Behavior of ultrathin liquid lubricant films for contact sliders in hard disk drives

In this paper, we describe the behavior of ultrathin liquid lubricant films for contact sliders in hard disk drives. In the experiments, the ultrathin liquid lubricant film behavior is investigated using Zdol and cyclotriphosphazene-terminated PFPE lubricant which have different end groups as a function of lubricant film thickness. The disks are examined with a scanning microellipsometer before and after contact slider experiments. It is found that the lubricant film thickness profiles almost do not change, when the lubricant film thickness is less than one monolayer. It can also be observed that lubricant film thickness instability due to dewetting occurs as a result of slider-disk contacts for the tested lubricants and the films undergo spontaneous redistributions, resulting in significantly nonuniform film thickness profiles, when the lubricant film thickness is thicker than one monolayer. In addition, it is found that the observed behavior of ultrathin liquid lubricant films for cyclotriphosphazine-terminated PFPE lubricant contrasts markedly with that for Zdol. The difference between cyclotriphosphazene-terminated PFPE lubricant and Zdol is only the functional end group. Therefore, it may be concluded that their unstable lubricant behavior depends on the chemical structure of functional end groups.     

Slider Wear on Disks Lubricated by Ultra-Thin Perfluoropolyether Lubricants with Different Molecular Weights

In this study, the wear properties of a magnetic head slider on disks lubricated by ultra-thin perfluoropolyether (PFPE) lubricants with different molecular weights were evaluated by the continuous sliding of magnetic head sliders using the slider contact by the dynamic flying height control. Two types of PFPE lubricants (Z-tetraol and D-4OH) with different molecular weights were evaluated. Results show that the slider wear depended on the coverage of the lubricant film; i.e., the lubricant film with sufficient coverage reduced slider wear. The lubricant film with a low molecular weight (low-Mw), including a lubricant material with a Fomblin and Demnum main chain, exhibited better coverage on a diamond-like carbon surface. Sliders with a low-Mw lubricant film showed less wear than those of a high molecular weight (high-Mw), and the depletion of the low-Mw lubricant film was less than that of the high-Mw lubricant film.     

Effects of PFPE Lubricant Properties on the Critical Clearance and Rate of the Lubricant Transfer from Disk Surface to Slider

The transfer of perfluoropolyether (PFPE) lubricant from the disk surface to the slider as a function of head-disk clearance has been investigated experimentally. The effects of lubricant thickness, bonding ratio, molecular polarity, and main chain stiffness on the lubricant transfer rate and the critical clearance below which lubricant transfer gets much enhanced are clarified. The critical clearance can be effectively reduced by decreasing the lubricant thickness or increasing the number of polar hydroxyl end-groups per lubricant molecule. Increasing the film bonding ratio or using lubricants with stiffer backbone can significantly decrease the lubricant transfer rate especially below the critical clearance. The results are discussed in terms of the effective disjoining pressure and its slope with respect to the film thickness.     

The Tribological Properties of a New Cyclotriphosphazene-Terminated Perfluoropolyether Lubricant

We have investigated the tribological properties of a novel perfluoropolyether (PFPE) lubricant truncated on one end by a hydroxyl group and on the other end by a cyclotriphosphazene derivative. A measurement of the friction force as a function of molecular weight indicates that the dynamic clearance between the slider and the disk can be reduced by ～1.5 nm by decreasing the molecular weight from 5300 to 2400 g/mol. However, the thermodynamic film stability of the novel PFPE lubricants, as determined by surface energy measurements and ellipsometric imaging of lubricant dewetting, becomes increasingly unstable at lower film thicknesses with decreasing molecular weight. Measurements conducted on lubricant mobility indicate that the novel PFPE lubricants are relatively immobile compared to the Zdol perfluoropolyether lubricants and hence resist film thinning to a greater degree. These data provide the direction for the optimization of the molecular weight of these novel PFPE lubricants.     

Molecular Dynamics Simulation of Lubricant Redistribution and Transfer at Near-Contact Head-Disk Interface

When the spacing between the slider and lubricant in a hard disk drive decreases to less than 5 nm, the effect of the intermolecular force between these two surfaces can no longer be ignored. This effect on the lubricant distribution at the near-contact head disk interface is investigated via molecular dynamics method. In this study, the lubricant is confined between a smooth disk surface and a rough slider surface represented as a partially cosinusoidal wave. The simulation results reveal that the intermolecular force-induced meniscus formation at the near-contact head disk interface is strongly sensitive to the slider-to-disk separation, lubricant film thickness and the asperity shape (or roughness) of the slider. The attractive van der Waals forces between the slider and lubricant become weaker with increasing slider-to-disk separation and asperity mid-height, but decreasing lubricant film thickness and asperity mid-width. The Hamaker theory application to van der Waals interactions is also introduced to verify the molecular dynamics simulation. It is found that the critical separation, below which the lubricant will lose its stability to form a meniscus, increases approximately linearly with the lubricant film thickness, for slider surfaces with or without roughness both in the molecular dynamics simulation and Hamaker theory application to van der Waals interactions. Moreover, it is observed that the critical separation between a smooth disk and rough slider surface will slightly decrease when the asperity mid-height increases. The same phenomenon is observed when the asperity mid-width reduces.     

The Contribution of Thin PFPE Lubricants to Slider–Disk Spacing

We have investigated the effect of the molecular weight (MW) and film thickness of a perfluoropolyether lubricant, Zdol, on the slider–disk spacing loss, or clearance. The major conclusion of this work is that Zdol films as thin as 10 Å can reduce the slider–disk clearance by 2 nm or more in the molecular weight range of 1000–5000 amu. This is attributed to the attractive van der Waals interaction between the slider and the disk surface that causes the Zdol main chain to interact with the slider surface, giving rise to a friction force. When the film thickness of the lubricant exceeds the monolayer thickness, dewetting can take place. The droplets that form occupy the space between the slider and disk surface reducing the slider–disk clearance by as much as 4 nm. There is a step increase in the acoustic emission signal at the dewetting thickness transition, indicative of a slider–disk interference.     

Molecular dynamics study of dynamic contact and separation between tip and disk surface

Molecular dynamics simulations were performed to study contact and separation between tip and lubricants on disk surface. The effects of contact indentation depth, indentation velocity, separation velocity, adhesive energy, lubricant molecular structure and lubricating film thickness on interacting force were analyzed. The results indicate that the tip force exerted by lubricants is velocity-dependent. The tip force increases with increasing indentation velocity and separation force reduces with increasing separation velocity. The damping of branched molecule and thick lubricating film is high. The high adhesive energy of tip material can produce high separation force which reduces bouncing vibration.     

Dynamics of transient events at the head/disk interface

Slider/disk contacts of nano and pico sliders are investigated using an acoustic emission sensor and a high bandwidth laser Doppler vibrometer (LDV). The following cases are studied: (a) influence of scratch impact on the airbearing stiffness; (b) influence of lubricant thickness on slider dynamics for single bump impacts; (c) influence of lubricant thickness on slider vertical stick–slip vibrations; (d) dynamics of take-off and landing. Linear time frequency analysis is applied to study simultaneously the impact response of the airbearing and the slider torsional and bending modes. The contact dynamics of single bump impacts is examined as a function of disk velocity and lubricant thickness. Increased slider vibrations are found for thick lubricant films both for sliding contacts as well as for single bump impacts. During the transition from sliding to flying a change of the bending mode frequency is observed.     

Investigation of Slider Dynamics Considering Bias Voltage and Lubricant Charge in the Unsteady Proximity Condition

The relationship between slider and lubricant becomes increasingly important as the mechanical spacing between slider and disk is reduced to satisfy the demand for higher areal density. At a reduced flying height, the slider easily contacts the lubricant, which can cause slider instability. This study analyzed slider dynamics to improve the head–disk reliability in the unsteady proximity condition, considering bias voltages between the slider, disk, and lubricant. Force–distance curves were measured using atomic force microscopy to investigate changes in lubricant performance induced by an applied voltage. Additionally, the touch-down power and take-off power were measured under various applied voltage conditions. Experiments were carried out to estimate slider instability as a function of charged disk and slider conditions, to improve the slider dynamics in the unsteady proximity condition. The effect of the bias voltage induced by a voltage applied to the lubricant was carefully examined to accurately understand slider dynamics. The relationship between the lubricant behavior and the applied voltage was investigated; the voltage applied to the disk was more influential in improving slider dynamics. Consequently, the effects of bias voltage and lubricant, as induced by a charged disk, should be considered when analyzing slider dynamics to improve head–disk interface reliability in an unsteady proximity condition.     

Dominant Factors in Lubricant Transfer and Accumulation in Slider-Disk Interface

Lubricant transfer from disk to slider and lubricant accumulation on slider are very important in designing a stable slider-disk interface of ultra-low spacing. In this article, the effects of different parameters on the lubricant transfer and accumulation are studied and the reasons behind the effects are explained. Furthermore, the time for the lubricant transfer to reach steady state is estimated. It is found that lubricant molecular weight plays a dominant role in the lubricant transfer and accumulation. Lubricant transfer and accumulation decrease dramatically with the increase in lubricant molecular weight. Lubricant transfer also strongly depends on lubricant thickness and bonding ratio on disk surface. A thinner lubricant and higher lubricant bonding ratio on disk surface reduce lubricant transfer obviously, which results in less lubricant accumulation. A diamond-like-carbon (DLC) overcoat of low adsorption area density on slider surface can reduce lubricant transfer and accumulation, especially for lubricant of low molecular weight. Lubricant accumulation increases with disk velocity and increases slightly with the decrease in slider flying height. Lubricant accumulation can be reduced by minimizing the area of slider pad. Lubricant transfer and accumulation become worse at higher ambient temperature. It takes seconds for lubricant of low molecular weight to reach steady transferred thickness and hours for lubricant of high molecular weight to reach the steady state.     

Investigation of Flying-Height Stability of Thermal Fly-Height Control Sliders in Lubricant or Solid Contact with Roughness

When the magnetic spacing in hard disk drives is reduced to sub-3 nm, contact between the slider and disk becomes inevitable. Stability analysis is used in this study to investigate the head–disk interface (HDI) stability of thermal fly-height control (TFC) sliders in light contact with the disk lubricant or solid roughness. We implement an improved DMT model with sub-boundary lubrication into the CML air bearing program and analyze the stability of equilibrium states of a TFC slider under different thermal actuations. It is found that stability is lost when the slider penetrates deeper into the lubricant layer, due to a fast growth in the adhesion force, and it is restored when the solid roughness contact develops. In addition, the critical point for the onset of this instability and the range of this instability region is found to vary with lubricant thickness and protrusion surface steepness, while keeping the air bearing design the same.     

Effect of Molecularly Thin Lubricant on Roughness and Adhesion of Magnetic Disks Intended for Extremely High-Density Recording

For extremely high-density recording using conventional technologies, the fly-height needs to decrease to less than ten nanometers. To allow such operation, disk and slider surfaces must become extremely smooth, down to root-mean-square (RMS) roughness values of a few angstroms. For super-smooth disks, molecularly thin lubricants are applied to improve tribological performance of head/disk interfaces. The focus of this study is to quantify the effect of lubricant thickness in terms of detailed roughness parameters and to evaluate the effect of roughness and molecularly thin lubricant on adhesion of magnetic disks intended for extremely high-density recording. Three identical ultra-low-flying disks have been fabricated from the same batch for this particular experiment. To investigate the effect of molecularly thin lubricants on disk roughness, super-smooth magnetic disks with increasing lubricant thickness have been measured and studied, using a primary roughness parameter set. It describes amplitude, spatial, hybrid, and functional aspects of surface roughness and is used to quantify the extremely smooth disk roughness as a function of lubricant thickness. It is found that in addition to simple amplitude parameters, hybrid and functional parameters also capture small features on the disk roughness and show distinct trends with increasing lubricant thickness. Subsequently, a continuum-based adhesion model that uses three parameters from the primary roughness parameter set, is used to predict how the varying thickness of molecularly thin lubricant and the resulting disk roughness affect intermolecular forces at ultra-low-flying head-disk interfaces. It is found that a thicker lubricant layer of 2nm causes higher adhesion forces for ultra-low-flying-heights in the range of 1–3 nm     

A Model for Lubricant Transfer from Media to Head During Heat-Assisted Magnetic Recording (HAMR) Writing

One of the challenges in heat-assisted magnetic recording (HAMR) is the creation of write-induced head contamination at the near-field transducer. A possible mechanism for the formation of this contamination is the transfer of lubricant from the disk to the slider (lubricant pickup) due to temperature-driven evaporation/condensation and/or mechanical interactions. Here we develop a continuum model that predicts the head-to-disk lubricant transfer during HAMR writing. The model simultaneously determines the thermocapillary shear stress-driven deformation and evaporation of the lubricant film on the disk, the convection and diffusion of the vapor phase lubricant in the air bearing and the evolution of the condensed lubricant film on the slider. The model also considers molecular interactions between disk–lubricant, slider–lubricant and lubricant–lubricant in terms of disjoining pressure. We investigate the effect of media temperature, head temperature and initial lubricant thickness on the lubricant transfer process. We find that the transfer mechanism is initially largely thermally driven. The rate of slider lubricant accumulation can be significantly reduced by decreasing the media temperature. However, as the amount of lubricant accumulation increases with time, a change in the transfer mechanism occurs from thermally driven to molecular interactions driven. A similar change in transfer mechanism is predicted as the head–disk spacing is reduced. There exists a critical value of head lubricant thickness and a critical head–disk spacing at which dewetting of the disk lubricant begins, leading to enhanced pickup.     

Simulation of the Performance of Various PFPE Lubricants Under Heat Assisted Magnetic Recording Conditions

Heat assisted magnetic recording (HAMR) is proposed for the next generation of hard disk drives. In HAMR systems, a laser beam heats the disk magnetic layer to the Curie temperature. This may cause the thin film lubricant coating the disk to deplete due to evaporation and surface tension gradient. In this study, we perform simulations for the Z-tetraol family of lubricants with four hydroxyl end-groups, including Z-tetraol 1200 as a low molecular weight member of the family and Z-tetraol 2200 as a high molecular weight of the family, and also for ZTMD (2,200 Da) with eight hydroxyl groups as a multi-dentate lubricant, which is manufactured based on the Z-tetraol family. All studies are performed for four cases of lubricant thicknesses including 5, 7, 12, and 14A. These numbers are chosen in order to provide a fair comparison with a previous study for Z-dol. We also investigate the relative effects of evaporation with respect to the thermocapillary shear stress. It is found that after a 2 ns illumination of the laser, a trough and two side ridges across the down-track direction can be seen in the lubricant. The performances of the lubricants can be ranked mainly based on the trough depth and also evaporation such that better lubricants show less deformation and trough depth under equal conditions of thermal spot size and peak temperature. We also found that all of the lubricants deplete rapidly and their depletion speed decreases gradually.     

Study on Lubricant Depletion Induced by Laser Heating in Thermally Assisted Magnetic Recording Systems: Effect of Lubricant Thickness and Bonding Ratio

In this study, we have carried out fundamental research on lubricant depletion due to laser heating in thermally assisted magnetic recording. In particular, we investigated the effects of lubricant film thickness and lubricant bonding ratio on lubricant depletion. Conventional lubricants Zdol2000 and Ztetraol2000 were used. The lubricant depletion characteristics due to laser heating were found to depend largely on the lubricant film thickness and material. That is, for films thicker than one monolayer, the lubricant depletion depth increased with the laser-irradiation duration, whereas the thickness of the lubricant after laser irradiation on the diamond-like carbon (DLC) films tended to remain at a constant film thickness of one monolayer. The lubricant depletion width gradually increased as the laser irradiation duration increased. The increasing trends for the lubricant depletion width were quantitatively very similar and almost independent of the initial lubricant film thickness. However, for lubricant films with thicknesses less than one monolayer, the lubricant depletion depth was very small. The lubricant depletion width increased remarkably to several hundred micrometers as the laser irradiation duration increased. The lubricant depletion depth and width were much smaller for Ztetraol2000 than Zdol2000. In addition, the lubricant-bonding ratio was found to greatly affect the lubricant depletion characteristics due to laser heating. In other words, the lubricant depletion depth and width decreased as the bonding ratio increased. The lubricant depletion mechanism involves the evaporation of mobile lubricant molecules when the maximum attained temperature is less than 100 °C. Another suggested lubricant depletion mechanism involves the thermocapillary stress effect, which is induced by the disk surface temperature gradient resulting from the non-uniformity of the laser spot intensity distribution.     

The Effect of Solvents on the Perfluoropolyether Lubricants Used on Rigid Magnetic Recording Media

The adsorption characteristics and tribological properties of the perfluoropolyether (PFPE) lubricants Zdol and Z-Tetraol on amorphous nitrogenated CN_x carbon are investigated as a function of solvent used to apply the lubricants. The solvents used in these studies include perfluorohexane, CF₃CHFCHFCF₂CF₃ and C₄F₉OCH₃. Deposition studies indicate that the applied thickness of PFPE films is strongly solvent-dependent that can be related to differences in the solubility parameters between the various lubricants and solvents. The results of ab initio computations on the molecular electronic structure of the solvent molecules show that their solvent power is correlated to their polarity and in particular to the acidity of the protons on the CF₃CHFCHFCF₂CF₃ and C₄F₉OCH₃ molecules. Tribological reliability, as measured by contact start-stop testing, slider-disk clearance, lubricant pickup by the slider, lubricant smearing on the disk surface, etc., is independent of solvent and is limited to the physical properties of the adsorbed lubricant film. The kinetics of lubricant mobility are charateristic of confined liquids that are independent of solvent as shown by lubricant flow profiles, bonding kinetics, and contact angle goniometry.     

Air Entrapment in Nanometer-Thick Lubricant Films and its Effect on Slider Flying Height in a Hard Disk Drive

Experimental data are presented, showing that the flying height of a slider in a hard disk drive can be altered by the chemical nature of the molecularly-thin lubricant film on the disk surface. It is suggested that this effect is likely due to entrapment of the air molecules, both nitrogen and oxygen, within the lubricant film, which results in pressurization loss within the air bearing gap, and lower slider flying height. For the two advanced multidentate lubricants reported in this study, the amount of flying height change is almost insignificant for one of them, but amount to about 0.7?nm, i.e. a significant fraction of the magnetic spacing budget for the other. Bulk air solubility data suggest that the magnitude of this effect is diminished for lubricant molecules with a lower density of backbone ether linkages.     

Lubricant Flow and Evaporation Model for Heat-Assisted Magnetic Recording Including Functional End-Group Effects and Thin Film Viscosity

The lubricant covering a hard disk in a heat-assisted magnetic recording drive must be able to withstand the writing process in which the disk is locally heated several hundred degrees Celsius within a few nanoseconds to reduce the coercivity of the media and allow writing of data. As a first step in modeling a robust lubricant, we have developed a simulation tool based on continuum theory that incorporates previously proposed variations of viscosity and an additional component of disjoining pressure due to functional end-groups with film thickness. Here we apply this simulation tool to a conventional perfluoropolyether lubricant, Zdol 2000, for which there exists experimental data. The simulation tool can be used equally well for other lubricants once their properties become known. Simulations at small length and time scales that are unobservable with current experimental capabilities are performed. We investigate the effect of the total disjoining pressure and thin film viscosity on evaporation and lubricant flow for different initial thickness. For films thicker than 1 nm, the inclusion of polar disjoining pressure suppresses the lubricant thickness change due to evaporation and thermocapillary shear stress compared with cases without this component. Thin film viscosity is an important property to consider for thinner lubricants. We also consider how lubricant depletion depends on laser spot size and thermal spot maximum temperature. The smaller spot profiles exhibit side ridges due to thermocapillary shear stress while the larger spot profiles show no side ridges, only a trough due to evaporation. The lubricant depletion zone width and depth increase with increasing thermal spot maximum temperature.     

Velocity-Dependent Adhesion with Lubricants on Thin-Film Disks

The well-known problem of stiction in a magnetic disk drive largely depends on the forces induced by the presence of a thin liquid film. It is commonly recognized that both adhesive and viscous effects contribute to the magnitude of the stiction force, but is is not known what relative roles the two effects have in a lubricated contact. In the present work, the nature of adhesive and viscous effects is investigated for the slider/disk interface under conditions of constant-speed sliding.

Friction measurements are conducted over a range of sliding speeds, 0.25-250 mm/s, with eight perfluoropolyether (PFPE) lubricants applied in various thicknesses, 0-6.6 nm, to carbon-coated magnetic thin-film disks. The lubricants were selected to cover a broad range of viscosities. For several sliding speeds and lubricant film thicknesses, the friction force is found to decrease significantly with increasing sliding speed for all lubricants. In several instances, large friction forces are observed at the lowest sliding speeds, indicating stiction-like behavior, whereas, at higher speeds, the friction is reduced to even below unlubricated friction levels. At the highest film thickness and sliding speed, the friction was found to increase with speed for some lubricants. The implications of these results on current models of lubricant-mediated adhesion are discussed.     

The Contribution of Thin PFPE Lubricants to Slider-Disk Spacing. 2. Effect of Film Thickness and Lubricant End Groups

We have investigated the effect of film thickness of a perfluoropolyether lubricant, Zdol 4000, on slider-disk spacing, or clearance. The major conclusion of this work is that the Zdol lubricant impacts the slider-disk spacing. A decrease in the film thickness of Zdol 4000 by 10Å results in an increase in the effective slider-disk spacing by 1 nm. The effect of end groups on slider-disk spacing is also investigated using the Zdol-TX and Z-Tetraol perfluoropolyether lubricants. At similar molecular weights and film thicknesses, the end groups do not affect the slider-disk spacing by causing any additional interference. The slider-disk interference is therefore attributed to the attractive van der Waals interaction between the slider and the disk surface that causes the Zdol main chain to interact with the slider surface, giving rise to a friction force.