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选用三唑二巯基铵盐(FSH)作为聚氯乙烯(PVC)的交联剂,考察了模压温度、模压时间和交联剂用量对PVC交联的影响,并通过红外分析、无转子硫化仪、电子万能试验机、维卡软化温度试验机和扫描电镜等,研究了交联PVC的化学结构、交联过程、力学性能、耐热性能和断面形貌。结果表明:FSH能使PVC交联且凝胶率较高;交联程度受模压温度和模压时间影响很大,当模压温度为180℃、模压时间为120 s时比较适宜;交联后PVC的拉伸强度和缺口冲击强度提高,断裂伸长率降低。交联剂用量为1.5份时,综合性能最好,拉伸强度达48.9 MPa,缺口冲击强度达16.3 kJ/m^2,维卡软化点达到75.9℃,较未交联PVC提高了18.4℃。 相似文献
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采用模压发泡一次成型法研究了橡塑并用,乳胶/EVA/LDPE/PVC四元共混发泡材料的制备,着重讨论了配方和加工工艺、橡塑比、交联剂、发泡剂、填料等用量对发泡体性能的影响,交联与发泡的协调与配合,并用电镜扫描观察了四元动态硫化共混物材料和共混交联发泡体的断面结构。实验结果表明,当橡塑比R/P=20/80时,共混发泡体的密度0.10g/cm~3,扯断强度1.15MPa,断裂伸长率180%,硬度(邵氏A)36,挠曲>4万次,适合于制作轻质泡沫衬垫或包装材料;当橡塑比R/P=5/95时,发泡体密度(g/cm~3)0.23,扯断强度2.13MPa、断裂伸长率(%)243、硬度60(邵氏A)、挠曲>4万次,成品适合于制作大、中底等鞋用材料。 相似文献
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NBR/PVC热塑性弹性体的耐油性能研究 总被引:2,自引:0,他引:2
考察了硫化剂种类及用量、橡塑比和PVC的相对分子质量对NBR/PVC热塑性弹性体(TPE)耐油性能的影响。实验结果表明,TCY(三聚硫氰酸)硫化体系制备的NBR/PVC的耐油性能最好,TMTD(二硫化四甲基秋兰姆)体系次之,酚醛树脂和硫磺2种体系最差;TCY的用量越大,TPE的耐油性越强,其最佳用量为2.0份;橡塑比中PVC所占比例增大,TPE的耐油性下降;增加PVC的相对分子质量,TPE的耐油性明显提高。 相似文献
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以聚氯乙烯(PVC)为基体,马来酸酐为接枝剂,异氰酸酯、三聚氰胺为交联剂,制备出性能优异的硬质交联PVC泡沫塑料;通过红外光谱、热失重和热机械分析及凝胶含量测定对硬质交联PVC泡沫塑料进行分析,证实交联反应发生在水煮工艺阶段,玻璃化转变温度在180℃左右;研究了马来酸酐用量对硬质交联PVC泡沫塑料凝胶含量的影响,马来酸酐的用量在塑化成型阶段对交联度的影响较小,硬质交联PVC泡沫塑料的凝胶含量随着马来酸酐用量的增加而增大;用光学显微镜对硬质交联PVC泡沫塑料的泡孔直径进行了测量。结果表明,硬质交联PVC泡沫塑料的泡孔直径分布较为均匀,密度为60 kg/m3的泡孔直径主要分布在100~130μm,密度为90 kg/m3的泡孔直径主要分布在70~80μm;测定了硬质交联PVC泡沫塑料的力学性能,结果显示,其具备同瑞士Airex C70产品相当的力学性能。 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
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中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
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中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献