国内外增塑剂工业现状及发展动态

本文论述了国内外增塑剂工业的现状，分析了国外增塑剂的发展动态以及国内与增塑剂工业相关的丁辛醇工业概况，并对发展我国增塑剂生产提出几点建议。     

朗盛公司致力于MESAMOLL增塑剂的开发

朗盛公司最近宣布已经攻克了MESAMOLL增塑剂和其它烷基磺酸酯类增塑剂的难关，这将使其能够继续为更多的全球用户提供非邻苯二甲酸酯增塑剂。采用连续生产工艺，完全使用现有设备就可以生产不含任何邻苯二甲酸酯污染物的MESAMOLL增塑剂及其衍生物。     

尼龙酸生产增塑剂的研究

叙述了以尼龙酸为主要原料生产塑剂的工艺过程，特别对尼龙酸二异丁酯增塑剂的物理性能和性能进行了研究，表明以尼龙酸为主要原料生产的增塑剂与聚氯上容性好，特别合适作耐寒增塑剂作用。     

我国增塑剂的生产现状与展望

本文介绍了我国增塑剂的生产现状，包括增塑剂的产量、规模、品种、工艺、质量、价格等，展望了我国增塑剂工业的发展方向。     

PVC人造革生产中增塑剂有机废气治理研究

增塑剂有机废气是PVC人造革生产过程中产生的主要污染物,文中系统分析了增塑剂有机废气中的主要污染成分,并据此提出了静电法处理该废气的工艺流程。实际工程运行监测结果表明：外排废气中的主要污染成分的去除率均达到97％以上,并达到有关排放标准的要求。     

增塑剂新产品开发,生产应用与市场需求

介绍了增塑剂系列新产品的性能、合成工艺进展、应用及国同外增塑剂的生产概况、ＰＶＣ在国内的需求，指出了增塑剂的良好发展前景。     

增塑剂新产品的开发与市场需求

本文介绍了增塑剂系列新产品的性能，生产方法及作用ＤＯＰ替代品等方面的应用与ＰＶＣ的市场，指明了增塑剂生产的发展远景。     

国内增塑剂现状及发展趋势

综述了我国增塑剂的生产与市场现状及技术进展，并以此为基础提出我国增塑剂的发展趋势与建议。     

国产增塑剂的现状与展望

本文介绍了国产增塑剂的产量，规模、品种、结构、生产装置、生产工艺、质量、价格等现状，展望了我国增塑剂的发展方向。     

增塑剂的生产及研发现状

本文介绍了近几年国内外增塑剂的生产现状，并阐述了我国增塑剂产品研发状况，提出了加大绿色增塑剂产品的研发力度，发展我国增塑剂产业规模，提高其环保性能的建议。     

Optimizing performance of benzoate and phthalate blends for vinyl applications

To achieve required performance, blends of plasticizers are commonly used in flexible vinyl applications. Typically, when fast fusion is required, high solvating phthalates have been utilized in plasticizer blends. Benzoate esters are high solvators and can also be used in these blends. However, even though benzoate plasticizers offer additional performance benefits that can complement general‐purpose phthalate performance, most of the literature does not include the use of benzoate plasticizers in blends with phthalates. The purpose of this article is to demonstrate the performance benefits of blending benzoate and phthalate plasticizers. The approach selected to accomplish this task was to develop performance data by utilizing a mixture design approach with DOE (design of experiments) software. A resilient flooring plastisol formulation was selected as the model. The following properties were obtained: degassing, low and high shear viscosity, viscosity stability of the plastisol, gel and fusion characteristics, tensile strength vs. temperature, vinyl heat stability, stain resistance, volatility, and UV stability. The data indicate how to utilize the advantage of benzoates as “process aids” to speed production rates and improve product quality. J. VINYL. ADDIT. TECHNOL. 11:150–154, 2005. © 2005 Society of Plastics Engineers     

聚氯乙烯环保型增塑剂的合成及应用

聚氯乙烯中常用的环保型增塑剂主要有柠檬酸酯类增塑剂、对苯二甲酸酯类增塑剂、聚酯类增塑剂、偏苯三酸酯增塑剂、环己烷二羧酸酯类增塑剂、植物油基增塑剂等,通过了解和分析这些增塑剂的特征和合成,推进环保型增塑剂在塑料生产中的应用.     

安全玻璃夹层用PVB膜片生产工艺配方的设计

采用胶片级聚乙烯醇缩丁醛(PVB)树脂为基础树脂，选用了不同的增塑剂和助剂，制成了夹层玻璃所用的膜片，分析了工艺流程中各原材料对产品质量的影响。实验表明，PVB树脂颗粒须粒径均匀，不同用途的夹层玻璃需选用不同的增塑剂，同时进行相应生产工艺的调整，才能实现稳定连续的生产。     

Migration resistant glucose esters as bioplasticizers for polylactide

Environmental and sustainability issues have catalyzed efforts to replace traditional polymer additives with biobased alternatives. Glucose pentaacetate (GPA) and sucrose octaacetate (SOA) as model commercial saccharide esters and three synthesized glucose hexanoate esters (GHs) were evaluated as bioplasticizers for polylactide (PLA). For the GHs different reaction times were utilized to reach plasticizers with different number of hexanoate groups to establish how the degree of substitution influences miscibility and migration resistance of the plasticizers. The synthesized GHs, GPA, and SOA all showed good miscibility with PLA. Largest improvements in strain at break were observed for the PLA films containing GH plasticizers. These films also exhibited simultaneous increase in stress at break as compared to plain PLA. The GH plasticizers had low tendency to migrate during aging in water and this migration resistance increased with increasing degree of substitution. The GHs are, thus, promising plasticizer alternatives for bioplastics as they also retain the biodegradable nature of these biobased materials. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41928.     

Smoke suppressants for plasticized poly(vinyl chloride)

Addition of plasticizers to poly(vinyl chloride) generally increases its flammability and frequently increases smoke production during its burning. Flame retardants added to plasticized PVC can reduce flammability, but increase smoke production. This study shows that proper choice of combined use of other polymers, phosphate plasticizers, fillers and other flame retardants, produces measured synergistic improvements in flame retardance and smoke suppression which could benefit applications such as PVC wire and cable insulation.     

Soft PVC foams: Study of the gelation,fusion, and foaming processes. II. Adipate,citrate and other types of plasticizers

Plasticized poly(vinyl chloride) (PVC) is one of the most useful polymeric materials on an industrial scale because of its processability, wide range of obtainable properties, and low cost. PVC plastisols are used in the production of flexible PVC foams. Phthalates are the most used plasticizers for PVC, and in a previous article (part I of this series), we discussed the influence of phthalate ester type plasticizers on the foaming process and on the quality of the foams obtained from the corresponding plastisols. Because the use of phthalate plasticizers has been questioned because of possible health implications, the objective of this work was to undertake a similar study with 11 commercial alternative plasticizers to phthalates. The evolution of the dynamic and extensional viscosity and the interactions and thermal transitions undergone by the plastisols during the heating process were studied. Foams were obtained by rotational molding and were characterized by the determination of their thermomechanical properties, density, and cell size distribution. Correlations were obtained between the molecular weight and structure of the plasticizer and the behavior of the corresponding plastisols. After the characterization of the final foamed product, we concluded that foams of relatively good quality could be prepared with alternative plasticizers for replacing phthalates. Several plasticizers {Mesamoll (alkylsulfonic phenyl ester), Eastman 168 [bis(2‐ethylhexyl)‐1,4‐benzenedicarboxylate], Hexamoll [di(isononyl) cyclohexane‐1,2‐dicarboxylate], Citroflex A4 acetyl tributyl citrate (ATBC), and Plastomoll (dihexyl adipate)} were found to be interesting alternatives in the production of soft PVC foams because they provided very good quality foams with properties similar to, or even better than, those obtained with phthalate plasticizers. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

邻苯二甲酸酯类增塑剂在食用香精中存在的问题及对策

邻苯二甲酸酯类增塑剂广泛地应用于塑料制品中,其安全性引起人们的高度关注.国内外对邻苯二甲酸酯类增塑剂的研究主要集中于检测方法和危害性方面.结合工作实际,探讨了邻苯二甲酸酯增塑剂在食用香精中存在的原因、检测过程和生产过程中遇到的问题并提出了对策,为食用香精企业对增塑剂的管理提供参考意见.     

Effect of inert plasticizers on mechanical,thermal, and sensitivity properties of polyurethane‐based plastic bonded explosives

Mechanical, thermal, and sensitivity properties of plastic bonded explosives (PBX) depend on the type of ingredients in their formulation. Aim of the work is to develop aluminized cast PBX formulations and process conditions by using alternative inert plasticizers to have similar or better properties than PBXN‐109 without compromising sensitivity properties. Although very small portion of total production of plasticizers is used for solid rocket propellant and explosive formulations, they play very significant role in that area. Both inert and energetic plasticizers have involved propellant and explosive formulations to improve process parameters, mechanical properties, and even insensitivity properties of them. Isodecyl pelargonate and dioctyl adipate are the most preferred inert plasticizers in polyurethane based thermoset propellant and explosive formulations. In addition to them, diisononyl adipate and diisononyl phthalate were used and screened as inert plasticizer candidates for aluminized cast PBX formulations. Mechanical, thermal, and sensitivity properties of PBX formulations were studied and compared in detail. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40907.     

The effect of accelerated ageing of building wires

The fire performance of two electric cables (building wires) designed for indoor use has been tested, both as new products and after accelerated thermooxidative ageing. The cables were aged for a maximum time of 16.5 weeks at 80°C. The cables are commercially available, and were constructed using a PVC material in one case and a non‐halogenated polyolefin‐based material, called Casico, in the other. The effects of ageing on the fire performance of the cables, and the chemical changes that have caused the observed fire behaviour, have been investigated and are discussed. Special attention is paid to the behaviour of the plasticizers that are used in the PVC cable, and how the fire behaviour is affected by the loss of plasticizers from the cable and by the migration of plasticizers between the parts of the cable (insulation, bedding and sheathing). Copyright © 2007 John Wiley & Sons, Ltd.     

Application of new oligomeric plasticizers based on waste poly(ethylene terephthalate) for poly(vinyl chloride) compositions

In this study, chemical recycling products of waste poly(ethylene terephthalate) with oligoesters were used as new plasticizers for poly(vinyl chloride) (PVC). The preparation conditions of the dry blend mixtures of the suspension PVC containing synthesised plasticizers were similar to the conditions of the preparing mixtures with commercial plasticizers. The plasticization efficiency of PVC plasticizers was then examined by analysis of the mechanical, physical and chemical properties, as well as the thermal resistance and migration of plasticizer molecules from polymer matrix. Test results proved that compositions with synthesised oligomeric plasticizers possessed similar or better properties than those containing commercial oligomeric plasticizers and much better properties than those having monomeric plasticizers. Thermal stabilities of the proposed plasticizers were higher than those of the commercial plasticizers either monomeric (bis(2-ethylhexyl)phthalate) or oligomeric, despite the fact that the synthesised oligoesters did not contain any antioxidant. The best properties, especially low volatility, very good mechanical properties, low migration were resulted of the transesterification of the waste PET with oligoesters based on adipic acid, triethylene glycol and 2-ethylhexanol which were selected as plasticizers synthesised on the technical scale. The tested plasticized PVC compositions possessed very good tear resistance, tensile strength, decrease of weight loss after 168 h at 80 °C and low migration. Processing properties of PVC compositions containing these synthesised plasticizers confirmed their effectiveness in these compositions for extrusion process.