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随着化石燃料的日益枯竭,生物柴油作为一种可再生的生物能源,其制备方法成为了各国研究开发的重点,藻类生物质则是生产生物柴油的优良原料。综述了制备微藻生物柴油的研究进程,着重阐述了酸催化法、碱催化法、酶催化法以及超临界法等国内外微藻制备生物柴油几种技术,并对其今后的研究重点进行了总结和展望。 相似文献
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微藻制备生物柴油的技术进展 总被引:1,自引:0,他引:1
生物柴油是一种新型的可再生能源,是石化柴油的替代品。微藻种类多、光合作用效率高、生长速度快、生物产量大、含油量高,已成为发展生物柴油产业的最有潜力的原料之一。综述了微藻制备生物柴油的优点及研究进展。针对目前微藻生物柴油存在的瓶颈问题和实际需求,指出未来研究和发展的主要方向。 相似文献
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Wan N. A. Kadir Man K. Lam Yoshimitsu Uemura Jun W. Lim Peck L. Kiew Steven Lim Siti S. Rosli Chung Y. Wong Pau L. Show Keat T. Lee 《Frontiers of Chemical Science and Engineering》2021,15(5):1257
In the present study, ozone was introduced as an alternative approach to harvest and disrupt microalgae cells (Chlorella vulgaris) simultaneously for biodiesel production. At the optimum ozonation conditions (6.14 g·h–1 ozone concentration, 30 min ozonation time, 1 L·min–1 of ozone flowrate at medium pH of 10 and temperature of 30 °C), the sedimentation efficiency of microalgae cells increased significantly from 12.56% to 68.62%. It was observed that the microalgae cells aggregated to form flocs after pre-treated with ozone due to the increment of surface charge from –20 to –6.59 mV. Besides, ozone had successfully disrupted the microalgae cells and resulted in efficient lipid extraction, which was 1.9 times higher than the control sample. The extracted microalgae lipid was mainly consisted of methyl palmitate (C16:0), methyl oleate (C18:1) and methyl linolenate (C18:3), making it suitable for biodiesel production. Finally, utilization of recycled culture media after ozonation pre-treatment showed robust growth of microalgae, in which the biomass yield was maintained in the range of 0.796 to 0.879 g·h–1 for 5 cycles of cultivation. 相似文献
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在高温液态水处理的甘蔗渣酶解过程中添加Tween80可使聚糖转化率提高11.4%。根据蔗渣酶解液中糖的种类及含量,用葡萄糖、木糖和纤维二糖标准品模拟蔗渣酶解液组成配制成相应的混合糖培养基,同时配制仅含葡萄糖的培养基,在有、无Tween80和BG11(Blue-Green 11)的条件下,考察小球藻在不同培养基中的异养生长及脂肪酸生成。结果显示Tween80对小球藻的生长具有抑制作用,纤维二糖也会影响小球藻的生长;小球藻在添加BG11的葡萄糖培养基中的生物量最高,为1.97 g·L-1,在添加BG11的蔗渣酶解液中的生物量高出未添加BG11的2倍,在含有Tween80和BG11的蔗渣酶解液中的总脂肪酸含量最高,达到6.90%,在所有培养基中产生的脂肪酸以C16:0、C18:1、C18:3、C20:1和C20:4为主;培养基组成优化可进一步提高微藻生物量和油脂产量。 相似文献
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Rui M. Carvalho Júnior José V. C. Vargas Luiz P. Ramos Cláudia E. B. Marino Jonas C. L. Torres 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2011,86(11):1418-1427
BACKGROUND: Microalgae have recently been considered a potential feedstock for biodiesel production, since they do not compete with agricultural land, unlike oil crops. However, the production processes must be energetically and economically viable. Therefore, an in situ methanolysis process is proposed for biodiesel production directly from microalgae biomass, to avoid the need for the separation and extraction steps. RESULTS: Biodiesel was obtained using methanol as the methylation reactant for the transesterification reaction and hydrochloric acid as the catalyst precursor, at 80 °C for 2 h of reaction. A mass return of 23.07 ± 2.76% (m/m) was obtained. Spectrometry in the infrared region showed that the product had equivalent bands of axial deformation of C?O, C? O and C? H, i.e. an ester. Tests showed the chromatographic profile of fatty acids in the sample. A process energetic efficiency value of 1.17 was obtained for microalgae derived biodiesel, which is higher than from soybean and sunflower, reportedly 1.06 and 1.12. CONCLUSIONS: Industrial sustainability results from low energetic, economic and environmental losses. The microalgae in situ methanolysis process showed greater fuel available energy than energy consumption, therefore is energetically sustainable. Economic and environmental issues should still be addressed. Copyright © 2011 Society of Chemical Industry 相似文献
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采用生活废水的二级出水培养微藻可有效提高微藻生物柴油生产过程的环境效益,降低其环境影响。本文基于生命周期分析原理,针对结合了废水培养微藻的两种微藻生物柴油生产技术路线,即传统路线和热解酯化路线,建立了环境影响评价模型;提出了水处理集成微藻生物柴油生命周期系统评价的水处理过程替代效应的概念及其环境效益定量评价方法;通过计算对比了基于新鲜水培养微藻的两种技术路线的总环境影响指数和废水培养微藻的两种技术路线的环境效益,表明热解酯化工艺结合废水培养微藻路线相较其他工艺路线具有最小的环境影响,表明水处理过程替代效应在水处理集成微藻生物柴油生命周期系统评价中的有效性和必要性。 相似文献
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Yun Cheng Wenguang Zhou Chunfang Gao Kenneth Lan Yang Gao Qingyu Wu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(5):777-781
BACKGROUND: As a potential source of biomass, Jerusalem artichoke has been studied for bioethanol production; however, thus far it has not been investigated for the production of other liquid biofuels, such as biodiesel. This work aims to develop a novel approach for biodiesel production from Jerusalem artichoke tuber using heterotrophic microalgae. RESULTS: In this study, Chlorella protothecoides utilized hydrolysate of Jerusalem artichoke tuber as carbon source and accumulated lipid in vivo, with lipid content as high as 44% by dry mass, and a carbon source to lipid conversion ratio of about 25% in a 4‐day scale cultivation. The lipids were extracted and then converted into biodiesel by transesterification. Cetane acid methyl ester, linoleic acid methyl ester and oleic acid methyl ester were the dominating components of the biodiesel produced. Unsaturated fatty acids methyl ester constituted over 82% of the total biodiesel content. CONCLUSION: This work suggests the feasibility of an alternative method of producing biodiesel from Jerusalem artichoke tuber using microalgae cultivation, and a cost reduction of carbon source feed in algal oil production can be expected. Copyright © 2009 Society of Chemical Industry 相似文献
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微藻能有效利用光能、CO2 和无机盐类合成蛋白质、脂肪、碳水化合物以及多种高附加值生物活性物质 ,可以培养微藻来生产健康食品、食品添加剂、动物饲料、生物肥料及其他天然产品。另外 ,近年来分子遗传学和基因工程研究证实 ,大肠杆菌的载体和启动因子往往可以适用于蓝藻 ,尤其是单细胞蓝藻的转基因 ,这使得蓝藻基因工程得到了较快的发展 ,利用藻类为宿主的基因产物的生产也日益受到关注 ,因此微藻的培养受到广泛重视。微藻的生长方式决定光照在反应器中的重要性。除了一些能完全自养的微藻培养可以在无光照条件下进行[1](此时反应器可以… 相似文献