Invasion,persistence and control in epidemic models for plant pathogens: the effect of host demography

Many epidemiological models for plant disease include host demography to describe changes in the availability of susceptible tissue for infection. We compare the effects of using two commonly used formulations for host growth, one linear and the other nonlinear, upon the outcomes for invasion, persistence and control of pathogens in a widely used, generic model for botanical epidemics. The criterion for invasion, reflected in the basic reproductive number, R₀, is unaffected by host demography: R₀ is simply a function of epidemiological parameters alone. When, however, host growth is intrinsically nonlinear, unexpected results arise for persistence and the control of disease. The endemic level of infection (I_∞) also depends upon R₀. We show, however, that the sensitivity of I_∞ to changes in R₀ > 1 depends upon which underlying epidemiological parameter is changed. Increasing R₀ by shortening the infectious period results in a monotonic increase in I_∞. If, however, an increase in R₀ is driven by increases in transmission rates or by decreases in the decay of free-living inoculum, I_∞ first increases (R₀ < 2), but then decreases (R₀ > 2). This counterintuitive result means that increasing the intensity of control can result in more endemic infection.     

Pressure-Volume-Temperature Relations in Liquid and Solid Tritium

PVT relations in liquid and solid T₂ near the melting curve were measured over 20.5 K–22.1 K and 0 MPa–7 MPa (0 bar–70 bar) with a cell that used diaphragms for pressure and volume variation and measurement. Because of ortho-para self conversion, the melting pressure P_m and the liquid molar volume V_lm increased with time. The rates were consistent with a second order reaction similar to that for c the J = odd concentration: dc/dt = ?k₁c² + k₂c(1 ? c), where k₁ = 6−9×l0⁻²h⁻¹. By extrapolation, the ortho and para forms differed by ΔP_m~6 bar and ΔV_lm~0.5%. Measurements of the volume change on melting and the thermal expansion and compressibility for liquid T₂ were consistent with those for H₂ and D₂. Impurities such as H₂, HT, DT, and ³He were removed by a technique using an adsorption column of cold activated alumina. Corrections for ³He growth during an experiment were adequate except near the triple point.     

High-pressure studies on Tc and crystal structure of iron chalcogenide superconductors

The superconducting transition temperature, T_c, in iron-based solids can be enhanced by applied pressure: T_c increases from 8 to 37 K for the 11-type FeSe when the pressure is raised from 0 to 4 GPa. High-pressure studies can elucidate the mechanism of superconductivity in such novel materials. In this paper, we present a high-pressure study of Fe(Se_1−xTe_x) and Fe(Se_1−xS_x). In the case of Fe(Se_1−xTe_x), the maximum T_c under high pressure did not exceed the T_c of FeSe, which can be attributed to the structural transition to the monoclinic phase. For Fe(Se_1−xS_x) (0 < x < 0.3), T_c exhibited a significant increase with pressure; however, the maximum T_c under high pressure did not exceed the T_c of FeSe. This may be due to the disorder induced by substituting S for Se, which is similar to the pressure effect on T_c for the 1111-type superconductor Ca(Fe_1−xCo_x)AsF. The T_c of Fe(Se_1−xS_x) showed a complex behavior below 1 GPa, first decreasing and then increasing with increasing pressure. From high-pressure x-ray diffraction measurements, the T_c (P) curve was correlated with the local structural parameter.     

Gd@C82 metallofullerenes for neutron capture therapy—fullerene solubilization by poly(ethylene glycol)-block-poly(2-(N,N-diethylamino)ethyl methacrylate) and resultant efficacy in vitro

Poly(ethylene glycol)-block-poly(2-(N,N-diethylamino)ethyl methacrylate) (PEG-b-PAMA) was found to solubilize fullerenes such as C₆₀, and this technique was applied to metallofullerenes. Gd@C₈₂ was easily dissolved in water in the presence of PEG-b-PAMA without any covalent derivatization, forming a transparent complex about 20–30 nm in diameter. Low cytotoxicity was confirmed in vitro. Neutron irradiation of cultured cells (colon-26 adenocarcinoma) with Gd@C₈₂-PEG-b-PAMA-complexed nanoparticles showed effective cytotoxicity, indicating the effective emission of gamma rays and internal conversion electrons produced from the neutron capture reaction of Gd. This result suggests a potentially valuable approach to gadolinium-based neutron capture therapy.     

Theoretical aspects of charge correlations in θ-(BEDT-TTF)2X

A review is given on the theoretical studies of charge correlations in θ-(BEDT-TTF)₂X. Various studies show that within a purely electronic model on the θ-type lattice with on-site U and nearest neighbor V_p and V_c interactions, the diagonal stripe, c-axis three-fold, and the vertical stripe charge correlations are favored in the regime V_p<V_c, V_p∼V_c, and V_p>V_c, respectively. In the realistic parameter regime of V_p∼V_c, there is competition between the c-axis three fold state and diagonal stripe state. Since these are different from the experimentally observed a-axis three fold and the horizontal stripe charge correlations, additional effects have to be included in order to understand the experiments. The electron–lattice coupling, which tends to distort the lattice into the θ_d-type, is found to favor the horizontal stripe state, suggesting that the occurrence of this stripe ordering in the actual materials may not be of purely electronic origin. On the other hand, distant electron–electron interactions have to be considered in order to understand the a-axis three fold correlation, whose wave vector is close to the nesting vector of the Fermi surface. These studies seem to suggest that the minimal model to understand the charge correlation in θ-(BEDT-TTF)₂X may be more complicated than expected. Future problems regarding the competition between different types of charge correlations are discussed.     

Identifying and rationalizing the morphological,structural, and optical properties of [... formula ...]-Ag2MoO4 microcrystals,and the formation process of Ag nanoparticles on their surfaces: combining experimental data and first-principles calculations

We present a combined theoretical and experimental study on the morphological, structural, and optical properties of β-Ag₂MoO₄ microcrystals. β-Ag₂MoO₄ samples were prepared by a co-precipitation method. The nucleation and formation of Ag nanoparticles on β-Ag₂MoO₄ during electron beam irradiation were also analyzed as a function of electron beam dose. These events were directly monitored in real-time using in situ field emission scanning electron microscopy (FE-SEM). The thermodynamic equilibrium shape of the β-Ag₂MoO₄ crystals was built with low-index surfaces (001), (011), and (111) through a Wulff construction. This shape suggests that the (011) face is the dominating surface in the ideal morphology. A significant increase in the values of the surface energy for the (011) face versus those of the other surfaces was observed, which allowed us to find agreement between the experimental and theoretical morphologies. Our investigation of the different morphologies and structures of the β-Ag₂MoO₄ crystals provided insight into how the crystal morphology can be controlled so that the surface chemistry of β-Ag₂MoO₄ can be tuned for specific applications. The presence of structural disorder in the tetrahedral [MoO₄] and octahedral [AgO₆] clusters, the building blocks of β-Ag₂MoO₄, was used to explain the experimentally measured optical properties.     

Liquidus Diagram of the Ba-Y-Cu-O System in the Vicinity of the Ba2YCu3O6+x Phase Field

This paper describes the melting equilibria in the vicinity of the high T_c phase Ba₂YCu₃O_6+x, including evidence for two Ba-Y-Cu-O immiscible liquids. Melting equilibria have been investigated in purified air using a combination of differential thermal analysis (DTA), thermogravimetric analysis (TGA), powder x-ray diffraction (XRD), MgO wick entrapment of liquid for analysis, scanning electron microscopy (SEM) coupled with energy dispersive x-ray analysis (EDS), and hydrogen reduction for determination of copper oxidation state. For relatively barium-rich compositions, it was necessary to prepare the starting materials under controlled atmosphere conditions using BaO. A liquidus diagram was derived from quantitative data for the melts involved in various melting reactions. In general the 1/2(Y₂O₃) contents of the melts participating in these equilibria were low (mole fraction <4 %). The primary phase field of Ba₂YCu₃O_6+x occurs at a mole fraction of <2.0 % 1/2Y₂O₃ and lies very close along the BaO-CuO_x edge, extending from a mole fraction of ≈43 % CuO to a mole fraction of ≈76 % CuO. It is divided by a liquid miscibility gap and extends on either side about this gap. The topological sequence of melting reactions associated with the liquidus is presented as a function of temperature. Implications for the growth of Ba₂YCu₃O_6+x crystals are discussed.     

(0 0 6)-oriented α-Al2O3 films prepared in CO2-H2 atmosphere by laser chemical vapor deposition using a diode laser

(0 0 6)-oriented α-Al₂O₃ films were prepared by laser chemical vapor deposition (LCVD) using aluminum acetylacetonate (Al(acac)₃) in CO₂-H₂ atmosphere. The effects of the CO₂ mole fraction (FCO₂) and laser power (P_L) on the crystal phase, microstructure, and deposition rate (R_dep) were investigated. α- and γ-Al₂O₃ mixture films were prepared at P_L = 90 W (deposition temperature of 818 K), whereas (0 0 6)-oriented single-phase α-Al₂O₃ films were obtained at P_L = 110 W (863 K). The texture coefficient and the grain size of the (0 0 6)-oriented films increased with increasing FCO₂. The orientation of the α-Al₂O₃ films changed from (0 0 6) to (1 0 4) to (0 1 2) with increasing P_L (T_dep). The R_dep of the (0 0 6)-oriented α-Al₂O₃ films increased with increasing FCO₂.     

Two-gap superconductivity in R2Fe3Si5 (R=Lu,Sc) and Sc5Ir4Si10

R₂Fe₃Si₅ (R= Sc, Y, Lu) contains nonmagnetic iron and has a relatively high superconducting transition temperature T_c among iron-containing superconductors. An anomalous temperature dependence of specific heat C(T) has been reported for polycrystalline samples down to 1 K. We have grown R₂Fe₃Si₅ single crystals, confirmed the anomalous C(T) dependence, and found a second drop in specific heat below 1 K. In Lu₂Fe₃Si₅, we can reproduce C(T) below T_c, assuming two distinct energy gaps 2Δ ₁/k_BT_c = 4.4 and 2Δ ₂/k_BT_c = 1.1, with nearly equal weights, indicating that Lu₂Fe₃Si₅ is a two-gap superconductor similar to MgB₂. Hall coefficient measurements and band structure calculation also support the multiband contributions to the normal-state properties. The specific heat in the Sc₂Fe₃Si₅ single crystals also shows the two-gap feature. R₅Ir₄Si₁₀ (R = Sc, rare earth) is also a superconductor where competition between superconductivity and the charge-density wave is known for rare earths but not for Sc. We have performed detailed specific heat measurements on Sc₅Ir₄Si₁₀ single crystals and found that C(T) deviates slightly from the behavior expected for weak-coupling superconductors. C(T) for these superconductors can also be reproduced well by assuming two superconducting gaps.     

Wurtzite-derived ternary I–III–O2 semiconductors

Ternary zincblende-derived I–III–VI₂ chalcogenide and II–IV–V₂ pnictide semiconductors have been widely studied and some have been put to practical use. In contrast to the extensive research on these semiconductors, previous studies into ternary I–III–O₂ oxide semiconductors with a wurtzite-derived β-NaFeO₂ structure are limited. Wurtzite-derived β-LiGaO₂ and β-AgGaO₂ form alloys with ZnO and the band gap of ZnO can be controlled to include the visible and ultraviolet regions. β-CuGaO₂, which has a direct band gap of 1.47 eV, has been proposed for use as a light absorber in thin film solar cells. These ternary oxides may thus allow new applications for oxide semiconductors. However, information about wurtzite-derived ternary I–III–O₂ semiconductors is still limited. In this paper we review previous studies on β-LiGaO₂, β-AgGaO₂ and β-CuGaO₂ to determine guiding principles for the development of wurtzite-derived I–III–O₂ semiconductors.     

Constraint-modified J−R curves and its application to ductile crack growth

The concept of J-controlled crack growth is extended to J–A ₂ controlled crack growth using J as the loading level and A ₂ as the constraint parameter. It is shown that during crack extension, the parameter A ₂ is an appropriate constraint parameter due to its independence of applied loads under fully plastic conditions or large-scale yielding. A wide range of constraint level is considered using five different types of specimen geometry and loading configuration; namely, compact tension (CT), three-point bend (TPB), single edge-notched tension (SENT), double edge-notched tension (DENT) and centre-cracked panel (CCP). The upper shelf initiation toughness J _IC, tearing resistance T _R and J–R curves tested by Joyce and Link (1995) for A533B steels using the first four specimens are analysed. Through finite element analysis at the applied load of J _IC, the values of A ₂ for all specimens are determined. The framework and construction of constraint-modified J–R curves using A ₂ as the constraint parameter are developed and demonstrated. A procedure of transferring the J–R curves determined from standard ASTM procedure to non-standard specimens or practical cracked structures is outlined. Based on the test data, the constraint-modified J–R curves are presented for the test material of A533B steel. Comparison shows the experimental J–R curves can be reproduced or predicted accurately by the constraint-modified J–R curves for all specimens tested. Finally, the variation of J–R curves with the size of test specimens is produced. The results show that larger specimens tend to have lower crack growth resistance curves.     

Can a Pressure Standard be Based on Capacitance Measurements?

We consider the feasibility of basing a pressure standard on measurements of the dielectric constant ϵ and the thermodynamic temperature T of helium near 0 °C. The pressure p of the helium would be calculated from fundamental constants, quantum mechanics, and statistical mechanics. At present, the relative standard uncertainty of the pressure u_r(p) would exceed 20 × 10⁻⁶, the relative uncertainty of the value of the molar polarizability of helium A_ϵ calculated ab initio. If the relativistic corrections to A_ϵ were calculated as accurately as the classical value is now known, a capacitance-based pressure standard might attain u_r(p) < 6 × 10⁻⁶ for pressures near 1 MPa, a result of considerable interest for pressure metrology. One obtains p by eliminating the density from the virial expansions for p and ϵ − 1. If ϵ − 1 were measured with a very stable, 0.5 pF toroidal cross capacitor, the small capacitance and the small values of ϵ − 1 would require state-of-the-art capacitance measurements to achieve a useful pressure standard.     

Comparisons of immersion and electrochemical properties of highly biocompatible Ti–15Zr–4Nb–4Ta alloy and other implantable metals for orthopedic implants

Metal release from implantable metals and the properties of oxide films formed on alloy surfaces were analyzed, focusing on the highly biocompatible Ti–15Zr–4Nb–4Ta alloy. The thickness and electrical resistance (R_p) of the oxide film on such an alloy were compared with those of other implantable metals. The quantity of metal released during a 1-week immersion test was considerably smaller for the Ti–15Zr–4Nb–4Ta than the Ti–6Al–4V alloy. The potential (E₁₀) indicating a current density of 10 μA cm⁻² estimated from the anodic polarization curve was significantly higher for the Ti–15Zr–4Nb–4Ta than the Ti–6Al–4V alloy and other metals. Moreover, the oxide film (4–7 nm thickness) formed on the Ti–15Zr–4Nb–4Ta surface is electrochemically robust. The oxide film mainly consisted of TiO₂ with small amounts of ZrO₂, Nb₂O₅ and Ta₂O₅ that made the film electrochemically stable. The R_p of Ti–15Zr–4Nb–4Ta was higher than that of Ti–6Al–4V, i.e. 0.9 Ω cm² in 0.9% NaCl and 1.3 Ω cm² in Eagle''s medium. This R_p was approximately five-fold higher than that of stainless steel, which has a history of more than 40 years of clinical use in the human body. Ti–15Zr–4Nb–4Ta is a potential implant material for long-term clinical use. Moreover, E₁₀ and R_p were found to be useful parameters for assessing biological safety.     

Facile synthesis of α-Fe2O3 nanodisk with superior photocatalytic performance and mechanism insight

Intrinsic short hole diffusion length is a well-known problem for α-Fe₂O₃ as a visible-light photocatalytic material. In this paper, a nanodisk morphology was designed to remarkably enhance separation of electron-hole pairs of α-Fe₂O₃. As expected, α-Fe₂O₃ nanodisks presented superior photocatalytic activity toward methylene blue degradation: more than 90% of the dye could be photodegraded within 30 min in comparison with a degradation efficiency of 50% for conventional Fe₂O₃ powder. The unique multilayer structure is thought to play a key role in the remarkably improved photocatalytic performance. Further experiments involving mechanism investigations revealed that instead of high surface area, ·OH plays a crucial role in methylene blue degradation and that O^·2− may also contribute effectively to the degradation process. This paper demonstrates a facile and energy-saving route to fabricating homogenous α-Fe₂O₃ nanodisks with superior photocatalytic activity that is suitable for the treatment of contaminated water and that meets the requirement of mass production.     

Ba(OH)2 Equilibria in the System Ba-O-H-F,With Application to the Formation of Ba2YCu3O6.5 + x From BaF2-Precursors

The ex situ process for fabricating Ba₂YCu₃O_{6.5 + x} superconducting tapes from BaF₂- based precursors involves a hydration/oxidation reaction at ≈730 °C to 750 °C generally written as: (2BaF2+Y+3Cu)(amorphous)+(2H2O+2.25O2)(g)→Ba2YCu3O6.5+x(s)+4HF(g).However, microscopic observations of partially processed films suggest the presence of a transient liquid phase during conversion. Alternatively, the conversion reaction can be rewritten as the sum of several intermediate steps, including the formation of a barium hydroxide liquid: (BaF2)(amorphous)+2H2O(g)→Ba(OH)2(liq)+2HF(g).To evaluate the possibility of a hydroxide liquid conversion step, thermodynamic calculations on the stability of Ba(OH)₂(liq) have been completed from 500 °C to 900 °C at 0.1 MPa p_total. Based on currently available data, the calculated phase diagrams suggest that a viable hydroxide reaction path exists in the higher part of this temperature range. The calculations indicate that Ba(OH)₂(liq) may be stable at log p_H2O (Pa) values from ≈4 to 5, provided log p_HF (Pa) values can be maintained below 0 to −1. Limited experimental confirmation is provided by results of an experiment on BaF₂(s) at 815 °C, 0.1 MPa p_H2O, in which essentially all F at the surface was replaced by O. It is therefore possible that processing routes exist for producing Ba₂YCu₃O_{6.5 + x} based on the presence of a Ba(OH)₂ liquid, which might have an effect on conversion rates and texturing in the superconducting film.     

New aspects of π–d interactions in magnetic molecular conductors

The 2 : 1 cation radical salts of bent donor molecules of ethylenedithio-tetrathiafulvalenoquinone-1,3-dithiolemethide (EDT-TTFVO), ethylenedithio-diselenadithiafulvalenoquinone-1,3-dithiolemethide (EDT-DSDTFVO), ethylenedithio-diselenadithiafulvalenothioquinone-1,3-diselenolemethide (EDT-DSDTFVSDS), ethylenedioxy-tetrathiafulvalenoquinone-1,3-dithiolemethide (EDO-TTFVO) and ethylenedioxy-tetrathiafulvalenoquinone-1,3-diselenolemethide (EDO-TTFVODS) with FeX₄⁻ (X = Cl, Br) ions are prepared by electrocrystallization. The crystal structures of these salts are composed of alternately stacked donor molecule and magnetic anion layers. The band structures of the donor molecule layers are calculated using the overlap integrals between neighboring donor molecules and are compared with the observed electronic transport properties. The magnetic ordering of the Fe(III) d spins of FeX₄⁻ ions is determined from magnetization and heat capacity measurements. The magnetic ordering temperatures are estimated by considering a combination of a direct d–d interaction between the d spins and an indirect π–d interaction between the conduction π electron and the d spins, whose magnitudes are separately calculated from the crystal structures with an extended Hückel molecular orbital method. The occurrence of a π–d interaction is proved by the negative magnetoresistance, and the magnitude of magnetoresistance reflects the strength of the π–d interaction. The effect of pressure on the magnetoresistance is studied, and the result indicates that the magnitude of magnetoresistance increases, namely, the π–d interaction is enhanced with increasing pressure. From these experimental results it is shown that (EDT-TTFVO)₂•FeBr₄ is a ferromagnetic semiconductor, (EDT-DSDTFVO)₂•FeX₄ (X = Cl, Br) and (EDT-DSDTFVSDS)₂•FeBr₄ are metals exhibiting antiferromagnetic ordering of the d spins, and (EDO-TTFVO)₂•FeCl₄ and (EDO-TTFVODS)₂•FeBr₄•(DCE)_0.5 (DCE =-dichloroethane) are genuine antiferromagnetic metals. Among them, the (EDT-TTFVO)₂•FeBr₄ salt is the first π–d molecular system where the d spins of FeBr₄⁻ ions are ferromagnetically ordered through antiferromagnetic interaction with the conduction π electrons. Corresponding to this ferromagnetic ordering, an anomalous dielectric slow-down phenomenon toward the ordering temperature is observed. The π–d interaction in (EDT-DSDTFVSDS)₂•FeBr₄ is very large and comparable to that in λ-(BETS)₂•FeCl₄, which has the highest reported value so far, while the d–d interaction is fairly small. Concerning the ratio between the magnitudes of π–d and d–d interactions (J_πd/J_dd), this salt is currently the best π–d molecular system.     

Powder X-Ray Reference Patterns of Sr2RGaCu2Oy (R = Pr,Nd, Sm,Eu, Gd,Dy, Ho,Er, Tm,and Y)

X-Ray Rietveld refinements were conducted on a series of eleven lanthanide phases, Sr₂RGaCu₂O_y (2112 phase, R = Pr, Nd, Sm, Eu, Gd, Dy, Ho, Y, Er, Tm, and Yb) that are structurally related to the high T_c superconductor Ba₂YCu₃O₇ (213). In the 2112 structure, instead of square planar Cu-O chains, tetrahedral GaO4 chains were found to run in a zig-zag fashion along the diagonal of the basal 213 ab-direction. Reference powder patterns for these compounds were prepared by using the Rietveld decomposition technique. The unit cell volume of these compounds follows the expected trend of the lanthanide contraction. The lattice parameters range from a = 22.9694(3) Å, b = 5.5587(2) Å, and c = 5.44743(7) Å for R = Pr, to a = 22.8059(2) Å, b = 5.46031(5) Å, and c = 5.37773(5) Å for R = Yb. An electon diffraction study of the Sm- and Er-analogs showed characteristic diffuse streaks along the b-axis, suggesting some disorder within the GaO₄ chains.     

Structure and cation distribution in perovskites with small cations at the A site: the case of ScCoO3

We synthesize ScCoO₃ perovskite and its solid solutions, ScCo_1−xFe_xO₃ and ScCo_1−xCr_xO₃, under high pressure (6 GPa) and high temperature (1570 K) conditions. We find noticeable shifts from the stoichiometric compositions, expressed as (Sc_1−xM_x)MO₃ with x = 0.05–0.11 and M = Co, (Co, Fe) and (Co, Cr). The crystal structure of (Sc_0.95Co_0.05)CoO₃ is refined using synchrotron x-ray powder diffraction data: space group Pnma (No. 62), Z = 4 and lattice parameters a = 5.26766(1) Å, b = 7.14027(2) Å and c = 4.92231(1) Å. (Sc_0.95Co_0.05)CoO₃ crystallizes in the GdFeO₃-type structure similar to other members of the perovskite cobaltite family, ACoO₃ (A³⁺ = Y and Pr-Lu). There is evidence that (Sc_0.95Co_0.05)CoO₃ has non-magnetic low-spin Co³⁺ ions at the B site and paramagnetic high-spin Co³⁺ ions at the A site. In the iron-doped samples (Sc_1−xM_x)MO₃ with M = (Co, Fe), Fe³⁺ ions have a strong preference to occupy the A site of such perovskites at small doping levels.     

Crack closure under high load-ratio conditions for Inconel-718 near threshold behavior

Fatigue-crack-growth (FCG) rate tests were conducted on compact specimens made of an Inconel-718 alloy to study the behavior over a wide range in load ratios (0.1 ? R ? 0.95) and a constant K_max test condition. Previous research had indicated that high R (>0.7) and constant K_max test conditions near threshold conditions were suspected to be crack-closure-free and that any differences were attributed to K_max effects. During a test at a load ratio of 0.7, strain gages were placed near and ahead of the crack tip to measure crack-opening loads from local load-strain records during crack growth. In addition, a back-face strain (BFS) gage was also used to monitor crack lengths and to measure crack-opening loads from remote load-strain records during the same test. The BFS gage indicated that the crack was fully open (no crack closure), but the local load-strain records indicated significant amounts of crack closure. The crack-opening loads were increasing as the crack approached threshold conditions at R = 0.7. Based on these measurements, crack-closure-free FCG data (ΔK_eff against rate) were calculated. The ΔK_eff-rate data fell at lower ΔK values and higher rates than the constant K_max test results. In addition, constant R tests at extremely high R (0.9 and 0.95) were also performed and compared with the constant K_max test results. The constant R test results at 0.95 agreed well with the ΔK_eff-rate data, while the R = 0.9 data agreed well with constant K_max test data in the low-rate regime. These results imply that the R = 0.7 test had a significant amount of crack closure as the threshold was approached, while the R = 0.9 and K_max test results may have had a small amount of crack closure, and may not be closure free, as originally suspected. Under the high load-ratio conditions (R ? 0.7), it is suspected that the crack surfaces are developing debris-induced crack closure from contacting surfaces, which corresponded to darkening of the fatigue surfaces in the near-threshold regime. Tests at low R also showed darkening of the fatigue surfaces only in the near-threshold regime. These results suggest that the ΔK_eff against rate relation may be nearly a unique function over a wide range of R in the threshold regime.     

Chemiluminescence analyzer of NOx as a high-throughput screening tool in selective catalytic reduction of NO

A chemiluminescence-based analyzer of NO_x gas species has been applied for high-throughput screening of a library of catalytic materials. The applicability of the commercial NO_x analyzer as a rapid screening tool was evaluated using selective catalytic reduction of NO gas. A library of 60 binary alloys composed of Pt and Co, Zr, La, Ce, Fe or W on Al₂O₃ substrate was tested for the efficiency of NO_x removal using a home-built 64-channel parallel and sequential tubular reactor. The NO_x concentrations measured by the NO_x analyzer agreed well with the results obtained using micro gas chromatography for a reference catalyst consisting of 1 wt% Pt on γ-Al₂O₃. Most alloys showed high efficiency at 275 °C, which is typical of Pt-based catalysts for selective catalytic reduction of NO. The screening with NO_x analyzer allowed to select Pt-Ce_(X) (X=1–3) and Pt–Fe₍₂₎ as the optimal catalysts for NO_x removal: 73% NO_x conversion was achieved with the Pt–Fe₍₂₎ alloy, which was much better than the results for the reference catalyst and the other library alloys. This study demonstrates a sequential high-throughput method of practical evaluation of catalysts for the selective reduction of NO.