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黏土负载型类Fenton催化剂是将活性金属固定在黏土上,用以催化活化H2O2产生羟基自由基去除难降解有机污染物,克服了均相Fenton氧化适用pH范围窄、易产生铁泥沉淀等缺点。本文从黏土的类型和结构特点出发,简述了层状与非层状黏土负载活性金属的特点及其催化性能;分析了柱撑、浸渍、沉积-沉淀等活性金属负载方法和黏土的改性手段;阐述了负载活性金属类型及其对催化性能的影响。针对黏土负载型类Fenton催化剂的特点和现阶段存在的问题,从黏土负载型催化剂的活性金属负载形式、负载方法和高效稳定催化性能的需求等角度指出了今后的研究方向。 相似文献
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弱酸性蓝GR在羟基铁柱撑膨润土上的吸附研究 总被引:18,自引:4,他引:14
用无机大分子羟基铁离子对浙江天然膨润目进行柱撑,研究表明羟基铁子交换制得的柱撑膨润土具有很好的吸附能力(好于单纯钠有机化膨润土);并研究了各测试条件的改变对弱酸性深蓝GR在改性膨润土的吸附去除率影响;测试了各种改性膨润土的等温吸附线。 相似文献
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二氧化钛柱撑膨润土对染料甲基橙的吸附行为 总被引:8,自引:0,他引:8
以sol-gel法制备TiO2溶胶和钇掺杂TiO2溶胶为柱化剂,制备出了TiO2柱撑膨润土和钇掺杂TiO2柱撑膨润土.X射线衍射分析表明经柱撑后的膨润土层间距明显增大,达1.9 nm以上,经500℃煅烧后其层间距稳定在1.8 nm以上.研究了甲基橙在4种TiO2柱撑膨润土上的吸附行为,结果表明4种TiO2柱撑膨润土吸附染料甲基橙的速率和吸附量均较大,其吸附动力学行为均遵循Bangham方程和Langmuir方程所描述的规律.平衡吸附量qe与平衡浓度ρe之间的关系符合Freundlich和Langmuir等温吸附方程.其吸附均为吸热过程,吸附热值在12~17kJ/mol,吸附表现为表面物理吸附和离子交换作用. 相似文献
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J. Ward Hills 《溶剂提取与离子交换》2013,31(2):347-359
ABSTRACT Extraction techniques for semi-volatile organic compounds from caustic and high ionic strength solutions are presented. It is demonstrated that simple liquid-liquid extraction from a high ionic strength aqueous solution can allow inorganic ions to partition from the aqueous phase into the organic extraction phase. The ability of solid-phase extraction (SPE) adsorbents to separate organic target compounds from a sample, without significant carry-over of inorganic material, is compared to that of Liquid-liquid extraction. The most useful SPE media was a commercially available alumina substrate coated with a robust non-polar phase. Extractions of three compound classes, are presented: aromatic, alkyl hydrocarbons and alkyl phosphates. Extraction yields ranged from 42 to 97.6% (6-12% RSD). The range of yields for each chemical class was 7.5-79.9%, 14.3-68.3% and 91.1-97.6% for the aromatic, alkyl hydrocarbons and alkyl phosphate compounds respectively. 相似文献
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可溶有机质介导硝基芳香化合物降解研究进展 总被引:2,自引:0,他引:2
大量研究表明, 可溶性有机质因自身的醌呼吸结构能够作为氧化还原体来催化转化多种有机和无机化合物, 然而其影响机制尚未完全了解, 因此需要更深层次的研究以阐明限制可溶性有机质介导化学和生物转化有机污染物的机理。本文以硝基芳香化合物为例, 全面阐述了其化学和生物降解机理以及可溶性有机质作为氧化还原电子穿梭体对其还原转化过程介导作用的研究进展;回顾了各种因素影响可溶性有机质催化转化硝基芳香化合物的效果, 并寻求氧化还原效率较高的可溶性有机质促进污染物的消减, 从而提高可溶性有机质对催化降解硝基芳香化合物的实际应用性。 相似文献
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《Fuel》1986,65(2):248-250
Pyrolysis yields for both coals and oil shales exhibit a common relation between the original aromatic carbon content of the sample and the residual organic carbon after pyrolysis. Corresponding measurements of organic carbon distribution by solid-state 13C n.m.r. and pyrolysis yields by Fischer assay or proximate analysis have been correlated for 125 coal and oil shale samples composed of widely differing types of organic matter and inorganic constituents. Even though these measurements have been accumulated from various laboratories using different instrumentation and interpretative procedures, there is a remarkably high degree of correlation between original aromatic carbon and residue carbon. The common relation between pyrolysis yield and organic carbon distribution generally supports the previous notion that aromatic carbon is resistant to volatilization and extends this same characterization of pyrolysis behaviour to oil shale kerogen as well as coal. 相似文献
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《Inorganic chemistry communications》2007,10(3):273-275
A new neutral layered borate B3O4(OH)(C4N2H10)0.5 (denoted BO-CJ 38) has been solvothermally synthesized. The piperazine molecules act as organic ligand and strcuture-directing agent. The left- and right-handed helical B–O–B chains are linked together via piperazine molecules to form infinite organic–inorganic hybrid layers. The aromatic piperazine molecules may play an important role in the formation of helical inorganic chains. 相似文献
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The comparative study on the effect of different type of dopants on the properties of polyaniline (PANI) is relative less although dopant has profound effect of the properties of PANI. So, the aim of the present work is to study the effect of different type of dopant, namely strong inorganic hydrochloric acid (HCl), organic and aromatic acids containing different aromatic substitution, namely p‐toluene sulfonic acid (PTSA), dodecylbenzenesulfonic acid (DBSA), organic and aliphatic acids having long hydrocarbon chain, namely lauric acid (LA), on the properties of PANI. The PANI was prepared through oxidative polymerization methods and doped with HCl, PTSA, DBSA, and LA and then characterized through different methods like conductivity measurement, UV, X‐ray, DSC, TGA, and SEM. It was found that the properties of doped PANI depend on the type and molecular size of the dopant. With the increase in dopant chain length, the crystallinity is decreased, whereas the d‐spacing, interchain separation, and solubility are increased. The bond formation of water molecules with the backbone nitrogen of the polymers is much less in presence of aromatic dopants when compared with those of inorganic or aliphatic dopants. All the doped polyanilines under investigation do not decompose up to 500°C. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Several important solvothermal (including hydrothermal) in situ metal/ligand reactions and their mechanisms, including dehydrogenative carbon-carbon coupling, hydroxylation of aromatic rings, cycloaddition of organic nitriles with azide and ammonia, transformation of inorganic and organic sulfur, as well as the CuII to CuI reduction, are outlined in this Account. The current progress clearly demonstrates the important potential of such reactions in the crystal engineering of functional coordination compounds and one-pot synthesis of some unusual organic ligands that are inaccessible or not easily obtainable via conventional methods, thereby substantiating our expectation that a new bridge has been created between coordination chemistry and synthetic organic chemistry. 相似文献
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Bitumen, separated from oil sands by the hot water extraction process, contains ultra‐fine (< 200 nm), inorganic solids (BS). Surfaces of BS particles are coated with toluene insoluble organic matter (TIOM). This organic material is polar and aromatic with contributions from both humic and asphaltene‐like components. Although the surfaces of BS particles are dominated by TIOM, the coverage is patchy rather than continuous. As a result, these solids are capable of stabilizing fine water emulsions in the bitumen phase. The nature of the organic matter on the surfaces of the particles is such that it has a high propensity to form coke. Therefore, these particles can also play a role in fouling on equipment and catalysts. 相似文献
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综述了近年来包核法技术在有机颜料改性方面的进展,重点介绍了有机包核颜料的制备机理,以及以S iO2、TiO2和其他一些无机物对有机颜料进行包覆的实例。对有机包核颜料的应用前景进行了展望。 相似文献
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O. F. Sidorov 《Coke and Chemistry》2013,56(1):25-31
The ability of organic and inorganic additives (polyethylene terephthalate, titanium dioxide, finely disperse carbon, petroleum bitumen) to reduce the carcinogenic impact of coal-pitch carbonization is studied. Additives may reduce the quantity of pitch sublimates and their content of carcinogenic polycyclic aromatic hydrocarbons. Some additives are able to reduce the benz[a]pyrene content in the exhaust gases, but its complete elimination is impossible, since benz[a]pyrene is a natural product of the high-temperature pyrolysis of organic materials. For this reason, additions of petroleum products to coal pitch cannot reduce the benz[a]pyrene emissions in the exhaust gases. 相似文献