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矿物掺合料与水胶比对混凝土耐久性的影响研究 总被引:2,自引:1,他引:2
为研究矿物掺合料与水胶比对混凝土耐久性的影响,测试了不同混凝土的抗氯离子渗透性、抗冻性、耐磨性和抗硫酸盐侵蚀性能,采用灰色关联分析的方法,分析了矿物掺合料掺量、水胶比和混凝土耐久性之间的关联程度和关联极性。研究结果表明:粉煤灰和矿渣粉掺入会提高混凝土的抗氯离子渗透性,并存在最佳掺量,本文水胶比为0.38的混凝土,粉煤灰和矿渣粉掺量为15%时,混凝土的抗氯离子渗透性最高。矿物掺合料掺量与混凝土相对动弹性模量、耐磨度和抗硫酸盐侵蚀系数为正关联;水胶比增大会导致混凝土的抗氯离子渗透性降低,与混凝土相对动弹性模量、耐磨度和抗硫酸盐腐蚀系数为负关联。 相似文献
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适量掺加矿物掺合料可以降低混凝土结构的孔隙率,提高水化产物的致密性,有效降低氯离子的渗透性,提高混凝土的使用寿命.本文主要研究了钢渣作为掺合料单掺或复掺对混凝土Cl-渗透性能及力学性能的影响,并分析探讨了其影响机理.结果表明:一定量的钢渣和粉煤灰复掺可以较好的提高混凝土抗压强度;随着钢渣掺量的增加,混凝土坍落度降低,抗氯离子渗透性能逐渐下降;钢渣与粉煤灰复掺时,混凝土抗氯离子渗透性能增加;大掺量(钢渣、粉煤灰掺量50%)掺合料可以提高混凝土抗氯离子渗透性能. 相似文献
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基于对兰新铁路第二双线混凝土耐久性分析,研究了矿物掺合料掺量、砂的粗细程度、石子表面特征、环境条件与养护方法对兰新铁路第二双线混凝土抗氯离子渗透性能的影响.研究结果表明:矿物掺合料的掺入会提高混凝土的抗氯离子渗透性,且不同种类的矿物掺合料复掺时存在最优掺量,就文中混凝土,粉煤灰和矿渣粉掺量为15%时,混凝土的氯离子渗透性最低;此外,混凝土抗氯离子渗透性随砂的细度模数增大、石子破碎面所占比例降低而降低;保温材料能降低混凝土内外温差,因此昼夜大温差条件下,保温保湿养护的混凝土抗氯离子渗透性优于仅保湿养护的混凝土. 相似文献
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以自燃煤矸石、煅烧煤矸石作为矿物掺合料,配制普通混凝土和高强混凝土.研究热活化煤矸石矿物掺合料在聚羧酸减水剂协同作用下,对混凝土抗氯离子渗透和抗冻性能的影响.结果表明:热活化的煤矸石粉具有微集料和火山灰效应,在保证普通混凝土、高强混凝土拌合物大流动性和硬化强度的前提下,抗氯离子渗透性能得到明显提高,也能获得较好的抗冻性.以自燃煤矸石矿物掺合料配制的普通混凝土,当掺量为35%时,混凝土28 d和60d氯离子渗透电通量为1836 C和758 C.当掺量为15%时,混凝土抗冻等级达到F1200;以煅烧煤矸石矿物掺合料配制的高强混凝土,当掺量为30%时,28 d和60 d氯离子渗透电通量仅为704 C和487 C,且经受1500次冻融后动弹性模量损失率仅为1.55%. 相似文献
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石灰石粉复合低品位粉煤灰矿物掺合料性能研究 总被引:2,自引:0,他引:2
对镁质石灰石粉复掺粉煤灰对混凝土的影响进行了研究。通过对不同比例矿物掺合料和不同比例石灰石粉掺料下混凝土的工作性、强度和耐久性的试验和分析,研究石灰石粉复合低品位粉煤灰对混凝土性能的影响。试验表明:镁质石灰石粉对萘系减水剂的适应性较差;掺入石灰石粉可以使混凝土获得更好的工作性能;矿物掺合料的比例达到30%和40%时,石灰石粉在矿物掺合料中的比例大小对混凝土的强度影响不大;掺入石灰石粉的混凝土具有和掺入粉煤灰的混凝土同样良好的抗氯离子性能和抗碳化性能。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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A perturbation viscometer is a differential capillary viscometer that measures the logarithmic viscosity gradient of the viscosity-composition curve for gas mixtures. Measurements are made at different gas mixture compositions. Integration of the logarithmic viscosity gradients measured over the full composition range gives the mixture viscosity relative to the viscosity of one of the pure components of the gas mixture. This method is attractive because, for measurements of equal precision, integration of the gradients is potentially an order of magnitude more precise than measurement of the viscosities directly. It can also work at high and low temperatures and perhaps high pressures.The perturbation viscometer has been used to make measurements on ideal gas mixtures at ambient and elevated temperatures. The situation is more complicated when the gas mixtures are non-ideal. Extra effects due to density differences, molar volume change on mixing and differential thermal expansion may be measured in addition to the desired viscosity change producing systematic errors in the results. Thus, a more sophisticated apparatus is required. The standard perturbation viscometer has been modified to separate out the extra effects to permit measurement of the true change in viscosity. In addition, the theoretical operation of the modified apparatus has been revised to account for the design changes to permit calculation of the viscosity-composition profiles from the results.The apparatus has been tested using helium-HFC-125 mixtures and two new viscosity-composition profiles are presented for these mixtures at 23 and . Internal consistency tests have been used to confirm that the data produced are of high quality with an estimated uncertainty in the viscosity ratio data at of 0.9% and at of 1.5%. 相似文献
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醋酸纤维素取代基分布与性质的关系 总被引:9,自引:0,他引:9
分析了以吡啶为溶剂的醋酸纤维素的13C-NMR核磁共振谱,得出了三种不同位置羟基的取代度。结合X—射线和DSC分析,初步说明具有相同取代度但未经水解和经过水解的醋酸纤维素(CA) 性质上的差异是由于三个羟基上的取代度分布不同及消晶程度差异所致。 相似文献