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1.
    
Triple base propellant (TBP) containing mainly nitrocellulose, nitroglycerine, and nitroguanidine has been manufactured and coated with plasticizer in the present work. The aim was to study ballistics of di-butyl phthalate (DBP)-coated TBP. DBP solution in ethanol containing nitrocellulose dope was used for coating onto the propellant grains. DBP-deterred propellant showed inhibition to burning, resulting in lowering the values of ballistic parameters namely peak pressure (Pmax), dPmax, pressure index (α), and burning rate coefficient (β) during closed vessel firing. Increase in percentage of DBP in coating solution led to further decrease in ballistic parameters. Dynamic evaluation of the surface-moderated propellant showed comparatively lower muzzle velocity and chamber pressure for deterred propellant batches without leaving any unburnt particles in gun chamber at subzero temperatures with the lowest possible charge mass. The DBP-coated propellant can be useful in 155-mm artillery gun to achieve higher loading density as it has lower flame temperature and chamber pressure as compared to uncoated propellant which will result in increasing barrel life due to reduction in the barrel erosion.  相似文献   

2.
为了获得X90钢级弯管的合理热处理工艺,采用Gleeble3500热模拟试验机,研究了高强度X90焊管焊缝和母材在不同加热温度下的组织与性能。试验结果显示,随着加热温度的升高,焊缝先共析铁素体减少,并出现粒状贝氏体组织,硬度上升;焊缝冲击功呈现先升后降趋势,当加热到925℃时,冲击功最低,加热到975℃时冲击功最高,但加热温度超过1 050℃时,针状铁素体板条粗大,夏比冲击功下降。因此得出结论,焊缝最佳的加热温度区间为950~1 025℃。在此温度区间内,母材随着加热温度的增加,块状铁素体逐渐减少,硬度上升,同时原奥氏体晶粒不断长大,夏比冲击功总体变化不大;当加热温度超过1 050℃时,粒状贝氏体晶粒粗化,冲击韧性快速下降。  相似文献   

3.
    
ABSTRACT

Two series of antihail rocket propellant grains failed only 3 months after production, due to the appearance of cracks in the grain channel. Structural integrity analysis demonstrated sufficient reliability at the beginning of service life. Further analysis showed that under temperature loads, cumulative damage during the short period in field stocks caused the grain failure, despite the established opinion that such failure can become significant only after lengthy storage. A linear cumulative damage law is evaluated by exposing a number of hydroxyl-terminated polybutadiene (HTPB) composite propellant specimens to different but constant stress levels. The analysis showed that cumulative damage must not be overlooked at the design stage. Further, a positive correlation between the propellant cumulative damage law and tensile strength is strongly indicated.  相似文献   

4.
    
In this work, a three-dimensional unsteady heat transfer model of base bleed unit with trilobite ammonium perchlorate (AP)/hydroxyl-terminated polybutadiene (HTPB) composite solid propellant is presented to analyze the cook-off characteristics. According to the two-step chemical reaction of AP/HTPB propellant, a small-scale cook-off test is established. A comparison of the experimental and calculated results is made to verify the rationality of the computation model. On this basis, a cook-off numerical simulation of the base bleed unit at the heating rates of 0.33, 0.58 and 0.83 K/s is presented to investigate the ignition and initiation characteristics. The results show that the ignitions occur on the head face of the AP/HTPB propellant and near the internal gas chamber in these conditions. As the heating rate increases, the runaway time decreases and the ignition temperature rises.  相似文献   

5.
6.
邻苯二甲酸二丁酯生产工艺流程的改进   总被引:1,自引:0,他引:1  
介绍传统邻苯二甲酸二丁酯(DBP)生产工艺的酯化、脱醇、脱色、过滤和废水处理过程中存在的不足及其改进方案。  相似文献   

7.
The coefficient of friction, μ, of PBX 9404 was measured on stainless steel, aluminum, polytetrafluoroethylene (PTFE), and the explosive itself between ambient and 135°C at a rotational speed of 0.0025 rad/s. The mean surface roughness, R a , of the various materials was analyzed by an optical profilometer. For PBX 9404 on stainless steel, μ increased from 0.22 at 25?°C to 0.34 at 95?°C, then decreased to about 0.23 at 125?°C. With aluminum μ increased from about 0.08 at 25?°C to 0.48 at 115?°C, then decreased slightly. Against PTFE μ was sigmoidal, increasing from about 0.3 at 25?°C to about at 0.49 above 115?°C. Against PBX 9404 itself, μ averaged 0.54 independent of temperature, but tended to increase during the measurement, probably because of adhesion of nitrocellulose to itself.  相似文献   

8.
研究了成核剂HPN-A,HPN-B对抗冲共聚聚丙烯2500H力学性能、热性能以及收缩率的影响。结果表明:成核剂HPN-B对2500H的性能影响较大,其添加量为0.08%(质量分数)时,试样的弯曲模量和拉伸强度分别提高22%和5.4%;成核剂HPN-B在提高试样刚性的同时,使试样的简支梁缺口冲击强度也略有提高。在热加工性能方面,成核剂HPN-B提高了试样的结晶温度和负荷变形温度,使试样的横向收缩率和纵向收缩率分别缩小6.15%和8.20%。  相似文献   

9.
埋地天然气放空管线是是集输体系重要的组成部分,借助宏观检查、材质分析、金相分析和力学性能测试等手段,对发生断裂的天然气埋放空线的宏观断1:7形貌、显微组织、力学性能等进行了研究,寻找管线发生断裂的原因,为以后类似管线的生产安装提供参考。结果表明,该管线在埋地过程中,管线受到了外力作用,使管线在最大变形处产生了很大的应力,最终发生脆性断裂。这就要求我们在埋地管线施工中,除了严格检查材料本身的质量依据有关标准,施工阶段合理保障管线不受外界因素的破坏,对每一个施工环节都要保证施工质量,确保管线能承压,不堵塞,符合设计的全部要求,才不至于出现一系列安全事故和质量事故的发生。  相似文献   

10.
林立恒 《焊管》2003,26(2):56-60
论述了时间因素使管道金属力学性能发生变化的理由,并就管道金属的力学性能,金相组织等与管道使用时间的关系进行了研究。对确定石油,天然气及其它输气管网的设计及使用年限规定有现实意义。  相似文献   

11.
    
《石油化工》2019,48(9):938
  相似文献   

12.
毕宗岳  牛辉  牛爱军  韦奉  黄晓辉  茹翔  王刚  谭赟 《焊管》2022,45(11):10-15
采用全管体扩径技术,研究了X80钢级Φ1 219 mm×22 mm螺旋埋弧焊管扩径前后力学性能的变化情况。结果表明,随着扩径率的增大,屈服强度和抗拉强度均有不同程度的增加,屈强比也随之增大,冲击韧性略有下降,DWTT性能变化不明显。在扩径率为0.88%情况下,管体横向屈服强度提高了15.2%,抗拉强度提高了5.8%,屈强比增大了9.8%;管体横、纵向屈服强度一致性提高了51.8%。总体上通过全管体扩径,管材力学性能的一致性得到进一步提高。  相似文献   

13.
使用双螺杆挤出机制备聚丙稀(PP)/线性低密度聚乙烯(LLDPE)共混物,通过GPC、DSC等手段判断了PP/LLDPE共混体系的相客性,使用常规物理机械方法测定了共混物的物理机械。结果表明:PP/LLDPE是热力学上完全不相客的体系,但是,基于结构和性质上的相似,该共混体系通过机械剪切共混可以达到一定的相客性。当PP/LLDPE=50:50-20:80时,LLDPE能明显改善PP的脆性大,同时,PP改善LLDPE的加工性、力学性能及耐热性能。  相似文献   

14.
焊剂碱度对焊剂工艺性能和焊缝机械性能,组织的影响   总被引:2,自引:2,他引:2  
马长权  杨满存 《焊管》1999,22(4):28-31
采用H08C焊丝,匹配GXHJ-1烧结焊剂,SQ42,HJ431焊剂,以及不同比例的混合焊剂,对X65级材质进行对接板试验,研究了焊接碱度在2.2-0.7之间变化时,焊剂碱度对焊剂工艺性能,焊缝机械性能,焊缝组织的影响。  相似文献   

15.
设备需要进行长时间保温或/和较高加热温度焊后热处理时,裙座筒体若与设备同炉整体焊后热处理则会造成实际力学性能下降,通过分析认为:在回火参数P较大时,裙座筒体材料应进行模拟焊后热处理或带母材试板,以检验材料实际力学性能能否满足要求,也可考虑局部热处理以减少保温时间.在裙座筒体各处轴向应力均为压应力情况下,必要时,可以考虑...  相似文献   

16.
随着在海冰区海洋工程结构物的增多,对海冰力学性质的研究引起了注意。1985-1987年在渤海进行了海冰物理力学性质的初步研究,进行了6个方面的测试。测试内容有海冰的单轴抗压强度,弯曲强度,剪切强度,冰晶体结构,冰温度、冰盐度、冰密度、弹性模量,泊松比和海冰的断裂韧度。海冰的强度与海冰温度有密切关系。冰温度降低,冰强度增加,通过测量海冰盐度和它的强度发现海冰盐度越高,冰强度越低。海冰强度与加载速度有关系,加载速度直接影响海冰强度。  相似文献   

17.
采用高真空封闭式循环反应系统,研究了丙烷在稀土氧化物及其对照物Al2O3、ZrO2、MgO上的直接脱氢和氧化脱氢反应。主要考察了生成丙烯的活性同催化剂表面的酸碱性、氧活性之间的关系。结果表明,催化剂表面强碱中心数目的多少与生成丙烯的活性有顺变关系,氧活性的强弱在丙烷氧化脱氢反应中也与丙烯的生成活性有顺变关系  相似文献   

18.
    
ABSTRACT

Graphene nanoplates (GNPs) were incorporated into a solid composite propellant (NC-TEGDN-RDX) to tune the thermal, mechanical, and combustion properties of the material. Physical, thermal, and combustion properties of NC-TEGDN-RDX with <2 wt% addition of GNPs were characterized using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), tensile/compressive/impact strength testing, and constant volume combustion experiments. Microstructure of the composite propellants examined using SEM demonstrated uniform dispersion of the GNPs at low-weight percent additives (<1 wt%), but began to show large agglomerations of the additives at higher additive content. Decomposition enthalpy of the propellant with 1 wt% GNPs increased by ~130 J/g compared to neat propellants. Moreover, the maximum burning rate was observed for samples containing 1 wt% GNPs, with values of 19 cm/s at 20°C and 17 cm/s at ?40°C. Dynamic vivacity of the propellant achieved a maximum upon addition of 1 wt% GNPs. The pressure exponent of the propellant decreased with the addition of GNPs, as well. The mechanical properties including tensile, compressive, and impact strength were improved at 20°C and ?40°C. These results demonstrate that the addition of GNPs may offer new methods by which to tune and improve thermal decomposition, thermal conductivity, combustion performance, and mechanical properties of the NC-TEGDN-RDX propellants.  相似文献   

19.
王国丽  李其 《石油学报》1995,16(2):117-124
对抽油杆材料35Mn2钢的机械性能和断裂韧度进行了大量的实验研究,并进行了可靠性分析.认为σsb,Ψ,δ均服从正态分布.对各参数进行了点估计和区间估计.为对抽油杆各部位、各种缺陷进行可靠性评定提供了依据.  相似文献   

20.
采用质量比为1∶1的十八烷基三甲基氯化铵与6-氨基己酸的混合溶液对蒙脱土进行复合有机化改性处理,制得层间距为1.83 nm的新型有机蒙脱土(OMMT),利用熔融共混法在双螺杆挤出机上制备了尼龙6-OMMT复合材料(简称复合材料),研究了OMMT含量对复合材料的机械性能和热性能的影响。通过X射线衍射、透射电子显微镜技术对复合材料的微观结构进行了表征。实验结果表明,与纯尼龙6相比,加入质量分数4%的OMMT后的复合材料的拉伸强度、弯曲强度和热变形温度分别提高了27.8%,37.2%,22℃;但缺口冲击强度和熔体流动指数有所下降。  相似文献   

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