Mn对Al-Mg-Si-Cu铝合金结晶相的影响

通过扫描电镜/能谱、 X射线衍射以及金相分析, 针对含0.3?(质量分数)的Al-Mg-Si-Cu铝合金, 研究了Mn含量对其结晶相的影响. 研究表明: 合金在铸造过程中形成的结晶相为Al1.9CuMg4.1Si3.3, Al5(FeMn)Si, Al8(FeMn)2Si以及少量的Mg2Si; 增大含Mn量, 合金中AlFeMnSi型结晶相数量增多; 对合金进行均匀化处理时, Al1.9CuMg4.1Si3.3相完全溶解, 发生Al5(FeMn)Si向Al8(FeMn)2Si相的转变; 对合金进行轧制及最终热处理后, 结晶相碎化且沿轧向呈纤维状分布, 但结晶相的类型不变.     

Effect of Mg on microstructures and properties of Al-Mg-Si-Cu aluminium alloys for automotive body sheets

The effects of variation of Mg content on microstructures, the tensile properties and the formability of Al-Mg-Si-Cu alloys for automotive body sheets were investigated by means of scan electron microscopy, optical metallographic analysis, tensile and Ericsson tests. The results show that for Al-Mg-Si-Cu aluminium alloys with excessive Si, with an increment of Mg content, the strength enhances, the specific elongation and Erisson values of alloys decrease, and the number of Mg2 Si constituent increases and that of AI(MnFe)Si type constituents reduces. Al-Mg-Si-Cu aluminium alloys with excessive Si for automotive body sheets can present obviously the paint bake hardenability during the paint hake cycle (i. e. artificial aging at 170℃ for 30 min immediately after the solution treatment and quenching). Suitable Mg content should be controlled in the range of 0.8% and 1.2%(mass fraction).     

Cu及热处理制度对Al—Mg—Si系合金晶间腐蚀敏感性的影响

采用浸泡腐蚀实验和电化学实验研究了强化元素Cu含量的改变及不同时效制度对Al-Mg-Si合金晶间腐蚀敏感性的影响,并利用XRD和SEM对腐蚀产物的构成及形貌进行了分析与观察,浸泡腐蚀实验结果表明：在峰时效的状态下,在0.5%Cu以上的合金中可观察到明显的晶间腐蚀而且随着Cu含量的增加,合金最大腐蚀深度增加;在欠时效状态下,1%Cu以上的合金中观察到了微弱的晶间腐蚀;在过时效状态下,所有实验合金均只出现点蚀,电化学实验结果表明：随着Cu含量的增加,合金的Ψcorr向正的方向变化,Jcorr增加,欠时效状态下的Ψcorr比峰时效状态下的负,腐蚀电流密度较小。     

Effect of strontium on crystallization of Mg2Si phase in Al—Si—Mg casting alloys

Otical microscope and SEM were used to observe the changes of the microstructure of Al-11.6%Si-0.4% Mg alloys with varying strontium additions and the effect of strontium on the crystallization of Mg2Si phase was discussed.It is found that Mg2Si phase nucleastes on the the surfaces of the eutectic silicon flakes in the unfully modified alloys,growing as meshwork or bamboo-shoot shape,however,very few and fine Mg2Si particles phase are isolated at the boundaries of the eurectic cells in the fully modified alloys.Strontium has an important influence on the crystallization of Mg2Si phase in the Al-Si-Mg casting alloys and it is thought to be related to the increase of the amunt of dendritic αphase and the modifying degree of eutectic silicon phase.     

合金元素对Mg-Al-Si系镁合金中Mg2Si相形貌影响的研究进展

合金化和微合金化作为变质Mg-A1-Si系镁合金中汉字状Mg2Si相的一种工艺手段,目前已引起国内外的广泛关注和高度重视,并对此开展了大量的研究。本文综述了合金元素变质Mg-Al-Si系耐热镁合金中汉字状Mg2Si相的研究进展,尤其是Al、Si、Sb、Ca、P、RE和Sr等合金元素对汉字状Mg2Si相形貌的影响及其变质机理,指出了目前还存在的问题,并对今后的发展进行了展望。     

铝含量对AS系列铸造镁合金机械加工性能的影响(英文)

研究铝含量对AS系列铸造镁合金机械加工性能的影响。通过测量切削力和表面粗糙度对镁合金的机械加工性能进行评估。研究合金的微观结构和拉伸性能。结果表明,切削力随着铝含量的增加而增大;AS91镁合金的表面粗糙度和力学性能最高;对力学性能有影响的主要机制是存在金属间相Mg2Si和Mg17Al12。在机械加工镁合金中,切削力随着切割速度的增大而增大。所测得的数据与机械加工合金的力学性能一致。     

Mg2Si强化相对AZ31镁合金挤压组织与力学性能的影响

通过Al-Si中间合金取代Al添加,并经热挤压成形,在AZ31镁合金中引入Mg₂Si强化相。采用光学显微镜(OM)、扫描电镜(SEM)、X射线衍射分析(XRD)、电子万能试验机等研究了Mg₂Si强化相对AZ31镁合金挤压组织与力学性能的影响。结果表明,添加Al-Si中间合金后的Mg-3(Al-Si)-Zn挤压组织呈现明显的双峰分布特征,Mg₂Si颗粒相可通过粒子激发形核(PSN)作用促进动态再结晶,在碎化的Mg₂Si颗粒相周围,合金组织显著细化,形成明显异于其他正常尺寸晶粒的细晶区。引入Mg₂Si强化相后,Mg-3(Al-Si)-Zn挤压态合金的屈服强度和抗拉强度都得到提高,分别达到175和269 MPa,同时伸长率略有降低。     

Effects of Al-10Sr master alloys on grain refinement of AZ31 magnesium alloy

The effects of Al-10Sr master alloys on grain refinement of AZ31 magnesium alloy were investigated, and the refinement efficiency of different Al-10Sr master alloys （commercial, solubilized, rolled and remelted＋rapidly cooled） was compared and analyzed. The results indicate that the morphology and size of Al4Sr phases in the microstructures of different Al-10Sr master alloys, are of great difference. For the commercial Al-10Sr master alloy, the Al4Sr phases evolve from coarse block shape to relatively fine block shape after being dissolved at 500 ℃ for 4 h and followed by water quenching; but after being rolled at 300 ℃ for 50% reduction or remelted and followed by rapid cooling, the Al4Sr phases mainly exhibit fine granule and fibre shapes. In addition, the different Al-10Sr master alloys can effectively reduce the grain size of AZ31 magnesium alloy, but their refinement efficiency is different. The refinement efficiency of the Al-10Sr master alloy obtained by remelting and rapid cooling is the best, then the rolled, solubilized and commercial Al-10Sr master alloys are in turn. The difference of refinement efficiency for different Al-10Sr master alloys may be related to the dissolution rates of Al4Sr phases with different morphologies and sizes in the melt of AZ31 magnesium alloy.     

均匀化退火对Mg-3Al-1Zn-2.2/5Sr镁合金中第二相的影响

为研究均匀化退火处理对Mg-3Al-1Zn-2.2/5Sr镁合金中第二相的影响,通过X射线衍射分析(XRD)、扫描电镜观察(SEM)和能谱分析(EDS)等手段,并结合Pandat热力学计算软件,对Mg-3Al-1Zn-2.2/5Sr镁合金均匀化退火后组织中的第二相的类型及形成原因进行了分析。结果表明:经过400℃,15 h(炉冷)的均匀化退火处理以后,合金铸态组织中原本存在的(Mg,Al)17Sr2相中固溶的Al元素所占原子分数有所降低。此外,Sr含量为2.2%(质量分数)的合金组织中可以观察到大量沿(Mg,Al)17Sr2相边缘分布的颗粒状Al4Sr相,而Sr含量为5%的合金中基本观察不到(Mg,Al)17Sr2相的变化。     

Si含量和冷却速率对Mg2Si/Al复合材料组织与耐磨性能的影响

用浇注方法制备了不同的Mg2Si/Al复合材料,研究Si含量和冷却速率对Mg2Si/Al复合材料的组织与耐磨性能的影响并分析其机理。结果表明,随着Mg2Si/Al复合材料中Si含量的上升,初生Mg2Si相的数量逐渐增多而尺寸不断减小,初生Si相的数量不断增加而尺寸基本不变或略有增加;随着冷却速率的增加,Mg2Si/Al复合材料中的初生Mg2Si相和Si相的数量不断增加且尺寸不断减少;在干滑动磨损条件不变的前提下,随着Si含量的逐渐上升,Mg2Si/Al复合材料的磨损体积不断减小。     

Effect of aluminum content on mechanical properties of hydrogenated Mg–Al magnesium alloys

The mechanical properties of hydrogenated Mg–Al magnesium alloys with various aluminum content were investigated. The ductility, yield strength (YS) and ultimate tensile strength (UTS) of the hydrogenated material decreased while the hardness increased with increasing the aluminum content. Microscopic observations of cross-sections of hydrogenated specimens with various Al content revealed that hydrogen cracks extended deeply as the Al content in the Mg–Al alloys increased. Moreover, X-ray diffraction (XRD) analysis revealed that MgH₂ and AlH₃ hydrides are formed during hydrogenation and were found to contribute to hydrogen embrittlement of Mg–Al alloys. However, the embrittled zone was observed to be larger at the fracture surface of Mg–15Al alloy than that of Mg–5Al alloy. Moreover, the fracture surface of Mg–30Al alloy exhibited completely brittle fracture after hydrogenation.     

RE对Mg-8Zn-4Al-0.3Mn合金组织的影响

研究了RE对Mg-8Zn-4Al-0．3Mn铸造镁合金显微组织的影响。结果表明：Mg-8Zn-4Al-0．3Mn-χRE铸造镁合金的显微组织主要由口(Mg)基体、φ(Al2Mg5Zn2)相、r(Mg32(Al,Zn)49)相和Mg3Al4Zn2RE相组成。随RE加入量的增加，合金晶界上三元相的形态由半连续网状改变为颗粒状，三元相的分布逐渐变得弥散而均匀。晶界上针状或棒状Mg3Al4Zn2RE相的量也随着RE加入量的增加而增加。加入1．5％的RE可显著细化合金的铸态组织，晶粒大小由120～130μm减小到40-50μm。合金的显微硬度值随着RE加入量的增加而增加。     

Solidification microstructural constituent and its crystallographic morphology of permanent-mould-cast Mg-Zn-Al alloys

1 Introduction Magnesium alloy exhibits light mass, high specific strength and stiffness. Therefore, extensive application of magnesium alloys to various automobile parts is expected to enhance fuel efficiency through mass reduction. However, the unsatisf…     

Grain refinement of AZ31 magnesium alloy by new Al-Ti-C master alloys

New Al₄C₃-containing Al-Ti-C master alloys (Al-0.6Ti-1C and Al-1Ti-1C) were developed by introducing Ti element into Al-C melt using melt reaction method, in which most of the TiC particles distribute around Al₄C₃ particles. It is believed that most of the C firstly reacts with Al melt and form Al₄C₃ particles by the reaction Al(l)+C(s)→Al₄C₃(s), and after adding Ti into the Al-C melt, the size of Al₄C₃ particles is decreased and the distribution of Al₄C₃ is improved through the reaction Ti(solute)+Al₄C₃(s)→TiC(s)+Al(l). With the addition of 1% Al-1Ti-1C master alloy, the average grain size of AZ31 is reduced sharply from 850 μm to 200 μm, and the grain morphology of α-Mg transits from a fully-developed equiaxed dendritic structure to a petal-like shape. Al-C-O-Mn-Fe compounds are proposed to be potent nucleating substrates for primary Mg. Appropriate addition of Ti is believed to increase the grain refinement efficiency of Al₄C₃-containing Al-Ti-C master alloys in AZ31 alloy.     

Al-Mg-Sc中间合金的制备

在非真空条件下用氟化物熔盐体系镁 (铝 )热还原法制备了Al Mg Sc中间合金 ,讨论了金属还原剂的选择及还原温度、时间等工艺条件对钪收率的影响 ,并研究制定了氧化钪固相氟化制备氟化钪熔盐工艺。采用Al Mg合金熔体为还原剂经二次还原后钪收率 >80 %,制备的Al Mg Sc中间合金铸锭中钪含量 >1.9%,最佳的还原反应温度为 110 0K ,还原时间 40min .。氟化钪还原产生的初生态钪与铝作用形成稳定的Al3 Sc化合物 ,促进了还原的进行 ,使钪收率得到了大幅度提高。