共查询到19条相似文献,搜索用时 109 毫秒
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采用电化学阻抗谱(EIS)研究了由水性无机富锌底漆、环氧中间漆和氯化橡胶面漆3种涂料配套而成的3种不同涂层体系在3.5%NaCl溶液中的电化学腐蚀行为,考察了氯化橡胶面漆、水性无机富锌底漆/氯化橡胶面漆、水性无机富锌底漆/环氧中间漆/氯化橡胶面漆这3种涂层体系的阻抗谱在浸泡过程中的演化并据此比较了3种涂层体系的防护性能。结果表明,两涂层体系的防护性能比单涂层的还要差,三复合涂层体系的防护性能最好。根据涂层腐蚀电化学阻抗谱特征推测,中间漆在三复合涂层体系中起到了使底漆和面漆结合更加紧密的桥梁作用。 相似文献
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首先提出一种相对简单的方法对无机涂层材料进行改性,即在处理的铝合金表面制备水性无机涂层,然后在无机涂层表面二次喷涂KH-550改性溶胶,对其进行改性,再经烘烤制备了有机改性无机涂层.对二次喷涂KH-550改性溶胶的一些因素对涂层表面性能影响的研究表明KH-550用量≥20%,能明显提高无机涂层的附着力、耐冲击性、耐水性等理化性能.对二次喷涂后涂层的微观形貌和接触角测试结果表明,在KH-550改性溶胶中引入无机纳米或超细粉体,获得了致密、平整的多功能涂层.最后通过对所提出方法的原理探讨及实验结果的分析,确定二次喷涂KH-550溶胶改性无机涂层材料,制备有机改性无机涂层的方法可行. 相似文献
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有机膨胀型钢结构防火涂料缺点是涂层中有机物易分解,且遇火时释出有毒物质。无机膨胀型钢结构防火涂料采用无机低温发泡层和高温发泡层的复合泡层,解决了火灾中钢结构前期升温快和后期阻火涂层熔问题,综合性能好。文中探讨了无机复合泡层梯次发泡机理,涂料配方与涂层结构对防火涂层的阻火隔热性能的影响。 相似文献
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This paper focuses on the structure and corrosion behavior of 316L stainless steel coated by inorganic ZrO2, hybrid ZrO2–PMMA, and combined inorganic–hybrid films. The coatings were deposited by a particulate sol–gel spin-coating route, using carboxymethyl cellulose as a nanoparticle dispersant. The electrochemical evaluations were conducted in a simulated body fluid, via potentiodynamic polarization and impedance spectroscopic experiments. According to the results, the hybrid coating presented a better corrosion protection compared to the inorganic coating, due to a lesser density of structural defects. However, the best corrosion resistance was found for a combined coating which consists of an inorganic bottom layer and a hybrid top layer, due to a desirable compromise of good adhesion and low defect density. 相似文献
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研究了无机、有机、复合光亮剂对高磷化学镀镍镀层外观、表面微观形貌、沉积速度、磷含量、孔隙率及耐蚀性的影响。试验证明:添加无机光亮剂时,镀层光亮,但存在微孔结构,导致孔隙率升高,耐蚀性大幅下降;添加有机光亮剂时,镀层光亮性略有下降,但镀层均匀性好,缺陷少;而复合光亮剂则可以实现较理想的效果,其镀层外观光亮,表面平整细致,沉积速度快,整体性能优良,复合光亮剂组成为:2mg/L Ce(SO4)2、3 mg/LTe(SO4)2、30 mg/L C6H5SO2Na、2 mg/L N,N-二乙基丙炔胺(DEP)。 相似文献
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To improve the corrosion protection of sol–gel derived hybrid silica/epoxy coatings containing boehmite nanoparticles, inorganic corrosion inhibitor was introduced into the coating via encapsulation in the nanoparticles. The morphology and chemical structure of the deposited films were studied by Scanning Electron Microscopy (SEM) and Fourier Transformed Infra-red Spectroscopy (FT-IR). The anticorrosion and self-healing properties of the coatings were evaluated by Electrochemical Impedance Spectroscopy (EIS). The high corrosion resistance performance of such coatings is due to the presence of encapsulated cerium nitrate corrosion inhibitor that can be released at the defects within the coating, hindering the corrosion reactions at defective sites. 相似文献
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《Progress in Organic Coatings》2011,70(4):384-391
To improve the corrosion protection of sol–gel derived hybrid silica/epoxy coatings containing boehmite nanoparticles, inorganic corrosion inhibitor was introduced into the coating via encapsulation in the nanoparticles. The morphology and chemical structure of the deposited films were studied by Scanning Electron Microscopy (SEM) and Fourier Transformed Infra-red Spectroscopy (FT-IR). The anticorrosion and self-healing properties of the coatings were evaluated by Electrochemical Impedance Spectroscopy (EIS). The high corrosion resistance performance of such coatings is due to the presence of encapsulated cerium nitrate corrosion inhibitor that can be released at the defects within the coating, hindering the corrosion reactions at defective sites. 相似文献
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无机粉体材料的表面处理方法 总被引:1,自引:0,他引:1
无机粉体材料的表面包覆及改性是近年来冶金及材料界为寻求制备新型材料而涌现的一个新的研究领域。粉体材料经无机包覆后,表面可具有新的物理化学性质,制成的复合粉体可用于陶瓷、催化、防腐、颜料、粘结、电子等行业。本文对无机粉体材料的表面处理方法进行了详细综述。 相似文献
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Organic–inorganic hybrid nanocomposite coatings contain inorganic particles that are dispersed in organic phase in nanometric dimensions. Ceria and zirconia colloidal dispersions are uniformly distributed in the epoxy silica-based hybrid nanocomposite by sol–gel method and coated on 1050 aluminum alloy substrate with spin-coating technique. The hybrid sol is prepared by organic–inorganic precursors formed by hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane and tetraethylorthosilicate (TEOS) in acidic solution using bisphenol A as networking agent and 1-methylimidazole as initiator in the presence of various ratios of ZrO2 and CeO2 colloidal nanoparticles. Particle size distribution, surface morphology and inorganic components distribution were determined by scanning electron microscopy (SEM) and EDXA techniques. SEM and Si, Zr, Ce mapping micrographs proved the uniform distribution of nanoparticles in the coatings. Transmission electron microscopy indicated that the nanoparticles dimension stay at the nanoscale level. The glass transition temperature (T g) and loss properties (damping) of coatings were evaluated by dynamic mechanical thermal analysis. The corrosion protection of the coatings on the 1050 AA substrate was studied by potentiodynamic measurements. The results indicated that by introducing ceria nanoparticles in 1:1 molar ratio to TEOS in coating composition, corrosion protection was improved. However, the simultaneous presence of two nanoparticles (i.e., ceria and zirconia in 1:1 molar ratio) in the coating compositions increased the corrosion protection efficiency up to 99.8 %. The multiple glass transitions and shifting to higher and wide range of temperatures by adding ceria and zirconia nanoparticles indicated a better network interaction between inorganic nanoparticles and organic molecular chains which also led to better corrosion protection of the coating in this composition. 相似文献