Effect of superplasticizer on plastic shrinkage of plain and silica fume cement concretes

Four types of superplasticizers were used in conjunction with three types of silica fume to prepare cement concrete slab specimens that were utilized to measure plastic shrinkage strain and time to attain maximum strain. The concrete slab specimens were cast and placed in an exposure chamber in which the relative humidity, temperature, and wind velocity were kept at 35 ± 5%, 45 ± 2 °C, and 15 ± 2 km/h, respectively. Results of this investigation indicate that the plastic shrinkage strain varied with the type of superplasticizer and the type of silica fume. Maximum plastic shrinkage strain was measured in the undensified silica fume cement concrete with all superplasticizers. Incompatibility was noted between polycarboxylic ether superplasticizer and plain and two types of silica fume cement concretes.     

Behavior of FRP-confined concrete after high temperature exposure

This paper presents the results of an experimental program to investigate the effect of high temperature on the performance of concrete externally confined with FRP sheets. For this purpose, a two-phase experimental program was conducted. In the first phase, 42 standard 100 × 200 mm concrete cylinders were prepared. Out of these specimens, 14 cylinders were left unwrapped; 14 specimens were wrapped with one layer of CFRP sheet; and the remaining 14 specimens were wrapped with one layer of GFRP sheet. Some of the unconfined and FRP-confined specimens were exposed to room temperature; whereas, other cylinders were exposed to heating regime of 100 °C and 200 °C for a period of 1, 2 or 3 h. After high temperature exposure, specimens were tested under uniaxial compression till failure. The test results demonstrated that at a temperature of 100 °C (a little more than the glass transition temperature (T_g) of the epoxy resin), both CFRP- and GFRP-wrapped specimens experienced small loss in strength resulting from melting of epoxy. This loss of strength was more pronounced when the temperature reached 200 °C. In the second phase of the experimental program, three 100 × 100 × 650 mm concrete prisms were prepared and then overlaid by one layer of CFRP and GFRP laminates for conducting pull-off strength tests as per ASTM D4541 – 09. The objective of this testing was to evaluate the degradation in bond strength between FRP and concrete substrate when exposed to elevated temperature environments. One prism was exposed to room temperature whereas the other two specimens were exposed to heating regime of 100 °C and 200 °C for a period of 3 h. It was concluded that a significant degradation in the bond strength occurred at a temperature of 200 °C especially for CFRP-overlaid specimens.     

Mechanical properties of normal and high strength concretes subjected to high temperatures and using image analysis to detect bond deteriorations

The effect of high temperatures, up to 250 °C, on mechanical properties of normal and high strength concretes with and without silica fume was investigated, and image analysis was performed on split concrete surfaces to see the change in bond strength between aggregate and mortar. Specimens were heated up to elevated temperatures (50, 100, 150, 200, 250 °C) without loading and then the residual compressive and splitting tensile strength, as well as the static modulus of elasticity of the specimens were determined. For normal strength concrete residual mechanical properties started to decrease at 100 °C, while using silica fume reduced the losses at high temperatures. In terms of percent residual properties, high strength concrete specimens performed better than normal strength concrete specimens for all heating cycles. Image analysis studies on the split surfaces have been utilized to investigate the effect of high temperatures on the bond strength between aggregate and mortar. Image analysis results showed that reduced water–cement ratio and the use of silica fume improved the bond strength at room temperature, and created more stable bonding at elevated temperatures up to 250 °C.     

Long-term bond performance of GFRP bars in concrete under temperature ranging from 20 °C to 80 °C

Eighty pull-out specimens were used to study the effect of temperature ranging from 20 °C to 80 °C in dry environment on bond properties between Glass Fiber Reinforced Polymer (GFRP) bars and concrete. The pullout-test specimens were subjected during 4 and 8 months to high temperatures up to 80 °C and then compared to untreated specimens (20 °C). Experimental results showed no significant reduction on bond strength for temperatures up to 60 °C. However, a maximum of 14% reduction of the bond strength was observed for 80 °C temperature after 8 months of thermal loading. For treated specimens, the coefficient β in the CMR model, which predicts the bond–stress–displacement behavior, seems to be dependant with the temperature.     

Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements

The aim of this work is to determine the most convenient calcination temperature of kaolinite clays in view of producing geopolymer cements. In this light, the clay fractions of three kaolin minerals were used. The clay fractions were characterized (chemical and thermal analyses and X-ray diffraction) and then calcined in the temperature range of 450 and 800 °C. The obtained amorphous materials were dissolved in a strongly alkaline solution in order to produce geopolymer cements whose pastes were characterized by determining their setting time, linear shrinkage and compressive strength. Hardened geopolymer cement paste samples were also submitted to X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy analyses. The setting time of geopolymer cement pastes produced from the clay fractions calcined at 450 °C was very long (test samples could be handled easily only after 21 days at the ambient atmosphere of the laboratory). For the clay fractions calcined between 500 and 700 °C, the setting time of geopolymer cement pastes reduced with increasing temperature and varied between 130 and 40 min. Above 700 °C, the setting time began to increase. The linear shrinkage of the hardened geopolymer cement paste samples aged between 21 and 28 days attained its lowest value around 700 °C. Above 700 °C, the linear shrinkage began to increase. The compressive strength of the hardened geopolymer cement paste samples was between 11.9 and 36.4 MPa: it increased with samples from the clay fractions calcined between 500 and 700 °C but dropped above 700 °C.It can be concluded that the most convenient temperature for the calcination of kaolinite clays in view of producing geopolymer cements is around 700 °C.     

Strengths and flexural strain of CRC specimens at low temperature

Crumb rubber concrete (CRC) is made by adding rubber crumbs into conventional concrete. This study undertakes an experimental study on the cubic compressive strength, axial compressive strength, flexural strength and splitting tensile strength of CRC specimens at both ambient temperature 20 °C and low temperature ?25 °C. The flexural stress–strain responses were also recorded. The averaged size of rubber crumbs used in the study is about 1.5 mm. Four levels of rubber contents are investigated, which are 0%, 5%, 10% and 15% by volume, respectively. The mix design aimed at 40 MPa of compressive strength and 100 mm of slump for all the CRC specimens. The results show that CRC increases its magnitude in strengths when temperature decreases, which is similar to the case of conventional concrete, but still exhibits ductility in low temperature. The conclusion from this study is that CRC may be more beneficial in its application in low temperature environments than in ambient temperature environments.     

The effect of cement dosage on mechanical properties of concrete exposed to high temperatures

Although concrete is a non-combustible material, it is found that when exposed to high temperatures, such as fire, the physical, chemical and mechanical properties of concrete can drastically change. Thus, it becomes important to assess the relative properties of concrete under high temperatures in order to evaluate and predict the post-fire response of reinforced concrete (RC) buildings and structures. This paper assesses the effects of elevated temperatures and cement dosages on the mechanical properties of concrete. Two concrete mix designs were considered in this research in an attempt to study the effects of cement dosage (250 and 350 kg/m³) on the post-fire response of concrete. Once cast, the test samples were first exposed to elevated temperatures ranging from 100 to 800 °C, and then allowed to cool down slowly to ambient room temperature of 20 °C before being tested to failure. Several tests were then carried out to determine the mechanical properties of the cooled concrete specimens. The test results indicated that at temperature above 400 °C, concrete undergoes significant strength loss when compared to the strength of non-heated concrete. In addition this strength reduction was found to be unaffected by the cement dosages. The experimental results were also compared with current European standard (BS EN 1992-1-2:2004 standard) strength equations and American Concrete Institute standard (ACI 216.1).     

Modeling mechanical performance of lightweight concrete containing silica fume exposed to high temperature using genetic programming

In this study, the mechanical performance of lightweight concrete exposed to high temperature has been modeled using genetic programming. The mixes incorporating 0%, 10%, 20% and 30% silica fumes were prepared. Two different cement contents (400 and 500 kg/m³) were used in this study. After being heated to temperatures of 20 °C, 200 °C, 400 °C and 800 °C, respectively, the compressive and splitting tensile strength of lightweight concrete was tested. Empirical genetic programming based equations for compressive and splitting tensile strength were obtained in terms of temperature (T), cement content (C), silica fume content (SF), pumice aggregate content (A), water/cement ratio (W/C) and super plasticizer content (SP). Proposed genetic programming based equations are observed to be quite accurate as compared to experimental results.     

Experimental behaviour of RACFST stub columns after exposed to high temperatures

The experimental studies on the behaviour of recycled aggregate concrete-filled steel tube (RACFST) stub columns after exposed to high temperatures are reported in this paper. Forty specimens, including 32 RACFST stub columns and 8 normal concrete-filled steel tube (CFST) stub columns as reference, were tested, and the failure pattern, load versus strain relation and ultimate strength of the specimens were presented and analysed. Five types of concrete were produced: one reference concrete with natural aggregates, two concrete mixes with recycled coarse aggregate (RCA) replacement ratios of 50% and 100%, and two concrete mixes with recycled fine aggregate (RFA) replacement ratios of 50% and 100%. The specimens were exposed to 300 °C, 600 °C and 800 °C for 3 h. The test results showed that, due to the existence of the recycled aggregates, the post-fire performance of RACFST stub columns was lower than the corresponding normal CFST specimens under the same maximum temperature suffered, and the RACFST specimens with RCA had a better behaviour than those with RFA under the same recycled aggregate replacement ratio.     

Effect of elevated temperature on the mechanical properties of concrete produced with finely ground pumice and silica fume

This study investigated the effect of elevated temperature on the mechanical and physical properties of concrete specimens obtained by substituting cement with finely ground pumice (FGP) at proportions of 5%, 10%, 15% and 20% by weight. To determine the effect of silica fume (SF) additive on the mechanical and physical properties of concrete containing FGP, SF has been added to all series except for the control specimen, which contained 10% cement by weight instead. The specimens were heated in an electric furnace up to 400, 600 and 800 °C and kept at these temperatures for one hour. After the specimens were cooled in the furnace, ultrasonic pulse velocity (UPV), compressive strength and weight loss values were determined. The results demonstrated that adding the mineral admixtures to concrete decreased both unit weight and compressive strength. Additionally, elevating the temperature above 600 °C affected the compressive strength such that the weight loss of concrete was more pronounced for concrete mixtures containing both FGP and SF. These results were also supported by scanning electron microscope (SEM) studies.     

Concrete cover effect on reinforced concrete bars exposed to high temperatures

The mechanical properties of structural reinforcement steel have been investigated after the exposure to high temperatures. Plain steel, reinforcing steel bars embedded into mortar and plain mortar specimens were prepared and exposed to 20, 100, 200, 300, 500, 800 and 950 °C temperature for 3 h individually. The S420 deformed steel bars with diameters of ∅10, ∅16 and ∅20 were used. The mortar was prepared with CEM I 42.5 N cement and fly ash. The tension tests on reinforcements taken from cooled specimens were performed, and the variations in yield strength, ultimate strength and in resilience of three different dimensioned reinforcements were determined. A cover of 25 mm provides protection against high temperatures up to 400 °C. The high temperature exposed plain steel and the steel with 25-mm cover has the same characteristics when the reinforcing steel is exposed to a temperature 250 °C above the exposure temperature of plain steel.     

Cementitious characteristics of hydrated cement paste subjected to various dehydration temperatures

This paper emphasizes on studying the cementitious characteristics and the relative rehydration capability of dehydrated cement paste (DCP). Several specimens of DCP were firstly prepared, respectively after pre-heating the powders of hydrated cement paste (HCP) at different temperatures ranging from 300 °C to 900 °C. The cementitious properties of each DCP were then evaluated by the required water of standard consistency, setting time, degree of rehydration, compressive strength development and microstructure evolution. The experimental results show that DCP has highly required water of standard consistency, short setting time and rapid rehydration rate compared with ordinary Portland cement, and also indicate that the rehydration capacity of DCP is influenced by the dehydration temperature.     

Formulation of blended cement: Effect of process variables on clay pozzolanic activity

Chemical, physical and mineralogical properties of crude and calcined local kaolinitic clay were studied in detail in order to use it as an artificial pozzolan. The aim of this study was to investigate and optimize the properties of mortars in which calcined clay is employed as a pozzolan.A three variable (calcination time: X1, calcination temperature: X2 and % of calcined clay in the blended cement: X3) rotatable orthogonal composite design was set up. It was concluded that the compressive strengths were governed by the calcination temperature and the percentage of the calcined clay in the blended cement. It was proven that the strengths could be improved by increasing simultaneously the percentage of incorporation and the calcination temperature of the clay. It was also demonstrated that at temperatures lower than 700 °C, the increase of the calcination time, improved the compressive strength, while above 700 °C, the opposite effect was observed. Finally, a blended cement composition has been formulated and optimized using the desirability functions. The optimized blended cement contains 25% of calcined clay, heated for 3 h at a temperature of 750 °C.     

Permeability of high-performance concrete subjected to elevated temperature (600 °C)

Permeability is one of the most important parameters to quantify the durability of high-performance concrete. Permeability is closely related with the spalling phenomenon in concrete at elevated temperature. This parameter is commonly measured on non-thermally damaged specimens. This paper presents the results of an experimental investigation carried out to study the effect of elevated temperature on the permeability of high-performance concrete. For this purpose, three types of concrete mixtures were prepared: (i) control high-performance concrete; (ii) high-performance concrete incorporating polypropylene fibres; and (iii) high-performance concrete made with lightweight aggregates. A heating–cooling cycle was applied on 160 × 320 mm, 110 × 220 mm, and 150 × 300 mm cylindrical specimens. The maximum test temperature was kept as either 200 or 600 °C. After the thermal treatment, 65 mm thick slices were cut from each cylinder and dried prior to being subjected to permeability test. Results of thermal gradients in the concrete specimens during the heating–cooling cycles, compressive strength, and splitting tensile strength of concrete mixtures are also presented here. A relationship between the thermal damage indicators and permeability is presented.     

Impact of melting and burnout of polypropylene fibre on air permeability and mechanical properties of high-strength concrete

This study intends to investigate the impact of high temperature, melting and burnout of Polypropylene Fibre (PP fibre) on mechanical properties, pore size distribution and air permeability of high strength concrete. The specimens were high-strength concrete with 120 MPa strength produced with a water-binder ratio of 20%. To examine the effects of melting and burnout of the PP fibre, the experiment was conducted using two mixtures. One mixture contained 1.5 kg/m³ of PP fibre, while the other did not contain any PP fibre. Heating temperatures were set to room temperature (RT), 120, 200, 300 and 400 °C, considering the temperatures for the melting and burnout of the PP fibre. After heating and cooling, compression tests were carried out on the concrete specimens to measure the modulus of elasticity and Poisson's ratio. Pore size distribution was measured using the fragments created by the compression tests. Air permeability was estimated by measuring the pore size distribution. It was found that melting and burnout of the fibre did not affect the compressive strength and modulus of elasticity but the Poisson's ratio of the specimens containing fibres increased at 400 °C. The effect of melting and burnout of fibre on pore volume and air permeability is quite small. If it is assumed that micro-cracks affected the air permeability, it is expected that high strength concrete with a large fibre content should create many micro-cracks at high temperature, leading to an increase of air permeability.     

Shear strength of RC beams subjected to cyclic thermal loading

The experiments were performed for assessing the influence of cyclic thermal loading on the shear strength of reinforced concrete (RC) beam specimens. One hundred eleven RC beams of 100 × 150 × 1200 mm size reinforced in tension zone with two bars of 8, 10 and 12 mm diameters were tested under four point loading. The beams were subjected to a number of thermal cycles varying from 7 to 28 cycles with peak temperature taken as 100, 200 and 300 °C. The effects of thermal cycles on the crack pattern, failure mechanism, first crack load and the shear strength of beams have been discussed. The shear strength of the beams has been found to increase by up to 10% at lower temperature cycles of 100 and 200 °C but reduces by up to 14% at higher temperature (300 °C) depending on the severity of thermal loading. The results of study emphasize the need for developing appropriate guidelines for the design of RC structural elements used in comparatively high temperature environment with cyclic thermal loading conditions.     

Determination of the optimum conditions for tire rubber in asphalt concrete

The Taguchi method was used to determine optimum conditions for tire rubber in asphalt concrete with Marshall Test. The tire rubber in asphalt concrete was explored under different experimental parameters including tire rubber gradation (sieve #10–40), mixing temperature (155–175 °C), aggregate gradation (grad. 1–3), tire rubber ratio (0–10% by weight of asphalt), binder ratio (4–7% by weight of asphalt), compaction temperature (110–135 °C), and mixing time (5–30 min). The optimum conditions were obtained for tire rubber gradation (sieve #40), mixing temperature (155 °C), aggregate gradation (grad. 1), tire rubber ratio (10%), binder ratio (5.5%), compaction temperature (135 °C), mixing time (15 min).     

Modeling temperature distribution and thermal property of asphalt concrete for laboratory testing applications

Material characterization from laboratory tests on asphalt concrete or predictions of pavement performance are meaningful only if temperature of the material is well taken into account. This paper discusses an analytical model to predict the transient temperature distribution within asphalt concrete and to determine its thermal properties. The paper also presents the laboratory test program designed to validate the model. Temperature measurements were carried out on a cylindrical specimen at different times after the specimen with a steady-state low temperature (3.5 °C) was placed inside an environmental chamber in a steady-state high temperature (36 °C). The temperature magnitude at different positions and its variation with time was recorded at a sampling rate of 1 min⁻¹. The analytical temperature models based on the classical planar wall and long cylinder were established to approximate the temperature distribution of asphalt concrete specimens with the geometry of a short cylinder or a beam. Thermal diffusivity as a function of thermal conductivity and heat convection is solved from the models, and then back-calculation was conducted to achieve the thermal properties using curve fitting. It was found that the analytical model could predict the measured temperatures reliably. For the materials used in this research, a thermal conductivity of 2.88 W/m °C and diffusivity of 1.42 × 10⁻⁶ m²/s were attained from the back-calculation. The time–temperature relationship, as determined from the prediction model, was found to be very sensitive to the geometric size and thermal properties of asphalt concrete.     

A study of the permeability and acid attack of corn cob ash blended cements

The durability of concrete made with corn cob ash (CCA) blended cement was investigated in this study. Permeability and chemical attack involving H₂SO₄ and HCl were the key parameters considered. Nine classes of CCA blended cements were employed with the CCA content ranging from 0% to 25%. The 0% CCA replacement involved the use of normal ordinary Portland cement and it served as the control. The water absorption of blended cement concrete was performed using 100 mm cube specimens of mix proportions 1:1½:3, 1:2:4 and 1:3:6 with 0.5, 0.6 and 0.7 water-to-binder ratios, respectively. The chemical attack test was carried out using 50 × 50 × 15 mm mortar specimens of mix proportions 1:1, 1:2 and 1:3 with water-to-binder ratio ranging between 0.26 and 0.29. The results indicated that the use of CCA blended cement reduces the water absorption of concrete specimens. Optimal reduction occurred at 10% CCA replacement for 1:1½:3 and 1:2:4 mix proportions and at 15% CCA replacement for 1:3:6 mix proportion. The resistance to chemical attack was improved as the addition of CCA up to 15% replacement level, caused a decrease in permeability and reduction in weight loss due to reaction of the specimens with HCl and H₂SO₄ acid water.     

Post-crack (or post-peak) flexural response and toughness of fiber reinforced concrete after exposure to high temperature

Several studies have already reported on the various effects of high temperature on the mechanical properties of fiber reinforced concrete (FRC). Some of these effects include changes in; compressive strength, compression toughness and splitting tensile strength. None of the previous studies have investigated the changes that might occur on the post-crack flexural response and flexural toughness. Post-crack (or peak) response and toughness is considered one of FRC’s key beneficial characteristics – as the purpose of adding fibers is to increase the energy absorption and load carrying capacity after an initial crack. In this study, the flexural toughness test according to ASTM C1018 was carried out on two types of concrete: plain concrete and fiber reinforced concrete with three different types of fiber (steel, polypropylene, and polyethylene) at 0.5% and 1.0% by volume fractions. Prior to the flexural test, the specimens were put in an oven chamber and subjected to high temperatures using the ISO/TR834 standards of: 400 °C, 600 °C and 800 °C. The results showed the typical load–deflection response of FRC was a double-peak response. The first peak represented the properties of concrete matrix and the second peak represented the properties of the fibers used. Under flexural load, instead of dropping (or remaining unchanged), the post-peak load and the toughness were found to increase at lower temperatures (400 °C) and later, decreased as the temperature increased (600 °C and 800 °C). Fiber type and content also played an important role. At a temperature of 400 °C, all FRCs exhibited higher flexural strength and increased post-peak response and toughness. A significant decrease in strength, toughness and load–deflection response was observed with synthetic or plastic FRC (PFRC) when the temperature approached 800 °C. When steel FRC (SFRC) was used, those effects were relatively small. It appears, SFRC has better heat resistance than the PFRC. The density (measured by ultrasonic pulse velocity) was found to decrease more in the PFRC than in the SFRC.