共查询到19条相似文献,搜索用时 265 毫秒
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硅钼蓝比色法测定钼酸铵中微量硅袁玉琴,陈泽民(湖北省化学研究所,武汉430074)硅钼蓝比色法是在微酸性溶液中,使硅与铅酸铵生成硅钼酸络离子,而硅钼酸络离子是氧化剂,可被合适的还原剂还原成钼蓝。在还原过程中,既不能使过剩的钼酸铰还原,又要保证硅钼酸络... 相似文献
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在酸性介质中,硫离子可以定量地将硅钼黄还原为硅钼蓝,通过测定硅钼蓝的吸光度,可间接测定硫离子的含量,从而建立了硅钼蓝分光光度法测定水中硫的新方法。论文详细探讨了硅钼蓝分光光度法测定硫离子的各种影响因素。结果表明,显色体系的最大吸收波长为730nm,硫离子质量浓度在0.4000~8.000μg/mL范围内服从比尔定律,线性相关系数γ=0.9996。方法用于测定河水、山泉水、井水、温泉水中硫离子的含量,标准加入回收率分别为97.5%~105.0%、97.1%~101.0%、95.8%~96.7%、101.4%~102.1%。 相似文献
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对硅钼蓝分光光度法测定磷矿石中的二氧化硅进行了研究。研究了硅钼黄的显色条件及干扰因素,在本方法试验控制H2SO4浓度范围内硅与钼酸钠生成硅钼黄,经FeSO4还原成硅钼蓝,SiO2含量在0~600μg/100ml范围内服从比耳定律。操作简便,重现性好,结果准确,测定磷矿石中的二氧化硅含量,结果满意。 相似文献
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水泥生料中SiO2的测定通常采用硅钼蓝分光光度法,但由于形成的硅钼蓝络合物不稳定,显色后来不及测定颜色便消失或者出现浑浊现象等,使测定结果受到影响.本文通过试验,找出了最佳测试条件,不仅能满足水泥生料中硅含量的测定,也可用于其他物料中少量或微量硅的测定. 相似文献
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通过探讨分光光度法测定水中常量二氧化硅的方法,在盐酸浓度为0.12 mol/L的酸度条件下,水样中活性硅与钼酸铵生成为硅钼黄,酒石酸掩蔽磷酸根等干扰物质,用抗坏血酸还原生成硅钼蓝,生成硅钼蓝络合物的颜色深度与水样中硅浓度成正比,符合郞伯比尔定律。本方法适用于SiO_2含量较高的水样中SiO_2的测定,如原水、循环冷却水和炉水等。此方法操作简单,准确度高,具有推广价值。 相似文献
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Lance D. Silverman Wieslaw A. Zdaniewski Nancy L. Brungard 《Journal of the American Ceramic Society》1990,73(9):2753-2756
A variety of ceramic coatings have been put on ceramic substrates by the molten metal transfer technique. In the diffision coating process a reactant metal dissolved in a molten "transfer agent" metal reacts with a substrate to form the coating. Titanium dissolved in molten tin has been reacted with silicon carbide, aluminum nitride, and silicon nitride substrates to produce titanium carbide and titanium nitride coatings, respectively. Similarly tantalum metal has been reacted to form carbide or nitride coatings. The unreacted tin is finally removed by decantation followed by acid leaching. 相似文献
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Simultaneous preparation of TiO2 and ammonium alum,and microporous SiO2 during the mineral carbonation of titanium-bearing blast furnace slag
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Yingjie Xiong Tahani Aldahri Weizao Liu Guanrun Chu Guoquan Zhang Dongmei Luo Hairong Yue Bin Liang Chun Li 《中国化学工程学报》1982,28(9):2256-2266
In this study, a route for simultaneous mineralization of CO2 and production of titanium dioxide and ammonium alum, and microporous silicon dioxide from titanium-bearing blast furnace slag (TBBF slag) was proposed, which is comprised of (NH4)2SO4 roasting, acid leaching, ammonium alum crystallization, silicic acid flocculation and Ti hydrolysis. The effects of relevant process parameters were systematically investigated. The results showed that under the optimal roasting and leaching conditions about 85% of titanium and 84.6% of aluminum could be extracted while only 30% of silicon entered the leachate. 84% of Al3+ was crystallized from the leachate in the form of ammonium aluminum sulfate dodecahydrate with a purity up to 99.5 wt%. About 85% of the soluble silicic acid was flocculated with the aid of secondary alcohol polyoxyethylene ether 9 (AEO-9) to yield a microporous SiO2 material (97.4 wt%) from the crystallized mother liquor. The Al- and Si-depleted solution was then hydrolyzed to generate a titanium dioxide (99.1 wt%) with uniform particle size distribution. It was figured out that approximately 146 kg TiO2 could be produced from 1000 kg of TBBF slag. Therefore, the improved process is a promising method for industrial application. 相似文献
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研究了应用浮选萃取光度法的原理测定钛酸钡中痕量硅的方法。在pH为1.2时,硅与钼酸铵生成硅钼杂多酸(硅钼黄),用抗血酸将其还原为硅钼蓝,当通入空气时,生成的硅钼蓝吸附在气泡上,随气泡上升到有机相,最终浮选分离进入异戊醇。络合物最大吸收波长位于803 nm,硅含量在0~1.4 mg/L范围内符合比尔定律,摩尔吸光系数为3×104 L/(mol.cm),相关系数为0.996 7,加标回收率在96%~102.5%。该方法集分离与测定于一体,具有灵敏度高、选择性好、方便、快速的特点,可用于钛酸钡中硅的测定。 相似文献
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提高硅钼黄比色溶液稳定性的研究 总被引:3,自引:0,他引:3
试验、分析和总结了影响β硅钼黄稳定性的显色条件、溶液组成及稳定剂的选用等诸多因素。发现丙酮的稳定效果比乙醇好,且没有光化学还原干扰。试验表明,在pH,0.6~1、钼酸铵含量为0.8%~1.2%、丙酮含量为5%~10%、大体积显色所形成的β硅钼黄在30,℃以下能稳定4,h以上,且重现性好,能较好地满足分析要求。用氟化钾和硼酸进行解聚处理后的试液,若在玻璃容量瓶中显色并放置,氟仍会侵蚀玻璃,引起干扰。研究改进后的硅钼黄法,其准确度和精密度与抗坏血酸还原-硅钼蓝法相似,分析微量二氧化硅S≤0.014%、RSD≤1.5%,但比硅钼蓝法快速、简便、节省试剂。 相似文献
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Yingjie Xiong Tahani Aldahri Weizao Liu Guanrun Chu Guoquan Zhang Dongmei Luo Hairong Yue Bin Liang Chun Li 《中国化学工程学报》2020,28(9):2256-2266
In this study, a route for simultaneous mineralization of CO2 and production of titanium dioxide and ammonium alum, and microporous silicon dioxide from titanium-bearing blast furnace slag (TBBF slag) was proposed, which is comprised of (NH4)2SO4 roasting, acid leaching, ammonium alum crystallization, silicic acid flocculation and Ti hydrolysis. The effects of relevant process parameters were systematically investigated. The results showed that under the optimal roasting and leaching conditions about 85% of titanium and 84.6% of aluminum could be extracted while only 30% of silicon entered the leachate. 84% of Al3+ was crystallized from the leachate in the form of ammonium aluminum sulfate dodecahydrate with a purity up to 99.5 wt%. About 85% of the soluble silicic acid was flocculated with the aid of secondary alcohol polyoxyethylene ether 9 (AEO-9) to yield a microporous SiO2 material (97.4 wt%) from the crystallized mother liquor. The Al- and Si-depleted solution was then hydrolyzed to generate a titanium dioxide (99.1 wt%) with uniform particle size distribution. It was figured out that approximately 146 kg TiO2 could be produced from 1000 kg of TBBF slag. Therefore, the improved process is a promising method for industrial application. 相似文献
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Karthik Ramani William J. Weidner Ganesan Kumar 《International Journal of Adhesion and Adhesives》1998,18(6):401-412
Thermoplastics, having strong polar or hydrogen bonding groups, are potential candidates for thin film bonding. In this investigation, a thermoplastic polymer poly(ether ketone ether ketone ketone) (PEKEKK) is used as an adhesive to bond the titanium alloy (Ti-6Al-4V). The titanium alloy is silicon-sputtered to improve the bond strength to PEKEKK. The bond strengths of butt-joined specimens prepared using silicon-sputtered, silane-coated, sodium hydroxide-anodized round bars of titanium alloy as adherends are determined and compared with that of untreated titanium alloy round bars. Of the various thicknesses of silicon layers studied, layers that are 200 Å thick proved to have a more durable bond, as demonstrated by soak test results in Ringer's solution. It is observed that silicon sputtering enhances the bond strength of titanium alloy/PEKEKK butt joints and provides a more resistant interface to intruding water. The combination of anodization followed by silicon sputtering further improves the durability of the bond. It is confirmed by XPS analysis that fracture does not take place between the silicon and the titanium substrate. Wetting studies by contact angle method using water as test liquid, indicate significantly better wetting after silicon sputtering for Ti-6AL-4V adherends. 相似文献
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Lili Wang Xiaying Jiang Chenglong Wang Yi Huang Yiding Meng Jianzhong Shao 《Coloration Technology》2020,136(1):15-22
To improve the properties of titanium dioxide particles and realise their firm anchorage in blue light curing film, three modified titanium dioxide particles were prepared by grafting 3‐(trimethoxysilyl)propyl methacrylate, 3‐aminopropyltriethoxysilane and hexadecyltrimethoxysilane. The surface changes of titanium dioxide particles after modification were characterised. The dispersion stability, photo‐polymerisation, rheological and mechanical properties of modified titanium dioxide blue light curing inks were investigated. Results showed that compared with native titanium dioxide, modified titanium dioxide particles were more appropriate for blue light curing ink. The particle sizes of the three modified titanium dioxide particles became smaller, their surfaces exhibited hydrophobicity, and the viscosity of the modified titanium dioxide inks decreased slightly. Of the three modified titanium dioxide particles, 3‐(trimethoxysilyl)propyl methacrylate‐ and hexadecyltrimethoxysilane‐modified titanium dioxide particles exhibited better dispersion stability in blue light curing ink. In particular, 3‐(trimethoxysilyl)propyl methacrylate‐modified titanium dioxide blue light curing ink showed the best photo‐polymerisation and mechanical properties, which indicated the participation of the pigment grafted by double bonds in the blue light curable polymerisation. Using modified titanium dioxide in blue light curing ink, the dry/wet rubbing fastness of the printed fabrics improved. 相似文献