石墨烯含量对Al-15Si-4Cu-Mg组织及摩擦磨损性能的影响

利用金相显微镜(OM)、摩擦磨损试验机、扫描电镜(SEM)对Al-15Si-4Cu-Mg复合材料微观组织形貌、摩擦磨损性能、磨痕表面形貌进行表征和分析。研究添加不同含量石墨烯对Al-15Si-4Cu-Mg复合材料微观组织及摩擦磨损性能的影响。结果表明,随石墨烯含量增加,复合材料中硅颗粒形貌逐渐变得圆钝且尺寸减小,复合材料的硬度有所增加,摩擦系数减小,耐磨性能显著提高;加入0.3%石墨烯的复合材料磨损机制为磨粒磨损,当石墨烯的含量达到0.7%时复合材料的磨损机制以轻微的粘着磨损为主并有少量的磨粒磨损。     

纤维组分比例对玄武岩/聚丙烯复合材料力学性能影响研究

采用非织造加工工艺,将玄武岩纤维和聚丙烯纤维通过开松混合后梳理成网,然后按照一定的尺寸制成预制件,使用模压成型工艺制备玄武岩/聚丙烯复合材料,研究不同比例的玄武岩纤维和聚丙烯纤维对复合材料力学性能的影响,并通过数学方差分析方法确定了影响因素的显著性.结果表明:当玄武岩纤维和聚丙烯纤维的比例为30/70时,复合材料的拉伸、弯曲强度和模量达到最高,最大拉伸强度、弯曲强度分别为92.998 MPa和156.134 MPa,最大拉伸和弯曲模量分别为3.400 GPa和1.288 GPa.     

含孔隙碳纤维/环氧树脂层合板力学性能模拟

为了探究孔隙率对织物碳纤维/环氧树脂复合材料层合板拉伸强度和压缩强度的影响规律,分别测量了孔隙率为0.33%、0.71%及1.50%的复合材料层合板的拉伸强度及压缩强度并进行有限元模拟.试验结果表明:随着孔隙率的增加,复合材料层合板的拉伸强度和压缩强度均呈下降趋势.建立了适用于织物纤维增强复合材料的静态力学强度的失效准则,结合刚度突然退化模型,通过引入不同孔隙率复合材料的基本强度参数,使用ABAQUS软件建立有限元模型,对不同孔隙率的织物碳纤维/环氧树脂复合材料层合板的拉伸强度及压缩强度进行了较为准确的预测.     

石墨烯/Al-18Si-3Cu-Mg复合材料微观组织及摩擦磨损性能研究

采用粉末冶金方法,制备石墨烯/Al-18Si-3Cu-Mg多元金属基复合材料。借助扫描电镜(SEM)、X射线衍射仪、往复摩擦磨损试验机,研究不同石墨烯添加量对石墨烯/Al-18Si-3Cu-Mg多元金属基复合材料微观组织、摩擦磨损性能的影响,并运用分形理论定量分析复合材料微观组织形貌及摩擦磨损机制。结果表明,石墨烯的添加可显著细化石墨烯/Al-18Si-3Cu-Mg多元金属基复合材料内Si颗粒的尺寸;当石墨烯添加量分别为0%、0.3%、0.5%、0.7%时,复合材料的硬度值呈现先升高后下降的趋势;石墨烯含量为0.5%时,硬度值最高摩擦系数最小,分别为84.8HB和0.48,摩擦系数比未添加石墨烯时降低了28%。分析试样磨痕形貌及微观组织形貌分形维数(D)发现,当石墨烯添加量为0.5%时,D值为2.0533,摩擦磨损机制为磨粒磨损。     

黄麻纤维/环氧树脂复合材料的力学性能

探讨了黄麻/环氧树脂复合材料板的制作方法,并对不同质量分数与长度的黄麻纤维增强的板材进行了拉伸及弯曲性能测试,采用扫描电镜观察了拉伸断面的微观形貌.讨论了纤维质量分数与长度对复合材料拉伸强度、拉伸模量、弯曲强度和弯曲模量的影响.实验结果表明,加入黄麻纤维有利于提升环氧树脂的拉伸和弯曲,纤维质量分数与长度对复合材料力学性...     

玻璃纤维对竹塑复合材料性能的影响

研究了不同玻璃纤维含量对于竹塑复合材料性能的影响.采用注塑成型工艺制备试样,然后测试试样的拉伸、冲击和弯曲强度,并用扫描电镜观察断面的形貌.试验结果表明当玻璃纤维含量在10%左右时,试样的综合力学性能最好.     

玄武岩玻璃粉体与短切纤维对复合材料力学性能影响的对比分析

分别添加0%、5%、10%、15%、20%、25%的玄武岩粉体和短切纤维,研究添加后木质复合材料关键力学性能的变化.当粉体添加质量分数为15%时,复合板的拉伸强度达到峰值24.3 MPa,比未增强的复合板高了94.3%;而玄武岩短切纤维添加质量分数为10%时,复合板拉伸强度达到峰值18.9 MPa,比未增强复合板提高50.8%.当粉体添加质量分数和玄武岩短切纤维添加质量分数均为10%时,复合板的弯曲强度达到峰值各为41.8 MPa和39.2 MPa,比未增强的复合板各提高了43.3%和34.4%.结果表明,玄武岩粉体不仅仅价格远低于玄武岩短切纤维,其增强效果也远优于该纤维.     

RTM工艺制备碳纤维复合材料的力学性能

本文选用树脂传递模塑成型(RTM)工艺制备(3K-T300,3312)碳纤维/环氧树脂复合材料,分别采用拉伸实验和弯曲实验研究复合材料的力学性能;并对样件的拉伸断口进行SEM观察,分析其失效形式。结果表明:碳纤维/环氧树脂复合材料的拉伸强度和弯曲强度分别为459.17MPa和576.82MPa;断口微观形貌表明环氧树脂充分浸润到碳纤维编织布层状界面和丝束之间的界面中,断口中碳纤维和环氧树脂脆性断裂以及碳纤维与环氧树脂界面裂纹萌生扩展并断裂是试样失效的机制,说明RTM具有较好的工艺应用性。     

玻璃纤维增强环氧树脂单向复合材料力学性能分析

采用连续玻璃纤维与环氧树脂相复合,通过金属模压成型工艺,制备出单向玻璃纤维／环氧树脂复合材料。通过三点弯曲实验论证单向纤维对树脂基体的增强作用,从而研究不同纤维含量下复合材料的弹性模量、纵向拉伸强度、纵向压缩强度的变化趋势。结果表明：随着纤维含量的增加,复合材料的力学性能均增强,当纤维体积含量为50％时,其各项性能均较好,弹性模量为40GPa,纵向拉伸强度为1200MPa,纵向压缩模量为700MPa。此外,对复合材料的其他常用力学性能参数进行检测。     

聚丙烯/PP-g-MA/蒙脱土纳米复合材料的制备和性能研究

采用聚丙烯接枝马来酸酐（PP-g-MA）作增容剂改性聚丙烯（PP）/蒙脱土（MMT）纳米复合材料,研究了不同PP-g-MA含量对PP/PP-g-MA/MMT的流动性、拉伸强度、冲击强度、耐热性、晶体形貌以及MMT分散的影响。结果表明：当PP-g-MA的质量分数为5%时,PP基体的晶粒细化,MMT分散得以改善,拉伸强度基本不变,冲击强度却大幅度增加。     

玄武岩纤维布增强环氧树脂复合材料研究

以玄武岩纤维平纹布 (BF) 加入到环氧树脂 (EP) 中,采用模压工艺制备BF／EP 复合材料,研究加入不同层数的玄武岩纤维布对复合材料力学性能和断裂韧性的影响。实验结果表明,BF/EP复合材料的弯曲强度、冲击强度和断裂韧性明显优于环氧树脂;与未加BF的环氧树脂相比,加入三层BF后复合材料的弯曲强度提高了2.76倍,缺口冲击强度提高了19.67倍,无缺口冲击强度提高了5.94倍,KIC提高了2.97倍。     

玄武岩纤维贫混凝土力学性能研究

从贫混凝土基层的复合式路面的使用状况来看,反射裂缝的问题比较突出.玄武岩纤维贫混凝土是一种能有效减弱或者避免贫混凝土产生反射裂缝的新型混合料.通过一系列室内试验,对玄武岩纤维贫混凝土的抗压强度、抗弯拉强度、抗冲击能力以及静力抗压弹性模量等力学性能进行了系统研究.得出玄武岩纤维最佳掺量为混合料总质量的2.0‰,最佳掺量范围为3～6 kg/m3.掺入玄武岩纤维后,能大幅提高贫混凝土的早期抗压、抗弯拉强度,且28 d龄期的纤维贫混凝抗压强度和抗弯拉强度也较一般贫混凝土提高了20%以上;可使贫混凝土具有良好的抗冲击性能,较普通贫混凝土提高了近1/3倍;可提高贫混凝土材料的静力抗压弹性模量,但提升幅度不大.     

Chemical and thermal resistance of basalt fiber in inclement environments

To study the applicability of the basalt fiber through various experimental works in thermal and chemical environments, glass fiber and carbon fiber were compared and discussed. The tensile strength testing was used to investigate the corrosive resistance of basalt fiber, meanwhile, surface study by scanning electron microscopy and microanalysis with complementary X-ray diffraction analysis (SEM/EDS) was also used to ascertain the durability of basalt fiber. The basalt fiber showed better strength retention than the glass fiber at relatively high temperature. Its tensile strength increased when exposed at 300 °C for several hours, and still maintain about 70% of the initial strength at 400 °C, whereas that of the glass fiber decreased dramatically. The better stability of the basalt fiber was observed in hydrothermal and chemical environment. The tensile strength of the basalt fiber increased by 20% after the immersion in boiling water and remained well in acid solution, when it comes to glass fiber, the tensile strength decreased to some extent. Although the alkali resistance of basalt fiber was poor at the initial stage, it shows better resistance than the glass fiber after long time treatment.     

Effect of sizing on the interfacial shear strength of carbon fiber/epoxy resin monofilament composite

The single fiber fragmentation test （SFFT） was used to measure the interracial shear strength （IFSS） of sized and unsized CF800/epoxy resin monofilament composite in order to evaluate the effect of sizing respectively. Besides, the interfacial reinforcing mechanism was explored by analyzing the surface morphology of the carbon fibers, the wettability between the carbon fibers and the epoxy resin, and the chemical characteristics of the fiber surface. Moreover, the effect of sizing on heat and humidity resistance of interface was investigated by aging test. The results show that sizing improves IFSS of CF800/epoxy resin monofilament composite by 59% through increasing the functional groups containing oxygen and through enhancing wettability, while after sizing the heat and humidity resistance of interface is decreased.     

橡塑型洗衣机脚垫胶料的配方设计

以高性能的西门子洗衣机脚垫胶料为研究方向,采用橡塑并用改性法,在丁腈橡胶(NBR)中加入一定比例的高苯乙烯树脂(HSR),以改善胶料的工艺性能,提高胶料的强度、硬度及耐磨性;通过对NBR/HSR橡塑并用胶力学、耐介质、耐老化及压缩等性能的分析测试,结果表明,当NBR/HSR橡塑并用比为80/20时,其并用胶的综合性能最好,其拉伸强度、磨耗体积、压缩永久变形分别为21.31 MPa、0.18 cm3和25%,并用胶的各项性能均符合西门子洗衣机脚垫胶料的性能指标要求.     

超支化聚膦酸酯改性环氧树脂的研究

以苯膦酰二氯（BPOD）为A2单体,三羟甲基丙烷（TMP）为B3单体,采用熔融缩聚法合成了超支化聚膦酸酯.利用动态力学热分析（DMA）、热失重分析（TGA）对环氧树脂固化体系的热性能进行了表征,研究了超支化聚膦酸酯的用量对环氧树脂固化体系的力学性能和阻燃性的影响.结果表明：加入15%的超支化聚膦酸酯,环氧树脂固化体系的拉伸强度和冲击强度分别提高了11.26%和306%,氧指数从22提高到33,说明超支化聚膦酸酯具有良好的阻燃性.     

Mechanical Properties of Phenolic-Resin Composites Reinforced with CF/BF Interlayer Hybrid Fibers

Phenolic-resin composites reinforced with carbon fiber (CF) and basalt fiber (BF) interlayer hybrid fibers plain fabric were fabricated. The tensile strength, compressive strength and interlaminar shear strength of the prepared composites were studied. The results indicated that hybrid fibers reinforced composites possessed the advantages of both CF and BF. When resin content was 35% by volume fraction, the comprehensive mechanical performance of BF/CF reinforced phenolic resin composites reached the optimal values with the warp and weft direction tensile strength, compressive strength and interlayer shear strength being 252 MPa and 487 MPa, 105 MPa and 129 MPa, 21 MPa and 20 MPa, respectively. The scanning electron microscope (SEM) observations showed that the BF/CF hybrid fibers reinforced composites had better interfacial adhesion.     

玻璃纤维增强环氧树脂基复合材料的低温性能研究

对S玻璃纤维和E玻璃纤维增强环氧树脂基复合材料的常温和低温力学性能进行实验,结果表明：玻纤／环氧树脂单向复合材料力学性能随着纤维含量增加而增强,当纤维体积含量为50％时,复合材料具有较好的综合力学性能,且复合材料的强度随着温度的降低呈增加趋势。当温度降到76K时材料的强度达到最高值,S玻纤／环氧复合材料的拉伸强度最高值可达2．1GPa;E玻纤／环氧复合材料的最大拉伸强度也达到1．4GPa。其原因是由于低温下玻璃纤维的横向收缩比树脂基体小,界面摩擦力得到增强,从而获得高的界面粘接强度。     

Surface adhesive properties of continuous PBO fiber after air-plasma-grafting-epoxy treatment

It was found that air dielectric barrier discharge(DBD) plasma contributed to the grafting of epoxy resin onto continuous PBO fiber surface. This air-plasma-grafting-epoxy method yielded a noticeable enhancement in the interfacial adhesion between PBO fiber and thermoplastic matrix resin, with the interlaminar shear strength of the resulting composites increased by 66.7%. DSC and FTIR analyses were then used to study the curing behavior of epoxy coating on PBO fiber surface, deduce the possible grafting reactions and investigate the grafting mechanism. More importantly, TGA measurement showed that the grafting of epoxy onto PBO fiber had almost no effect on the composite heat resistance, and there was more thermoplastic matrix resin adhering to the fiber surface; the latter could also be clearly found in the SEM photos. Thereby, the air-plasma-grafting-epoxy treatment was proved to be an effective method for the improvement of continuous PBO fiber surface adhesive properties.