共查询到16条相似文献,搜索用时 140 毫秒
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有机硅改性聚酯的合成及其粉末涂料的性能 总被引:5,自引:0,他引:5
利用有机硅中间体合成了有机硅改性聚酯树脂。通过IR、GPC、SEM等分析了改性聚酯的结构与形态 ,用电子探针分析了改性聚酯的表面组成 ,考察了有机硅含量对改性树脂玻璃化温度、熔融黏度、对水的接触角及表面张力的影响。研究发现 ,改性聚酯中的含硅聚酯在表面富集 ,大大降低了聚酯树脂的表面张力 ,提高了其粉末涂料的涂膜耐候性。相对于纯聚酯树脂 ,有机硅质量分数为 1 %可使树脂的表面张力从 49.5降到 2 8.4mN/m ;经 2 1 6h中波紫外线照射后 ,涂膜的光泽保留率从 81 %上升到 91 .3 %。含有机硅质量分数超过 5 %后 ,涂膜的抗冲性能下降。 相似文献
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研究不同种类高酸值树脂对干混消光粉末涂层光泽、流平以及细腻度的影响规律,通过改变高酸树脂合成中单体的种类、数量以及活性,合成不同种类的高酸值聚酯树脂.采用差式扫描量热仪(DSC)测试其玻璃化转变温度(Tg),并将合成的聚酯树脂与固化剂、颜填料和助剂制备成90/10异氰脲酸三缩水甘油酯(TGIC)固化型快组份粉末涂料,采... 相似文献
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以乙醇为溶剂,将正硅酸乙酯(TEOS)与乙烯基三乙氧基硅烷(VTEOS)经酸催化合成了一种表面带有乙烯基的活性二氧化硅粒子,然后将其与丙烯酸树脂聚合得到透明的有机硅改性阳极电泳漆。研究了有机硅的添加方式对反应过程,有机硅含量对改性丙烯酸树脂的玻璃化转变温度、黏度以及电泳漆性能的影响,采用傅里叶变换红外光谱、差示扫描量热和热重分析等对改性丙烯酸树脂进行了表征。结果表明,有机硅的最佳添加方式是与部分单体预混后逐滴滴加。随着有机硅含量的增大,改性丙烯酸树脂的黏度、玻璃化转变温度和耐热性提高。当有机硅添加量为0.8%~1.2%时,电泳漆膜的综合性能较好。 相似文献
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研究了高耐候亚光透明粉末涂料配方的消光体系、树脂的耐候性、消光剂的种类、流平剂的透明度、紫外线吸收剂对耐候性的影响,以及潜伏性促进剂的使用,制备了适用于汽车铝轮毂罩光用亚光透明粉末涂料,并研究了其在汽车铝轮毂涂装中的施工性和应用效果。还研究了汽车铝轮毂罩光用亚光透明粉末涂料与高光丙烯酸型透明粉末涂料的兼容状况和烘烤温度适应性,最终制备了可以和高光环氧基丙烯酸透明粉末涂料共用生产线的亚光透明粉末涂料,依据汽车铝轮毂罩光用粉末涂料各项指标要求,该涂料综合性能相当,且在健康环保、节能、成本和贮存稳定性方面更具优势。 相似文献
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Sang Sun Lee Jung Hee Koo Sung Soo Lee Soo Gyum Chai Jong Chan Lim 《Progress in Organic Coatings》2003,46(4):266-272
This study describes the crucial role played by acrylic resin and curing agents in the gloss reduction of low temperature curable hybrid powder coatings. The incompatibility of the acrylic resin with the primary (epoxy/polyester) resins induces a two-phase morphology and initiates the formation of micro-structured surface. DSC measurements on various mixtures reveal the relative reactivity and the role of curing agents in the gloss reduction. These results indicate that the optimization of relative reactivity and compatibility is required to achieve low gloss coatings at low curing temperature. In addition, the gloss level is strongly affected by extruding conditions. These experimental results give a possibility to develop matt and semi-matt low temperature curable powder coatings. 相似文献
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Polyurethane powder coating systems consisting of polyester resin, blocked polyisocyanate and two types of “nanopowders” containing core–shell nanoparticles where the core was silicone resin of very low glass transition temperature and the shell was poly(methyl methacrylate) were examined. The blocked polyisocyanate was synthesized using biuretpolyisocyanate obtained from ureapolyisocyanate as starting material capable for blocking and ɛ-caprolactam as blocking agent. The surface properties of cured powder coatings were investigated using scanning electron microscopy (SEM) combined with energy dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). The surface structure was correlated with the chemical structure of the coatings and macroscopic surface behavior: contact angle, surface free energy, gloss, abrasion resistance, hardness and adhesion to the steel surface. 相似文献
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Preparation and characterization of weather resistant silicone/acrylic resin coatings 总被引:3,自引:0,他引:3
H. -S. Park S. -R. Kim H. -J. Park Y. -C. Kwak H. -S. Hahm S. -K. Kim 《Journal of Coatings Technology》2003,75(936):55-64
Preparation and characterization of weather resistant silicone/acrylic resin coatings were conducted. In order to prepare
these coatings, a silicone/acrylic resin (KLD) was first prepared by an addition polymerization reaction of monomers, including
n-butyl acrylate, methyl methacrylate, n-butyl methacrylate, and 3-methacryloxypropyltrimethoxysilane (MPTS). In the preparation
of the silicone/acrylic resin, Tg of the acrylic copolymer was fixed at 40°C and the contents of MPTS were varied to be 10, 20, and 30 wt%. The weather resistant
silicone/acrylic resin coatings were then prepared by blending the synthesized silicone/acrylic resin and TiO2. The viscosity of the synthesized resin decreased with the content of MPTS, whereas the thermal stability at high temperature
increased. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the
coatings were satisfactory. The weatherability of the coatings was tested three ways: outdoor exposure test, Weather-Ometer
(WOM), and QUV accelerated weatherability tester (QUV). The gloss retention, yellowness index difference, color difference,
and lightness index difference were improved at high MPTS concentration. The coatings containing 30 wt% MPTS have especially
good weather properties.
Dept. of Chem. Eng., Yongin 449-728, Korea.
Ansan 425-110, Korea. 相似文献