微波非热效应对有机硫化合物结构的影响

为探究微波辐照脱除煤中有机硫的作用机理以及影响程度,通过核磁共振氢谱、红外光谱和激光共聚焦显微拉曼光谱技术,研究了微波非热效应对有机硫模型化合物结构性能的影响。红外光谱测试说明,微波辐照有机硫化合物存在非热效应并影响化学键的键能分布、基团的振动强度和稳定性,但仅限于分子的极化机制,不会破坏分子中原有的化学键也不会生成新的化学键和基团;核磁共振氢谱揭示非热效应影响了模型化合物分子内部的电子云密度分布和磁环境,对含硫化合物产生的双重极化作用既可改变微观的电子或原子极化,也可改变分子固有偶极矩的取向;显微激光拉曼光谱证明非热效应可有效极化含硫键,使之振动强度减弱,从而有助于有机硫的微波辐射脱除。     

Study on the plasma generation characteristics of an induction-triggered coaxial pulsed plasma thruster

At present,spark plugs are used to trigger discharge in pulsed plasma thrusters (PPT),which are known to be life-limiting components due to plasma corrosion and carbon deposition.A strong electric field could be formed in a cathode triple junction (CTJ) to achieve a trigger function under vacuum conditions.We propose an induction-triggered electrode structure on the basis of the CTJ trigger principle.The induction-triggered electrode structure could increase the electric field strength of the CTJ without changing the voltage between electrodes,contributing to a reduction in the electrode breakdown voltage.Additionally,it can maintain the plasma generation effect when the breakdown voltage is reduced in the discharge experiments.The induction-triggered electrode structure could ensure an effective trigger when the ablation distance of Teflon increases,and the magnetic field produced by the discharge current could further improve the plasma density and propagation velocity.The induction-triggered coaxial PPT we propose has a simplified trigger structure,and it is an effective attempt to optimize the micro-satellite thruster.     

Determination of the Velocity of a Magnetic-Field Driven Gliding Arc by Using a Photo-Multiplier

The gliding arc is an important approach to production of non-thermal plasma at atmospheric pressure, it can offer high-energy efficiency and high-electivity for chemical reactions. In this paper, the gliding arc driven by the transverse magnetic field is described and its velocity is measured by using a photo-multiplier. The mean velocity of the gliding arc increases with increasing magnetic induced-intensity, and its value varies from 7.8 m/s to 32 m/s.     

Effects of pulsed magnetic field on density reduction of high flow velocity plasma sheath

A three-dimensional model is proposed in this paper to study the effect of the pulsed magnetic field on the density distribution of high flow velocity plasma sheath. Taking the typical parameters of plasma sheath at the height of 71 km as an example, the distribution characteristics and time evolution characteristics of plasma density in the flow field under the action of pulsed magnetic field, as well as the effect of self-electric field on the distribution of plasma density, are studied. The simulation results show that pulsed magnetic field can effectively reduce the density of plasma sheath. Meanwhile, the simulation results of three-dimensional plasma density distribution show that the size of the density reduction area is large enough to meet the communication requirements of the Global Position System(GPS) signal. Besides, the location of density reduction area provides a reference for the appropriate location of antenna. The time evolution of plasma density shows that the effective density reduction time can reach 62% of the pulse duration, and the maximum reduction of plasma density can reach 55%. Based on the simulation results, the mechanism of the interaction between pulsed magnetic field and plasma flow field is physically analyzed. Furthermore, the simulation results indicate that the density distributions of electrons and ions are consistent under the action of plasma self-electric field.However, the quasi neutral assumption of plasma in the flow field is not appropriate, because the self-electric field of plasma will weaken the effect of the pulsed magnetic field on the reduction of electron density, which cannot be ignored. The calculation results could provide useful information for the mitigation of communication blackout in hypersonic vehicles.     

Study the Influence of the Bank Energy on the Dynamical Pinch in Plasma Focus

The plasma focus discharge can generate, accelerate and pinch the plasma up to high density and temperature in a pulsed mode manner. Applications aspects of discharge require high efficiency of the fusion products. This situation acquires optimized operational parameters for the proper discharge. In this article, we have studied the plasma parameters and neutron performance dependency on bank energy. First, analytical expressions are derived from the equation of motion for the plasma particles in the radial phase. Then, the related fusion neutrons, both thermal and non-thermal, together with the discharge anisotropy in the low pressure regimes for the ‘Dena’ plasma focus device as function of bank energy are presented. The analytic models are compared with experimental data.     

Conversion of plasma energy into electrical pulse by magnetic flux compression

A conceptual study of magnetic flux compression inside a cylindrical coil by an expanding inertial fusion plasma sphere across the magnetic field produced by the coil itself have been performed numerically using a two-dimensional magnetohydrodynamic (MHD) simulations. The concept may find application in inertial fusion energy (IFE) system as a direct energy conversion scheme to convert a part of fusion plasma kinetic energy into pulsed electrical energy. Important theoretical and technical issues that has to be addressed are discussed. Preliminary theoretical analysis are given for the analysis of MHD interchange instabilities of expanding plasma across magnetic field. Overall efficiency of the system is determined numerically for a typical set of initial plasma and system parameters. Ultrahigh coil inter-turn voltages are predicted. Therefore, the application of magnetic self-insulation to avoid coil inter-turn break-down is considered. Also, we have analysed the system performance with different load conditions.     

Influence of electrical parameters on H2O2 generation in DBD non-thermal reactor with water mist

A dielectric barrier discharge (DBD) reactor is introduced to generate H2O2 by non-thermal plasma with a mixture of oxygen and water mist produced by an ultrasonic atomizer.The results of our experiment show that the energy yield and concentration of the generated H2O2 in the pulsed discharge are much higher than that in AC discharge,due to its high energy efficiency and low heating effect.Micron-sized liquid droplets produced by an ultrasonic atomizer in water mist have large specific surface area,which greatly reduces mass transfer resistance between hydroxyl radicals and water liquids,leading to higher energy yield and H2O2 concentration than in our previous research.The influence of applied voltage,discharge frequency,and environmental temperature on the generated H2O2 is discussed in detail from the viewpoint of the DBD mechanism.The H2O2 concentration of 30 mg 1-1,with the energy yield of 2 g kW-1h 1 is obtained by pulsed discharge in our research.     

Study on deposition of Al2O3 films by plasma-assisted atomic layer with different plasma sources

In this paper,A12O3 thin films are deposited on a hydrogen-terminated Si substrate by using two home-built electron cyclotron resonance (ECR) and magnetic field enhanced radio frequency plasma-assisted atomic layer deposition (PA-ALD) devices with Al(CH3)3 (trimethylaluminum,TMA) and oxygen plasma used as precursor and oxidant,respectively.The thickness,chemical composition,surface morphology and group reactions are characterized by in situ spectroscopic ellipsometer,x-ray photoelectric spectroscopy,atomic force microscopy,scanning electron microscopy,a high-resolution transmission electron microscope and in situ mass spectrometry (MS),respectively.We obtain that both ECR PA-ALD and the magnetic field enhanced PA-ALD can deposit thin films with high density,high purity,and uniformity at a high deposition rate.MS analysis reveals that the A12O3 deposition reactions are not simple reactions between TMA and oxygen plasma to produce alumina,water and carbon dioxide.In fact,acetylene,carbon monoxide and some other by-products also appear in the exhaustion gas.In addition,the presence of bias voltage has a certain effect on the deposition rate and surface morphology of films,which may be attributed to the presence of bias voltage controlling the plasma energy and density.We conclude that both plasma sources have a different deposition mechanism,which is much more complicated than expected.     

Comparison of discharge characteristics and methylene blue degradation through a direct-current excited plasma jet with air and oxygen used as working gases

Through using a direct-current driven plasma jet operated underwater, degradation of methylene blue(MB) is investigated with air and oxygen used as working gases. With a low power voltage,a plasma plume extends from the needle electrode, which is purple in air. It turns pink after it bridges the two electrodes. During the process, oxygen plasma remains white. Discharge operates in a pulsed mode or a continuous one, which depends on the magnitude of power voltage. For the pulsed mode, oxygen discharge has a shorter plume and a higher pulse frequency than air discharge under the same power voltage. For the same current of the continuous mode, both power and gap voltages of oxygen discharge are higher than those of air discharge. Moreover, MB degradation efficiency increases with increasing power voltage or initial concentration of MB solution. Compared with air discharge, oxygen discharge has a higher degradation efficiency with the same power voltage and treatment time. The pulsed oxygen discharge with power voltage of about 6.5 k V has the highest efficiency in degrading MB dye, reaching approximately 85.8% after 10 min treatment. As a comparison, after 10 min treatment in air discharge, the highest degradation efficiency is 63.7%, which appears in the continuous mode at a power voltage of 10.6 kV. Besides, optical spectra from the discharges are also compared for the two types of working gases.     

Experimental study on toluene removal by a two-stage plasma-biofilter system

Volatile organic compounds (VOCs) are typical pollutants that affect air quality. Discharge plasma is thought to be a potential method that can remove VOCs from flue gas. In this experiment, pulsed corona discharge plasma combined with a biological tower was carried out to remove the benzene series, and toluene was selected as the typical VOC. The results indicated that the removal efficiency of toluene by pulsed corona plasma was slightly higher than that of direct current (DC) corona plasma, while its energy efficiency was much higher than DC corona plasma. Under the optimal experimental conditions of pulse voltage 8.5 kV, initial toluene concentration 1400 mg m−3, and toluene flow rate of 12 l h−1, the toluene removal efficiency reached 77.11% by the single method of pulsed corona discharge plasma, and the energy efficiency was up to 1.515 g/(kW·h) under the pulse voltage of 4.0 kV. The trickling biofilter was constructed by using the screened and domesticated Acinetobacter baumannii, and the highest toluene removal efficiency by the pulsed corona discharge plasma combined with the trickling biofilter rose up to 97.84%. Part of the toluene was degraded into CO2, H2O, and some intermediate products such as o-diphenol under the influence of Acinetobacter baumannii. When the remaining waste gas passed through the discharge plasma reactor, the benzene ring structure could be directly destroyed by the collision between toluene and plasma. Meanwhile, O·, OH·, and some other oxidizing radicals generated by the discharge also join into the oxidative decomposition of toluene and its intermediate products, thereby further improving the removal efficiency of toluene. Therefore, the two-stage plasma-biofilter system not only showed a high toluene removal efficiency, but also had a good energy efficiency. The results of this study will provide theoretical support and technical reference for industrial VOC treatment.     

Advanced oxidation technology for H2S odor gas using non-thermal plasma

Non-thermal plasma technology is a new type of odor treatment processing. We deal with H2S from waste gas emission using non-thermal plasma generated by dielectric barrier discharge. On the basis of two criteria, removal efficiency and absolute removal amount, we deeply investigate the changes in electrical parameters and process parameters, and the reaction process of the influence of ozone on H2S gas removal. The experimental results show that H2S removal efficiency is proportional to the voltage, frequency, power, residence time and energy efficiency,while it is inversely proportional to the initial concentration of H2S gas, and ozone concentration. This study lays the foundations of non-thermal plasma technology for further commercial application.     

Effects of O2 addition on the plasma uniformity and reactivity of Ar DBD excited by ns pulsed and AC power supplies

Dielectric barrier discharges (DBDs) have been widely used in ozone synthesis, materials surface treatment, and plasma medicine for their advantages of uniform discharge and high plasma-chemical reactivity. To improve the reactivity of DBDs, in this work, the O₂ is added into Ar nanosecond (ns) pulsed and AC DBDs. The uniformity and discharge characteristics of Ar ns pulsed and AC DBDs with different O₂ contents are investigated with optical and electrical diagnosis methods. The DBD uniformity is quantitatively analyzed by gray value standard deviation method. The electrical parameters are extracted from voltage and current waveforms separation to characterize the discharge processes and calculate electron density n_e. The optical emission spectroscopy is measured to show the plasma reactivity and calculate the trend of electron temperature T_e with the ratio of two emission lines. It is found that the ns pulsed DBD has a much better uniformity than AC DBD for the fast rising and falling time. With the addition of O₂, the uniformity of ns pulsed DBD gets worse for the space electric field distortion by O₂⁻, which promotes the filamentary formation. While, in AC DBD, the added O₂ can reduce the intensity of filaments, which enhances the discharge uniformity. The ns pulsed DBD has a much higher instantaneous power and energy efficiency than AC DBD. The ratio of Ar emission intensities indicates that the T_e drops quickly with the addition of O₂ both ns pulsed and AC DBDs and the ns pulsed DBD has an obvious higher T_e and n_e than AC DBD. The results are helpful for the realization of the reactive and uniform low temperature plasma sources.     

磁驱动滑移电弧直径的研究

大气压非热电弧的直径是确定电弧电流密度、从而确定等离子体电子密度和电子温度的重要参数之一.采用CCD摄影方法对大气压磁驱动滑移电弧在运动中的形状和尺寸进行了观察和测量,将电弧在CCD上的影像转换成灰度(光强)分布数据,对电弧图片径向上的灰度分布数据进行曲线拟合来确定电弧径向边界和直径;分别测量了电弧在运动方向的投影直径(正向直径)和垂直于运动方向上的投影直径(侧向直径),分析了电弧直径与电弧电流以及外加磁场之间的变化关系,并对电弧正向直径和侧向直径进行了对比分析.     

Regulation of the density distribution of a strongly dissipative plasma by a pulsed magnetic field

A pulsed transverse magnetic field with pulse width of 12 ms and magnitude of 2 T was used to modify the density distribution of a weakly-ionized plasma flow with strong collisions between the charged particles and neutrals.The morphology of the plasma is changed substantially,with the density increased upstream and decreased downstream.Meanwhile,the plasma toward the axis contracts laterally and gradually converges to a collimated flow.In addition,a drift wave is observed to be excited in the inhomogeneous plasma by the magnetic field.     

Electrodeless plasma thrusters for spacecraft: a review

The physics of electrodeless electric thrusters that use directed plasma to propel spacecraft without employing electrodes subject to plasma erosion is reviewed.Electrodeless plasma thrusters are potentially more durable than presently deployed thrusters that use electrodes such as gfidded ion,Hall thrusters,arcjets and resistojets.Like other plasma thrusters,electrodeless thrusters have the advantage of reduced fuel mass compared to chemical thrusters that produce the same thrust.The status of electrodeless plasma thrusters that could be used in communications satellites and in spacecraft for interplanetary missions is examined.Electrodeless thrusters under development or planned for deployment include devices that use a rotating magnetic field;devices that use a rotating electric field;pulsed inductive devices that exploit the Lorentz force on an induced current loop in a plasma;devices that use radiofrequency fields to heat plasmas and have magnetic nozzles to accelerate the hot plasma and other devices that exploit the Lorentz force.Using metrics of specific impulse and thrust efficiency,we find that the most promising designs are those that use Lorentz forces directly to expel plasma and those that use magnetic nozzles to accelerate plasma.     

Kinetic simulation of the transition from a pulse-modulation microwave discharge to a continuous plasma

The generation of a very strong peak current in the first period(PCFP) in a pulse-modulated microwave discharge has been discussed in previous studies. In this paper we focus on the transition process from a pulsed discharge to a fully continuous one driven by the pulsed microwave power source by means of a kinetic model. The computational results show that by increasing the duty cycle or voltage modulation rate(VMR), the discharge eventually becomes fully continuous and PCFP can no longer be observed. In the transition process, the distributions of the electric field, electron energy probability function(EEPF) and plasma density are discussed according to the simulation data, showing different discharge structures. The simulations indicate that many high-energy electrons with electron energy larger than 20 eV and low-energy electrons with electron energy less than 3 eV could be generated in a pulsed microwave discharge, together with a reversal electric field formed in the anode sheath when PCFP occurs. However, only medium-energy electrons could be observed in a fully continuous discharge. Therefore, by investigating the transition process the pulse-modulated microwave discharges can be further optimized for plasma applications at atmospheric pressure.     

Research of magnetic self-balance used in a repetitive high voltage rectangular waveform pulse adder

Compared with a sinusoidal operation, pulsed operation has more homogeneity and more efficiency in dielectric barrier discharge. In this paper, an improved pulse adder is designed and assembled to create repetitive high voltage rectangular pulses when resistive loads or capacitive loads exist. Beyond the normal pulse adder based on solid-state switches, additional metal–oxide–semiconductor field effect transistors are used in each stage for a faster falling edge.Further, the voltage difference between stages is eliminated by balancing windings. In this paper,we represent our theoretical derivation, software simulations and hardware experiments on magnetic self-balance. The experiments show that the voltage difference between stages is eliminated by balancing windings, which matches the result of simulations with almost identical circuits and parameters.     

A comparative study on the activity of TiO2 in pulsed plasma under different discharge conditions

In the present study,a combination of pulsed discharge plasma and TiO_2(plasma/TiO_2)has been developed in order to study the activity of TiO_2by varying the discharge conditions of pulsed voltage,discharge mode,air flow rate and solution conductivity.Phenol was used as the chemical probe to characterize the activity of TiO_2in a pulsed discharge system.The experimental results showed that the phenol removal efficiency could be improved by about 10%by increasing the applied voltage.The phenol removal efficiency for three discharge modes in the plasma-discharge-alone system was found to be highest in the spark mode,followed by the spark–streamer mode and finally the streamer mode.In the plasma/TiO_2system,the highest catalytic effect of TiO_2was observed in the spark–streamer discharge mode,which may be attributed to the favorable chemical and physical effects from the spark–streamer discharge mode,such as ultraviolet light,O_3,H_2O_2,pyrolysis,shockwaves and high-energy electrons.Meanwhile,the optimal flow rate and conductivity were 0.05 m~3l~(-1)and 10μS cm~(-1),respectively.The main phenolic intermediates were hydroquinone,catechol,and p-benzoquinone during the discharge treatment process.A different phenol degradation pathway was observed in the plasma/TiO_2system as compared to plasma alone.Analysis of the reaction intermediates demonstrated that p-benzoquinone reduction was selectively catalyzed on the TiO_2surface.The effective decomposition of phenol constant(D_e)increased from 74.11%to 79.16%when TiO_2was added,indicating that higher phenol mineralization was achieved in the plasma/TiO_2system.     

An Eulerian MHD model for the analysis of magnetic flux compression by expanding diamagnetic fusion plasma sphere

The process of magnetic flux compression (MFC) inside a solenoid by expanding diamagnetic plasma sphere produced by an inertial fusion micro-explosions and its application as a direct energy conversion scheme to convert a part of plasma kinetic energy into pulsed electrical energy has been recently reported [1]. For a detailed analysis of this concept, an Eulerian multi-material MHD model is developed using magnetic vector potential formulation for electro-magnetic field calculations and classical volume-of-fluid method for material interface tracking. The diffusion term in the magnetic induction equation is solved implicitly while the advection terms are computed using a second-order MUSCL scheme. An iteration procedure using ADI scheme is used for the free space field calculation. In this paper, we describe the details of the new MHD model, its validation against the semi-analytical solutions (for magnetic Reynolds number ?1) of magnetic convective-diffusion equations and application to explore the concept of MFC by expanding plasma sphere. The simulation results show that the algorithm is capable of handling complex plasma dynamics inside the MFC system. Also, the results indicate the development and the evolution of MRT like instability near the stagnation point. The magnetic field diffusion into the plasma during the expansion phase is found to be negligible.     

Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air

Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectri...