共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
《国际聚合物材料杂志》2012,61(11):576-582
Mineralization of gelatin electrospun nano and micro fiber was investigated in order to prepare a biomimetic bone nanocomposite. For this aim, at first, calcium containing gelatin nanofibers were electrospun by a novel ethanol/water/salt solution. Fibers with mean diameters varying from 300 to 3000 nm were acquired. Then, fiber mats were exposed to phosphate ions by soaking them in phosphate solution or laminating them between phosphate containing gelatin films. SEM micrographs demonstrated the presence of nano to micro sized minerals on gelatin fibers. FTIR and XRD results illustrated that the calcium phosphates in all samples are combinations of brushite and hydroxyapatite. 相似文献
3.
Hong Lin Tetsuro Jin riy Dmytruk Tetsuo Yazawa 《Journal of the American Ceramic Society》2003,86(11):1991-1993
A translucent, conductive, porous nanocomposite was designed and prepared by depositing SnO2 on the inner surfaces of the pores of a porous glass plate and on its outer surface using a chemical vapor deposition method. The porous nanocomposite almost maintained its large surface area and pore volume because the pores remained open after they were deposited with SnO2 . Conductivity between the two outer surfaces of the nanocomposite plate was confirmed for the first time. 相似文献
4.
5.
6.
Preparation of Barium Titanates from Oxalates 总被引:6,自引:1,他引:5
Michael Stockenhuber Helmut Mayer Johannes A. Lercher 《Journal of the American Ceramic Society》1993,76(5):1185-1190
The decomposition of mixed barium titanium oxalates was studied by means of various thermochemical as well as spectroscopic methods. Infrared (IR) spectra of the mixed oxalates indicate the existence of an octahedral complex with Ti chelated by oxalate groups. In general, the results of both IR and the thermochemical analyses suggest that the oxalates are first converted to unidentate carbonate, then to ionic carbonate, and finally to mixed oxides of perovskite structure. The decomposition processes were found to depend upon the atmosphere. In the presence of oxygen the stoichiometrically mixed oxalates decompose by forming TiO2 and BaCO3 as intermediates. Under vacuum, two routes of decomposition occur in parallel. In one route, TiO2 and BaCO3 are formed as intermediates; in the other, partially reduced TiOx (x < 2) is formed, which further reacts with BaCO3 to produce also BaTiO3 , CO2 and CO. 相似文献
7.
Sven Van der Gijp Louis Winnubst Henk Verweij 《Journal of the American Ceramic Society》1999,82(5):1175-1180
The peroxo-oxalate complexation method is a method that can be used for the preparation of doped barium titanate. In this paper we focus on BaTi0.91 Zr0.09 O3 , which can be used for discharge capacitors in lamp starters. The preparation method described here is based on the complexation and subsequent precipitation in basic environment of Ba, Ti, and Zr ions with hydrogen peroxide and oxalate. The influence of several process parameters, like precipitation temperature and pH, on powder properties is described. A single-phase perovskite crystal structure is obtained after calcination starting from a chloride precursor solution using a precipitation temperature of 40°C and a pH of 9. Because the peroxo-oxalate process starts with inexpensive chlorides and is performed in air, the peroxo-oxalate process is suitable for the commercial production of doped barium titanate. 相似文献
8.
Pectin–ZnO nanocomposite was prepared in the aqueous solution condition at room temperature. The Fourier transform infrared,
X-ray diffraction, and transmission electron microscope (TEM) measurements confirmed the nanoscaled structure of pectin–ZnO
composite. According to the TEM observation, the average composite granules size was about 150 nm and the embedded ZnO nanoparticles
were uniform with an average diameter of 70 nm. 相似文献
9.
10.
11.
12.
13.
Preparation of High-Purity Submicron Barium Titanate Powders 总被引:1,自引:0,他引:1
K. S. MAZDIYASNI R. T. DOLLOFF J. S. SMITH II 《Journal of the American Ceramic Society》1969,52(10):523-526
Simultaneous hydrolytic decomposition of barium bis isopropoxide and titanium tetrakis tertiary amyloxide was used to produce stoichiometric BaTiO3 . The particle size range was 50 to 150 Å. The purity was 99.98+%, the major contaminant being silicon from the glass apparatus. The homogeneity and stoichiometry of the powder were demonstrated by electron microscopy and wet chemical analysis. X-ray and infrared analyses indicate that the material, as-prepared and helium-dried at 5O°C, has the titanate crystal structure. The powder sinters at 1300°C to a high density, translucent body with a uniform microstructure. The experiments suggest that the alkoxy-based preparation of oxides may provide a broad base for improving the quality and reproducibility of electrical and structural ceramics. 相似文献
14.
15.
合成了一种油溶性化合物正十二烷硫基硼酸钡(Ba-SB),并将其作为润滑油添加剂,采用四球摩擦磨损试验机评价了其摩擦学性能。结果表明:该添加剂具有较好的油溶性能和热稳定性能。十二烷硫基硼酸钡使HVI500基础油的抗磨性能明显改善,承载能力得到明显提高,摩擦系数明显降低,采用扫描电镜对钢球磨斑表面形貌进行分析,加了该添加剂的钢球磨斑表面平整、光滑,犁沟浅且钢球磨斑表面有沉积物,从EDS谱图上可以看出摩擦副表面含有B、N、Cr、Fe、S元素。从XPS分析添加剂在摩擦过程中发生了摩擦化学降解反应,并在摩擦副表面生成了BaO,B2O3和FeB的个物质抗磨减摩膜,从而改善了其摩擦磨损性能。 相似文献
16.
17.
环氧树脂/膨润土纳米复合材料的制备 总被引:2,自引:0,他引:2
本文制备了有机膨润土和环氧树脂/膨润土纳米复合材料,利用X-ray衍射对有机膨润土和纳米复合材料进行了表征,分析了烷基铵链在澎润土及其复合材料中的聚集状态。 相似文献
18.
利用浸渍提拉方法,在平均孔径500 nm的管状a-Al2O3陶瓷管载体上成功制备了无缺陷的Beta/碳纳米复合分子筛膜. 通过室温下单组分气体渗透实验,发现当Beta分子筛在聚糠醇/丙酮溶液中的含量逐渐加大时,复合膜的气体分离因数略有增加,同时气体渗透通量明显加大. 经优化后氢气渗透通量比纯碳膜增加了一个数量级,说明Beta分子筛起到了加快气体渗透通量的作用. 由SEM照片可以发现,随着Beta分子筛含量的增加,制备的纳米复合膜的厚度由平均14 mm减少到7 mm左右,从而减少了气体渗透的阻力.结合实验数据,探讨了沸石分子筛/碳复合膜气体渗透路径. 相似文献
19.
The nanocomposite of a poly(methyl methacrylate)/silica containing calcium salt was synthesized through the sol–gel method. Methyl methacrylate was co-polymerized with 3-(trimethoxysilyl)propyl methacrylate and then co-condensed with tetraethyl orthosilicate and calcium nitrate tetrahydrate. Low crystalline hydroxycarbonate apatite was successfully formed on the surface after soaking in simulated body fluid for 1 week at 36.5°C. This study demonstrates that this nanocomposite may be used as a bioactive bone substitute or filler for poly(methyl methacrylate) bone cement. 相似文献