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使用粉煤灰和碱激发剂制备粉煤灰基土壤聚合物混凝土,并系统研究其物理力学性能、干缩和耐久性能。粉煤灰基土壤聚合物混凝土早期强度相对较低,后期增长明显。粉煤灰基土壤聚合物砂浆的干缩主要发生在早期,14d龄期后的干缩率均显著小于普通水泥砂浆,在150d龄期时为普通水泥砂浆的71.8%。硫酸盐侵蚀试验表明:在3%硫酸钠溶液中,粉煤灰基土壤聚合物砂浆没有产生任何膨胀,具有优良的抗硫酸盐侵蚀性能。即使粉煤灰基土壤聚合物含碱量高达10.6%,也不会产生危害性的碱-硅酸反应。粉煤灰基土壤聚合物混凝土快速碳化28d的碳化深度为14.0mm,抗冻等级在F100以上。自然浸泡法试验表明:粉煤灰基土壤聚合物混凝土的水溶性氯离子有效扩散系数为1.79×10-12m2/s,是混凝土的30.5%,具有比普通混凝土更好的抗氯离子侵蚀性能。粉煤灰基土壤聚合物混凝土具有适用的物理力学性能,较低的干缩,优良的耐久性能,是一种新型的结构材料。 相似文献
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以粉煤灰、矿粉两种工业废料为主要原材料,模数为1.2~1.8的水玻璃作为激发剂制备地聚合物。采用五因素四水平的正交试验组成设计方案,测试了水胶比(W)、碱激发剂掺量(S)、矿粉取代率(B)和水玻璃模数(M)在不同水平下试样的流动度、凝结时间、抗压强度和拉伸粘结强度。通过对结果进行极差分析和因素指标分析,得出这种绿色环保型修补材料的组成设计与性能指标之间的关联。综合分析得出,当水胶比为0.28,碱激发剂掺量为0.14,矿粉取代率为0.4,水玻璃模数为1.2时,制备出的地聚合物性能良好,达到绿色环保型建筑修补材料的要求。 相似文献
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《Planning》2019,(12)
针对无机陶瓷膜支撑体制备成本高及粉煤灰污染环境的问题,以粉煤灰和黄土为原料,以羧甲基纤维素(carboxymethyl cellulose,CMC)为粘结剂,以木屑为造孔剂,采用滚压法和固态粒子烧结法制得低成本支撑体,并通过X射线衍射仪(X-ray diffractometer,XRD)、扫描电子显微镜(scanning electron microscope,SEM)、压汞法、三点弯曲法及自制纯水通量测定装置分析了支撑体的物相组成、微观形貌、孔隙率及孔径分布、抗折强度及纯水通量,探究了原料配比、CMC及木屑添加量对支撑体性能的影响。结果表明,当粉煤灰与黄土配比为3∶2、CMC添加量为4%、木屑添加量为1%时,制得支撑体性能最佳,更有利于陶瓷膜的工业化生产,产品的纯水通量为37 516.69 L/(m~2·h),抗折强度为11.28 MPa,孔隙率为26.23%,平均孔径为5.11μm。 相似文献
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E. Vasconcelos S. Fernandes J.L. Barroso de Aguiar F. Pacheco-Torgal 《Construction and Building Materials》2011,25(8):3213-3221
This paper presents results about the use of metakaolin based geopolymers mortars for retrofitting purposes. Two main situations are addressed, the use of geopolymeric mortars as a repairing layer or as a binding agent to insure the adhesion between CFRP sheets and the concrete substrate. Several compositions of metakaolin geopolymer mortars were executed by varying the percentage of sand/binder mass ratio and the concentration of sodium hydroxide. It was found that metakaolin geopolymer mortars show a high mechanical resistance and a relevant adhesion to the concrete substrate. Although their adhesion strength is lower than the one present by commercial pre-pack repair mortars, they are very cost-effective (5–10 times less expensive). On the other hand, the adhesion strength between CFRP and geopolymer mortars proved to be lower than expected which could be due to the fact that the composition of the geopolymeric mortars was not optimized and also to the fact that the CFRP used was not prone to this kind of application. 相似文献
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在以粉煤灰为主的胶结料中掺入适量的矿渣能大幅度提高其强度,矿渣掺量以控制在15% ̄25%为宜;石灰对粉煤灰和矿渣都起激发剂的作用,在本试验范围内,石灰适宜掺量为15% ̄25%;粉磨细度与强度成正比关系,综合考虑产量、质量与电耗的关系,胶结料的比表面积控制在420 ̄450m2/kg。以粉煤灰、矿渣、石灰和石膏配置的胶结料,后期强度能大幅增长,凝结时间可调,抗大气稳定性较好。若采用蒸养技术,可得到3d抗压强度达45MPa以上,后期抗压强度能继续增长的硅酸盐制品。 相似文献
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本文利用化学活化和物理活化相结合的原理 ,研制出一种复合型混凝土矿物外加剂 ,通过有效激发粉煤灰的活性 ,利用粉煤灰可以作为胶结材的性质 ,取代部分水泥 ,在满足使用要求的基础上大幅度降低水泥用量。 相似文献
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《Construction and Building Materials》2007,21(6):1295-1300
About 10 million tonnes of fly ash are produced yearly as waste from coal fired thermal power plants in Turkey. Only a small portion of this waste is utilized as a raw material in the production of cement and concrete. In this study, Seyitömer power plant fly ash was investigated in the production of light weight bricks. Fly ash, sand and hydrated lime mixtures were steam autoclaved under different test conditions to produce brick samples. An optimum raw material composition was found to be a mixture of 68% fly ash, 20% sand and 12% hydrated lime. The optimum brick forming pressure was 20 MPa. The optimum autoclaving time and autoclaving pressure were found 6 h and 1.5 MPa, respectively. The compressive strength, unit volume weight, water absorption and thermal conductivity of the fly ash–sand–lime bricks obtained under optimum test conditions are 10.25 MPa, 1.14 g/cm3, 40.5% and 0.34 W m−1 K−1 respectively. The results of this study suggested that it was possible to produce good quality light weight bricks from the fly ash of Seyitömer power plant. 相似文献
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采用比表面积为14000cm2/g的超细磨粉煤灰和高效减水剂配制出坍落度243mm,28d抗压强度108.55MPa,180d抗压强度140.4MPa的超高强高性能混凝土。对用原状粉煤灰、硅灰、超细磨粉煤灰分别作混凝土的掺合料进行了性能对比,指出超细磨粉煤灰既有粉煤灰本身的“滚珠轴承”润滑作用和火山灰反应增强作用,又有硅灰的填隙挤水和密实增强作用。 相似文献
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以粉煤灰和废玻璃为主要原料,辅以适宜的外加剂,用烧结法制备了粉煤灰掺量高达40%。体积密度低达155.1kg/m^3的粉煤灰泡沫玻璃。对影响粉煤灰泡沫玻璃质量的工艺因素进行了分析讨论。 相似文献
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通过正交试验优化外加剂配比,配制了一种柔韧性好、自收缩小的蒸压粉煤灰砖专用砌筑砂浆,研究了该砂浆与蒸压粉煤灰砖的粘结性能和砌体抗剪切性能。结果表明,Ⅱ级粉煤灰等量取代25%的水泥,纤维素醚、5010N型可再分散醋酸乙烯酯-乙烯共聚胶粉和萘系高效减水剂掺量分别为0.1%、2%和0.6%,胶砂比1∶5的专用砌筑砂浆与蒸压粉煤灰砖的28 d粘结强度和砌体抗剪切强度分别为0.58 MPa和0.51 MPa,明显高于普通砂浆(粘结强度0.28 MPa、抗剪切强度0.14 MPa),可满足表面较光滑、易干燥收缩的蒸压粉煤灰砖砌筑的要求。 相似文献
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Osama A MOHAMED Rania AL-KHATTAB Waddah AL-HAWAT 《Frontiers of Structural and Civil Engineering》2022,16(6):781
Experimental evaluations were conducted to determine the water sorptivity, setting time, and resistance to a highly acidic environment, of mortar with alkali-activated ground granulated blast furnace slag (GBS) binder and also of combinations of fly ash and GBS binders. Binders were activated using mixtures of NaOH and Na2SiO3 solutions. The molarity of NaOH in the mixtures ranged from 10 mol·L−1 to 16 mol·L−1, and the Na2SiO3/NaOH ratio was varied from 1.5 to 2.5. Mortar samples were produced using three binder combinations: 1) GBS as the only binder; 2) blended binder with a slag-to-fly ash ratio of 3:1; and 3) mixed binder with 1:1 ratio of slag to fly ash. Mortar samples were mixed and cured at (22 ± 2) °C till the day of the test. The impact of activator solution alkalinity, activator ratio Na2SiO3/NaOH, GBS content on the rate of water absorption were evaluated. After 7, 28, and 90 d of immersion in a 10% sulfuric acid solution, the resistance of a geopolymer matrix to degradation was assessed by measuring the change in sample weight. The influence of solution alkalinity and relative fly ash content on setting times was investigated. Alkali-activated mortar with a slag-to-fly ash ratio of 3:1 had the least sorptivity compared to the two other binder combinations, at each curing age, and for mortars made with each of the NaOH alkaline activator concentrations. Mortar sorptivity decreased with age and sodium hydroxide concentrations, suggesting the production of geopolymerization products. No reduction in weight of sample occurred after immersion in the strong acid H2SO4 solution for three months, regardless of binder combination. This was due to the synthesis of hydration and geopolymerization products in the presence of curing water, which outweighed the degradation of the geopolymer matrix caused by sulfuric acid. 相似文献