献
18.
One of the most fascinating properties of materials in nature is the superhydrophobic and self‐cleaning capabilities of different plant surfaces. This is usually achieved by the hydrophobic cuticles that are made of cutin and contain wax crystals both within them and on their surfaces. Here, bioinspired n‐hexatriacontane wax films are deposited via thermal evaporation and it is shown that the surface evolves in time via self‐assembly. This leads to a dramatic change in the wetting properties with a transition from hydrophobic to superhydrophobic characteristics, which takes place within several days at room temperature. This phenomenon is investigated and strain‐induced recrystallization is proposed to be the mechanism for it. This work could become the basis for the inspiration and production of tuned, time‐dependant, temperature‐sensitive, variable‐wettability surfaces. 相似文献
19.
Weiyang Lv Qingqing Mei Jianliang Xiao Miao Du Qiang Zheng 《Advanced functional materials》2017,27(48)
Developing novel filtering materials with both high permeation flux and rejection rate presents an enticing prospect for oil/water separation. In this paper, robust porous poly(melamine formaldehyde) (PMF) sponges with superwettability and controlled pore sizes through introducing layered double hydroxides (LDH) and SiO2 electrospun nanofibers are reported. The LDH nanoscrolls endow the sponge with inherent superhydrophilicity and the SiO2 nanofibers act as pore size regulators by overlapping the PMF mainframe. This approach allows the intrinsic large pores in the pristine sponge to decrease quickly from 109.50 to 23.35 µm, while maintaining porosity above 97.8%. The resulting modified sponges with varied pore sizes can effectively separate a wide range of oil/water mixtures, including the surfactant‐stabilized emulsions, solely by gravity, with ultrahigh permeation flux (maximum of 3 × 105 L m?2 h?1 bar?1) and satisfactory oil rejection (above 99.46%). Moreover, separation of emulsions stabilized by different surfactants, such as anionic, nonionic, and cationic surfactants has been investigated for further practical evaluation. It is expected that such a pore size tuning technology can provide a low cost and easily scaled‐up method to construct a series of filtering materials for high‐efficient separation of target oil/water mixtures. 相似文献
20.