不同冷却方式下X80M管线钢的组织演变

针对当前开发高强韧性、低屈强比管线钢的需求,利用光学显微镜和透射电镜,研究了4种不同冷却方式下X80M管线钢的组织性能演变。结果表明：轧后空冷钢板的屈强比较高,金相组织主要为PF+P,没有明显的亚结构,位错密度低,强度低,均匀伸长率好,但落锤性能差;轧后钢板弛豫至Ar₃温度以下,水冷前会先析出一部分PF,快速冷却过程中富碳奥氏体在更低温下会发生贝氏体转变,随着冷却速率的增大,组织形貌由块状演化为条片状贝氏体,由PF+B的双相组织构成,存在较高密度的位错,具有较好的均匀伸长率与硬化指数,该工艺适合抗大变形管线钢的生产;轧后钢板直接快速冷却至M_s温度以下,钢板强度高韧性好,但均匀伸长率与硬化指数下降,金相组织为典型AF+MA,该工艺适合常规高钢级管线钢的生产。     

7075铝合金TIG焊焊缝的组织和性能与耐腐蚀性

采用自研的7075铝合金焊丝对7075铝合金板材进行焊接试验,研究焊接电流(160?～?180?A)对焊缝组织和性能与耐蚀性的影响;同时观察T6热处理(480?℃?+?1?h,120?℃?+?24?h)后性能的变化.结果表明,焊缝组织均匀为等轴晶,而且随电流增大晶粒尺寸不断增加,热处理后晶界变窄,明显看出析出相变少;X...     

冷却条件对镁合金耐蚀性能的影响

通过浸泡腐蚀质量损失试验,研究了不同凝固冷却速度(空冷、水冷和盐水冷)对AZ31和AZ81镁合金在3.5%Na Cl溶液中耐腐蚀性能的影响。研究结果表明,镁合金中Mg17Al12相的尺寸、形貌、分布、析出量及合金凝固组织的均匀性对抗Na Cl溶液腐蚀产生重要影响;Mg17Al12相对镁合金耐蚀性能具有双重作用(起阻障及电偶阴极的作用);同时凝固组织均匀化程度的改善能提高耐蚀性能。在3种因素的叠加作用下,AZ31合金的耐蚀性能随着冷却速度的提高而得以改善,而AZ81合金的耐蚀性能则表现为:空冷盐水淬水冷。     

冷却速度对Zn-Al-Mg合金组织及腐蚀性能的影响

研究了不同冷速下Zn+6%Al+3%Mg合金原始镀液凝固组织和形貌的变化,并对不同冷速下合金的耐腐蚀性能进行了分析。结果表明,不同冷速条件下,合金中出现先析出相Al、Al和Zn、Al/Mg Zn2共晶组织、Zn/Al/Mg Zn2三元共晶组织,但炉冷,水冷下还生成了Zn/Al/Mg Zn11三元共晶。随冷却速度增加,晶粒尺寸愈加细小。空冷下合金耐腐蚀性能相对较好,炉冷相对较差,这与其晶粒度和Mg2Zn11相有关。     

快速凝固Ti-48Al合金的组织及纳米硬度(英文)

研究冷却速度对熔体旋转法制备的快速凝固Ti-48%Al合金组织的影响。结果表明:同传统凝固相比,快速凝固明显细化了Ti-48%Al合金的组织,并使合金的成分变得均匀。随着冷却速度的增加,合金的晶粒明显细化。研究薄带厚度、辊速与冷却速度的关系。随着辊速的增加,冷却速度增加,薄带厚度呈减小的趋势。由于细晶强化的作用,快速凝固薄带的纳米硬度随着冷却速度的增加而增加。     

Characterisation of titanium alloy, IMI-834 for corrosion resistance under different environmental conditions

The current paper explains the corrosion characteristics of the titanium alloy, IMI-834 in three different environments which simulates acidic, marine and industrial environments at various temperatures. The titanium alloy forms a protective oxide scale under different environmental conditions at lower temperatures. However, they do not form a protective oxide scale at higher temperatures. The corrosion rate in different environments and at different temperatures increases by about five times in acidic and industrial environments when the temperature increases by a factor of 2. While in marine environments, the corrosion rate was found to increase by two times when the temperature increases by two times. The pitting corrosion studies in different environments revealed that the alloy is resistant to pitting and crevice corrosion at lower temperatures but is susceptible at higher temperatures. The corrosion morphologies were correlated and the degradation mechanism that is leading the titanium alloy to fail under various environmental conditions was discussed. Finally, based on the results obtained with different techniques, the alloy was recommended to fabricate components intended to use in a variety of environmental conditions.     

热变形含镁Zn-Cu-Ti合金组织特征、力学性能和耐腐蚀性能

本文采用挤压加轧制的方法制备Zn-0.75Cu-0.15Ti-0.3Mg合金板材,并探讨其组织演变过程、力学性能和耐腐蚀性能。结果表明：挤压变形后Zn-0.75Cu-0.15Ti-0.3Mg合金呈细小的等轴晶形貌,Zn基体中存在微米级TiZn3和MgCuZn颗粒相以及纳米级CuZn5颗粒相。轧制变形促使合金的晶粒发生长大,并且晶粒尺寸较为不均匀。随着轧制变形量的增大,基体形变诱导晶内更多MgCuZn颗粒相的析出。轧制变形后合金的强度和延伸率均呈降低趋势,抗拉强度从142.7MPa降低到不到110MPa,这主要归因于晶粒的长大和脆性第二相的增多。不过,轧制变形有助于合金耐腐蚀性能的提高,轧制态合金具有较低的腐蚀电流密度(25.47×10-5Amp/cm2)和较高的腐蚀产物层电阻(166.7Ω/cm2)。     

多向强应变-时效下7075合金组织、拉伸及抗晶间腐蚀性能

通过OM、TEM、力学性能和晶间腐蚀测试等手段研究了7075铝合金经多向锻造和80 ℃×1260 min时效处理后的组织及性能变化,并着重分析了试样在不同状态下的抗晶间腐蚀性能。结果表明:试样经多向锻造和80 ℃×1260 min时效处理后,晶粒得到明显细化,强度大幅提升并使塑性保持良好,晶界的析出相呈不连续分布,抗晶间腐蚀性能得到改善。最终,试样的最佳综合性能为:抗拉强度640.25 MPa、伸长率16.59%、自腐蚀电流密度1.077×10^-4 A·cm^-2。     

Dependence of crack and corrosion resistance of alloy 1450 on cooling conditions during quenching

Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 12, pp. 26–28, December, 1992.     

AlZnMgCuMn高熵合金的微观组织、力学和耐腐蚀性能及其机理

为探究轻质高熵合金AlZnMgCuMn的微观组织、力学性能、耐腐蚀性能及合适的热处理工艺,本研究采用XRD、SEM、EDS分析了合金的微观组织,通过电子万能试验机和维氏硬度计测试其力学性能,利用动电位极化测试、阻抗谱、CLSM和AFM对耐腐蚀性能及其机理进行分析。结果表明,AlZnMgCuMn高熵合金由Al-Mn准晶体相和hcp相组成,前者表现为枝晶形貌,后者则分布于枝晶间。热处理对两相形貌、分布和体积分数的影响较小。铸态AlZnMgCuMn的抗压强度、压缩率和显微维氏硬度(HV0.5)分别为415MPa、4.4%、4519.7MPa,自腐蚀电位和电流分别为-726.344 mV和1.882μA/cm2。电化学腐蚀之后合金表面产生明显的腐蚀坑,其深度约为11.8μm,枝晶Al-Mn相具有较低的电位作为阳极而优先被腐蚀,随着腐蚀的加剧,腐蚀微区彼此连接并发展成为大面积的腐蚀坑。     

Microstructure and magnetostrictive behavior of Fe-15 at% Ga alloy with different cooling rates

The main attention of this paper was devoted to the study of the effect of different cooling rates on the magnetic domain configuration and magnetostrictive behavior of heat-treated Fe-15 at% Ga alloy. After annealing at 1,000 °C for 3 h, the samples were subjected to water quenching, air cooling, and furnace cooling treatments. Phase constitution and magnetic domain structures of the samples were studied using X-ray diffraction(XRD) and magnetic force microscopy(MFM).XRD results indicate a single phase of a-Fe with disordered bcc(A2) structure for all samples. MFM results show that both water-quenched(WQ) and air-cooled(AC)samples are mainly made from ordered stripe domain structures, whereas a mixture of irregular stripe, zigzag,and plate domain patterns are observed in furnace-cooled(FC) sample. Magnetostrictive strain was measured in the presence of an externally applied magnetic field. It is found that WQ sample has the highest magnetostriction, while AC and FC samples exhibit moderate and the lowest magnetostriction, respectively, against the applied field.The dependence of initial domain configurations on thermal history is found to be conducive to the change in saturation magnetostrictions of the samples.     

不同轧制方法制得镁合金板材的组织和织构特点

介绍了热轧、冷轧、交叉轧制、累积叠轧、不对称轧制等不同的镁合金板材轧制工艺。分析了不同轧制工艺对应板材的组织特点及晶粒细化机制。分析了不同轧制工艺下板材织构特点及形成原因。对提高镁合金板材性能,改进轧制工艺提供参考借鉴。     

6061铝合金厚板搅拌摩擦焊接头组织与耐蚀性

采用搅拌摩擦焊对30 mm厚的6061铝合金进行了双面对接焊,分别采用金相显微镜、显微硬度仪和电化学工作站对焊接接头的组织、硬度和耐蚀性能进行观察、测量和研究。金相观察显示,双面搅拌摩擦焊焊缝前进侧与母材有明显的分界,后退侧分界模糊;焊核区呈均匀细小的等轴晶。硬度测试表明,搅拌摩擦焊接接头硬度呈“W”形特征分布,硬度最低值出现在前进侧热影响区。腐蚀试验表明,双面焊焊核重叠区腐蚀电流(2.396 3×10-5A/cm2)较大,一旦开始腐蚀,腐蚀速度很快,耐腐蚀能力相对较差。     

固溶冷却方式对AM50镁合金组织和耐蚀性能的影响

通过XRD、SEM、EDS、电化学腐蚀测试,研究了铸造AM50镁合金固溶后水冷和炉冷两种处理方式对组织及耐蚀性能的影响。结果表明,固溶处理后,由于大量Al固溶进α-Mg中,两种方式冷却的AM50镁合金相组成主要为α-Mg、Al₆Mn和少量β-Mg₁₇Al₁₂。由于冷却速率的不同,炉冷样比水冷样的β-Mg₁₇Al₁₂的数量多,体积大,并且围绕Al₆Mn相析出,而且大多在晶界处析出。由极化曲线和腐蚀速率曲线可以看出炉冷样的腐蚀速率较高,耐蚀性较差。由于β-Mg₁₇Al₁₂数量的增加以及α-Mg相中固溶Al的数量减少,导致炉冷试样比水冷试样的腐蚀速率高,而且经过168 h腐蚀形成了蚀坑带。     

稀土Er改性AM50镁合金热挤压态的组织及耐蚀性能

通过ICP-AES、SEM、EDS分析、光学显微镜观察、电化学测试及腐蚀质量损失测定等方法研究了稀土Er改性铸造AM50镁合金经热挤压加工后的组织及耐蚀性能。结果表明,添加稀土Er后,组织中出现Al3Er和Al7ErMn5两个新相,减少了β-Mg17Al12相的数量,从而提高了AM50镁合金的耐蚀性能。腐蚀试验表明,热挤压加工的Er改性AM50镁合金表面腐蚀坑数量较多,但是蚀坑较浅,主要是由于热挤压加工导致了α-Mg的数量的增加。     

不同状态条件下AZ80镁合金微观组织演化

利用电子背散射衍射(EBSD)技术观察研究了不同状态条件下AZ80镁合金的微观组织,分析了不同状态条件下AZ80镁合金的微观组织演化.结果表明:按照铸态、均质化热处理态和塑性变形态顺序,试样平均晶粒尺寸逐渐减小,平均晶粒形状纵横比呈先增大后减小的变化趋势,网状β-Mg17Al12相逐渐消失,材料塑性和强度得到提高;晶界...     

Microstructure and corrosion behaviors of as-rolled Mg-Zn-Er alloy sheets

The corrosion behaviors and mechanism of the as-rolled Mg-xZn-0.5Er (x=0.5, 2.0, 3.0 and 4.0, in wt.%) alloys were investigated. The potential difference between the second phase and matrix was determined by the type and size of the second phases. The dominated nano-scale W-phase on matrix in the Mg-0.5Zn-0.5Er alloy induced a sharp local pitting corrosion. However, as the volume fraction of the coarse W-phase or I-phase increased, the corrosion reaction was inclined to happen around the coarse W-phase or I-phase preferentially, leading to an obvious uniform corrosion and great acceleration of corrosion rate. The long-term immersion (14 d) results indicated that the corrosion resistance decreasing sequence was Mg-0.5Zn-0.5Er > Mg-2.0Zn-0.5Er > Mg-3.0Zn-0.5Er > Mg-4.0Zn-0.5Er.     

Deformation resistance of Fe-Mn-V-N alloy under different deformation processes

The deformation resistance of Fe-Mn-V-N alloy under different deformation conditions was investigated by hot compression method on thermal simulator.Effects of deformation degree, deformation temperature,and strain rate on deformation resistance were analyzed.The results show that when other conditions are constant,the deformation resistance increases with the increase in deformation degree and strain rate and decreases with the increase in deformation temperature. At the same time, the mathematical model of deformation resistance for Fe-MnV-N alloy was established by 1 stOpt software using the Levenberg-Marquardt optimization algorithm carried out on the fitting of regression coefficients, which has higher fitting precision.     

镁合金板材的微观组织演变及腐蚀行为

本研究在室温下对AZ31镁合金板材分别沿与挤压方向成0o, 30o, 45o, 60o和90o五个方向进行了预拉伸变形,之后研究了其微观结构和预变形后板材的腐蚀性能。结果表明,随着角度的增加,孪晶数量也随之增加,孪晶量多的镁合金板材（～52%）具有较好的抗腐蚀性。这主要是因为拉伸孪晶引入的更多晶界,使合金的微观结构更为均匀,从而可以抑制腐蚀行为产生。