秸秆纤维水泥基复合材料性能的研究

对秸秆纤维水泥复合材料的基体相、界面相、复合效果、秸秆纤维水泥基复合材料性能，以及界面剂对其性能的影响等方面进行了研究，结果表明，在界面剂的作用下，秸秆植物纤维和水泥之间取得了良好的界面效果。     

聚乙烯醇纤维强化水泥基复合材料的抗盐冻性能

通过氯盐环境中的快速冻融试验研究了纤维体积率、冻融循环次数、粉煤灰、硅粉对聚乙烯醇(PVA)纤维水泥基复合材料抗盐冻性能的影响。通过扫描电镜观察内部微观结构随盐冻作用的变化规律、PVA纤维在水泥基体中分布情况和界面结合状况。试验结果表明:PVA纤维的掺入可明显改善水泥基复合材料的抗盐冻性能;PVA纤维在基体中分散性较好,且与水泥基体界面结合状况较好;而粉煤灰、硅粉的掺入未明显改善PVA纤维水泥基复合材料的抗盐冻性能。     

纤维水泥砂浆与混凝土粘结性能双面剪切试验研究

在砂浆中分别掺入聚乙烯醇纤维、聚丙烯纤维、钢纤维以及适量的外加剂制备纤维水泥砂浆。使用千斤顶对外包纤维水泥砂浆的混凝土构件进行双面剪切试验,研究纤维种类、混凝土强度、纤维水泥砂浆抗压强度对纤维水泥砂浆与混凝土界面粘结性能的影响。试验结果表明:掺聚乙烯醇纤维的水泥砂浆与混凝土界面的剪切强度最大,聚丙烯纤维次之,钢纤维最小;剪切强度随混凝土抗压强度的提高而增大,随纤维水泥砂浆抗压强度的提高而增大;剪切强度与纤维水泥砂浆抗压强度之间存在线性相关关系。本研究中的纤维种类较多,纤维水泥砂浆强度范围涉及较广,可以较好地为加固工程实际提供理论指导。     

LD早强外加剂对复合水泥强度影响的研究

通过使用以β-萘磺酸盐并复合硫酸钙的LD早强外加剂,研究外加剂对复合水泥早期强度的激发作用。研究结果显示：LD早强外加剂的掺入可有效降低复合水泥标准稠度用水量,缩短凝结时间,显著提高早期强度,28d抗压强也有一定提高。     

纤维-基体早龄期界面性能的影响因素

通过自行改造的测试系统,实现了对早龄期纤维增强水泥基复合材料体系中纤维–基体界面性能的测定,考察了龄期、基体组成、埋入深度、纤维表面特征等因素对界面性能的影响规律.结果表明:随着龄期的增加,界面的黏结强度逐渐增加,相对密实的基体组成有利于提高界面性能;随着埋入深度的增加,纤维–基体的界面黏结强度降低;而三角形截面及化学沉积改性的纤维与基体之间具有更高的界面黏结强度.     

玻璃纤维/石膏复合材料的耐水性能研究

采用硅烷偶联剂和苯丙乳液对玻璃纤维进行表面处理，有效地改善了玻璃纤维石膏复合材料的界面结合状况，使其力学性能和耐水性能得到显著提高；掺入石蜡乳液、硫铝酸盐水泥、聚乙烯醇等物质对石膏基体改性，各种外加剂相互作用，产生协同效应，提高了玻璃纤维/石膏复合材料的耐水性能；利用扫描电子显微镜对试样进行了微观分析，研究了外加剂改善复合材料耐水性能的作用机理。     

掺合料对过硫磷石膏矿渣水泥早期性能的影响

研究了矿物掺合料偏高岭土、硅灰、硫铝酸盐水泥和外加剂水玻璃对过硫磷石膏矿渣水泥凝结速率、早期强度等早期性能的影响规律,并通过XRD、SEM等对过硫磷石膏矿渣水泥的水化及结构发展进行了研究。结果表明,在过硫磷石膏矿渣水泥中掺加水玻璃和偏高岭土,能显著提高该水泥的凝结速率和早期强度,3d、7d、28d抗压强度分别达到17MPa、32MPa、46MPa。     

水泥基稻草纤维材料性能及结构的研究

采用稻草纤维质量损失率表征稻草纤维中糖类物质的溶出率,研究质量分数不同的氢氧化钠溶液、浸泡时间对稻草纤维质量损失的影响,研究氢氧化钠溶液处理后及未处理的稻草纤维对水泥基稻草纤维材料(CSF)性能及结构的影响.研究结果表明,稻草纤维在质量分数为4%NaOH溶液中浸泡12 h,稻草纤维的质量损失基本达到最大值,NaOH溶液不仅破坏了稻草纤维表面的蜡质层,而且使稻草纤维中的糖类物质溶出;与未处理稻草纤维制备的CSF相比,NaOH处理后的稻草纤维制备的CSF 28d抗压强度提高100%,氢氧化钠溶液处理的稻草纤维改善了稻草纤维与水泥石的界面结构,有效地提高稻草纤维与水泥石的粘结.     

复合型外加剂对碱式硫酸镁水泥强度研究

碱式硫酸镁水泥作为一种轻质高强、节能环保的新型镁质胶凝材料,外加剂对它起着至关重要的作用.本文使用有机酸A分别与不同的强碱弱酸盐B、C配制了复合型外加剂,研究了不同外加剂及外加剂用量对碱式硫酸镁水泥抗折、抗压强度的影响,得到两种较为优秀的复合型外加剂AB3、AC5,并结合SEM及XRD进行表征.结果表明:当AB3、AC5掺量为轻烧氧化镁质量的0.2%时,可比未掺加外加剂的试件28 d抗折强度提高300%以上,抗压强度提高120%以上.复合型外加剂AB3、AC5用量的增加均会降低碱式硫酸镁水泥的早期强度,但后期强度有所提高,AC5比AB3型外加剂更能使碱式硫酸镁水泥形成较高的早期强度,掺加AC5型外加剂的试件28 d抗折强度较高,掺加AB3型外加剂的试件28 d抗压强度较高,复合型外加剂兼具了不同的络合与调节溶液pH的作用,为碱式硫酸镁水泥的推广应用提供了更多选择性.     

调凝型外加剂对水泥凝结硬化性能的影响

研究了缓凝剂、速凝剂单掺以及与其它品种外加剂复配掺入时，对水泥凝结与硬化性能的影响。通过XRD、SEM微观测试手段，研究了调凝型水泥基材料的微观结构特征。试验结果表明：缓凝剂、速凝剂与防水剂、减水剖复配使用，调凝效果显著，水泥硬化体形成的空间网络结构密实、强度高。     

垃圾焚烧灰用于水泥混合材的研究

研究了垃圾焚烧灰用于水泥混合材的可能性.以不同比例的焚烧炭掺入水泥,测定水泥的各种物理性能.结果表明,炉底灰具有一定活性,水泥各项物理性能正常,可用于水泥混合材;飞灰活性较差,有害物含量较高,对水泥性能影响较大,不宜大量掺入.     

A Blended Cement Containing Blast Furnace Slag and Phosphorous Slag

Blended cement comaining blast furnace slag( BFS ) and phosphorous slag( PS) is a new kind of cement. The total content of blended materials could increase if two additives were used. Using the same admixtures , the properties of the blended cement with 70% additives could reach the standard of 525-grade slag cement according to GB. The strength of cement with 80% additives could reach the standard of 425-grade slag cement. The tests of strength, pore structure, hydration products, inhibiting alkali-aggregate reaction, resistance to sulfate corrosion of BFS-PSC were performed.     

湿塑性水泥土增强研究

从水泥在水泥－水－粘土系统中水化的特点出发，阐述了湿塑性水泥土的强度形成过程，通过实验研究了几种外加剂及矿物掺和料对湿塑性水泥土的增强作用及各种外加剂的适宜掺量，并对外加剂和掺矿物掺合料对水泥土强度的作用机理进行了讨论。     

混合材对MSWI制CSA水泥性能的影响

以城市垃圾焚烧飞灰（MSWI）为主要原料,在实验室成功烧制了硫铝酸钙（CSA）水泥熟料.研究了单掺或复掺不同种类、不同掺量的混合材后,CSA水泥的力学性能和水化性能.结果表明：石灰石粉（LI）/矿渣粉（SL）在CSA水泥中较为适用,而粉煤灰（FA）/MSWI的活性较差;单掺4种混合材均对CSA水泥早期强度产生不利影响;单掺LI/SL对后期强度发展有益;复掺混合材较单掺效果好,尤其是试样10％LI＋10％SL、10％LI＋10％MSWI和5％LI＋15 ％SL.     

Influence of Rheological Active Additives on the Properties of Self-compacting Concrete

The effect of rheological-active additives on the properties of cement suspensions and self-compacting concrete mixtures have been studied.In order to increase the rheological matrix and provide high fluidity,stone powders were used during the crushing of local mountain rocks in self-compacting concrete.Taking into account the high dispersion of rheological-active additives,highly effective plasticizers were used to regulate the reotechnological properties of cement-based mixtures.The effect of sulfonaphthalen-formaldehyde oligomer and polycarboxylate-based hyperplasticizer on rheological properties of cement systems as plasticized additive on methodology proposed by V Kalashnikov was evaluated.The flow rate of cement suspension is determined by means of mini-viscosimeter,spreading of cement-sand mortar by means of Hegermann cone,and the slump of concrete mixture by means of Abraham’s cone.On the basis of obtained results,it was determined that limestone powder was more efficient than other stone powders.Thus,when adding 40% limestone powder to the mixture,the compressive strength of the samples taken from self-compacting concrete mixture increases by 15%-30% compared to the control samples.The optimal quantities of rheological-active additives and plasticizers have been identified and the possibility of obtaining high-strength self-compacting concrete based on them has been confirmed.     

硅藻土改善胶乳水泥性能的室内研究

利用国产胶乳开发胶乳水泥体系时,通常采用外加剂的复配克服胶乳外渗和消除体系气泡.由于复配中需要注意的问题很多,给实际应用带来诸多困难;化学添加剂价格昂贵也增加了固井成本;这些问题给胶乳水泥体系的开发形成了障碍.通过室内研究发现,按照材料科学干涉原理,在胶乳水泥体系中加入一定量硅藻土,可克服胶乳外渗、消除体系气泡,并能提高水泥石的抗压与抗折强度、降低滤失量与析水量、增强体系的防窜性能;同时硅藻土价格低廉且用量较少,现场使用较为方便,具有很好的应用价值.     

碳纤维增强水泥基复合材料的力学性能研究进展

碳纤维(Carbon Fibers, CFs)作为增强相运用在复合材料中一直是研究热点。综述了CFs的种类、分散方式及其在水泥基复合材料中分散性的评估方法、CFs表面涂层改性的制备工艺及其优缺点。通过改善CFs在水泥基体中的分散性和对CFs表面进行涂层改性处理,可以制备性能良好的碳纤维增强水泥基复合材料（CFRC）。同时,对CFRC力学性能的影响因素进行了系统的探讨及研究,包括水灰质量比、养护龄期、成型工艺、硅粉掺量、外加剂、CFs掺量和长度等。总结出进一步提高CFRC力学性能的关键在于改善CFs在水泥基体中的分散性和相容性,并为今后制备高性能CFRC提供参考。     

Hydraulicity of Wet-milling Ultra-fine Grouting Cement

The physical and mechanical properties of wet-milling ultra-fine grouting cement were studied,and its microstructure was abserted through modern instrwnentation analysis such as scanning electronic micoscoty (SEM),X-ray diffraction and Hg-intrusion micromeritics ,The experimertal results indicate that wet-milling ultra-fine cement possesses high rheological properties and groutability,It can be filles densely in cracks of rock and hydrate fully,which may endow hydrated cemetnt with high mechanical strength Main hydration products of wetmilling ultra-fine cement are poorly crystalline G-S-H(I),acicular AFt and plank-shape Ca(OH)2,The dense crystal-netwonk structure can be formed in the rock gaps filled with cement psate ,but some weak regions exist owing to Ca(OH)2,The features of micro-pore structure of hydrated wet-milling ultra-fine cement are few big harmful pores,abundant harmless micro pores and little most possible pore radius.     

Preparation and properties of a long-life cementbased mortar used on metal oilcans

Organic-based materials are often used as the coating of metal oilcans. But they need to be sprayed several times in the whole life of oilcans because of the short-life of organic components. To overcome this problem, a type of long-life flexible cement-based anti-corrosion material used on the surface of metal oilcans was developed according to the principle that the steel reinforced concrete can remain the same life with buildings. The materials with different formulas composed of acrylic ~nulsion, cement and other additives were prepared. Because the ratios of polymer to cement played the decisive role in the adhesion and anti-corrosion characteristics, their effects on the physical performances were investigated by comparing the mechanical properties, anti-corrosion and anti-aging properties. The relationship between microstructure and macroscopic properties was also discussed.     

粉煤灰矿渣复合水泥试验研究及其应用

通过试验研究了粉磨方式、细度、复合组分比例及添加剂对粉煤灰、矿渣、石灰石与少量熟料组成的复合水泥性能的影响 .研究结果表明 :当以上三组分比例适当时 ,通过添加剂的有效作用 ,采取合理的粉磨工艺和制度 ,在熟料掺量 5 0 %时可以配制出 6 2 5R或 6 2 5复合水泥 ,熟料掺量 4 0 %可以配制出 6 2 5或 5 2 5R复合水泥 ,熟料掺量 30 %可以配制出 5 2 5或 4 2 5R复合水泥 .同时 ,对上述部分水泥配制的高性能混凝土进行了试验研究