共查询到20条相似文献,搜索用时 15 毫秒
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采用Mannich法对纯化木质素进行胺化改性,以提高其活泼氢数量和木质素的反应活性;然后以此作为部分聚乙二醇的替代物,将其与异氰酸酯反应合成PU(聚氨酯)胶粘剂。结果表明:胺化木质素中引入的氮含量约为2.64%,说明木质素的活性明显提高;当w(胺化木质素)=25%时,相应PU胶粘剂的湿胶接强度(1.53 MPa)达到GB/T 9846—2004标准中Ⅰ类胶合板的指标要求,并且其热稳定性能得以明显提高;胺化木质素可以取代部分聚乙二醇,其含量对胶粘剂的力学性能和热稳定性能影响显著。 相似文献
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Water is eco-friendly and safe; thus, it used as a blowing agent in the fabrication of water-blown polyurethane (PU) foam. However, water-blown PU foam may experience dimensional instability due to shrinkage of the cells inside the foam. In order to reduce cell shrinkage due to the loss of CO2 gas, vacuum formation is prevented in the closed-cell foam and the maximum reaction temperature must be raised to increase the degree of curing of the PU foam. In this study, two flame retardants, aluminum trihydrate (ATH) and magnesium dihydrate (MDH), were selected as additives to partially open the cells and increase the maximum reaction temperature. ATH and MDH were both effective for increasing the maximum foam reaction temperature and decreasing dimensional change. Notably, PU foams with 7.5 wt% ATH were the most dimensionally stable at both room temperature and high temperature. Moreover, the compressive strength and flexural strength of such foams were also improved compared to those of the foams without any additive. 相似文献
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聚氨酯胶粘剂的耐热性差,大大限制了其在高温环境下的应用。综述了聚氨酯降解过程和降解机制的研究进展,重点论述硬段、软段及交联密度对聚氨酯耐热性的影响以及提高聚氨酯胶粘剂耐热性的方法。 相似文献
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汽车用聚氨酯胶粘剂的研究进展 总被引:6,自引:0,他引:6
介绍了几种最常用的聚氨酯胶粘剂,如单组分湿固化聚氨酯挡风玻璃密封胶、粘接FRP和SMC材料用聚氨酯结构胶粘剂、汽车内饰用水性聚氨酯胶粘剂等在汽车制造和修理上的应用现状及各自的研究进展,展望了汽车用聚氨酯胶粘剂的未来发展前景。 相似文献
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Optimizing the lignin based synthesis of flexible polyurethane foams employing reactive liquefying agents 下载免费PDF全文
Jacopo Bernardini Irene Anguillesi Maria‐Beatrice Coltelli Patrizia Cinelli Andrea Lazzeri 《Polymer International》2015,64(9):1235-1244
The present work is focused on the optimization of a green process based on the employment of by‐products obtained from wood treatments as raw materials for producing flexible polyurethane foams. More specifically, lignin was employed in flexible polyurethane foams in order to partially replace the usual fossil polyols; therefore glycerol (GLY) and glycerin polyglycidyl ether (EJ 300) were used as the polyol fraction for lignin liquefaction. Polypropylene glycol triol was used as a chain extender in different ratios with liquefaction solvents, and polymeric diphenylmethane diisocyanate as an isocyanate fraction. Liquefaction of lignin was performed by microwave irradiation, thus reducing the processing time and energy required compared to present industrial production processes. All the foams were produced in controlled expansion through the adoption of a ‘one‐shot’ approach, using water as a blowing agent and with an isocyanate index (NCO/OH) of less than 100 to improve the flexibility of the foam. This approach allowed for the substitution of up to 12% of common petro derived polyol with commercial soda lignin. Finally, the foams were characterized, presenting properties that could be modulated as a function of lignin content, GLY/EJ 300 ratio and isocyanate index. The qualities of the foams were compatible with existing materials used for furniture and for the interiors of car seats and couches. © 2015 Society of Chemical Industry 相似文献
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研究了溶剂型聚氨酯鞋用胶粘剂,探索了合成的最优工艺条件,并进行了性能测试。胶粘剂采用PBA2000、BDO、TD180/20在溶剂丁酮下合成预聚体。最优条件为:扩链剂BDO与PBA摩尔比为0.4,异氰酸酯指数R控制在0.98-0.99范围,丁酮为首选溶剂,以二乙烯三胺和二丁基二月桂酸锡作复合催化剂,反应温度为75-85℃,反应时间为3h。合成的溶剂型聚氨酯胶粘剂具有良好的剥离强度和综合性能,添加(0.2-0.3)%的固化剂JQ-6能提高胶粘剂的最终剥离强度(20-30)%。 相似文献
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Xiaohua KongGuoguang Liu Jonathan M. Curtis 《International Journal of Adhesion and Adhesives》2011,31(6):559-564
A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100 °C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior. 相似文献
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采用异佛尔酮二异氰酸酯(IPDI)、聚四氢呋喃醚二醇2000(PTMG2000)为原料,二月桂酸二丁基锡、1,4-丁二醇和2,2-二羟甲基丙酸分别为催化剂、小分子扩链剂和亲水单体,制得水性聚氨酯预聚体(PPU);接着以丙烯酸甲酯、二乙醇胺和三羟甲基丙烷为原料合成了超支化聚(胺-酯)(HPAE);最后制备出不同HPAE含... 相似文献
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Moumita Kotal Suneel Kumar Srivastava Saraswathi Kesavapillai Manu Aravind Kumar Saxena Kailash Nath Pandey 《Polymer International》2013,62(5):728-735
The present work deals with the effect of stearate intercalated layered double hydroxide (St‐LDH) loadings on the morphological, mechanical, thermal, adhesive and flame retardant properties of polyurethane (PU)/St‐LDH nanocomposites prepared by the in situ polymerization method. X‐ray diffraction and transmission electron microscopy studies confirmed that exfoliation takes place at 3 wt% loading followed by intercalation at higher filler loadings in the PU matrix. The exfoliated structure has been further verified by atomic force microscopy. The measurements of stress‐strain, thermogravimetric analysis, dynamic mechanical analysis, lap shear strength and peel strength analysis showed that the nanocomposites containing 3 wt% St‐LDH exhibit excellent improvement in tensile strength (ca 175%) and log storage modulus (ca 14%), while PU/St‐LDH (5 wt%) possesses optimum improvement in glass transition temperature (ca 6 °C), lap shear strength (200%) and peel strength (130%) over neat PU. In addition, the gradual improvements in limiting oxygen index value with St‐LDH loading indicated the higher effectiveness in providing better barrier properties as well as better flame retardant behavior. Copyright © 2012 Society of Chemical Industry 相似文献
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湿固化聚氨酯热熔胶研究进展 总被引:4,自引:0,他引:4
概述了目前反应型湿固化聚氨酯热熔胶的应用和研究方向,介绍了改善热熔胶的初粘强度、韧性、耐热性等性能的方法,以及国内外在聚氨酯预聚体、增韧树脂、增粘树脂、催化剂、添加剂等方面取得的一些研究进展。 相似文献
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简要介绍了一种制备聚氨酯水分散体的方法,着重探讨了反应时间、反应温度及中和剂用量等因素对聚氨酯胶粘剂性能的影响。 相似文献