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以实验室自制的硼酸双甘油酯和硬脂酸为主要原料制备了硼酸双甘油酯双硬脂酸酯。首先考察了反应温度对产品收率的影响,获得了最佳反应温度。在此基础上,系统研究了催化剂用量对产品收率的影响,获得了适宜的催化剂用量。最后,利用红外光谱技术对产品进行了分析,分析结果表明,实验获得的产品即为目标产物。 相似文献
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硼酸酯类偶联剂的合成 总被引:3,自引:0,他引:3
本文报道以价廉易得的原料、简单可行的路线合成硼酸酯之结果。在理论分析的基础上,采用反应一精馏一体化法合成了硼酸三异丙酯,确定了带水剂,考察了原料配比、带水剂浓度对收率的影响,原料配比、浓硫酸催化剂对反应速率的影响。进而以硼酸三异丙酯为中间体,运用酯交换法合成了硼酸酯偶联剂,所确定的合成方法具有操作简便、产品收率高等优点。 相似文献
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以硼砂和消石灰为原料,经反应、过滤、洗涤及干燥制备出偏硼酸钙(CaO*B2O3*6H2O)产品.经过实验研究确定了适宜的工艺条件:硼钙配料比(氧化硼与氧化钙质量比)在2.2∶ 1左右;液固体积质量比为2.76 mL/g左右;温度为35 ℃;反应时间为8~10 h.在此工艺条件下制得的偏硼酸钙产品含氧化硼质量分数为29%~31%、氧化钙质量分数为23%~25%、氧化钠质量分数≤0.5%.产物的X射线衍射分析和热重分析表明,合成的产品为六水合偏硼酸钙纯相,扫描电镜显示产物为白色的不规则六边形条状晶体. 相似文献
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硫酸钛催化合成柠檬酸三丁酯的研究 总被引:7,自引:0,他引:7
研究了以硫酸钛为催化剂合成柠檬酸三正丁酯(TBC)的工艺条件,考察了醇酸摩尔比、催化剂用量及反应时间等因素对酯化反应的影响,并确定了最佳反应条件。 相似文献
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硫酸钛催化合成乙酸酯的研究 总被引:3,自引:0,他引:3
研究了硫酸钛催化下乙酸酯(乙酸正丁酯)的合成,考察了加热温度、原料配比、催化剂用量和反应时间对反应的影响,发现在加热温度为190℃,醇酸摩尔比为1.2:1,催化剂用量为0.015mol/mol乙酸时,反应90min乙酸转化率可达99.1%。该催化剂对伯醇和仲醇酯化的催化效果都比较理想。加入一定量惰性固体可以改善催化剂的使用效果和寿命。 相似文献
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以工业钛液为原料,采用外加晶种常压水解工艺制备了金红石型二氧化钛,研究了水解钛液的组成和操作参数对二氧化钛消色力的影响。实验结果表明:二氧化钛消色力(Tcs)和蓝相光谱值(Scx)随晶种添加量的增加先增大后减小,随判灰延时时间的增加先增大后减小,随钛液F值的增加先稍有增加后明显降低,随钛液二氧化钛质量浓度的增大而增加。在钛液F值(游离硫酸加上与钛结合的硫酸之和与二氧化钛质量浓度的比值)为1.90左右、铁钛比(铁元素与二氧化钛质量浓度的比值)<0.5、二氧化钛质量浓度为190~200 g/L、晶种添加量(晶种中二氧化钛质量与对应批次水解浓钛液中二氧化钛质量的比值)为2.0%~2.2%、灰点为“基点+20 min”、熟化时间为0~30 min、稀释水在二沸后100 min加入的条件下进行水解,经过一次洗涤—漂白—二次洗涤—盐处理—煅烧,所得金红石型二氧化钛的消色力更好。 相似文献
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Gilvan P. Pires Marcelo P. Gil Juliana A. Rohrman Fernanda C. Stedile Osvaldo L. Casagrande Joo H. Z. dos Santos Tsuneji Sano 《应用聚合物科学杂志》2006,99(5):2002-2009
A series of hybrid supported catalysts were prepared by combining (iBuCp)2ZrCl2 and {TpMs*}TiCl3 complex (TpMs* = HB(3‐mesityl‐pyrazolyl)2(5‐mesityl‐pyrazolyl)?) sequentially grafted onto MAO (methylaluminoxane)‐modified silica according to a Plackett Burmann 23 design. Supported catalysts were prepared taking into account the immobilization order, silica pretreatment temperature, and grafting temperature. Grafted metal content was comparatively determined by Rutherford backscattering spectrometry (RBS), X‐ray photoelectronic spectroscopy (XPS), and inductively coupled plasma–optical emission spectroscopy (ICP–OES). The resulting catalysts were evaluated in terms of catalyst activity and polymer properties. According to RBS measurements, grafted metal content remained comprised between 0.1 and 0.5 wt % Zr/SiO2 and 0.1 and 0.3 wt % Ti/SiO2 depending on the immobilization order and on silica pretreatment temperature. All the systems were shown to be active in ethylene polymerization having external MAO as cocatalyst. Catalyst activity seemed to be governed by the zirconocene species, influenced slightly by Ti ones. Resulting polymers were characterized by DSC and GPC. The polyethylenes mostly presented higher molecular weight than those produced by homogeneous catalysts or by zirconocene grafted on bare or on MAO‐modified silica. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
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Gino Paolucci Marco Bortoluzzi Laura Sperni 《Inorganic chemistry communications》2009,12(10):1001-1003
The neutral titanium(III) complex Ti(BP)3 {BP = dihydrobis(pyrazol-1-yl)borate} was synthesized by reacting TiCl3(THF)2 with an excess of the potassium salt of the ligand in THF. The compound was isolated as a green solid and characterized by elemental analysis, NMR and IR spectroscopy, Mass spectrometry and magnetic and conductivity measurements. The molecular ion was detected in the Mass spectrum. 11B NMR data suggested a distortion from the ideal octahedral geometry caused by the d1 electronic configuration of the metal centre and this hypothesis was confirmed by means of DFT calculations. 相似文献
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Mauricio Rodríguez Chialanza José Fabian Schneider Romina Keuchkerian Mariano Romero Ricardo Faccio Alvaro Olivera Heinkel Bentos Pereira 《Journal of the American Ceramic Society》2020,103(5):3126-3137
Oxyfluoride glass and glass-ceramics are being studied due to the possibility of their utilization in many applications, such as thermoluminescent dosimeters, optical fibers, fluorescent concentrators, and temperature sensors. In order to improve the properties of glass, they are often crystallized. For this crystallization to be effective, knowledge and control of the structure of the starting material is required. Much work was done on silicate glass; however, a great interest exists in obtaining these kinds of materials in other matrices such as germanates, phosphates, and borates. Here, we present a structural study of some oxyfluoride borate glass with different concentrations of PbF2 by means of Nuclear Magnetic Resonance (NMR), Raman, and Fourier Transform Infrared (FTIR) spectroscopies. We also analyzed glass-crystallization using Differential Scanning Calorimetry (DSC). The crystallization study was complemented with the use of Transmission Electron Microscopy (TEM) and Selected Area Electron Diffraction (SAED), for the purpose of identifying possible mechanisms of crystallization. Our results indicate, from the structural point of view, that the glass present groups with one or two BO4 species, such as diborate or pentaborate. The small variation in the BO4 fraction with the increase in PbF2 concentration would be an indication of the formation of F−BO3/2 species. Oxyfluoride borate glass containing BaO as a cation modifier and 30% PbF2 represents a good starting point for obtaining glass-ceramics with a narrow size distribution of BaF2 nanocrystals. We also propose that the possible mechanism for oxyfluoride borate glass crystallization started with a separation of phases. 相似文献
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采用氧化锌、硼酸为原料,利用微波加热合成低水硼酸锌(ZB-2335),以缩短反应时间、提高反应效率。实验中考察了反应温度、微波辐射时间、原料比等因素的影响;确定了适宜的反应条件为:反应温度105—110℃,微波辐射时间55min,氧化锌与硼酸的物质的量比1:11,氧化锌与水的物质的量比1:140,产率达97.6%。产品的组成分析结果符合要求,其失水温度高于340℃。微波加热条件下的反应速率约是常规加热法反应速率的13倍,该方法具有不引入外来离子,产物单一,不需精制、分离,反应母液可以重复利用,反应过程容易控制等特点,是合成阻燃剂ZB-2335的较佳路线。 相似文献
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