含尖晶石空心球的刚玉-尖晶石材料制备及性能

采用电熔-喷吹法制备了镁铝尖晶石空心球,结合空心球结构与性质特征,将其引入刚玉-尖晶石材料,对比研究了不同粒径空心球对材料显微结构、力学强度及隔热能力的影响.结果 表明:制备的空心球球形度高,球壁由单层或多层镁铝尖晶石晶粒镶嵌结合而成,球体的抗压能力取决于球壁厚度及其均匀性.降低粒径、引入复合粒径空心球,通过球体之间的...     

含Cr管线钢的力学性能和耐蚀性能

基于国内油气工业管线应用需要,采用控轧控冷工艺,研制了强韧性匹配优良的2%Cr低合金管线钢,并测试了其组织和力学性能.以针状铁素体和多边形铁素体为主的含2%Cr管线钢具有良好的强韧性组合.采用高温高压冷凝釜模拟湿气管线中的CO₂顶部腐蚀环境试验方法,研究含2%Cr低合金管线钢的抗CO₂顶部腐蚀性能.相较于传统管线钢,添加2%Cr后,其CO₂腐蚀产物膜是一层连续、致密的富Cr胶泥状非晶态产物膜,从而提高了其抗CO₂顶部腐蚀性能.     

造孔剂法制备多孔镍及其性能

添加氯化钠作为造孔剂,采用粉末冶金方法制备高孔隙率小孔径多孔镍。对多孔镍的孔隙特征、力学性能进行了研究。结果表明：通过调整造孔剂比例、烧结温度及冷却时间工艺参数,可以制备出孔隙率为60.84%～64.92%,平均孔径为0.20～8.80μm,小于20μm孔径占比为92.0%～96.1%,压缩屈服强度为8.9～13.4 MPa的多孔镍;随着烧结后冷却时间的增加,平均孔径减小,压缩强度呈增加趋势。     

Preparation of Rare Earth Doped Alumina-Siloxane Gel and Its ER Effect

Poly(methyl methacrylate) (PMMA) was used to wrap alumina-siloxane sol through emulsion polymerization. A kind of suspensions with notable ER effect was produced by fully mixing the prepared microcapsule with silicon oil. Meanwhile a series of PMMA wrapped alumina - siloxane gel doped with rare earths was obtained and its ER effect was tested, like viscosity of different rare earth ion doped samples in different powder concentrations and at different temperatures, at the same time, leak current density and dielectric constant were measured. Resuits show that the ER effect of this suspension is remarkable, and its stability is much better. The condition of emulsion polymerization and the mechanism of effect are discussed.     

Preparation and properties of polymeric colloidal crystals containing rare earth complexes

Rare earth organic complexes were introduced into the polymerization system, and the polymeric colloidal nanospheres containing rare earth complexes were prepared by emulsion copolymerization. The characterization results indicated that the polymeric spheres were small at nanometer size and the diameter was monodisperse, particularly the nanospheres possessed good fluorescent properties. Moreover, the polymeric nanospheres were self-assembled to fabricate the colloidal crystals, which were three-dimensional regular multilayer films. The polymeric colloidal crystal films exhibited excellent luminescent and novel optical properties.     

12%SiCp/Al复合材料制备工艺及力学性能研究

对碳化硅颗粒进行表面氧化酸洗处理，采用粉末冶金加热挤压工艺制备了12％SiCp／Al（体积分数）复合材料。利用金相显微镜和电镜对微观组织进行了观测，拉伸试验测试复合材料的力学性能。试验结果表明：SiC颗粒在铝基体中分布比较均匀；T6热处理条件下12％SiCp／Al复合材料的屈服强度和抗拉强度分别约为472．4MPa、525．7MPa，伸长率为6．5％，弹性模量为92．7GPa。     

喷射成形含锰高强Al-Zn-Mg-Cu的组织和性能

利用喷射成形和热挤压的方法制备了含锰为2%(质量分数)的高强铝合金Al-8.8Zn-2.9Mg-1.6Cu合金,用X射线衍射(XRD)、光学显微镜(OM)和扫描电镜(SEM)和透射电镜(TEM)等方法研究了铝合金的微观组织,并进行了力学性能测试.研究结果表明:喷射成形制备的含锰铝合金经过热挤压和固溶处理后,基体组织为细小均匀的再结晶晶粒组织,平均尺寸约8μm.MnAl6颗粒在喷射沉积过程中沿晶界析出,经过热挤压后,尺寸大的颗粒破碎,大部分的颗粒则沿挤压方向产生一定的塑性变形.固溶处理对MnAl6颗粒尺寸的影响不明显,但棒状/片状颗粒的边角处发生球化,有利于降低诱发显微裂纹的应力或应变集中.时效后,铝合金达强度为775MPa,延伸率达4.3%,断口以细小的韧窝为主,尺寸小于500nm.     

Ti-B-N纳米复合薄膜的制备及结构和力学性能

利用反应磁控溅射方法在(100)单晶硅和高速钢(W18Cr4V)基片上制备出不同B含量的Ti-B-N纳米复合薄膜.使用X射线衍射(XRD)和高分辨透射电镜(HRTEM)研究了Ti-B-N纳米复合薄膜的组织结构,并用纳米压痕仪测试了它们的纳米硬度和弹性模量.结果表明:通过改变TiB₂靶功率和Ti靶功率的方法可制备出非晶-纳米晶复合结构的Ti-B-N薄膜;Ti-B-N薄膜中主要含有TiN纳米晶,随着B含量的增加,形成的TiN纳米晶尺寸变小,非晶成分增加;当B含量很高时会出现很小的TiB₂纳米晶,此时薄膜性能不好;当TiN晶粒尺寸为5 nm左右时,Ti-B-N薄膜力学性能最优,纳米硬度和弹性模量分别达到32.7 GPa和350.3 GPa.     

Preparation and properties of rare earth luminous fiber containing red organic fluorescent pigment

Rare earth luminous fiber was prepared by method of melt spinning. X-ray diffraction （XRD）, scanning electron micros-copy （SEM）, and fluorescence spectrophotometer as well as afterglow brightness tester were used to characterize the resulting sam-ples. Results from XRD and SEM demonstrated that the phase of SrA12O4：Eu2＋,Dy3＋in the fiber was not destroyed in the manufac-turing process and the as-formed luminous fiber consisted of irregular particles. Under ultraviolet excitation, the luminous fiber exhib-ited a yellow-green and orange-red emission band with a maximum at 520 nm and around 600 nm originating from SrAl2O4：Eu2＋, Dy3＋and red organic fluorescent pigments. The energy transfer process was further studied. Furthermore, the emission colors of lu-minous fibers could be tuned from yellow-green to orange-red easily by doping red organic fluorescent pigment, making the materials have potential application in many areas.     

含钪Al-Zn-Mg-Zr合金薄板材MIG焊接接头的组织与性能

采用新型Al-Mg-Sc-Zr焊丝对含钪Al-Zn-Mg-Zr合金薄板材进行MIG焊,借助显微硬度及拉伸性能测试、OM,SEM,TEM等检测手段对焊接接头的微观组织和性能进行研究。结果表明:焊缝区为典型的铸态组织;热影响区靠近焊缝一侧呈现大量细小等轴晶组织,靠近基材区为纤维状组织和少量再结晶组织;基材区为纤维状组织。焊接接头的显微硬度以焊缝为中心呈近似对称,且中心处硬度值最低;抗拉强度为481 MPa,屈服强度为320MPa,伸长率为10.1%,焊接系数约0.83。同时,焊丝和基材中微量的Sc和Zr元素在合金中形成大量细小且与基体共格的Al3(Sc,Zr)粒子,能显著细化晶粒组织,有效抑制再结晶发生,大大改善焊缝区的力学性能。     

热处理对含Y元素AZ31镁合金板材组织和性能的影响

对含Y元素AZ31镁合金板材进行退火处理后的组织和性能进行了研究.结果表明:随着退火温度的升高,镁合金晶粒尺寸逐渐增大,力学性能略有提高然后降低;退火时间对镁合金晶粒尺寸影响不大;在300℃下退火1 h后板材性能达到最佳,抗拉强度为255 MPa,屈服强度为170 MPa,延伸率为24%;经过热处理后镁合金断裂方式为准解理断裂和韧性断裂的复合形式.     

Study on Preparation and Properties of La2O3/MC Nylon Nanocomposites

MC nylon,monomer casting nylon,is a newtypeof engineering plastics,whichis synthesized by anion-ic polymerization with caprolactam as the major rawmaterial,under normal pressure,pouring directlyto amould preheatedto a certaintemperature.It has manyadvantages,such as low polymerized temperature,si mple technology,high crystallinity,low-cost,highequipment efficiency as well as good mechanical prop-erties,shock decrease but wear proof,corrosion-resis-ting,self-ubricant,chemicals-resisting,wide us…     

Preparation and magnetic properties of Cu0.4Zn0.6Cr0.5Sm0.06Fe1.44O4/polyaniline nanocomposites

A self-propagating combustion synthesis (SPCS) method, citrate SPCS method, was used to synthesize Cu0.4Zn0.6Cr0.5SmxFe1.5-xO4 (x=0-0.1) nanosized powders at relatively low temperature. Polyaniline/Cu0.4Zn0.6Cr0.5Sm0.06Fe1.44O4 (CZCS0.06FO) nanocomposites were prepared by in situ polymerization of aniline in the presence of CZCS0.06FO ferrites. The structures, morphologies, and ferromagnetic properties of ferrite powders and nanocomposites were characterized by powder X-ray diffractometer (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM), and vibrating sample magnetometer (VSM). The results indicated that ferrite powders were coated effectively by polyaniline, which reduced the agglomeration of ferrite particles to certain extent, and was helpful to the decentralization and stabilization of nanoparticles. The nanocomposites with core-shell structure under applied field exhibited hysteresis loops of the ferromagnetic nature. The nanocomposites were fit for being used as soft magnetic material because of their lower coercivity than that of pure ferrites.     

无镍不锈钢17Cr10Mn2MoN的制备与性能

采用气雾化法制备含氮无镍不锈钢粉末,利用热等静压成形并对材料进行固溶处理.热等静压后,材料具有良好的强度、塑性及韧性,抗拉强度为850 MPa,屈服强度为505 MPa,延伸率为44.5%,断面收缩率为47.5%,冲击功为44 J.材料经1 100℃固溶处理1 h后,塑性和韧性得到进一步提高,延伸率为50.0%,断面收缩率为55.5%,冲击为68 J.材料强度和耐蚀性优于316L不锈钢.     

Preparation and mechanical properties of bulk ultrafine (W0.5Al0.5)C0.65 with minor Fe binder by reactive hot-pressing

Binderless (W_0.5Al_0.5)C_0.65 produced by reactive hot-pressing (RHP) has high hardness but low bending strength and fracture toughness. In this work, bulk ultrafine (W_0.5Al_0.5)C_0.65 with minor addition of Fe as the binder phase has been prepared by RHP. Rapid synthesis and high densification can be achieved for the (W_0.5Al_0.5)C_0.65 with 0.4–1.0?wt-%Fe by RHP at a relatively low temperature. Pure (W_0.5Al_0.5)C_0.65 without sub-carbide phase or brittle η-type phase can be synthesised due to the fact that the carbon vacancy in (W_0.5Al_0.5)C_y can reach 50%. And thanks to the combined effect of nanoscaled initial powders, low temperature, rapidly reactive sintering and pressure, bulk ultrafine (W_0.5Al_0.5)C_0.65-Fe with a grain size of about 0.2?μm can be obtained by RHP. Thus, with an appropriate amount of Fe (about 0.8?wt-% in this work), the bending strength and fracture toughness of (W_0.5Al_0.5)C_0.65 can be highly improved.