The effect of chemical admixtures and mineral additives on the properties of self-compacting mortars

Mortar serves as the basis for the workability properties of self-compacting concrete (SCC) and these properties could be assessed by self-compacting mortars (SCM). In fact, assessing the properties of SCM is an integral part of SCC design. The objective of this study was to evaluate the effectiveness of various mineral additives and chemical admixtures in producing SCMs. For this purpose, four mineral additives (fly ash, brick powder, limestone powder, and kaolinite), three superplasticizers (SP), and two viscosity modifying admixtures (VMA) were used. Within the scope of the experimental program, 43 mixtures of SCM were prepared keeping the amount of mixing water and total powder content (portland cement and mineral additives) constant. Workability of the fresh mortar was determined using mini V-funnel and mini slump flow tests. The setting time of the mortars, were also determined. The hardened properties that were determined included ultrasonic pulse velocity and strength determined at 28 and 56 days. It was concluded that among the mineral additives used, fly ash and limestone powder significantly increased the workability of SCMs. On the other hand, especially fly ash significantly increased the setting time of the mortars, which can, however, be eliminated through the use of ternary mixtures, such as mixing fly ash with limestone powder. The two polycarboxyl based SPs yield approximately the same workability and the melamine formaldehyde based SP was not as effective as the other two.     

Effects of mechanical properties of concrete constituents including active mineral admixtures on fatigue behaviours of high performance concrete

In order to explore the links between the macroscopic and microstructural characteristics of concrete with admixtures of active mineral additions, four series of concrete prisms, of mortar matrix prisms and mortar-aggregate Interfacial Transition Zone (ITZ) are prepared and tested under monotonic and cyclic loads. Five static mechanical parameters (compressive and bending strength, fracture energy, elastic modulus, Poisson ratio) and bending fatigue performance (fatigue life, critical maximum displacement and strain, fatigue damage) of such materials are experimentally evaluated. The results show that degradation laws of concrete properties under both monotonic and cyclic loads vary with the different cohesive strength ratio and elastic modulus ratio of ITZ and mortar matrix. The single or double additions of ground slag and fly ash with optimized mass fractions remarkably enhance the static and bending fatigue properties as well as change the failure mechanisms of concrete.     

Effect of mineral admixtures on formwork pressure of self-consolidating concrete

Owing to enhanced filling ability, self-consolidating concrete offers accelerated casting and superior quality control during construction. However, its high fluidity and high placement rate increase the lateral pressure on the formwork, necessitating an extensive supporting system to retain fresh mixtures in a desired shape. Current recommendations of formwork design for self-consolidating concrete adopt the concept of hydrostatic pressure, even though the measured pressure could be less than the recommended level. This study shows that mineral admixtures such as processed clays can appreciably lessen the formwork lateral pressure. In addition, the correlation between the formwork pressure response and the loss of slump flow is derived, providing an approximate method to estimate the reduction in formwork pressure.     

Fresh properties of self-compacting cold bonded fly ash lightweight aggregate concrete with different mineral admixtures

This paper presents the results of an experimental study on the fresh properties of the self-compacting lightweight concretes made with cold bond fly ash (FA) lightweight aggregates. Binary and ternary use of FA and silica fume (SF) blends have been investigated in the production of self-compacting cold bonded FA lightweight aggregate concretes (SCLWCs). A total of 9 SCLWC mixtures were proportioned having constant water-binder ratio of 0.35 and the total binder content of 550?kg/m³. The control mixture contained only Portland cement (PC) as the binder while the remaining mixtures incorporated binary and ternary blends of PC, FA, and SF. After mixing, the fresh properties of the SCLWC were tested for T ₅₀₀ slump flow time, slump-flow diameter, V-funnel flow time and L-box height ratio. The fresh properties of SCLWCs with and without mineral admixtures were also evaluated by statistical technique, namely GLM-ANOVA. The results indicated that the combination use of FA and SF together decreased the slump flow time and V-funnel flow time. L-box height ratio, on the other hand, improved significantly.     

炭纤维增强轻质矿粉混凝土的热电行为

炭纤维增强混凝土能用来感知温度,其因在于短炭纤维的P-型传导性引起的塞贝克(Seebeck)效应所致.通过测量添加炭纤维或矿质掺和物(飞灰、硅土粉)前后六种波特兰水泥基混凝土的热电功率,研究了炭纤维增强轻质混凝土热敏的能力及其矿质掺合物对Seebeck效应的影响.结果表明: 炭纤维增强轻质混凝土具有类似于炭纤维增强标准混凝土的Seebeck效应,只是Seebeck系数因掺合了矿粉而减低.掺有矿粉的炭纤维增强轻质混凝土可用作建筑物的热传感器.     

Plastic shrinkage cracking of concrete incorporating mineral admixtures and its mitigation

In recent years, there has been a rapid increase in the use of mineral admixtures for high performance and durable concrete. Plastic shrinkage cracking in such concretes is a serious concern in large surface area/volume applications. The present study has two objectives: firstly, to investigate the influence of incorporating fly ash and granulated blast furnace slag (GGBS) on the susceptibility to such cracking; and secondly, to assess the techniques, such as fibre and shrinkage reducing admixture (SRA) addition, and spraying of curing compounds, to mitigate the cracking. The results indicate that replacement of ordinary Portland cement (OPC) with fly ash and GGBS increases the possibility of plastic shrinkage cracking significantly, with higher severity as the replacement level increases; 30% replacement of OPC with fly ash and GGBS doubled and quadrupled the crack area, respectively, mainly due to higher binder finesses, and the delay of setting and strength gain. Among the fibres tested, polypropylene and polyester fibres, at the recommended dosages of about 0.9 kg/m³, completely eliminated cracking in the most affected concrete (i.e., with 30% GGBS) while the dosages of the polyacrylonitrile and glass fibres had to be increased to provide a higher volume fraction. Two glycol-based SRAs, and two curing compounds based on acrylic resin and methacrylate mitigated cracking by significantly reducing evaporation from the surface of concrete.     

Physical and pozzolanic action of mineral additions on the mechanical strength of high-performance concrete

Pozzolans play an important role when added to Portland cement because they usually increase the mechanical strength and durability of concrete structures. The most important effects in the cementitious paste microstructure are changes in pore structure produced by the reduction in the grain size caused by the pozzolanic reactions pozzolanic effect (PE) and the obstruction of pores and voids by the action of the finer grains (physical or filler effect). Few published investigations quantify these two effects. Twelve concrete mixtures were tested in this study: one with Portland cement (control), nine mixtures with 12.5%, 25% and 50% of replacement of cement by fly ash, rice husk ash and limestone filler; two with (12.5+12.5)% and (25+25)% of fly ash and rice husk ash. All the mixtures were prepared with water/binder ratios of 0.35, 0.50, and 0.65. The compressive strength for the samples was calculated in MPa per kg of cement. The remaining contents of calcium hydroxide and combined water were also tested. The results show that the pozzolanic and physical effects have increased as the mineral addition increased in the mixture, being higher after 91 days than after 28 days. When the results for the same strength values are compared (35 and 65 MPa), it was observed that the filler effect (FE) increased more than the pozzolanic effect. The PE was stronger in the binary and ternary mixtures prepared with rice husk ash in proportions of 25% or higher.     

Effect of mineral admixtures and steel fiber volume contents on the behavior of high performance fiber reinforced concrete

High Performance Fiber Reinforced Concrete (HPFRC) is a structural material with advanced mechanical properties. The structural design of HPFRC members is based on the post-cracking residual strength provided by the addition into the mix of the fibers. Moreover, the addition of different types of mineral admixtures influences the overall behavior of this material. In order to optimize the performance of HPFRC in structural members, it is necessary to evaluate the mechanical properties and the post-cracking behavior in a reliable way. As a result, an experimental study on six different sets of HPFRC specimens was carried out. The main parameters that varied were the fiber volume content and the types of mineral addition. The behavior in compression, in flexural tension and the shrinkage properties were evaluated and critically analyzed in order to give a guide for structural use.The results showed that by adding high fiber volume content and the Algerian blast furnace slag into the mix, the HPFRC material obtained has a very good performance and it is suitable for use in practice.     

Effect of admixtures on the setting times of high-strength concrete

The effect of silica fume (SF), metakaolin (MK), fly ash (FA) and ground granulated blast-furnace slag (GGBS) on the setting times of high-strength concrete has been investigated using the penetration resistance method (ASTM C 403). In addition, the effect of a shrinkage-reducing admixture (SRA) on the setting times of normal and high-strength concrete was also studied. The setting times of the high-strength concrete were generally retarded when the mineral admixtures replaced part of the cement. While the SRA was found to have negligible effect on the setting times of normal strength concrete, it exhibited a rather significant retarding effect when used in combination with superplasticiser in high-strength concrete. The inclusion of GGBS at replacement levels of 40% and greater resulted in significant retardation in setting times. In general, as replacement levels of the mineral admixtures were increased, there was greater retardation in setting times. However, for the concrete containing MK, this was only observed up to a replacement level of 10%.     

Use of mineral admixtures to improve the resistance of limestone cement concrete against thaumasite form of sulfate attack

In this work the effect of mineral admixtures on the thaumasite form of sulfate attack in limestone cement concrete is studied. Additionally, the effect of the type of sand (calcareous or siliceous) and the storage temperature is investigated. Limestone cement, containing 15% limestone, was used. Concrete specimens were prepared by replacing a part of cement with the studied minerals. The specimens were immersed in a 1.8% MgSO₄ solution and stored at 5 °C and 25 °C for 3 years. A well designed concrete made with limestone cement and fly ash, blastfurnace slag or metakaolin seems to have the ability to withstand thaumasite form of sulfate attack. The addition of natural pozzolana presented only a limited improvement of concrete’s sulfate resistance. The type of the sand and its cohesion with the cement paste has a remarkable effect on the performance of concrete at low temperature. Finally, no damage was observed in the specimens exposed to sulfate solution at 25 °C.     

Evaluation of thermodynamic properties of concrete substrates and cement slurries modified with admixtures

The study of the creation and the stability of the interface between concrete substrates and repair systems needs the knowledge of the thermodynamic properties of materials. The measurement of the surface free energies of liquids is realised by means of Wilhelmy plate method on reference liquid and repair products. In order to determine polar and dispersive components, it is necessary to measure the contact angle of these liquids and products on reference solid surfaces and on concrete, mortars and aggregates. Centrifuged solutions of repair product systems elements were prepared in order to measure surface free energies on pure liquids without solid particles in suspension. Evolution of properties versus time were also taken into account and analysed in comparison with well-known liquids and products.

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Résumé L'étude de la stabilité de l'interface entre un support en béton et un système de réparation nécessite la connaissance des propriétés thermodynamiques des matériaux. La mesure des énergies libres de surface des liquides est réalisée au moyen de la plaque de Wilhelmy sur des liquides de référence et des produits de réparation. Dans le but de déterminer les composantes polaires et dispersives de ces produits, il est nécessaire de mesurer les angles de contact que font ces liquides et produits sur des surfaces solides de référence. Des solutions centrifugées de produits intervenant dans les systèmes de réparation ont été préparées afin de mesurer les énergies libres de surface des liquides purs, en l'absence de particules solides en suspension. L'évolution de ces propriétés avec le temps est aussi prise en compte et analysée en comparaison avec des produits liquides et solides bien connus. Des conclusions sont tirées quant à l'utilité et la qualité de ces mesures pour la prédiction du comportement des matériaux durcis.

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Editorial Note Dr. Ir. Luc Courard is a RILEM Senior Member.     

Mix design and fresh properties for high-performance printing concrete

This paper presents the experimental results concerning the mix design and fresh properties of a high-performance fibre-reinforced fine-aggregate concrete for printing concrete. This concrete has been designed to be extruded through a nozzle to build layer-by-layer structural components. The printing process is a novel digitally controlled additive manufacturing method which can build architectural and structural components without formwork, unlike conventional concrete construction methods. The most critical fresh properties are shown to be extrudability and buildability, which have mutual relationships with workability and open time. These properties are significantly influenced by the mix proportions and the presence of superplasticiser, retarder, accelerator and polypropylene fibres. An optimum mix is identified and validated by the full-scale manufacture of a bench component.     

Evaluation of mineral admixtures on the viewpoint of chloride ion migration through mortar

Recently, it has been said that deterioration of concrete structures occurs due to migration of ions, such as Cl⁻ or Na⁺, through concrete. In addition, some electrochemical methods which control migration properties through concrete, like desalination or re-alkalization, are becoming more important. However, the mechanisms of ion migration, in electric fields, through concrete are not well understood. Moreover, the effects of mineral admixtures, such as fly ash, silica fume and ground-granulated blast furnace slag on ion migration through concrete have not been closely investigated. From this viewpoint, for the evaluation of mineral admixtures, the properties of chloride ion migration through mortar containing fly ash, silica fume and ground-granulated blast furnace slag have been investigated.     

Fracture mechanical properties of high-performance concrete—Influence of silica fume

High-performance concrete and high-quality ordinary concrete, with or without silica fume, were tested for mechanical and fracture mechanical properties. Testing was performed at 28 days and 2 years. Ten percent silica fume resulted in a 20 to 25% increase in the direct tensile strength and a 10 to 20% increase in flexural and compressive strength, but had little effect on the dynamic modulus of elasticity. The brittleness appeared to increase with the presence of silica fume.

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Résumé Les propriétés mécaniques de la rupture ont été testées sur des bétons de hautes performances et sur des bétons ordinaires de haute qualité, avec ou sans fumée de silice. Les essais ont été effectués à 28 jours et à 2 ans. L’ajout de dix pour cent de fumée de silice a pour effet l’augmentation de la résistance en traction directe de 20 à 25% ainsi que l’augmentation des résistances en flexion et en compression de l’ordre de 10 à 20%, mais a peu d’effet sur le module d’élasticité dynamique. Par ailleurs, la fragilité du béton est accrue en présence de fumée de silice.

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Editorial Note Dr. Olafur Wallevik is a RILEm Senior Member. He participates in RILEM TCs 145-WSM (Workability of special concrete mixes) and 174-SCC (Self-Compacting Concrete) as well as in RILEM TC 181-EAS (Early age shrinkage induced stresses and cracking in cementitious systems) as a Corresponding Member.     

The effect of a new generation surface-applied organic inhibitor on concrete properties

The influence of a new organic surface-applied corrosion inhibitor (SACI) on selected concrete properties is studied including compressive strength, tensile strength, steel–concrete bond strength, permeability, drying shrinkage, and freeze–thaw resistance. The inhibitor is an aminoalcohol-based (AMA) corrosion inhibitor and it is applied on the hardened concrete surface. The results show that the inhibitor can be used safely and it does not have any significant harmful effect on the properties of hardened concrete and it improves some properties of concrete with its pore-blocking effect.     

Effects of mineral admixtures on fresh and hardened properties of self-compacting concretes: binary,ternary and quaternary systems

The paper presented herein investigates the effects of using supplementary cementitious materials in binary, ternary, and quaternary blends on the fresh and hardened properties of self-compacting concretes (SCCs). A total of 22 concrete mixtures were designed having a constant water/binder ratio of 0.32 and total binder content of 550 kg/m³. The control mixture contained only portland cement (PC) as the binder while the remaining mixtures incorporated binary, ternary, and quaternary cementitious blends of PC, fly ash (FA), ground granulated blast furnace slag (GGBFS), and silica fume (SF). After mixing, the fresh properties of the concretes were tested for slump flow time, L-box height ratio, V-funnel flow time, setting time, and viscosity. Moreover, compressive strength, ultrasonic pulse velocity, and electrical resistivity of the hardened concretes were measured. Test results have revealed that incorporating the mineral admixtures improved the fresh properties and rheology of the concrete mixtures. The compressive strength and electrical resistivity of the concretes with SF and GGBFS were much higher than those of the control concrete.