An attempt to evaluate phosphorus fertilizer requirements of western Nigeria savannah soils

A greenhouse fertilizer trial was carried out on 60 surface soils of the western Nigeria savannah derived from basement complex rocks. Bray's P₁ available P in the soils varied between 1 and 112µg ml^–1. There was maize response to P addition and a critical P level of 12.7µg ml^–1 was calculated for the soils.For 22 of the soils, a laboratory incubation technique was used in evaluating changes in Bray's P₁ extractable P at various rates with time. The initial rapid decline in soil available P was completed between 28 and 84 days of incubation. A fertilizer factor, calculated from extracted P in treated and untreated soils varied between 1.5 and 16.7µg ml^–1 and was significantly correlated with soil pH and citrate-dithioniteextractable oxides of Fe and Al.Fertilizer rates based on critical soil P, available soil P and fertilizer factor, correlated significantly with greenhouse estimates for optimum yield obtained with the linear response plateau model (r = 0.91,p < 0.001). At ten field locations varying in available P content, response was only to P applications lower than 60 kg ha^–1 and the calculated P rates using a mean fertilizer factor of 3.0µg ml^–1 corresponded to P rates at which maximum yields were obtained in the sites.     

Granite powder as a source of potassium for plants: a glasshouse bioassay comparing two pasture species

The effect of granite powder (<70µm) as a K fertilizer was investigated in a glasshouse pot experiment conducted with three acid, sandy topsoils from podzols of South Western Australia and with three fertilizer treatments: a control without K application, a KCl treatment (90 mg K kg^–1 soil) and a granite treatment (20 g granite kg^–1 soil, yielding 640 mg K kg^–1 soil). Subterranean clover (Trifolium subterraneum) and ryegrass (Lolium rigidum) were cropped in triplicated pots for 7 weeks, harvested and allowed to regrow for another 13 weeks. Clover growth at 7 weeks was in the following order: control < granite < KCl. The growth of ryegrass after 7 weeks was not significantly affected by granite as compared to the control treatment. After another 13 weeks, both species showed a significant growth response to granite application for two of the three soils studied. For both species and all three soils K concentrations in the plant tissue were systematically and significantly higher for KCl relative to granite and for granite relative to control treatment. Minor dissolution of granite occurred during the short duration of the experiment as indicated by changes in soil exchangeable K in uncropped pots (about 1-2% of K applied) and resulted in the increased K concentration in plants and the growth response of subterranean clover after 7 and 20 weeks and ryegrass after 20 weeks of cropping. The possible use of granite powder as a slow-release K fertilizer is discussed.     

Selenium concentration in spring wheat as influenced by basal application and top dressing of selenium-enriched fertilizers

A multisite field experiment was conducted to study the effect of topdressed Se-enriched Ca(NO₃)₂ (CN) and basal applied NPK on the selenium (Se) concentration in spring wheat (Triticum aestivum L.). Selenium was applied either through CN (at the rates of 0, 6.45, and 12.91 g Se ha^–1) or NPK (5.83 g Se ha^–1). Selenium concentration in wheat grains increased consistently with increasing rate of Se-enriched CN or NPK. However, the superiority of Se-enriched CN over NPK in raising the Se concentration in wheat grain depended on location and growth conditions. At the same rate both methods of Se-application were found to be equally effective in raising the Se concentration of wheat grains. The Se concentration of grain was generally higher in the light textured soils than in the medium to heavy textured soils. Without Se application, the Se-concentration in wheat grain was about 16µg kg^–1 which is regarded insufficient to meet the Se requirement for Se in animal and human. Calcium nitrate enriched with 25 mg Se kg^–1 (6.45 g Se ha^–1) increased the Se concentration in wheat grain to a desired level.     

Effects of gypsum on growth and mineral content of Brussels sprouts,and soil properties of Orthic Podzols

Studies of crop response to Ca fertilizers are generally few as well as information concerning the Ca nutrition of Brussels sprouts (Brassica oleracea var.gemmifera). Six field studies were conducted, over three years, to determine yield response of Brussels sprouts to soil applied gypsum (CaSO₄.2H₂O), lime (calcite), and elemental S on sandy loam to loamy sand Orthic Podzols in Prince Edward Island. Relative yield of marketable (0–32mm) Brussels sprouts were related to soil ammonium acetate extractable Ca (r = 0.71). The highest yields (11 to 13 t ha^–1) were associated with an extractable Ca of above 400µg g^–1 soil, while a Ca level below 400µg reduced yield by 20%. Highest marketable yields were associated with a Ca level in the leaf tissue (in upper mature leaves at sprout formation) of above 2.2% (w/w) (r = 0.55), this in turn was associated (r = 0.87) with an extractable soil Ca above 400µg g^–1 soil. Calcite and elemental S did not influence yield or mineral content. Gypsum, as expected increased leaf S content, but leaf tissue S levels were not related to marketable yield. Slight decreases in soil pH due to increasing gypsum rate (0.5–4.3 t ha^–1) were associated with changing accumulations of B, Mn, Fe, Ca, and Zn in the leaf tissue. Gypsum had little effect on soil porosity and structure indices, but changing pH (in both gypsum and lime treatments) significantly influenced soil microbial biomass.     

Evaluation of ammonium thiosulfate as a soil urease inhibitor

Interest in use of ammonium thiosulfate (ATS) in conjunction with urea as a fertilizer has been stimulated by recent reports that this compound retards hydrolysis of urea by soil urease and thereby reduces volatilization of urea N as ammonia from soils fertilized with urea. We evaluated ATS as a soil urease inhibitor by studying its effects on urea hydrolysis, seed germination, and early seedling growth in soil. We found that ATS significantly retarded urea hydrolysis only when applied at rates as high as 2,500 or 5,000µg g^–1 soil, whereasN-(n-butyl) thiophosphoric triamide (NBPT) (a patented inhibitor of urea hydrolysis in soil) caused substantial retardation of urea hydrolysis when applied at rates as low as 1µg g^–1 soil. We also found that ATS had an adverse effect on germination of corn or wheat seeds in soil when applied at the rate of 2,500 or 5,000µg g^–1 soil and caused a dramatic reduction of early seedling growth of corn or wheat when applied at the rate of 1,000, 2,500, or 5,000µg g^–1 soil. These findings indicate that ATS has little, if any, potential value for retarding hydrolysis of urea fertilizer in soil.     

Silicate rock powder: effect on selected chemical properties of a range of soils from Western Australia and on plant growth as assessed in a glasshouse experiment

Soil samples were collected from 20 locations from the south western part of Western Australia and incubated at 25 °C for 60 days without or with finely ground granite powder at a rate of 20 g kg^–1 soil, equivalent to about 20 t ha^–1. Electrical conductivity and exchangeable Na, Ca and Mg were not significantly affected by granite application for most soils. Conversely, among the 20 soils studied, nine exhibited a significant increase in exchangeable K (atp<0.01) due to granite application. Six of them showed a consistent increase in soil pH as measured in a CaCl₂ extract, corresponding to less than 0.26 pH units. The concomitant increase in exchangeable K due to granite application ranged between 10 and 390%. However, in absolute value it amounted to less than 0.07 cmol K kg^–1 soil, suggesting that a maximum of 59 g kg^–1 of the applied granite dissolved during the course of this incubation experiment. One of the most granite responsive soils was used for a pot experiment conducted with wheat grown for 88 days in a glasshouse. In this experiment, the soil was either untreated (control) or mixed with either granite or diorite powders at six different rates of application. The wheat biomass and cation contents in plant tissue were not significantly affected by the application of diorite at any rate of application. Conversely, for the granite-treated soil a significant increase in wheat biomass was encountered for rates larger than 2.5 g kg^–1 soil. Since a significant increase in K content was obtained at the same rates of application it was concluded that the positive response of wheat growth to granite application was due to potassium supplied by granite dissolution. The use of granite powder as a potential K fertilizer thus needs further attention even though its efficiency as compared to a soluble fertilizer would almost certainly be poor.     

Effect of phosphate on the sorption,desorption and plant-availability of selenium in soil

Phosphate, applied at 5µg P cm^–3, decreased selenite sorption by from 30–70% in three soils studied. Both maximum sorption (X_m) and the binding-energy of sorption as indicated by the binding-energy related constant (k) or the molar free energy (G) of the sorption reaction derived from the Langmuir equation were considerably decreased. On the other hand, phosphate sorption was decreased by increasing concentration of selenite from 0.2µg Se cm^–3 to 1.0µg Se cm^–3 in the initial solution. The competitive sorption of phosphate with selenite was likely the main mechanism involved in the P-Se interactions. The competitively sorbed selenite exhibited much larger desorption in 0.01M CaCl₂ solution, more readily extractable to 0.5M NaHCO₃ and significantly higher isotopic exchangeability compared to that sorbed without the competing anion. Results from pot trial using ryegrass indicated that phosphate application increased more efficiently the plant-availability of applied fertilizer Se than that of indegeneous Se in soil.     

Phosphate sorption isotherms in relation to P nutrition of wheat (Triticum aestivum)

The phosphate sorption isotherms are needed to explain differential plant responses to P fertilization in soils. Laboratory and greenhouse experiments investigated the use of phosphorus sorption isotherms in relation to P fertilizer requirement of wheat in ten benchmark soils of Punjab, India. The modified Mitscherlich Equation (3) was used to describe plant response observed in different soils. Maximum obtainable yield (MOY) ranged from 11.6 g pot^–1 in Gurdaspur (I) sandy clay loam to 7.0 g pot^–1 in Nabha sandy clay loam. Response to P applied @ 25 mg P kg^–1 soil was maximum (77%) in Bathinda sand and minimum in Chuharpur clay loam (33%). The response curvature varied from 3.74 × 10^–2 in Nabha sandy clay loam to 4.43 × 10^–2 in Kanjli sandy loam. The soil solution P required to produce optimum yield (90% MOY) varied from 1.61 µg ml^–1 in Bathinda sand to 0.10 µg ml^–1 in Sadhugarh clay. Dry matter yield obtained at 0.2 µg ml^–1 solution P concentration ranged from 55% in Bathinda sand to 85% of MOY in Gurdaspur (II) clay loam. At the same solution P concentration (0.1 µg P ml^–1), dry matter yield was 91% in Sadhugarh clay, 80% in Gurdaspur (II) clay loam and, 43% of MOY in Bathinda sand and eventually coincided with the decreasing maximum buffer capacity (MBC) in these soils. At the same level of sorbed P (100 mg P kg^–1 soil) the yield was observed to be inversely proportional to MBC. The study, therefore, concludes that, soils should be grouped according to their P sorption characteristics and MBC before using critical soil solution P as a criterion for obtaining optimum yields.     

Predicting external sulphur requirement of alfalfa from sulphate sorption isotherm of Tanzanian soils

For Tanzanian soils dominant in hydrous oxides of iron and amorphous ferri-alumino silicate, a 48-hour (hr) mixing period with the sulphate (SO₄) solution was adequate for a near-equilibrium condition. Although differing in their SO₄ sorption capacity, all the soils sorbed SO₄ at or beyond 1µg ml^–1 sulphur (S) concentration in the supernatant. Hydroxyl (OH) ions were displaced during SO₄ sorption as indicated by a significant positive correlation between the amount of sorbed SO₄ and the difference in pH values determined in 0.1N K₂ SO₄ and 0.1N KCl, i.e. the dpH values.In a greenhouse experiment, alfalfa was grown on eight soils at six adjusted S concentrations. Sulphur deficiency symptoms appeared in the control pots of those soils which were low in native sorbed SO₄, SO₄ sorption capacity and initial soil solution S concentration. Sulphur fertilization increased dry matter (DM) yield as well as response to applied S. The external S concentration, i.e. adjusted S concentration required for 95% of the maximum DM yield, ranged from 0.8 to 8.2µg S ml^–1 with values less than 2.0 on most of the soils. The external S concentration decreased hyperbolically as the SO₄ sorption capacity of the soils increased. The total amount of fertilizer S required to obtain the external S concentration in solution, and at the same time satisfy the SO₄ sorption capacity of the soil at the external S concentration (determined from the sorption isotherm) was defined as the external S requirement for the specified yield level of alfalfa. The external S requirement for 95% of the maximum yield of alfalfa varied from soil to soil due to differences in their capacity and intensity for S nutrition.Part of a thesis by the senior author for the MSc (Agric) degree of the University of Dar es Salaam     

Critical manganese deficiency level for soybean grown in Ustochrepts

A greenhouse study with 15 soils, having a range in DTPA extractable Mn, was conducted to determine the critical deficiency level of Mn in Ustochrepts for predicting response of soybean to Mn application. Soil application of 10 mg Mn kg^–1 soil significantly increased the dry matter yield in deficient soils. Soil Mn was significantly related with Bray's per cent yield (r = 0.72^**) and Mn uptake (r = 0.75^**). Both graphical and statistical models of Cate and Nelson indicated the critical level to be 3.3 mg kg^–1 soil of DTPA extractable Mn. Critical Mn deficiency level in recently matured terminal leaflet blade at V6 growth stage in soybean plant was 22.0µg g^–1 dry matter. The predictability of soil and plant critical Mn level was 87 per cent.     

Response of pearl-millet to zinc fertilization in relation to DTPA extractable zinc

The response of pearl-millet (Pennisetum americanum) grown on forty eight diverse soils to applied zinc fertilization was examined in a screenhouse experiment. The DTPA-extractable soil zinc ranged from 0.34 to 1.42 mg kg^–1. In many of the soils yield was increased by the addition of zinc and there were large differences in the size of the response. The critical level of zinc in soil and plant — below which response to applied zinc may be expected — was determined by a graphical method. The values found were 0.65 and 18 mg kg^–1, respectively. Bray's percent yield was positively and significantly related with both soil Zn (r = 0.88) and plant Zn (r = 0.72).     

Adsorption and desorption of phosphate in some semi-arid tropical Indian Vertisols

Adsorption and desorption of phosphorus in soils are among the key processes governing its availability to crops. There have been very few studies on the phosphorus adsorption and desorption characteristics of Vertisols. The P adsorption and desorption characteristics of four Vertisols belonging to three agriculturally important soil series were studied. The amounts of P adsorbed by the soils at 0.2µg ml^–1 equilibrium solution P concentration was low and ranged from 34.3 to 79.5µg g^–1 soil. The phosphate adsorption was very well described by Langmuir and Freundlich isotherms. The P adsorbed by a Vertisol (BR-1) fertilized with different rates of P in the previous season (0, 10, 20 and 40 kg P ha^–1) was similar (34.3–41.3µg g^–1 soil) indicating little effect of fertilization on P adsorption. The correlation studies indicated that the DTPA-extractable Fe was the most important factor accounting for P adsorption in these soils. Clay and CaCO₃ content were found to be relatively less important factors affecting P adsorption in the soils studied.The capacity of the two extractants and EUF (electro-ultrafiltration) to desorb the adsorbed P followed the order: EUF (400V, 80°C)>sodium bicarbonate>EUF (200V, 20°C)>calcium chloride. The average amounts of P desorbed from the four Vertisols using these methods were 74, 63, 50, and 3% respectively of the adsorbed P. In the Begamganj soil, the amount of P desorbed by EUF (400V, 80°C) exceeded 100%, indicating that all of the adsorbed P was desorbable including some native P.In conclusion the results of our study show that the Vertisols studied have low phosphate adsorption capacity and that the P they adsorbed is easily desorbable.Approved for publication as Journal Article No. 983 by International Crops Research Institute for the Semi-Arid Tropics (ICRISAT).     

Determination of critical level of zinc in non-calcareous soils for predicting response of wheat to applied zinc

Studies were conducted in ten non-calcareous arid brown soils (India) to determine the critical level of soil Zn for predicting response of wheat to zinc fertilization. The per cent mean response at 5 mg kg^–1 added Zn varied from 1.3 to 51.4 with a mean value of 17.5 per cent over control in terms of grain yield (g pot^–1). Further, Zn application resulted in significant increase in Zn concentration in various plant parts in all the soils irrespective of the initial Zn status. The critical level of Zn in soil and plant below which response to applied Zn may be expected was found to be 1.75 mg kg^–1 for 0.1 N HC1 extractable soil Zn and 1.7 mg kg^–1 for plant tissue Zn.     

Response of chickpea (Cicer arietinum) to zinc fertilization and its critical level in soils of semi-arid tropics

In a greenhouse experiment the response of chickpea (Cicer arietinum) to zinc fertilization was examined using 27 soils from the semi-arid tropics. The critical level of DTPA extractable soil Zn was evaluated. Zinc additions to the soil increased the dry matter yield of six weeks old plant shoot, grain and straw significantly at the 5 mg kg^–1 level, but tended to decrease it at the 10 mg kg^–1 level.The DTPA extractable Zn of the soils ranged from 0.28 to 1.75 ppm and was negatively correlated at 1 per cent level with pH (r = – 0.81) and positively with organic carbon (r = 0.79) and Olsen's P (r = 0.63). The per cent yield increase or decrease over zero zinc ranged from 67 to – 16 in respect of grain yield and was positively correlated with available Zn (r = 0.86^**). Zinc concentration in plants was greatly increased with the application of Zn and accumulation of Zn was higher in grain than straw. The critical level of available zinc in soil below which plant response to Zn fertilization may be expected was 0.48 mg Zn kg^–1 soil. Soils between 0.48 to 0.70 mg kg^–1 of DTPA extractable Zn appear boarderline and a negative response to applied Zn was observed in soils of high Zn category. The results show the suitability of DTPA soil test for demarcating soils on the basis of plant response to zinc fertilization.     

Scientific basis for establishing country greenhouse gas estimates for rice-based agriculture: An Indian case study

A comprehensive scientific assessment of CH₄ budget estimation for Indian rice paddies, based on a decade of measurements in India, is presented. Indian paddy cultivation areas contain soils that have low to medium levels of soil organic carbon. The average seasonally integrated CH₄ flux (E _sif) values calculated from these measurements were 15.3 ± 2.6 g m^–2 for continuously flooded (CF), 6.9 ± 4.3 g m^–2 for intermittently flooded (IF) single aeration (SA) and 2.2 ± 1.5 g m^–2 for IF multiple aeration (MA) rice ecosystems. For CF and IF (MA) rice ecosystems having high soil organic carbon, without organic amendments, the CH₄ flux (E _sif) may be increased by 1.7 times relative to low soil organic carbon, whereas it may enhance by 5.3 for CF if amended organically. Organic amendment and high soil organic carbon paddy areas do not alter the methane budget estimates for India (3.6±1.4 TgY^–1) much, due to their small paddy harvested area. Methane estimated using average emission factors (E _sif) for all paddy water regimes, which include harvested areas having soils with high organic carbon and organic amendments, may give a budget of 5 TgY^–1 for India.     

Evaluation of chromium release during the decomposition of leather meal fertilizers applied to the soil

Greenhouse studies of 14 soils, having a range in DTPA extractable Mn, were made to determine the critical deficiency level of Mn in ustochrepts for predicting response of green gram to Mn application. Soil Mn was significantly related with Bray's per cent dry matter yield (r = 0.68^**). Soil application of 20 mg Mn kg^–1 soil significantly increased the yield. Both graphical and statistical models of Cate and Nelson indicated the critical level to be 2.9 mg kg^–1 soil of DTPA extractable Mn. The critical deficiency level in youngest matured terminal leaf (YML) of 40 day green gram plants was 19.0µg g^–1. The predictability of soil and plant critical Mn level was 93 per cent.     

Influence of calcium carbonate on the dissolution of Sechura phosphate rock in soils

Different amounts of CaCO₃ (5.3 to 20% w/w) (180-75µm) were mixed with Sechura phosphate rock (SPR) (180-75µm) and incubated with Davidstow and Withnell soils. These soils differ in their proton supply and Ca-buffering capacity. The Ca-buffering capacity of Davidstow soil was also changed by adding different amounts of cation-exchange resin (CER). The consumption of protons and the release of Ca during the preferential dissolution of CaCO₃ decreased the dissolution of the SPR (measured by P release). However, the negative effect of CaCO₃ on SPR dissolution at near equilibrium (60 d) depended on both the proton supply and Ca-sink size of the soil. The Davidstow soil had an adequate proton supply (43.6 mmol H kg^–1 pH unit^–1) but a small Ca sink (32.0 mmol kg^–1), and the dissolution of SPR at 60 d decreased linearly from 27.5 to 19.5% with increasing CaCO₃ content. The Withnell soil had an adequate Ca sink (75.5 mmol kg^–1) but a small proton supply (21.4 mmol H kg^–1 pH unit^–1), and the amount of P dissolved at 60 d also decreased (from 49 to 35%) with increasing CaCO₃ content. Adding CER to the Davidstow soil increased the Ca-sink size from 32.0 to 39.0 mmol kg^–1 and almost prevented the decrease in SPR dissolution with increasing CaCO₃ content. This suggests that, in soils with an adequate proton supply and Ca-sink size, CaCO₃ present as an accessory mineral in PR materials has a negligible effect on the dissolution of the PR.     

An evaluation of water extraction as a soil-testing procedure for phosphorus II. Factors affecting the amounts of water-extractable phosphorus in field soils

The effects of seasonal variation, sampling depth, and fertilizer P addition on water-extractable P values were investigated in two field experiments, involving soils of contrasting P retention capacity (Ramiha and Tokomaru) under permanent pasture over 12 months. The effects of the same parameters on Olsen-extractable P were also evaluated. The amounts of water-extractable P in soil were always lower than those of Olsen-extractable P. Over the 12-month period, the average value of water-extractable P in the unfertilized Ramiha soil (0–7.5 cm depth) was 1.8µg g^–1 soil compared to an Olsen-extractable P value of 12.6µg g^–1. The variability associated with water-extractable P at each sampling time was comparable with that for Olsen-extractable P. However, the relative seasonal variation over 12 months was larger for water-extractable P than for Olsen-extractable P. The results obtained with both extractants showed a seasonal fluctuation which was closely related to the pattern of pasture P uptake. The amounts of water- and Olsen-extractable P were higher in samples taken from the 0–4.0 cm than the 0–7.5 cm sampling depth. Fertilizer P addition resulted in larger increases in water-extractable P in the 0–4.0 cm sampling depth than in the 0–7.5 cm depth. The relative increase in water-extractable P following fertilizer P addition was larger than that of Olsen-extractable P. Seasonal changes in the soil microbial biomass P were not related to changes in either water-extractable P or plant uptake of P. Microbial biomass P may be a less sensitive index of soil P availability than is commonly thought.     

Investigation into manganese deficiency in mature oil palms(E. guineensis) in Malaysia

Manganese deficiency was confirmed on prominently chlorotic palms with small canopies grown on very sandy colluvium. An experiment to assess the effects of the Mn deficiency on palm growth and yield was carried out. The effectiveness of the application of MnSO₄ at various rates to correct the deficiency was tested. Manganese concentration < 25µg Mn g^–1 in Frond 17 was found to be indicative of deficiency. Soil application of MnSO₄ at 150 g palm^–1 plus 60 g palm^–1 as foliar spray was most effective for short term correction. Higher rates (300 g MnSO₄ palm^–1) were required for soil application only. Cumulative yield over 42 months after treatment showed significantly higher number of harvested fresh fruit bunches. Full recovery of canopy size, colour and vigour took up to two years.     

Effects of urea fertigation of apple trees on soil pH,exchangeable cations and extractable manganese in a sandy loam soil in New Zealand

Changes in soil pH, exchangeable aluminium (Al), calcium (Ca), magnesium (Mg), and potassium (K) and extractable manganese (Mn) were investigated after urea fertigation of a sandy loam soil in an apple orchard in New Zealand. Urea at three rates (0, 25, 50 kg N ha^–1 yr^–1 or 0, 16.9, 33.8 g N emitter^–1 yr^–1) was applied in 4 equal fertigations. Soil cores at 4 profile depths (0–10, 10–20, 20–40 and 40–60 cm) directly below and 20 cm from the emitter were sampled approximately 4 weeks after each fertigation and in the following winter. Results obtained showed that the largest changes in soil pH and cations occurred in soils directly below the emitter in the 50 kg N ha^–1 yr^–1 treatment where the soil pH decreased by 1.6 pH units at all soil depths. The lowest pH of 4.3 was observed at a depth of 27 cm. Exchangeable Al and extractable Mn levels increased to 11 meq kg^–1 and 78µg g^–1 respectively. Estimated losses of Ca, Mg and K from the upper soil profile depth (0–10 cm) represented 23, 63 and 27% of their respective total exchangeable levels. At lower profile depths (>20 cm), accumulation of displaced K was evident. Variable, and generally non-significant, chemical changes recorded in soils 20 cm from the emitter were attributed to restricted lateral water movement, and therefore urea movement, down the profile.The present study showed that one season of urea fertigation by trickle emitters, applied to a sandy loam, at half the rate conventionally applied to apple orchards (50 kg N ha^–1 yr^–1) resulted in pH and mineral element imbalances which were potentially and sufficiently severe to inhibit tree growth.