A numerical comparison among different water-based hybrid nanofluids on their influences on natural convection heat transfer in a triangular solar collector for different tilt angles

Natural convection inside a triangular solar collector is investigated numerically for different nanofluids and hybrid nanofluids in this study. The individual effects of Al₂O₃–water, carbon nanotubes (CNT)–water, and Cu–water nanofluids are observed for different solid volume fractions of nanoparticles (0%–10%). Three types of hybrid nanofluids are prepared using different ratios of Al₂O₃, CNT, and Cu nanoparticles in water. A comparison is made varying the Rayleigh numbers within laminar range (10³–10⁶) for different tilt angles (0°, 30°, 60°, and 90°) of the solar collector. The inclined surface of the triangular solar collector is isothermally cold and the bottom wall (absorber plate) is isothermally hot, whereas the vertical wall with respect to the absorber plate is considered adiabatic. Average Nusselt numbers along the hot wall for different parameters are observed. Streamlines and isotherm contours are also plotted for different cases. Dimensionless governing Navier–Stokes and thermal energy conservation equations are solved by Galerkin weighted residual finite element method. Better convective heat transfer is found for higher Rayleigh number, solid volume fraction, and tilt angle. In the case of hybrid nanofluid, increasing the percentage of the nanoparticle that gives better heat transfer performance individually results in enhancing natural convection heat transfer inside the enclosure.     

Synthesis and thermal conductivity of Cu2O nanofluids

We apply the chemical solution method to synthesize Cu₂O nanofluids: suspensions of cuprous-oxide (Cu₂O) nanoparticles in water, and experimentally study the effect of reactant molar concentration and nanofluid temperature on the thermal conductivity. Substantial conductivity enhancement up to 24% is achievable with the synthesized nanofluids. The nanoparticle shape is variable by adjusting some synthesis parameters. The thermal conductivity shows both sensitivity and nonlinearity to the reactant molar concentration and the nanofluid temperature.     

Experimental and theoretical study of a single-basin solar sill in Jordan

This paper presents experimental results of a single-basin solar still using various absorbing materials. The still has equal angle double-sloped covers with an effective basin area of 3 m². The experiments were conducted in Amman, Jordan during the months of April and May. The materials used to enhance the absorptivity of water for solar radiation include dissolved salts, violet dye, and charcoal. The salts were potassium permanganate (KMnO₄) and potassium dichromate (K₂Cr₂O₇). Significant increase in still efficiency and productivity was obtained. For example, the addition of potassium permanganate resulted in 26% improvement in efficiency. Also, a comparison between theoretical and measured water productivity is presented. It was found that there is a good agreement between theory and experiment.     

Experimental investigation on the effect of MgO and TiO2 nanoparticles in stepped solar still

This work aims at augmenting the amount of potable water using MgO and TiO₂ in stepped solar still. Experiments were carried out for the climatic conditions of Chennai, India, with two different concentrations of nanofluids inside a stepped basin under three different cases. Results show that there is an improvement in yield of fresh water from stepped solar still by 33.18% and 41.05% using 0.1% and 0.2% volume concentration of TiO₂ nanofluid, respectively, whereas the freshwater yield from stepped still with MgO nanofluids improved by 51.7% and 61.89%. Furthermore, the economic analysis revealed that the cost of potable water from the modified solar still reduced from 0.029 to 0.016 $/kg. Similarly, the useful annual energy, yearly cost per kilogram, and annual cost per kilowatt hour are significantly profitable with the use of MgO nanofluid in the stepped basin and found as 512.46 kWh, 0.025 $/kg, and 0.026 $/kWh, respectively. It is also found that the cost of potable water from the modified still significantly increases as the amount of fresh water produced is decreased with increased fabrication cost of the solar still.     

Efficiency improvement of a solar direct volumetric receiver utilizing aqueous suspensions of CuO

In this paper, an experimental study was performed to investigate the photothermal conversion properties of CuO‐H₂O nanofluid‐based volumetric receiver mainly considering the effects of nanoparticle (NP) concentration, irradiation time, and receiver depth. First, stable aqueous suspensions of CuO with NPs having average diameter close to 10 nm were produced by the precursor transformation method. The spectral transmittances of CuO‐H₂O nanofluids decrease with increasing the NP concentration (0.01‐0.25 wt%) at wavelengths of 200 to 1350 nm. The photothermal conversion performance of CuO‐H₂O nanofluids is sensitive to the receiver depth, irradiation time, and NP concentration. The higher NP concentration causes stronger optical absorption in the upper part and reduces the temperature at the bottom accordingly. The temperature difference between CuO‐H₂O nanofluid and distilled water increased initially and then decreased with the increase of penetration depth, and there existed an optimal depth of 1 cm with respect to the best photothermal conversion performance. The receiver efficiency decreased with increasing the light irradiation time, and an efficiency improvement up to 30.4% was achieved for the 0.25 wt% nanofluid at the optimal depth of 1 cm as compared with water. This work shows that volumetric receivers provide a potential alternative for solar thermal energy utilization versus surface‐based absorber especially under concentrated solar radiation.     

Heat Transfer by Nanofluid with Different Nanoparticles in a Solar Collector

The buoyancy flow and heat transfer characteristics inside a solar collector having the flat‐plate cover and sinusoidal corrugated absorber are analyzed numerically. The water‐based nanofluid with alumina and copper nanoparticles is used as the working fluid inside the solar collector. The governing partial differential equations with proper boundary conditions are solved by the finite element method using Galerkin's weighted residual scheme. The behavior of both nanoparticles related to performance such as temperature and velocity distributions, radiative and convective heat transfers, mean temperature, and velocity of the nanofluid is investigated systematically. This performance includes the solid volume fraction, namely ?₁ and ?₂, with respect to Al ₂ O ₃ and Cu nanoparticles. The results show that the better performance of heat transfer inside the collector is found by using the highest ?₂ than ?₁. The result of this study expresses a good agreement with the theoretical result available in the literature. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res, 43(1): 61–79, 2014; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21061     

Experimental analysis of SiO2-Distilled water nanofluids in a Polymer Electrolyte Membrane fuel cell parallel channel cooling plate

An experimental report on the thermal performance of Silicone Dioxide (SiO₂) nanofluid coolants based on a PEM fuel cell cooling system is presented. The aim of this study is to evaluate the feasibility of applying these nanofluids coolants as an alternative to conventional distilled water through detailed analysis of thermofluids behaviour in a simulated cooling plate environment. SiO₂ nanoparticles were dispersed in distilled water at 0.1%, 0.3% and 0.5% volume concentrations and tested in a parallel channel cooling plate system. A constant heat load was supplied to simulate a fuel cell stack thermal condition. At inlet flow conditions from 750 to 900 Reynolds number, the SiO₂ nanofluids reduced the average plate temperatures by 15%–20% compared to conventional water coolant. The nanofluids also increased the cooling effectiveness by a similar margin, as well as improving the bulk heat transfer coefficient to a range between 2700 and 4400 W m⁻². ^oC⁻¹. However, the required pumping power was also increased due to the added viscous effect. Through the Advantage Ratio (AR) analysis, it was concluded that the enhancement in heat transfer mechanics was more significant than the penalties in fluid flow dynamics. Thus, the SiO₂ nanofluids and the cooling plate design are possible options for advanced PEM fuel cell thermal management practice in future stack designs.     

Experimental evaluation of a single-basin solar still using different absorbing materials

Single-basin solar stills can be used for water desalination. Probably, they are considered the best solution for water production in remote, arid to semi-arid, small communities, where fresh water is unavailable. However, the amount of distilled water produced per unit area is somewhat low which makes the single-basin solar still unacceptable in some instances. The purpose of this paper is to study the effect of using different absorbing materials in a solar still, and thus enhance the productivity of water. Experimental results show that the productivity of distilled water was enhanced for some materials. For example, using an absorbing black rubber mat increased the daily water productivity by 38%. Using black ink increased it by 45%. Black dye was the best absorbing material used in terms of water productivity. It resulted in an enhancement of about 60%. The still used in the study was a single-basin solar still with double slopes and an effective insolation area of 3 m².     

Mathematical modeling and the thermal performance of floating cum tilted-wick type solar still

In this paper, mathematical modeling for the thermal performance of floating cum tilted-wick type solar still has been presented. Explicit expressions for the temperatures of various components of the proposed system and its efficiency have been developed. The effect of mass flow rate due to capillary action of jute wick has been investigated for evaporative, convective, and radiative heat transfer from the evaporating surface to the condensing surface.It has been found that the mass flow rate of 2.5 x 10^?3 kg/s is optimum for effective distillation. Also, the effect of absorptivity of the wick surfaces (floating and tilted-wick) on the productivity of the solar still has been studied and found that α_w1 (absorptivity of the tilted-wick surface) and α_wf(absorptivity of the floating-wick surface) of 0.85 have given higher productivity.For enunciation of the analytical results, numerical calculations have been made using meteorological parameters for a typical winter and summer day in Coimbatore.The theoretical results are in good agreement with the experimental results.     

Factors influencing solar energy collector efficiency

The effects of glazing, solar flux, emissivity and absorptivity of the absorber surface on collector performance have been predicted for different plate temperatures (60°C and 100°C). At low solar flux levels (200–600 W m^?2) double- or triple-glazed collectors are superior to single-glazed collectors. For collectors with selective absorber coatings, the optimal number of glazing panes is two. Higher values of absorptivity and lower values of emissivity are more effective for single-glazed than for double-glazed collectors.     

Experimental investigation on the thermal efficiency and performance characteristics of a flat plate solar collector using SiO2/EG–water nanofluids

Application of nanofluids in thermal energy devices such as solar collectors is developing day by day. This paper reports the results of experiments on a flat plate solar collector where the working fluid is SiO₂/ethylene glycol (EG)–water nanofluid with volume fractions up to 1%. The thermal efficiency and performance characteristics of solar collector are obtained for mass flow rates between 0.018 and 0.045 kg/s. The curve characteristics of solar collector indicate that the effects of particle loading on the thermal efficiency enhancement are more pronounced at higher values of heat loss parameter. The results of this work elucidate the potential of SiO₂ nanoparticles to improve the efficiency of solar collectors despite its low thermal conductivity compared to other usual nanoparticles.     

Theoretical and Experimental Studies of the Ultra-Thin-Channel Solar Water Collector

Ultra-thin-channel solar water collector efficiency (UCSWC) was investigated theoretically and experimentally. An ultra-thin-channel solar water collector was constructed using several flat plates with an ultra-thin fluid channel formed using an adjustable flexible silicon frame inserted between the absorber plate and bottom plate. The advantages of the ultra-thin-channel solar water collector are low absorber plate temperature and low total water mass flow rate, resulting in considerable collector efficiency improvement with high outlet fluid temperature and low pump power requirement. A simple and general modeling method was developed to predict the collector efficiencies and mean temperatures of the glass cover, absorber plate and fluid. Good agreement was achieved between the calculated and experimental values. The superior collector efficiencies of the UCSWC are obtained as 82.2% and 75.5% for the inlet temperatures 30°C and 70°C, respectively, operating at a total fluid mass flow 8.3 × 10^?3 kg/s and solar radiation incident of 1100 W/m².     

Theory and experimental investigation of a weir-type inclined solar still

A weir-type solar still is proposed to recover rejected water from the water purifying systems for solar hydrogen production. This consists of an inclined absorber plate formed to make weirs, as well as a top basin and a bottom basin. Water is flowed from the top basin over the weirs to the bottom collection basin. A small pump is used to return the unevaporated water to the top tank. Hourly distillate productivity of the still with double- and single-pane glass covers was measured and the latter showed higher production rates. The average distillate productivities for double- and single-pane glass covers are approximately 2.2 and 5.5 l/m²/day in the months of August and September in Las Vegas, respectively. Mathematical models that can predict the hourly distillate productivity are developed. These compared well with the experimental results. Productivity of the weir-type still with a single-pane glass was also compared with conventional basin types tested at the same location. The productivity of the weir-type still is approximately 20% higher. The quality of distillate from the still is analyzed to verify the ability of the still to meet the standards required by the electrolyzers.     

Research on Thermophysical Properties of Nanoliquids Based on SiO<Subscript>2</Subscript> Nanoparticles for Use as a Heat-Transfer Medium in Solar-Thermal Converters

This paper presents an analysis of the modern state of studies of the thermophysical properties of nanofluids and the heat-transfer mechanism in them. The results of experimental studies of obtaining and determining the dynamic viscosity of the nanofluids (SiO₂ + water) with various concentrations of nanoparticles are given. Nanofluids are obtained using a two-stage method in an ultrasonic field with a frequency of 20 kHz. It is shown that, in the SiO₂ + water system, nanoparticles with sizes of 7, 12, and 16 nm are most stable. Various SiO₂ concentrations in the volume range 0.5–5% were tested, and their thermophysical properties were studied for the purpose of using them as a heat-transfer medium in flat-plate solar collectors.     

Surface modification of aligned TiO2 nanotubes by Cu2O nanoparticles and their enhanced photo electrochemical properties and hydrogen generation application

In this work, we report the synthesis of cuprous oxide (Cu₂O) nanoparticles modified vertically oriented aligned titanium dioxide (TiO₂) nanotube arrays through wet chemical treatment of TiO₂ nanotubes and their multi-functional application as enhanced photo electrochemical and hydrogen generation. The synthesized samples were characterized by X-ray diffraction, SEM, TEM, and UV–Vis spectroscopy. The structural characterization revealed that the admixed Cu₂O nanoparticles on the TiO₂ surface did not alter its crystalline structure of vertically oriented aligned TiO₂ nanotube. The photocatalytic performance and hydrogen generation of as synthesized Cu₂O nanoparticles modified aligned TiO₂ nanotube was found to highly depend on the Cu₂O content. The optical characterizations reveal that the presence of Cu₂O nanoparticles extends its absorption into the visible region which improves the photocurrent density in comparison to pristine aligned TiO₂ nanotubes electrodes due to enhanced photoactivity and better charge separation. The optimum photocurrent density and hydrogen generation rate has been found to be 3.4 mA cm^?2 and 127.5 μmole cm^?2 h^?1 in 1 M Na₂SO₄ electrolyte solution under 1.5 AM solar irradiance of white light with illumination intensity of 100 mW cm^?2.     

An efficient tandem photoelectrochemical cell composed of FeOOH/TiO2/BiVO4 and Cu2O for self-driven solar water splitting

An integrated solar water splitting tandem cell without external bias was designed using a FeOOH modified TiO₂/BiVO₄ photoanode as a photoanode and p-Cu₂O as a photocathode in this study. An apparent photocurrent (0.37 mA/cm² at operating voltage of +0.36 V_RHE) for the tandem cell without applied bias was measured, which is corresponding to a photoconversion efficiency of 0.46%. Besides, the photocurrent of FeOOH modified TiO₂/BiVO₄–Cu₂O is much higher than the operating point given by pure BiVO₄ and Cu₂O photocathode (∼0.07 mA/cm² at +0.42 V_RHE). Then we established a FeOOH modified TiO₂/BiVO₄–Cu₂O two-electrode system and measured the current density-voltage curves under AM 1.5G illumination. The unassisted photocurrent density is 0.12 mA/cm⁻² and the corresponding amounts of hydrogen and oxygen evolved by the tandem PEC cell without bias are 2.36 μmol/cm² and 1.09 μmol/cm² after testing for 2.5 h. The photoelectrochemical (PEC) properties of the FeOOH modified TiO₂/BiVO₄ photoanode were further studied to demonstrate the electrons transport process of solar water splitting. This aspect provides a fundamental challenge to establish an unbiased and stabilized photoelectrochemical (PEC) solar water splitting tandem cell with higher solar-to-hydrogen efficiency.     

Experimental study on conventional solar still integrated with inclined solar still under different water depth

This study primarily focuses on comparative experimental analysis on standalone conventional solar still (CSS), inclined solar still (ISS), and integrated conventional and inclined solar still (CSS‐ISS) for different parameters that affect the freshwater yield. For enhancing the freshwater yield only a few studies are available on still‐still integration. The present novel study provides a greater improvement in improving the freshwater yield by integrating ISS with CSS. This experimental work mainly concentrates on the importance of water depth (d _w) and mass flow rate of water ( m _w) in the solar still. Water depth inside the conventional still varied from 0.02 to 0.06 m whereas, water is constantly flown with a mass flow rate of 8.33 kg/hour in an ISS with baffles. The experimental result shows that the accumulated freshwater yield from CSS‐ISS, ISS, and CSS were 6.2, 5.04, and 4.24 kg, respectively. CSS‐ISS and ISS produced 46.23% and 18.87% higher productivity than the CSS. From the experimental investigation, it is also identified that the water temperature is significantly improved by 20% using integration as compared with CSS without integration under the same water depth of d _w = 0.02 m. The overall improvement in yield was higher in the case of CSS‐ISS. The deviations between experimental and theoretical values of yield from the conventional and modified solar still were in the range of ±7%.     

Thermal evaluation of nanofluids in heat exchangers

Nanofluids, suspensions of nanoparticles (less than 100 nm) in a basefluid, have shown enhanced heat transfer characteristics. In this study, thermal performances of nanofluids in industrial type heat exchangers are investigated. Three mass particle concentrations of 2%, 4%, and 6% of silicon dioxide–water (SiO₂–water) nanofluids are formulated by dispersing 20 nm diameter nanoparticles in distilled water. Experiments are conducted to compare the overall heat transfer coefficient and pressure drop of water vs. nanofluids in laboratory-scale plate and shell-and-tube heat exchangers. Experimental results show both augmentation and deterioration of heat transfer coefficient for nanofluids depending on the flow rate and nanofluid concentration through the heat exchangers. This trend could be explained by the counter effect of the changes in thermo-physical properties of fluids together with the fouling on the contact surfaces in the heat exchangers. The measured pressure drop while using nanofluids show an increase when compared to that of basefluid which could limit the use of nanofluids in industrial applications.     

Investigation of engines radiator heat recovery using different shapes of nanoparticles in H2O/(CH2OH)2 based nanofluids

In this paper, a flat tube of an engine radiator is modeled numerically for improving the cooling process or heat recovery of the engine using nanofluids. Two hydrogen based fluids (water (H₂O) and ethylene glycol or EG ((CH₂OH)₂) and four nanoparticles (CuO, TiO₂, Al₂O₃ and Fe₃O₄) in different shapes (Brick, Cylindrical, Platelet and Spherical) are considered for modeling the nanofluids in four different Reynolds numbers (500, 1000, 1500 and 2000). Hamilton correlation is used to calculate the thermal conductivity of nanofluids in different shapes of nanoparticles. Furthermore, the effect of nanoparticles volume fraction on the Nusselt number for all nanoparticle shapes is discussed in this study. Results show that EG-TiO₂ with platelet shape and larger volume fraction of nanoparticles has the best cooling performance for the engine among other modeled nanofluids.     

Natural convective heat transfer in trapezoidal enclosure of box-type solar cooker

This paper presents simple thermal analysis to evaluate the natural convective heat transfer coefficient, h_c12 for a trapezoidal absorber plate-inner glass cover enclosure of a double-glazed box-type solar cooker. Several indoor simulation experiments in steady state conditions have been performed to measure the temperatures of absorber plate, inner and outer glass covers, ambient air, electrical input supply and wind speed. The experimental data has been correlated by an equation of the form, Nu = CRaⁿ. The values of the constants C and n, obtained by linear regression analysis are used to calculate the convective heat transfer coefficient. The heat transfer analysis predicts that h_c12 varies from 4.84 to 6.23 W m^{−2 o}C⁻¹ for the absorber plate temperature from 54 to 141 ^oC. The results of h_c12 are compared with those of rectangular enclosure for the same absorber-inner glass cover temperatures and gap spacing. The study reveals that the values of convective heat transfer coefficient and top heat loss coefficient for rectangular enclosure are lower by 31–35% and 7% respectively.