Cd_(1-x)Zn_xTe晶片中Zn组分的室温显微光致发光平面扫描表征

用显微光致发光 (μ- PL)平面扫描的方法对 Cd Zn Te(CZT)晶片进行了研究 .分别在 19μm× 16 μm的缺陷区域进行微米尺度和 7.9mm× 6 .0 mm的大面积范围内进行毫米尺度的逐点 PL 测量 .对测得每一点的 PL 谱进行了拟合 ,得到测量点的禁带宽度等参数 ,其平面分布对应于 CZT中 Zn的组分分布 .统计的结果给出禁带宽度的不均匀性 .对样品进行溴抛光后重复类似的测量 ,结果表明禁带宽度的均匀性大为改善 ,接近了材料组分的真实分布     

Cd1-xZnxTe晶片中Zn组分的室温 显微光致发光平面扫描表征

用显微光致发光（μ-PL）平面扫描的方法对CdZnTe(CZT)晶片进行了研究．分别在19μm×16μm的缺陷区域进行微米尺度和7.9mm×6.0mm的大面积范围内进行毫米尺度的逐点PL测量．对测得每一点的PL谱进行了拟合,得到测量点的禁带宽度等参数,其平面分布对应于CZT中Zn的组分分布．统计的结果给出禁带宽度的不均匀性．对样品进行溴抛光后重复类似的测量,结果表明禁带宽度的均匀性大为改善,接近了材料组分的真实分布．     

CdZnTe晶片中沉积相分布特性的研究

利用红外显微镜分别对富Cd和富Te配料生长的两组碲锌镉晶片的沉积相进行观察,对观察结果做统计分析,发现两组晶片中的沉积相在形状和分布情况方面有很大差别,采用数据拟合的方法发现两组CdZnTe晶片中不同尺寸的沉积相颗粒的密度满足指数分布.     

Cd1-xZnxTe晶片中Zn组分的室温 显微光致发光平面扫描表征

用显微光致发光（μ-PL）平面扫描的方法对CdZnTe(CZT)晶片进行了研究．分别在19μm×16μm的缺陷区域进行微米尺度和7.9mm×6.0mm的大面积范围内进行毫米尺度的逐点PL测量．对测得每一点的PL谱进行了拟合,得到测量点的禁带宽度等参数,其平面分布对应于CZT中Zn的组分分布．统计的结果给出禁带宽度的不均匀性．对样品进行溴抛光后重复类似的测量,结果表明禁带宽度的均匀性大为改善,接近了材料组分的真实分布．     

CdZnTe晶片显微光致发光谱中的等效温度分布研究

提出并实现了用微米级空间分辨率的显微光致发光（μ-PL)平面扫描谱对CdZnTe(CZT)晶片的表面亚微米层特性研究。在含缺陷区域进行微米尺度和在大面积范围内进行毫米尺度的逐点PL测量。对测得每一点的PL谱进行了拟合。拟合参数中等效温度Tc的统计分布给出两个分布中心,表明存在有两种机制的发光过程。同时统计结果给出发光各点的不均匀性。等效温度的平面分布图直观地给出了各温度的平面位置,样品经溴 抛光后重复类似的测量,结果表明等效湿度的统计均匀性大为改善。抛光后的不同的缺陷点表现出不同的发光特性,意味着各自起源的不同。大面积PL扫描的统计结果和平面分布给出样品特性的整体评价。     

改进的垂直布里奇曼法生长CdZnTe晶体中的成分偏离现象

采用多种测试方法,对改进的垂直布里奇曼法生长Cd0.96Zn0.04Te晶体中的成分偏离标准化学计量比现象及其对晶体性能的影响进行了研究.X射线能谱成分测试表明,在晶锭的头部即初始结晶位置,(Cd Zn)/Te比大于1;而在中部及末端,小于1.表明这种方法生长的CZT晶体仍然存在对标准化学计量比的偏离现象,开始结晶是在富Cd熔体中,生长至中后段则是在富Te条件下进行的.PL谱测试表明,富Cd的晶片内存在大量Te空位,严重富Te的晶片内Cd空位及其杂质复合体等引起的缺陷密度显著增加.晶体红外透过率测试结果表明,接近化学计量配比的CZT晶片具有高的红外透过率.     

改进的垂直布里奇曼法生长CdZnTe晶体中的成分偏离现象

采用多种测试方法,对改进的垂直布里奇曼法生长Cd0.96Zn0.04Te晶体中的成分偏离标准化学计量比现象及其对晶体性能的影响进行了研究.X射线能谱成分测试表明,在晶锭的头部即初始结晶位置,(Cd+Zn)/Te比大于1;而在中部及末端,小于1.表明这种方法生长的CZT晶体仍然存在对标准化学计量比的偏离现象,开始结晶是在富Cd熔体中,生长至中后段则是在富Te条件下进行的.PL谱测试表明,富Cd的晶片内存在大量Te空位,严重富Te的晶片内Cd空位及其杂质复合体等引起的缺陷密度显著增加.晶体红外透过率测试结果表明,接近化学计量配比的CZT晶片具有高的红外透过率.     

InN的光学性质

对采用MOCVD(metalorganic chemical vapor phase deposition)技术生长在GaN/Sapphire衬底上的InN薄膜进行了Hall、吸收谱以及低温光致发光(photoluminescence,PL)谱的测量和分析.Hall测量发现,样品的载流子浓度分布在1018～1019cm-3.在10K温度下进行PL测量,并对其线形进行分析,得到InN的带隙在0.7eV左右.综合Hall、吸收谱及PL谱的结果发现,吸收边以及PL谱的峰值能量都随载流子浓度的增加而蓝移.此外,我们还讨论了由吸收谱计算InN带隙的存在的不确定性.     

InN的光学性质

对采用MOCVD(metalorganic chemical vapor phase deposition)技术生长在GaN/Sapphire衬底上的InN薄膜进行了Hall、吸收谱以及低温光致发光(photoluminescence,PL)谱的测量和分析.Hall测量发现,样品的载流子浓度分布在1018～1019cm-3.在10K温度下进行PL测量,并对其线形进行分析,得到InN的带隙在0.7eV左右.综合Hall、吸收谱及PL谱的结果发现,吸收边以及PL谱的峰值能量都随载流子浓度的增加而蓝移.此外,我们还讨论了由吸收谱计算InN带隙的存在的不确定性.     

生长温度对MOCVD外延生长InGaN的影响

采用金属有机化学气相沉积(MOCVD)方法,在GaN/蓝宝石复合衬底上生长了InGaN薄膜,并研究了生长温度对InGaN薄膜的In组分、结晶品质和发光特性的影响.实验中发现随着生长温度的降低,InGaN薄膜中的In组分提高,但结晶品质显著下降.X射线衍射(XRD)联动扫描的结果显示即使在In组分增大至0.57时也没有发现相分离现象,光致发光(PL)谱测量的结果表明InGaN薄膜的PL峰位随着In组分升高而向低能方向移动,半高宽随着In组分增加而增加.     

碲锌镉晶体Zn组分的光致发光实用化研究

利用激光显微光致发光光谱仪测试了碲锌镉晶片的室温显微光致发光谱,对测得的光致发光谱进行拟合得到碲锌镉材料带隙的Eg值,根据实验总结出的Eg与Zn组分的室温计算公式,结合自主开发的Zn组分计算程序得到碲锌镉晶片上的Zn组分。所得的Zn组分结果用X射线双晶衍射进行验证,结果显示,室温下显微光致发光测得的Zn组分是相对准确可信的,可作为大量常规工艺测定Zn组分的有效工具,并且获得的Zn组分可成为外延碲镉汞薄膜时筛选匹配衬底的重要依据,同时还为研究和优化碲锌镉晶体生长工艺提供重要帮助。     

Phase separation in Zn-doped InGaN grown by metalorganic chemical vapor deposition

Zn-doped InGaN thin films were deposited on GaN/sapphire by metalorganic chemical vapor deposition, and studied by a combination of high-resolution X-ray diffraction (HR-XRD), micro-photoluminescence (PL) and secondary ion mass spectrometry (SIMS). Indium phase separation is studied comparatively. HR-XRD exhibits a GaN band and a single band from InGaN for samples without phase separation, but two InGaN bands corresponding to different x(In) for samples with phase separation. PL excitation power dependence measurements reveal 2 sets of InGaN PL emissions for samples with phase separation, but only 1 set for samples without phase separation. SIMS data showed that phase separated InGaN:Zn films possess a high Zn concentration near the InGaN–GaN interface and non-uniform distributions of In and Zn contents, which are in contrast with data from InGaN:Zn films with no In-phase separation.     

流体静压力下Hg_(1-x)Cd_xTe p-n结的伏安特性

在77K和室温下,研究了Hg_(1-x)Cd_xTe(x=0.5)p—n结伏安特性随流体静压力的变化,从中得到了禁带宽度E_g的压力系数。结果表明,在低压范围(01.4GPa),E_g～P关系明显偏离线性。实验还观察到,在正、反向小偏压区域,I—V特性随压力的变化呈现“反常”行为。     

Optical properties of Zn-diffused InP layers for the planar-type InGaAs/InP photodetectors

Zn diffusion into InP was carried out ex-situ using a new Zn diffusion technique with zinc phosphorus particles placed around InP materials as zinc source in a semi-closed chamber formed by a modified diffusion furnace.The optical characteristics of the Zn-diffused InP layer for the planar-type InGaAs/InP PIN photodetectors grown by molecular beam epitaxy (MBE) has been investigated by photoluminescence (PL) measurements.The temperature-dependent PL spectrum of Zn-diffused InP samples at different diffusion temperatures showed that band-to-acceptor transition dominates the PL emission,which indicates that Zn was commendably diffused into InP layer as the acceptor.High quality Zn-diffused InP layer with typically smooth surface was obtained at 580 ℃ for 10 min.Furthermore,more interstitial Zn atoms were activated to act as acceptors after a rapid annealing process.Based on the above Zn-diffusion technique,a 50μm planar-type InGaAs/InP PIN photodector device was fabricated and exhibited a low dark current of 7.73 pA under a reverse bias potential of-5 V and a high breakdown voltage of larger than 41 V (I ＜ 10 μA).In addition,a high responsivity of 0.81 A/W at 1.31 μm and 0.97 A/W at 1.55 μm was obtained in the developed PIN photodetector.     

Effect of precursor molar ratio of [S2?]/[Zn2+] on the lifetime of ZnS nanocrystals

Undoped ZnS nanocrystals(NCs) with different precursor molar ratios of [S2-]/[Zn2+] are prepared by the chemical precipitation method.The structural and optical properties of the samples are characterized by the X-ray diffraction(XRD) spectra,photoluminescence(PL) spectra and PL decay spectra.The XRD analysis shows that the crystal quality of ZnS NCs becomes better and the grain size is larger at higher [S2-]/[Zn2+] ratios.The PL peaked at 430 nm decreases with the [S2-]/[Zn2+] ratio increasing,which is asc...     

Luminescence and bandgap studies of high purity MgXZn1−XTe Ternary Alloys

High purity Mg_XZn_1−XTe alloys in the range of 0 < x < 0.45 have been prepared by the Bridgman technique. Wavelength modulated reflectivity measurements have been performed at 300 K. The structure of the spectra near the fundamen-tal edge is similar to the one for ZnTe. The bandgap va-riation versus the composition x is Eg (x) = 2.271 + 0.7 x + 0.6 x². Cathodoluminescence at 300K and 110K shows a single bandedge narrow peak. The variation with composition of the emission peak energy Ep (X) follows the same law as Eg (x). Undoped crystals are highly resistive (> 10⁵Ωcm) but when phosporus is introduced into the melt, the resis-tivity decreases to 10³ Ωcm.     

Morphology and photoluminescence studies of electrochemically etched heavily doped p-type GaAs in HF solution

Porous GaAs layers have been produced by electrochemical anodic etching of (100) heavily doped p-type GaAs substrate in HF solution. Scanning electron microscopy revealed the presence of etch pits ranging in size from 0.01 to 2 μm and they were strongly dependent on the electrochemical etching conditions. The etch pits chemical composition consists of O, Ga and As whereas the porous structure consists predominantly of GaAs as performed by energy dispersive X-ray analyzer. Typical porous structure with pores diameter ranging from 15 to 50 nm has been obtained. Room temperature photoluminescence (PL) investigations reveal the presence of two and in one case three PL bands besides the PL band of the started GaAs. Peaks wavelengths positions were approximately located in 600-900 nm range. The PL bands peaks wavelengths positions depend on the electrochemical etching conditions and they were approximately unchanged with increasing temperature. However, their PL intensity increased slowly with increasing temperature and tend to saturate. The observed PL bands were explained by the quantum confinement effects in GaAs nanocrystallites.     

Synthesis and photoluminescence properties of the 4H-SiC/SiO2 nanowires

4H-SiC/SiO2 nanowires are synthesized and the temperature-dependent photoluminescence （PL） properties of the nanowires are studied. Their structure and chemical composition are studied by scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, X-ray diffraction （XRD）, and Raman spectra. At room temperature, an ul- traviolet PL peak and a green PL band are observed. From the PL spectrum measured in the temperature range from 80 K to 300 K, the free excition emission, donor bound excition emission and their multiple-phonon replicas have been observed in ultraviolet region, and their origins have been identified. Moreover, it has been found that the temperature dependence of the free exciton peak position can be described by standard expression, and the thermal activation en- ergy values extracted from the temperature dependence of the free exciton and bound exciton peak integral intensity are about 40 meV and 181 meV, respectively.     

Vertical bridgman techniques to homogenize zinc composition of CdZnTe substrates

In order to improve the Zn homogeneity along the axial direction of CdZnTe boule, we have employed a modified Bridgman technique using a (Cd, Zn) alloy source in communication with the melt, whose temperature has been gradually changed from 800 to 840°C during growth. Electron probe microanalysis (EPMA) measurements of Zn composition in the boule shows an excellent homogeneity of Zn along the axis of the CdZnTe boule compared with results in a boule grown by using a fixed source temperature. We have performed a numerical simulation to obtain the approximate temperatures of additional heating and cooling needed to improve the radial Zn homogeneity. CdZnTe boule has been grown by seeded vertical Bridgman furnace with two zones of heater and cooler. Ultraviolet/visible spectroscopic measurements of Zn composition over the length of the boule indicate that the radial distribution of Zn composition is very homogeneous in the body region of the boule, where the radial variation of Zn composition is ±0.0005.