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1.
Theimpactofrareearthsonenvironment,healthandecosystem ,anditslong termbio logicaleffectshavedrawnpeople′smuchatten tion ,manyworkshavebeendone ,butlittlehasknownabouttheeffectofrareearthontraceelements[1 ] .Traceelementsplayanim portantroleindevelopment ,meta…  相似文献   

2.
Currentlytheincidenceandlethalityofthrombusillnessareveryhigh ,anditseriouslythreatenspublichealth .Thrombolysisisoneoftherelativelyeffectivemethodstotreatthedis ease .Single chainurokinase typeplasminogenactivator (scu PA 3 2k )oflowmolecularweight(3 2kD)wasdi…  相似文献   

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Itwasprovedbypreviousworks[1] thatrareearthelementspromotethegrowthandde velopmentofplantsandincreasetheyieldofcropsatlowconcentration ,butwhenthecon centrationishigh ,theywillinhibitthegrowthofplants .Itwasalsoproved[2 ,3] thatrareearthelementsexhibitbothpos…  相似文献   

5.
The methylotrophic yeast ,Pichia pastorishasbeen developed to be an outstanding host for the pro-duction of foreign proteins since its alcohol oxidasepromoter was isolated and cloned ,and its transforma-tion was first reported in 1985[1 ,2].This organismh…  相似文献   

6.
Becauseoftheexcellentspectroscopicandmagneticpropertiesoftri positivelan thanideionscoupledwiththesimilaritiesbe tweenthemandCa2 + ionparticularlywithre gardtoionicradii,ligandexchangeratesandcoordinationnumbers[1] ,manystudieshavefo cusedonapplicationoflan…  相似文献   

7.
Rare earth complexes with trans-1,2-diaminocyclohexane-N,N,N ,N -tetraacetic acid (DCTA) of the Ln(dcta) type exhibited an unusual sequence of affinity on the polystyrene anion exchangers: pm^3+〉Nd^3+〉Sm^3+〉Pr^3+〉Ce^3+〉Eu^3+〉Gd^3+〉La^3+〉Sc^3+〉Tb^3+〉Dy^3+〉 Ho^3+〉Y^3+〉Er^3+〉Tm^3+〉Yb3+〉Lu^3+[1]. Taking into account the position of Y^3+, Sm^3+, and Nd^3+ in this affinity series, for the monodispersive polystyrene anion exchangers, Lewatit MonoPlus M 500, Lewatit MonoPlus M 600, Lewatit MonoPlus MP 500, Lewatit MonoPlus MP 64, and for the heterodispersive anion exchanger, Lewatit MP 62, the weight (Dg) and bed (Dv) distribution coefficients of these complexes and working ion exchange capacities (Cw) were determined. Based on these values, purifications of Y^3+ from Nd^3+ and Y^3+ from Sm^3+ in the macro-micro component system on these anion exchangers were studied. The application potential of this method was highlighted for the separation of Y^3+ in the presence of Nd^3+ and Sm^3+. With 1 L of monodispersive and strongly basic polystyrene gel anion exchanger Lewatit MonoPlus M 500 in the acetate form, it is possible to obtain approximately 79 g Y2O3 purified from Nd2O3 and 70 g Y2O3 purified from Sm2O3 in the same process condition.  相似文献   

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Influence of CaO on thermal decomposition of REFCO3 was studied. The results showed that CaO did not affect significantly the decomposition ratio of REFCO3. The XRD experiment showed that there was a great deal of CaF2 in the masting production, the gas chromatographic analysis on the gas of REFCO3 decomposed, and the 70% content of fluorine in the gas of REFCO3 added 15% CaO was reduced. CaO could absorb the fluorine from the decomposition of REFCO3, and the environmental pollution of the fluorine was greatly alleviated,  相似文献   

10.
Cadmiumis non-nutrition element for the plantgrowth,it can cause potential threat to the environ-ment safety as it remains in the nature for a very longti me,and once its concentrations reach or exceed acertainthreshold value,it will interfere withthe met…  相似文献   

11.
longwiththewidespreadapplicationoftheREEinagriculture ,animalhusbandaryandmedicineofourcountry ,theincreasingconcernwiththeREEcallsforthextensivestudiesontheirmetabolicaccumulationandbi ologicaleffects .ThatsomecellscantakeinREEbymeansofphagocytosisorpi…  相似文献   

12.
Inthelastfewyears ,theapplicationsofpolyox ometalates (POMs)havereceivedmuchattention[1~ 3]fortheiruniquestructuresandproperties ,however ,thepreparationofthemareallofsolid solidorliquid liquidreactions[1] .Fromtheknowledgeoffundamen taltheory ,wethinkthatrareearthelementscanbepermeatedintoPMOsthroughthesolid gasinterfacereaction ,andtoourknowledgethiskindofexperi menthasnotbeencarriedoutuntilnow .Inthispaper ,thechemistry heateddiffusedperme ationmethod[4 ] wasusedtotreatK10 H3[Dy(SiW4 M…  相似文献   

13.
RE oxide and mixedoxide electrodes were prepared bythermal decomposition procedure.The effect of precursor, decomposition temperature and coatingtimes on oxide properties wasstudied. The results from the measurements of polarization curvesfor various RE compounds in equimolar NaCI-KCI smelts at 700℃show that some RE oxide electrodes can decrease anodic overpotential by 50-110 mV at an industrial current density of 0.6A cm - 2. Repeated experimentalerrors are less than 30 mV. Theelectroc…  相似文献   

14.
稀土纳米材料   总被引:11,自引:1,他引:10  
稀土纳米材料是一种新型材料,已经引起人们的极大兴趣。本文综述了稀土纳米材料的进展,着重叙述了稀土永磁材料、稀土化合物纳米粉末、稀土合金和复合材料。  相似文献   

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稀土大磁致伸缩材料研究   总被引:12,自引:0,他引:12  
本文采用丘克拉尔斯基法制备晶粒取向的(Tb0.28Dy0.72)Fe1.95磁致伸缩材料,研究了材料的微观结构对磁致伸缩系数的影响。当(Tb0.28Dy0.72)Fex中x=1.95时,有明显的压应力效应,在10MPa、200kA/m时,磁致伸缩系数1500×10-6,当x=2时,由于出现RFe3相,压应力效应随之减小。  相似文献   

17.
Thefirstcommerciallysuccessfulelectrolumi nescencedisplayofthethinfilmMISIMtype(metal in sulator semiconductor insulator metal)withS=ZnS∶Mn reiescompletelyonaspecialhighfieldelectronictrans portmodecalled“travellingspiketransport”.Optimum excitationefficiencyandavalanchinghavebeenachie vedwiththisballistic(loss freewithrespecttopho nons)accelerationprocess.Itsthresholdfieldstrength isabout106V·cm-1inZnS,andislowenoughforthe resultingelectricbreakdowntobemadereversiblevia chargecontrol,…  相似文献   

18.
We presented results of electrical resistivity, magnetoresistivity and Seebek effect measurements done in the paramagnetic state of an antiferromagnetically ordering intermetallic compound TmIn3. It was found that the magnetic part of the electrical resistivity showed maximum at 18 K and the lgT dependence in temperature range 20<T<100 K. The magnetoresistivity was negative. The transversal magnetoresistivity fulfilled the single-ion Kondo scaling for temperatures 2<(T+0.5 K)<28 K. Thermoelectricpower displayed a sharp minimum at 10 K. Electrical properties indicated that TmIn3 is likely a dense Kondo system.  相似文献   

19.
稀土元素在硬质合金中的分布和存在形态   总被引:3,自引:1,他引:3  
研究了稀土元素在硬质合金中的分布和存在形态。结果表明:液相烧结温度下,稀土金属原子吸附在WC/液相(YG合金)和(Tj,W)C/液相(YT合金)界面上;室温下,稀土元素在WC/γ相和(Ti,W)C/γ相界面处富集;在WC/γ相界和γ相中有球状析出物(含有稀土元素)存在。初步推测,稀土在此处以原子态存在,但不排除以化合状态存在的可能。  相似文献   

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