Diagnosis of Electron, Vibrational and Rotational Temperatures in an Ar/N2 Shock Plasma Jet Produced by a Low Pressure DC Cascade Arc Discharge

In this paper,a low pressure Ar/N2 shock plasma jet with clearly multicycle alternating zones produced by a DC cascade arc discharge has been investigated by an emission spectral method combined with Abel inversion analysis.Plasma emission intensity,electron,vibrational and rotational temperatures of the shock plasma have been measured in the expansion and compression zones.The results indicate that the ranges of the measured electron temperature,vibrational temperature and rotational temperature are 1.1 eV to 1.6 eV,0.2 eV to 0.7 eV and 0.19 eV to 0.22 eV,respectively,and it is found for the first time that the vibrational and rotational temperatures increase while the electron temperature decreases in the compression zones.The electron temperature departs from the vibrational and the rotational temperatures due to non-equilibrium plasma efects.Electrons and heavy particles could not completely exchange energy via collisions in the shock plasma jet under the low pressure of 620 Pa or so.     

Atmospheric air dielectric barrier discharge excited by nanosecond pulse and AC used for improving the hydrophilicity of aramid fibers

In this paper, a long line-shape dielectric barrier discharge excited by a nanosecond pulse and AC is generated in atmospheric air for the purpose of discussing the uniformity, stability and ability of aramid fiber treatment. The discharge images, waveforms of current and voltage,optical emission spectra, and gas temperatures of both discharges are compared. It is found that nanosecond pulsed discharge has a more uniform discharge morphology, higher energy efficiency and lower gas temperature, which indicates that nanosecond pulsed discharge is more suitable for surface modification. To reduce the water contact angle from 96° to about 60°, the energy cost is only about 1/7 compared with AC discharge. Scanning electron microscopy,Fourier transform infrared spectroscopy and x-ray photoelectron spectroscopy are employed to understand the mechanisms of hydrophilicity improvement.     

Electrical characters and optical emission spectra of VBD coupled SBD excited by sine AC voltage in atmospheric air

In this paper,volume coupled surface barrier discharge(V-SBD) with three structures possessing different volumes is excited by sine AC power in atmospheric air.Discharge images,waveforms of applied voltage and discharge current,and optical emission spectra simulating rotational and vibrational temperatures are recorded and analyzed.The effects of applied voltage on emission intensities of N_2(C~3Π_u→ B~3Π_g) and N_2~+(B~2∑_u~+ → X~2E_g~+),and rotational and vibrational temperatures are investigated.The results show that as applied voltage rises,emission intensities and rotational temperatures increase while vibrational temperatures decrease.In addition it is found that,as applied voltage varies,the rotational temperature of surface discharge changes faster than that of volume discharge.     

Spectroscopic study of bipolar nanosecond pulse gas-liquid discharge in atmospheric argon

Atmospheric gas-liquid discharge with argon as a working gas is presented by employed nanosecond pulse power. The discharge is presented in a glow-like mode. The discharge powers are determined to be less than 1 W, and remains almost constant when the discharge duration time increases. Bountiful active species are determined by capturing optical emission spectra,and their main generation processes are also discussed. The plasma gas temperature is calculated as 350 K by comparing the experimental spectra and the simulated ones of N_2(C~3Ⅱ_g→B~3Ⅱ_g, Δv =-2). The time resolved vibrational and rotational temperature is researched to present the stability of discharge when pulse voltage and discharge duration vary.The electron density is determined to be 10~(16) cm~(-3) according to the Stark broadening effect of the H_α line.     

Volume added surface barrier discharge plasma excited by bipolar nanosecond pulse power in atmospheric air: optical emission spectra influenced by gap distance

In this paper, volume barrier discharge with different gap distances is added on the discharge border of high-voltage electrode of annular surface barrier discharge for generating volume added surface barrier discharge (V-SBD) excited by bipolar nanosecond high-voltage pulse power in atmospheric air. The excited V-SBDs consist of surface barrier discharge (d=0 mm) and volume added surface barrier discharges (d=2 mm and 3 mm). The optical emission spectra are recorded for calculating emission intensities of N₂ (C ³Ⅱ_u →B³Π_g ) and N₂⁺ (B ²Σ_u⁺ → X ²Σ_g⁺ ), and simulating rotational and vibrational temperatures. The influences of gap distance of V-SBD on emission intensity and plasma temperature are also investigated and analyzed. The results show that d=0 mm structure can excite the largest emission intensity of N ₂ (C ³ Π_u →B ³Π_g ), while the existence of volume barrier discharge can delay the occurrence of the peak value of the emission intensity ratio of N₂⁺ (B ²Σ_u⁺ → X ²Σ_g⁺ )/N ₂(C³Π_u →B³Π_g ) during the rising period of the applied voltage pulse and weaken it during the end period. The increasing factor of emission intensity is effected by the pulse repetition rate. The d=3 mm structure has the highest threshold voltage while it can maintain more emission intensity of N₂(C³ Π _u →B ³Π_g ) than that of d=2 mm structure. The structure of d=2 mm can maintain more increasing factor than that of the d=3 mm structure with varying pulse repetition rate. Besides, the rotational temperatures of three V-SBD structures are slightly affected when the gap distance and pulse repetition rate vary. The vibrational temperatures have decaying tendencies of all three structures with the increasing pulse repetition rate.     

Effects of O2 addition on the plasma uniformity and reactivity of Ar DBD excited by ns pulsed and AC power supplies

Dielectric barrier discharges (DBDs) have been widely used in ozone synthesis, materials surface treatment, and plasma medicine for their advantages of uniform discharge and high plasma-chemical reactivity. To improve the reactivity of DBDs, in this work, the O₂ is added into Ar nanosecond (ns) pulsed and AC DBDs. The uniformity and discharge characteristics of Ar ns pulsed and AC DBDs with different O₂ contents are investigated with optical and electrical diagnosis methods. The DBD uniformity is quantitatively analyzed by gray value standard deviation method. The electrical parameters are extracted from voltage and current waveforms separation to characterize the discharge processes and calculate electron density n_e. The optical emission spectroscopy is measured to show the plasma reactivity and calculate the trend of electron temperature T_e with the ratio of two emission lines. It is found that the ns pulsed DBD has a much better uniformity than AC DBD for the fast rising and falling time. With the addition of O₂, the uniformity of ns pulsed DBD gets worse for the space electric field distortion by O₂⁻, which promotes the filamentary formation. While, in AC DBD, the added O₂ can reduce the intensity of filaments, which enhances the discharge uniformity. The ns pulsed DBD has a much higher instantaneous power and energy efficiency than AC DBD. The ratio of Ar emission intensities indicates that the T_e drops quickly with the addition of O₂ both ns pulsed and AC DBDs and the ns pulsed DBD has an obvious higher T_e and n_e than AC DBD. The results are helpful for the realization of the reactive and uniform low temperature plasma sources.     

Simulation of the spatio-temporal evolution of the electron energy distribution function in a pulsed hollow-cathode discharge

This article presents the 2D simulation results of a nanosecond pulsed hollow cathode discharge obtained through a combination of fluid and kinetic models. The spatio-temporal evolution of the electron energy distribution function(EEDF) of the plasma column and electrical characteristics of the nanosecond pulsed hollow cathode discharge at a gas pressure of 5 Torr are studied. The results show that the discharge development starts with the formation of an ionization front at the anode surface. T...     

Spectroscopic diagnosis of plasma in atmospheric pressure negative pulsed gasliquid discharge with nozzle-cylinder electrode

The plasma characteristics of a gas-liquid phase discharge reactor were investigated by optical and electrical methods.The nozzle-cylinder electrode in the discharge reactor was supplied witha negative nanosecond pulsed generator.The optical emission spectrum diagnosis revealed that OH(A~2∑~+?→?X~2Π,306–309 nm),N~3_2(CΠ→B~3Π_g,337 nm),O(3p~5p→3s~5s~0,777.2 nm)and O(3p~3p→3s~3s~0,844.6 nm)were produced in the discharge plasma channels.The electron temperature(T_e)was calculated from the emission relative intensity ratio between the atomic O 777.2 nm and 844.6 nm,and it increased with the applied voltage and the pulsed frequency and fell within the range of 0.5–0.8 e V.The gas temperature(T_g)that was measured by Lifbase was in a range from 400 K to 600 K.     

Investigation on plasma characteristics in a laser ablation pulsed plasma thruster by optical emission spectroscopy

In order to further improve the propulsion performance of pulsed plasma thrusters for space micro propulsion, a novel laser ablation pulsed plasma thruster is proposed, which separated the laser ablation and electromagnetic acceleration. Optical emission spectroscopy is utilized to investigate the plasma characteristics in the thruster. The spectral lines at different times,positions and discharge intensities are experimentally recorded, and the plasma characteristics in the discharge channel are concluded through analyzing the variation of spectral lines. With the discharge energy of 24 J, laser energy of 0.6 J and the use of aluminum propellant, the specific impulse and thrust efficiency reach 6808 s and 70.6%, respectively.     

Experimental study on nanosecond pulsed pin-to-plate discharge in supersonic air flow

Development of magnetohydrodynamic acceleration technology is expected to improve wind tunnel simulation capability and testing capability. The underlying premise is to produce uniform and stable plasma in supersonic air flow, and gas discharge is an effective way to achieve this. A nanosecond pulsed discharge experimental system under supersonic conditions was established, and a pin-to-plate nanosecond pulsed discharge experiment in Mach 2 air flow was performed to verify that the proposed method produced uniform and stable plasma under supersonic conditions. The results show that the discharge under supersonic conditions was stable overall, but uniformity was not as good as that under static conditions. Increasing the number of pins improved discharge uniformity, but reduced discharge intensity and hence plasma density. Under multi-pin conditions at 1000 Hz, the discharge was almost completely corona discharge, with the main current component being the displacement current, which was smaller than that under static conditions.     

Time-resolved spectroscopy of femtosecond laser-induced Cu plasma with spark discharge

The combination of spark discharge and laser-induced breakdown spectroscopy (LIBS) is called spark discharge assisted LIBS. It works under laser-plasma triggered spark discharge mode, and shows its ability to enhance spectral emission intensity. This work uses a femtosecond laser as the light source, since femtosecond laser has many advantages in laser-induced plasma compared with nanosecond laser, meanwhile, the study on femtosecond LIBS with spark discharge is rare. Time-resolved spectroscopy of spark discharge assisted femtosecond LIBS was investigated under different discharge voltages and laser energies. The results showed that the spectral intensity was significantly enhanced by using spark discharge compared with LIBS alone. And, the spectral emission intensity using spark discharge assisted LIBS increased with the increase in the laser energy. In addition, at low laser energy, there was an obvious delay on the discharge time compared with high laser energy, and the discharge time with positive voltage was different from that with negative voltage.     

Sputtering of graphite in pulsed and continuous arc and spark discharges

The environment that leads to the sputtering of graphite electrodes and formation of carbonaceous discharge has been studied with emission spectroscopy. Population level densities, excitation & vibrational temperatures and electron densities have been obtained from a set of three ion sources. The sources operate in continuous and pulsed discharge modes. The sputtered species include monatomic, diatomic and higher carbon clusters. The main sputtered species are excited and ionized C₁ (CI, CII, respectively) and C₂. In the continuous arc discharge the vibrational temperature derived from the Swan band of C₂ is ∼10,000 K, whereas, in the pulsed arc the excitation temperature of Neon is ∼11,000 K. The spark discharge yields an average excitation temperature of CI and NI ∼ 5500 K.     

Investigation on discharge characteristics of a coaxial dielectric barrier discharge reactor driven by AC and ns power sources

A coaxial dielectric barrier discharge(DBD) reactor with double layer dielectric barriers has been developed for exhaust gas treatment and excited either by AC power or nanosecond(ns)pulse to generate atmospheric pressure plasma. The comparative study on the discharge characteristics of the discharge uniformity, power deposition, energy efficiency, and operation temperature between AC and ns pulsed coaxial DBD is carried out in terms of optical and electrical characteristics and operation temperature for optimizing the coaxial DBD reactor performance. The voltages across the air gap and dielectric layer and the conduction and displacement currents are extracted from the applied voltages and measured currents of AC and ns pulsed coaxial DBDs for the calculation of the power depositions and energy efficiencies through an equivalent electrical model. The discharge uniformity and operating temperature of the coaxial DBD reactor are monitored and analyzed by optical images and infrared camera. A heat conduction model is used to calculate the temperature of the internal quartz tube. It is found that the ns pulsed coaxial DBD has a much higher instantaneous power deposition in plasma, a lower total power consumption, and a higher energy efficiency compared with that excited by AC power and is more homogeneous and stable. The temperature of the outside wall of the AC and ns pulse excited coaxial DBD reaches 158 ℃ and 64.3 ℃ after 900 s operation, respectively.The experimental results on the comparison of the discharge characteristics of coaxial DBDs excited by different powers are significant for understanding of the mechanism of DBDs,reducing energy loss, and optimizing the performance of coaxial DBD in industrial applications.     

Comparison of sample temperature effect on femtosecond and nanosecond laser-induced breakdown spectroscopy

In this paper, we investigated the emission spectra of plasmas produced from femtosecond and nanosecond laser ablations at different target temperatures in air. A brass was selected as ablated target of the experiment. The results indicated that spectral emission intensity and plasma temperature showed similar trend for femtosecond and nanosecond lasers, and the two parameters were improved by increasing the sample temperature in both cases. Moreover, the temperature of nanosecond laser-excited plasma was higher compared with that of femtosecond laser-excited plasma, and the increase of the plasma temperature in the case of nanosecond laser was more evident. In addition, there was a significant difference in electron density between femtosecond and nanosecond laser-induced plasmas. The electron density for femtosecond laser decreased with increasing the target temperature, while for nanosecond laser, the electron density was almost unchanged at different sample temperatures.     

Electron-Vibrational Energy Exchange in Nitrogen-Containing Plasma: a Comparison Between an Analytical Approach and a Kinetic Model

This paper investigates the electron-vibrational (e-V) energy exchange in nitrogencontaining plasma,which is very efficient in the case of gas discharge and high speed flow.Based on Harmonic oscillator approximation and the assumption of the e-V relaxation through a continuous series of Boltzmann distributions over the vibrational states,an analytic approach is derived from the proposed scaling relation of e-V transition rates.A full kinetic model is then investigated by numerically solving the state-to-state master equation for all vibrational levels.The analytical approach leads to a Landau-Teller (LT)-type equation for relaxation of vibrational energy,and predicts the relaxation time on the right order of magnitude.By comparison with the kinetic model,the LT-type equation is valid in typical electron temperatures in gas discharge.However,the analytical approach is not capable of describing the vibrational distribution function during the e-V process in which a full kinetic model is required.     

Study the Influence of the Bank Energy on the Dynamical Pinch in Plasma Focus

The plasma focus discharge can generate, accelerate and pinch the plasma up to high density and temperature in a pulsed mode manner. Applications aspects of discharge require high efficiency of the fusion products. This situation acquires optimized operational parameters for the proper discharge. In this article, we have studied the plasma parameters and neutron performance dependency on bank energy. First, analytical expressions are derived from the equation of motion for the plasma particles in the radial phase. Then, the related fusion neutrons, both thermal and non-thermal, together with the discharge anisotropy in the low pressure regimes for the ‘Dena’ plasma focus device as function of bank energy are presented. The analytic models are compared with experimental data.     

Properties of the acrylic acid polymers obtained by atmospheric pressure plasma polymerization

Plasma polymers of acrylic acid were obtained using an atmospheric pressure discharge system. The plasma polymerization reactor uses a dielectric barrier discharge, with the polyethylene terephthalate dielectric acting as substrate for deposition. The plasma was characterized by specific electrical measurements, monitoring the applied voltage and the discharge current. Based on the spatially resolved optical emission spectroscopy, we analyzed the distribution of the excited species in the discharge gap, specific plasma temperatures (vibrational and gas temperatures) being calculated with the Boltzmann plot method. The properties of the plasma polymer films were investigated by contact angle measurements, infrared and UV-Vis spectroscopy, scanning electron microscopy. The films produced by plasma polymerization at atmospheric pressure showed a hydrophilic character, in correlation with the strong absorbance of OH groups in the FTIR spectrum. Moreover, the surface of the plasma polymers at micrometric scale is smooth and free of defects without particular features.     

Kinetic simulation of the transition from a pulse-modulation microwave discharge to a continuous plasma

The generation of a very strong peak current in the first period(PCFP) in a pulse-modulated microwave discharge has been discussed in previous studies. In this paper we focus on the transition process from a pulsed discharge to a fully continuous one driven by the pulsed microwave power source by means of a kinetic model. The computational results show that by increasing the duty cycle or voltage modulation rate(VMR), the discharge eventually becomes fully continuous and PCFP can no longer be observed. In the transition process, the distributions of the electric field, electron energy probability function(EEPF) and plasma density are discussed according to the simulation data, showing different discharge structures. The simulations indicate that many high-energy electrons with electron energy larger than 20 eV and low-energy electrons with electron energy less than 3 eV could be generated in a pulsed microwave discharge, together with a reversal electric field formed in the anode sheath when PCFP occurs. However, only medium-energy electrons could be observed in a fully continuous discharge. Therefore, by investigating the transition process the pulse-modulated microwave discharges can be further optimized for plasma applications at atmospheric pressure.     

Experimental study on plasma actuation characteristics of nanosecond pulsed dielectric barrier discharge

Combining high-speed schlieren technology and infrared imaging technology, related research has been carried out on the influence of parameters such as actuation voltage, repetition frequency, and electrode size of an actuator on the discharge characteristics, induced flow field characteristics, and thermal characteristics of nanosecond pulsed dielectric barrier discharge. The results show that increasing the value of the actuation voltage can significantly increase the actuation intensity, and the plasma discharge area is significantly extended. Increasing the repetition frequency can increase the number of discharges per unit time. Both will cause more energy input and induce more changes in the flow field. The effect of temperature rise is more significant. The width of the covered electrode will affect the potential distribution during the discharge process, which in turn will affect the extension process of the plasma discharge filament. Under the same actuation intensity, the wider the covered electrode, the larger range the induced flow field and temperature rise is. Preliminary experimental analyses of high-frequency actuation characteristics, temperature field characteristics, flow field characteristics and actuation parameter settings provide support for the parameter selection and partial mechanism analysis of plasma anti-icing.     

Spectral Characteristics of Laser-Induced Graphite Plasma in Ambient Air

An experimental setup of laser-induced graphite plasma was built and the spectral characteristics and properties of graphite plasma were studied. From the temporal behavior of graphite plasma, the duration of CN partials(B~2∑~+→X~2∑~+) emission was two times longer than that of atomic carbon, and all intensities reached the maximum during the early stage from0.2 μs to 0.8 μs. The electron temperature decreased from 11807 K to 8755 K, the vibration temperature decreased from 8973 K to 6472 K, and the rotational temperature decreased from7288 K to 4491 K with the delay time, respectively. The effect of the laser energy was also studied, and it was found that the thresholds and spectral characteristics of CN molecular and C atomic spectroscopy presented great differences. At lower laser energies, the electron excited temperature, the electron density, the vibrational temperature and rotational temperature of CN partials increased rapidly. At higher laser energies, the increasing of electron excited temperature and electron density slow down, and the vibrational temperature and rotational temperature even trend to saturation due to plasma shielding and dissociation of CN molecules. The relationship among the three kinds of temperatures was T_(elec)T_(vib)T_(rot) at the same time. The electron density of the graphite plasma was in the order of 10~(17)cm~(-3) and 10~(18)cm~(-3).