共查询到19条相似文献,搜索用时 109 毫秒
1.
2.
3.
制备了一种聚(丙烯酸-CO-丙烯酰胺)/膨润土/腐植酸钠三维网络凝胶吸附剂,重点考察了该吸附剂对Cd2+吸附能力的pH依赖性、吸附动力学和吸附等温线。结果表明,Cd2+溶液的pH值对吸附容量有较大影响。 相似文献
4.
5.
6.
互穿网络聚合物(IPN)水凝胶在分离技术领域具有广泛的应用前景,这些年受到人们广泛关注.本文介绍了聚多糖基(壳聚糖、海藻酸、淀粉和其他聚多糖)、蛋白质基(明胶、胶原蛋白、丝纤蛋白和大豆蛋白)和合成聚合物基(非离子型和离子型)IPN水凝胶的制备方法,主要包括同步-IPN、分步-IPN和半-IPN的制备方法.为了提高聚合物水凝胶的生物相容性、溶胀率和机械强度,采用天然高分子与合成高分子共混制备IPN水凝胶.与单网络水凝胶相比,IPN水凝胶对染料和重金属离子的吸附速率快、吸附容量大.为了达到选择性吸附和提高水凝胶的比表面积,制备离子印迹IPN水凝胶和多孔IPN复合冷冻凝胶,是未来研究高效吸附IPN水凝胶的发展方向之一. 相似文献
7.
8.
9.
《精细化工》2016,(12)
以丙烯酸(AA)和壳聚糖(CS)为原料,N,N'-亚甲基双丙烯酰胺(MBA)为交联剂,利用辉光放电电解等离子体(GDEP)技术在水溶液中一步引发制备了壳聚糖/聚丙烯酸(CS/PAA)水凝胶。采用FTIR、XRD和SEM对水凝胶的结构和形貌进行了表征,考察了溶液p H、吸附时间和初始质量浓度对Cu~(2+)和Cd~(2+)吸附的影响,探讨了水凝胶的重复利用性。结果表明:AA成功接枝到了CS链上,形成了具有多孔三维网络结构的CS/PAA水凝胶;该水凝胶对Cu~(2+)和Cd~(2+)的吸附符合准二级动力学模型和Langmuir吸附等温式;在最佳吸附p H下(p H=4.3),吸附120 min,CS/PAA水凝胶对Cu~(2+)和Cd~(2+)的最大实际吸附量分别为151.2和298.8 mg/g;该水凝胶在0.015mol/L乙二胺四乙酸四钠(EDTA-4Na)溶液中吸附解吸4次后,吸附量变化不大,说明CS/PAA水凝胶具有优异的再生和重复利用性。 相似文献
10.
水凝胶是一种高含水量的三维网状聚合物,广泛应用于各个领域,但力学性能较差的特点限制了其在生物医用领域的应用。因此,如何提高水凝胶的力学强度成为国内外专家学者研究的重点。本文主要介绍了几种新型高强度水凝胶的合成及研究进展,包括滑动水凝胶、双网络水凝胶、复合水凝胶以及其它水凝胶,详细分析了影响这些水凝胶力学性能的因素。指出研制具有生物相容性、可生物降解、可注射、可负载活性因子并且具备良好的力学性能水凝胶是今后的研究方向。 相似文献
11.
This research studied the characteristics of poly(acrylamide) and methylcellulose (PAAm‐MC) hydrogels as a novel adsorbent material for removal of pesticide paraquat, from aqueous solution, with potential applications in curbing environmental risk from such herbicides. PAAm‐MC hydrogels with different acrylamide (AAm) and MC concentrations were prepared by a free‐radical polymerization method. The capability of the hydrogels in removing paraquat dichloride from aqueous solution was determined using UV–Vis analysis. The scanning electron microscopy method was used to study the morphological properties of the hydrogels, and swelling degree (Q) of the hydrogels was also measured. The entrapped MC in PAAm chains provoked significant changes in morphological, hydrophilic, and adsorption properties of the PAAm‐MC hydrogels. The adsorption capacity of hydrogels was strongly influenced by AAm, MC, and paraquat concentrations with the highest adsorption capacity (qeq = 14.3 mg g?1) was observed for hydrogels synthesized with 6.0% AAm with 0.75% MC swollen in 45.7 mg L?1 of paraquat solution. Freundlich model performed better than Langmuir model in describing the adsorption isotherm of PAAm‐MC/paraquat system, implying a heterogeneous surface. These results suggest that PAAm‐MC hydrogels are potentially viable absorbents for removal of paraquat pesticide from aqueous solution and cleaning water contaminated with dyes, heavy metals, and others pesticides. © 2009 Wiley Periodicals, Inc. Journal of Appl Polym Sci, 2009 相似文献
12.
以丙烯酸(AA)为原料,二丙烯酸酯(Pul DA)分散的氧化石墨烯(GO)纳米胶粒(GO-Pul DA)为增强剂,N,N'-亚甲基双丙烯酰胺(BIS)为交联剂,通过自由基共聚合制备了一系列结构均一的聚丙烯酸/氧化石墨烯复合水凝胶(PAA/GO-Pul DA)。考察了BIS质量浓度、GO质量浓度以及溶液pH值对复合水凝胶力学性能、吸水性和亚甲基蓝(MB)吸附量的影响。结果表明,当GO质量浓度从0.1 g/L增加至1.0 g/L时,复合水凝胶拉伸强度从5.0 k Pa增加至10.4 k Pa,断裂伸长率高于100%,当GO的质量浓度为0.3 g/L时,复合水凝胶的断裂伸长率最高为151%;复合水凝胶表现出pH敏感的高吸湿性,pH从3.0增加至6.8时,平衡溶胀比(SRe)变化可达386 g/g,pH=6.8时最大SRe高达490 g/g。当溶液pH值从3.0增加至11.0时,PAA/GO-Pul D对MB的平衡吸附量(qe)可增加1 400~1 500 mg/g,pH=11.0时最大的qe高达1 789 mg/g。复合水凝胶对MB的吸附行为符合准一级动力学模型。5次吸附-解吸附循环后,相对于首次吸附,PAA/GO-Pul D对MB的吸附能力仍保持高达60%,解吸附效率高于90%。 相似文献
13.
M. Çağil Akkaya Serkan Emik Gamze Güçlü Tülin Banu İyim Saadet Özgümüş 《应用聚合物科学杂志》2009,114(2):1150-1159
In this study, Acrylic acid (AA)/2‐acrylamido‐2‐methlypropane sulfonic acid (AMPS) hydrogels were prepared by free radical polymerization in aqueous solutions of AA, AMPS, and N,N‐methylenebisacrylamide (NMBA) as crosslinker. Potassium persulfate (PPS)/potassium bisulfide (PBS) were used as initiator and accelerator pair. The water absorption capacities and dye adsorption properties of the hydrogels were investigated. Adsorption properties of the hydrogels were evaluated by depending on different adsorption conditions such as different initial dye concentration and contact time. The concentrations of the dyes were determined using UV/Vis Spectrophotometer at wavelength 530 nm for safranine T (ST) and 622 nm for brilliant cresyl blue (BCB). Adsorption kinetic studies showed that pseudo‐first order kinetic model is suitable to explain the adsorption kinetic data of the hydrogels. Langmuir and Freundlich isotherm models were used to describe adsorption data. The result revealed that the adsorption of basic dyes onto hydrogels fit very well both Langmuir and Freundlich isotherms. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
14.
New sorbent hydrogels for removal of acidic dyes and metal ions from aqueous solutions 总被引:1,自引:0,他引:1
Hasine Kaşgöz 《Polymer Bulletin》2006,56(6):517-528
Summary Poly(N-hydroxymethylacrylamide), PHMA, hydrogels were prepared by using N-hydroxymethylacrylamide, HMA, monomer and polyethyleneglycol(400)diacrylate
as a crosslinking agent in aqueous medium and then amine groups were incorporated onto PHMA hydrogels by amination reaction
with different diamines. The obtained hydrogels were characterized by determination of amine value, hydroxymethyl group content
and FTIR spectra. The amine value of hydrogels changed from 2.23 to 4.64 mmol/g by depending on the amine compounds used in
amination reaction. Their swelling degree increased at acidic pH values and they showed pH dependent swelling behaviour. They
were used as sorbent for removal of indigo carmine and Cu(II) ion, as a model dye molecule and metal ion, respectively, from
aqueous solutions. The adsorption properties of the hydrogels were investigated by depending on pH, time and initial indigo
carmine or Cu(II) ion concentration. It was seen that the amine group incorporated hydrogels have quite high adsorption rate
and adsorption capacity, and their adsorption capacities changed with pH of the solution. Langmuir isotherm model was the
best fit for adsorption of both indigo carmine and Cu (II) ion. 相似文献
15.
Simultaneous interpenetrating polymer network (IPN) hydrogels have been prepared by UV-initiated polymerization of a mixture of 2-acrylamido-2-methyl-1-propansulfonic acid (AMPS) and triethylene glycol divinyl ether (DVE-3) with enhanced adsorption properties for heavy metal ion removal. The swelling ratio of the IPN hydrogels determined by gravimetric method increased with the AMPS content in the formulation. The IPN hydrogels were used to remove heavy metal ions from aqueous solution. The effects of pH value of the feed solution and AMPS content in the formulation on the adsorption capacity were investigated. The results indicated that the adsorption capacity increased with the pH values and AMPS content in the formulation. Furthermore, the synergistic complexation of metal ions with two polymer networks in the IPN was found in the adsorption studies. The adsorption isotherm of the IPN hydrogels can be well fitted to the Freundlich model. The adsorption kinetics on IPN hydrogels clearly followed an initial transport-controlled adsorption process, but transited to an attachment-controlled adsorption kinetics in the later stage. Thermodynamic parameters such as the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) for the adsorption were estimated. Results suggested that the adsorption process was a spontaneous, exothermic process that had positive entropy. 相似文献
16.
《Ceramics International》2023,49(8):12201-12213
Tetracycline (TC) and oxytetracycline (OTC) are antibiotic compounds increasingly detected in various water sources. In this study, Fe-metal organic framework incorporated biopolymer-clay hydrogels (CAMIL-MMT and CAMIL-SEP) were prepared to remove TC and OTC from water. The physicochemical properties of the as-prepared hydrogels were thoroughly characterized, and the effect of various operating parameters on the adsorption performance was systematically examined. The CAMIL-MMT hydrogel showed the maximum adsorption capacity for TC and OTC (24.59 and 26.14 mg/g, respectively) compared to the CAMIL-SEP and other forms of biopolymer hydrogel precursors. The effects of the contact time and initial concentration on TC and OTC adsorption by CAMIL-MMT and CAMIL-SEP hydrogels were well suited to the pseudo-second-order kinetics and Freundlich isotherm models. The adsorption performance of CAMIL-MMT and CAMIL-SEP hydrogels slightly decreased with an increase in solution pH, while it was not much influenced by the co-existing anions. The thermodynamic study indicated that the reactions for the uptake of TC and OTC were spontaneous and highly favorable. Moreover, the as-synthesized CAMIL-MMT and CAMIL-SEP hydrogels demonstrated strong potential for reuse in TC and OTC removal with high reusability and strong stability. The photocatalysis study revealed that residual TC and OTC after adsorption could be further degraded by CAMIL-MMT and CAMIL-SEP hydrogels under visible light irradiation. From the above-mentioned results, the as-synthesized CAMIL-MMT and CAMIL-SEP hydrogels are promising to be considered alternative materials for the adsorptive and photocatalytic removal of TC and OTC in practical application of water and wastewater treatment. 相似文献
17.
Dextrin as a biodegradable natural polymer has hydrophilic nature that capable to increase the swelling properties and biodegradability of the synthetic hydrogels. This study describes the synthesis of a poly (acrylic acid-co-acryloyl tetrasodium thiacalix[4]arene tetrasulfonate) grafted dextrin superabsorbent hydrogels (ADA) via solution polymerization. The effects of acryloyl tetrasodium thiacalix[4]arene tetrasulfonate (ACSTCA) dose (20–60) on swelling properties of the hydrogels were studied. The synthesized hydrogels were characterized by FTIR, TGA, DMTA and rheometry. The metal ion removal capacity of the gels was investigated by atomic absorption for Cd2+, Pb2+, and Hg2+. The tendency of metal ions adsorption decreased in the order of Pb2+>Cd2+>Hg2+. The effect of key operating parameters including ACSTCA content, contact time, adsorbent dosage, solution pH, and crosslinker density was experimentally studied on Pb2+ adsorption from aqueous solution. The equilibrium data was analyzed using Langmuir and Freundlich adsorption isotherms. Our experimental data are in best agreement with Freundlich isotherms, and adsorption of metal cation onto hydrogel followed a pseudo second-order kinetic model. According to the thermodynamic parameters, the adsorption of Pb2+ occurred spontaneously. The hydrogels could be regenerated after releasing heavy metal ions, and reused 5 times with less than 7 % loss of adsorption capacity. 相似文献
18.
In this study, sequential interpenetrating polymer network (IPN) hydrogels based on poly(polyethylene glycol diacrylate) poly(PEGDA)
and poly(methacrylic acid) (PMAA) were prepared with enhanced adsorption properties for heavy metal ion removal. The swelling
behavior and mechanical property of the IPN hydrogels were characterized. It was found that swelling ratio increased, and
mechanical strength decreased with the PMAA content in the IPN. The IPN hydrogels were used to remove heavy metal ions from
aqueous solution under the non-competitive condition. The effects of pH values of the feed solution at the range of 3–5 and
PMAA content in the IPN on the adsorption capacity were investigated. The results indicated that the adsorption capacity of
the IPN hydrogels increased with the pH values and PMAA content in the IPN. Furthermore, the synergistic complexation of metal
ions with two polymer networks in the IPN was found in the adsorption studies. Regeneration studies suggested that metal rebinding
capacity of the IPN hydrogels did not change significantly through repeated applications compared with the first run. It was
concluded that the poly(PEGDA)/PMAA hydrogels could be used as fast-responsive, high capacity, and renewable sorbent materials
in heavy metal removing processes. 相似文献
19.
In this study, N-isopropylacrylamide-based temperature and pH-sensitive hydrogels were synthesized by free radical polymerization for removal
of cationic dyes from aqueous solutions. For this purpose, N-isopropylacrylamide was copolymerized with various amounts of sodium salt of itaconic acid in the presence of crosslinking
agent (N,N-methylene bisacrylamide). The chemical structures of hydrogels were characterized by FT-IR analysis. In order to investigate
swelling properties of the hydrogels, water absorption (swelling) and shrinking (deswelling) kinetics, the equilibrium swelling
ratios in water and different pH buffer solutions, and the temperature dependent swelling ratios were determined. Then, their
adsorption properties such as adsorption capacities, kinetics, isotherms were investigated in case of their usage in removal
of Safranine T (ST), Brilliant Green (BG), and Brilliant Cresyl Blue (BCB) aqueous solutions. According to adsorbed dye amount,
the adsorption capacities are followed the order BG > ST ≅ BCB. In addition, the results indicated that the pseudo-second-order
kinetic model fitted better than the data obtained from pseudo-first-order model for the adsorption of all dyes onto hydrogels.
Furthermore, according to effect of the initial dye concentration findings, it is concluded that, Freundlich isotherm explains
the adsorption better than Langmuir isotherm. 相似文献