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通过考察A356合金在静置过程中细化效果的变化,研究了亚共晶铝硅合金细化处理的孕育期和衰退期.细化处理的孕育期的形成是由于细化初期的溶质过冷度小造成的,随着溶质Ti含量的增加,溶质过冷度增大,从而激活更多的形核质点,限制枝晶生长;长时间静置后,尽管细化元素Ti含量基本不变,但是成分偏析倾向加剧,形核质点粗化并沉淀,有效核心减少,出现细化效果衰退;采用预细化合金锭可以缩短甚至消除细化处理的孕育期. 相似文献
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通过SEM分析手段,研究了液固反应法制备的Al—Ti—C晶粒细化剂的组织特征,并通过不同Ti/C的Al—Ti—C晶粒细化剂的细化效果比较,确定Al—Ti—C合金的最佳成分范围;分析了Al熔体凝固过程的形核过冷度、以及α-Al形核与长大驱动力,探讨了凝固过程中α-Al细化机制。结果表明:细化效果决定于TiC的数量、形核活性及晶粒生长限制因子的综合作用。 相似文献
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《特种铸造及有色合金》2017,(8)
在2219铝合金凝固阶段添加不同质量分数的Al-Ti-C细化剂,利用光学显微镜(OM)、差示量热法(DSC)等研究了铸锭的凝固组织,并从合金的微观组织及过冷度演变规律展开研究,探讨Al-Ti-C细化剂对2219合金铸锭组织的细化机理。结果表明,Al-Ti-C细化剂的添加能促使晶粒细化,且细化剂含量为0.5%时具有最佳的细化效果;铝熔体过冷度随着晶粒细化剂含量的增加而呈递减趋势,当Al-Ti-C含量大于0.5%时,过冷度不再显著降低;Al-Ti-C熔化后分解出的TiC粒子可作为异质形核核心,凝固阶段TiC粒子的团聚导致形核基底颗粒增大,使得润湿角与临界形核能下降,减小了熔体形核时所需过冷度。 相似文献
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研究了Ti含量对电解加钛A356合金晶粒细化效果的影响,并与相应Ti含量的熔配加钛A356合金进行了比较.结果表明,Ti含量对两种合金的组织均有明显影响.随Ti含量增加,电解加钛合金和熔配加钛合金的晶粒组织和一次枝晶均明显细化,Si颗粒纵横比均趋于降低,其圆形度却增大,表明了Si颗粒形貌的改善.两种合金凝固过程的DSC分析表明,电解A356合金具有较熔配合金更低的激活能和结晶过冷度,从而表现出更优异的晶粒细化效果和Si颗粒形貌. 相似文献
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采用熔融玻璃净化与循环过热相结合手段,研究Co70Cu30和Co50Cu50亚稳不混溶合金的非平衡凝固组织细化规律。结果表明:随着过冷度的增加,不混溶合金的初生枝晶主干不断细化,枝晶碎断现象更加明显。在未发生液相分离条件下,Co50Cu50合金由于具有更高的溶质含量,溶质过冷度增加,动力学过冷度降低,枝晶细化更加明显而易发生碎断。在大过冷度条件下,合金不混溶效应不断增强,液相分离现象发生,凝固组织中分别出现富Co和富Cu区。对于Co70Cu30(ΔT=237 K)和Co50Cu50(ΔT=188 K)合金,溶质含量对快速凝固过程中初生枝晶的影响程度减弱,非平衡凝固组织的晶粒尺寸及成分未发生明显变化。Co50Cu50合金由于具有更低的临界分离过冷度,不混溶阶段经历的时间更长,液相分离进行得更彻底。 相似文献
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不同加钛方法对6063合金细化的研究 总被引:1,自引:1,他引:1
加钛方式不同,钛含量不同,对铝及其合金的晶粒细化效果不同。对比研究了用电解低钛铝合金、加Al—5Ti中间合金、Al—5Ti—1B中间合金及电解低钛铝合金加Al—B中间合金4种加钛方式及不同钛含量对6063合金的晶粒细化效果。研究结果表明:不同的加钛方式对6063合金均有明显的细化效果,随着钛含量增加,晶粒逐渐变细;钛含量相同时,电解加钛的细化效果优于Al—5Ti中间合金的细化效果;当合金中含有硼时,钛含量相同时,电解加钛加Al—B中间合金的细化效果优于加Al—5Ti—1B的细化效果。 相似文献
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Ce对镁及镁合金中晶粒的细化机理 总被引:22,自引:0,他引:22
研究了Ce对镁及镁合金晶粒细化效果和力学性能的影响。结果表明:纯镁结晶时易形成粗大的柱状晶和扇形晶,加入微量稀土元素Ce后,晶粒被明显细化,柱状晶全部转化成等轴晶。在AZ31合金中添加微量稀十元素Ce,晶粒由未细化前的约300μm下降到约30μm。稀土Ce在镁及AZ31合金中的固溶度很小,在凝固过程中固/液界面前沿Ce容易富集引起成分过冷形成新形核带导致晶粒细化。凝固过程中溶质再分配造成固液界面前沿成分过冷度增大是稀土元素细化镁及镁合金的主要机理。 相似文献
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静置及重熔对AlSi7Mg组织及性能的影响 总被引:1,自引:1,他引:0
采用Al-5Ti-B和Al-10Sr对AlSi7Mg合金进行细化和变质处理,研究不同的静置时间和重熔次数对AlSi7Mg合金组织和性能的影响.结果表明,在4h的静置过程中,AlSi7Mg合金晶粒尺寸先减小后增加.熔体中Ti含量几乎保持不变,但是形核核心聚集沉淀,有效形核核心减少.Sr在静置4h中产生烧损,所以共晶硅的变质效果严重衰退.重熔两次时,细化效果衰退不明显,Sr含量急剧减少,共晶硅的形貌恢复到变质前的状况.从静置和重熔的实验中发现,Sr含量低于0.004%时,对共晶硅的变质效果不显著. 相似文献
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将Mg-3%Al合金熔体进行碳质孕育处理并保温不同时间,评估保温时间对孕育细化效果的影响。利用计算机辅助热分析技术对经碳质孕育并保温不同时间合金熔体的凝固特性进行分析。结果表明:碳质孕育能显著细化Mg-3%Al合金。当保温时间延长至60 min时孕育衰退不明显。碳质孕育能明显改变合金熔体的冷却曲线,孕育处理后初始形核温度和最低形核温度升高,再辉过冷度和再辉时间几乎降低至0。碳质孕育的晶粒细化效果能通过冷却曲线形状和凝固特征参数进行评估,包括初始形核温度、最低形核温度、再辉过冷度和再辉时间。 相似文献
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Jianhua Wang Tao Li Xuping Su Hao Tu Ya Liu Changjun Wu Jielin Li 《Journal of Materials Engineering and Performance》2013,22(7):2012-2018
The microstructural evolution and grain refining efficiency of sub-rapidly solidified (SRS) Al-10Ti master alloy has been studied. The results show that the mean size of Al3Ti particles in the SRS Al-10Ti master alloy decreased significantly and the morphology changed from strip-like to blocky and short rod-like compared with the conventional Al-10Ti master alloy. Grain refining experiments show that the SRS Al-10Ti master alloy is more effective than the conventional master alloy for refining Al-7Si alloy. The conversion rate of columnar to fine equiaxed grain structure in the Al-7Si alloy was promoted by the addition of SRS master alloy, and the microhardness of Al-7Si alloy increased. The mechanisms of grain refinement of aluminum by inoculation with improved Al-10Ti master alloy are discussed based on the solute theory. The decrease in size, increase in quantity, and change in morphology of Al3Ti particles are considered as the reasons for the improvement of microstructure and microhardness. 相似文献
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Jin Zou Qi-Jie Zhai Fang-Yu Liu Ke-Ming Liu De-Ping Lu 《Metals and Materials International》2018,24(6):1275-1284
A rotating magnetic field (RMF) was applied in the solidification process of Cu-8Fe alloy. Focus on the mechanism of RMF on the solid solution Fe(Cu) atoms in Cu-8Fe alloy, the influences of RMF on solidification structure, solute distribution, and material properties were discussed. Results show that the solidification behavior of Cu–Fe alloy have influenced through the change of temperature and solute fields in the presence of an applied RMF. The Fe dendrites were refined and transformed to rosettes or spherical grains under forced convection. The solute distribution in Cu-rich phase and Fe-rich phase were changed because of the variation of the supercooling degree and the solidification rate. Further, the variation in solute distribution was impacted the strengthening mechanism and conductive mechanism of the material. 相似文献
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采用两种粉状细化剂(Ti5B1和Ti5C1)在不同工艺条件下细化A356铝合金,然后应用金相显微镜和万能试验机等较详细研究了Ti5B1和Ti5C1细化剂在不同含量、保温时间下对A356铝合金细化效果的影响.试验结果表明两种细化剂对A356铝合金均有细化作用,细化失效时间均大于8 h.同时通过对比两种铸件的组织和力学性能发现 Ti5B1对A356铝合金的细化效果优于Ti5C1. 相似文献
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Effects of grain refinement on mechanical properties and microstructures of AZ31 alloy 总被引:1,自引:0,他引:1
Cerium was added in AZ31 alloy with the contents of 0.4%,0.8%and 1.2%respectively to produce experimental alloys. The grain refinement of Ce in the as-cast and rolled AZ31 alloy were studied by using Polyvar-MET optical microscope with a VSM2000 quantitative analysis system,KYKY2000 SEM and Tecnai G~2 20 TEM.And the mechanical properties of AZ31+Ce alloy were tested on a CSS-44100 testing system with computerized data acquisition.The results show that the cerium has a good grain refinement effect on the ... 相似文献
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通过向工业纯铝中单独或复合添加微量Zr、Ti元素,研究了Zr、Ti合金化对纯铝微观组织、力学性能及抗细化衰退性能的影响。结果表明:Zr元素能显著提高纯铝的硬度,对晶粒有一定的细化作用,但其细化效果远不及Ti;Ti元素具有较强的晶粒细化效果,但对合金的硬度影响较Zr元素小;当Zr、Ti复合添加时,Ti能明显改善Zr元素对晶粒的细化能力,使细化后的合金达到强度、硬度和塑性的合理匹配。Zr、Ti复合孕育剂具有良好的抗晶粒细化衰退性能,这很大程度上取决于Al3(Ti,Zr)粒子优异的晶粒细化性能、热稳定性能及抑制晶粒长大性能。 相似文献
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The metallographic structure of LM-29 aluminum-silicon alloy modified by electric pulse treatment has been investigated and compared with those untreated. The solidification structure of LM-29 alloy has been analyzed by means of M1AP3 Quantimet image processing and analysis system, and then the solidification process has been analyzed by means of differential scanning calorimetry (DSC). The results indicate that the primary silicon phase was refined remarkably by electric pulse while the tensile strength and elongation properties increased accordingly. Electric pulse treatment can also increase the binding power between silicon clusters and alloy melt matrix, as a result, the precipitation of primary silicon phase is suppressed to meet the demand of supercooling degree for nucleating, correspondingly. The electric pulse modification has great influence on the size of silicon atomic cluster as well as its distribution in the melt, subsequently, leads to the refinement of solidification structure. 相似文献