La对Al2O3f/Al-Mg复合材料凝固溶质偏析的影响

利用挤压铸造法制备了Al2O3／Al-Mg-La复合材料。研究了La在铝合金基体中的分布，并探讨了La对基体凝固时溶质元素偏析的影响。结果表明，La富集在界面附近，有利于改善铝合金液对Al2O3f的润湿性，但是在界面上未发现任何富稀土相的形成。La的加入对基体合金中的Mg的偏聚没有很明显的影响，Mg和La作为表面活性元素都在界面处富集，且它们的分布位置大致一样。     

La在A1_2O_(3(sf))/Al-5.0%Cu复合材料界面的分布及界面结构研究

挤压铸造A12O3(sf)/Al-5.0%Cu复合材料时添加适量稀土La,并研究了界面附近La元素的分布。添加稀土后能明显的改善纤维与基体的润湿性,并促进了界面反应的发生,在纤维与基体合金之间生成致密的厚度约2μm的过渡层,并建立了界面的生成及结构模型。     

La在Al2O3(sf)/Al-5.0%Cu复合材料界面的分布及界面结构研究

挤压铸造Al2O3（sf）／Al-5．0％Cu复合材料时添加适量稀土La，并研究了界面附近La元素的分布。添加稀土后能明显的改善纤维与基体的润湿性．并促进了界面反应的发生．在纤维与基体合金之间生成致密的厚度约2μm的过渡层．并建立了界面的生成及结构模型。     

稀土La对铝镁合金凝固曲线和微观组织的影响

研究了稀土La对铝镁合金凝固区间和微观组织的影响.结果表明,La对铝镁合金凝固区间和微观组织有明显的影响.加入La,合金凝固区间变大、凝固时间增加,合金流动性能得到改善.La的加入对合金有变质作用,晶粒数量增多,尺寸变小,形貌圆整.     

挤压铸造工艺参数对Al_2O_(3f)/Al-4.5%Cu复合材料凝固方式与组织的影响

挤压铸造制备了Al2O3短纤维/Al 4 5%Cu合金复合材料,研究了关键工艺参数对基体合金凝固方式与组织的影响。结果表明:Al2O3短纤维表面不能作为基体α初晶非自发形核衬底;随凝固冷却速度ε的增大,复合材料基体组织将细化,基体中有更多完整的晶界出现,偏析第二相主要分布于晶界上,其量随ε的增大而明显增多;纤维体积分数Vf的增大将细化基体晶粒尺寸至纤维间隙大小,同时随Vf的增大,主要分布于纤维/基体界面的偏析第二相的量将有所降低;模具、预制块预热温度及合金液浇注温度对复合材料凝固过程的影响归结到对凝固冷却速度的影响上来;外加压力的提高使复合材料基体组织细化。     

挤压铸造工艺参数对Al2O3f/Al-4.5%Cu复合材料凝固方式与组织的影响

挤压铸造制备了Al2O3短纤维／Al-4．5％Cu合金复合材料，研究了关键工艺参数对基体合金凝固方式与组织的影响。结果表明：Al2O3短纤维表面不能作为基体α初晶非自发形核衬底；随凝固冷却速度ε的增大，复合材料基体组织将细化，基体中有更多完整的晶界出现，偏析第二相主要分布于晶界上，其量随ε的增大而明显增多；纤维体积分数Vf的增大将细化基体晶粒尺寸至纤维间隙大小，同时随Vf的增大，主要分布于纤维／基体界面的偏析第二相的量将有所降低；模具、预制块预热温度及合金液浇注温度对复合材料凝固过程的影响归结到对凝固冷却速度的影响上来；外加压力的提高使复合材料基体组织细化。     

稀土La和冷却速度对A1-5Fe合金组织和相组成的影响

分别采用真空熔炼、吸铸和单辊甩带法制备了铸态、亚快速凝固和快速凝固状态下A1-5Fe和A1-5Fe-1.5La合金,探讨了冷却速度和稀土La对A1-5Fe合金组织和相组成的影响。通过OM、TEM和XRD对合金组织和相组成进行分析。结果表明,冷却速度的提高使合金的组织得到进一步细化;添加1.5wt%La后,铸态合金中针状富铁相Al3Fe转变为花朵状,并使亚快速凝固Al-5Fe的基体发生变化。同时,在合金中出现了亚稳相Al6Fe和具有高熔点的Al11La3相。     

快速凝固/粉末冶金AZ91/SiCp镁基复合材料的相组成及界面

采用双辊雾化法制备快速凝固AZ91镁合金粉末,并用粉末冶金方法制备SiC颗粒增强的镁基复合材料棒材,研究AZ91/SiCp复合材料的微观组织、相组成及增强相与合金基体间的界面结构特点。结果表明：双辊雾化快速凝固AZ91镁合金粉末的相组成为α-Mg固溶体主相和微量细小的T-AlMg2Zn相,尺寸在0.2 μm左右;在后续热挤压过程中合金基体中析出大量的球形β-Mg17Al12,尺寸在0.5 μm左右,而T-AlMg2Zn相的形貌和尺寸无明显变化;复合材料在加热过程中,增强相SiC颗粒表面的SiO2层与合金基体之间发生界面反应。     

镧镨铈混合稀土对Mg-Li-Al合金组织及力学性能的影响

采用光学显微镜、带能谱仪的扫描电镜、X射线衍射仪以及电子万能试验机,研究了镧镨铈混合稀土对Mg-Li-Al合金显微组织和力学性能的影响。结果表明:加入镧镨铈混合稀土能显著细化合金组织,起到细晶强化和提高塑性的作用;同时Al和La生成稀土化合物Al11La3,大量富集在晶界上,能阻止晶界滑移和基体变形,有强化晶界的作用。随着稀土加入量增大,Mg与La生成Mg3La,消耗了部分Mg,使得强度略为降低,塑性提高,相对于未加入混合稀土的Mg-Li-Al合金,其抗拉强度和伸长率分别提高了27.3%和1248.1%;当混合稀土含量为3%时合金强度最高,含量为4%时塑性最好。     

氧化铝纤维对锌合金复合材料凝固组织的影响

利用挤压铸造制备了氧化铝纤维增强锌合金复合材料，研究了氧化铝纤维对锌合金复合材料凝固组织的影响。结果表明，在复合材料中，纤维与基体间存在致密界面层，合金元素通过适当的化学反应可改善纤维与基体的结合；在凝固过程中，氧化铝纤维可作为锌合金共晶体非自发形核的衬底，纤维／基体界面上的硅在共晶体的共生生长过程中起了领先相作用，导致复合材料的共晶转变由铝硅共晶转变和锌铝共晶转变两者组成     

Solidified structure and solute segregation in Al2O3/A356-La alloy composites

1. Introduction Because of the addition of reinforcement, the field of temperature, field of flow, field of concen-tration, and thermodynamics and dynamics of crys-tal growth during the composite solidification as well as the structural morphology of the composite are changed in processing of the fiber-reinforced Al matrix composite manufactured by liquid infiltration. The flow of solute is hindered by the fibers because the reinforcement acts as a barrier to solute diffusion ahead of the liqu…     

Distribution and segregation of solute in Al2O3 short fiber reinforced Al-5%Cu alloy containing La by squeeze casting

Al2O3 short fiber reinforced La-bearing Al-5%Cu alloy was fabricated by squeeze casting, and the solidified structure and the solute segregation during alloy solidification were studied. The results indicated that La has been enriched near the interface which is favorable to improve the wettability between the fiber and Al alloy, but the RE-rich phase was not formed at the interface. At the end of the solidification of the composites, the change of the solute in the surplus liquid phase results in the type of matrix alloy being changed because of the selective crystallization, and the segregation at the interface is finally formed. There is no special influence by La on the Cu segregation in the matrix alloy.     

Effect of the partial substitution of Mg by Al on the crystal structure and hydrogenation behavior of La2Mg17

The effect of the partial substitution of Mg by A1 on the crystal structure of La2Mg17 has been investigated. It was found that the LaEMgl7 phase disappears after the partial substitution of Mg by Al. The LaE（Mgo.gAl0.1）17 alloy contains La（Mg,AI）12 and La（Mg,Al）2. Further increasing the Al content, the La2（Mg0.8Al0.2）17 alloy consists of La（Mg,Al）12, La（Mg,Al）2, and Mg. The La（Mg0.93Al0.07）12 phase in the La2（Mg0.9Al0.1）17 alloy crystallizes with the ThMn12-type structure in space group 14/mmm （No. 139）. The lattice parameters were determined to be a = 1.03246（7） nm and c = 0.59410（6） nm. In the ThMn12-type structure, AI atoms occupy 8f site but the A1 content is limited. Moreover, the hydrogenation character- istics have also been compared. La2Mgl7 decomposes into LaH3 and MgH2 under hydrogen, but the La（Mgo.93Alo.o7）12 phase can be hydrogenated into LaH3, MgH2, and La3Al11 at 473 K.     

稀土La及Sn对铸造铝合金组织、力学和阻尼性能的影响

研究了稀土La对含质量分数4%Sn铸造铝合金组织、阻尼和力学性能的影响,从La对Sn的形态和分布、La对Sn和铝合金基体润湿特性的影响等方面探讨了阻尼提高机制。结果表明,La含量为0.2%时,4%Sn的AlMgMnSi合金晶粒尺寸得到细化,β-Sn由大颗粒状变为细小、弥散分布,继续提高La含量至0.83%,晶粒变大,且在晶界处出现块状稀土化合物。La的加入可以有效提高含4%Sn铸造铝合金的阻尼性能,当La添加量为0.2%时,含4%Sn的AlMgMnSi和ZL102合金分别比不添加La的提高了约70%和100%。La改善了β-Sn与铝基体的润湿性,使β-Sn呈弥散、细小分布,从而有利于提高相界面阻尼,是本试样具有较高阻尼性能的主要原因。     

First-principles investigation of the structure and synergistic chemical bonding of Ag and Mg at the Al | Ω interface in a Al–Cu–Mg–Ag alloy

Density functional theory was used to characterize the atomic structure and bonding of the Al | Ω interface in a Al–Cu–Mg–Ag alloy. The most stable interfacial structure was found to be connected by Al–Al bonds with a hexagonal Al lattice on the surface of the Ω phase sitting on the vacant hollow sites of the Al {1 1 1} matrix plane. The calculations predict that when substituted separately for Al at this interface, Ag and Mg do not enhance the interface stability through chemical bonding. Combining Ag and Mg, however, was found to chemically stabilize this interface, with the lowest-energy structure examined being a bi-layer with Ag atoms adjacent to the Al matrix and Mg adjacent to the Ω phase. This study provides an atomic arrangement for the interfacial bi-layer observed experimentally in this alloy.     

镁偏析对铝合金晶界性能影响的计算机模拟

采用嵌入原子法对铝晶界上Mg的偏析性质及其对晶界性能的影响进行了计算机模拟。结果表明 ,Mg的晶界偏析具有自发性 ,并且降低基体的电荷密度和空位形成能 ,从而导致晶界脆化。     

Effect of mischmetal and yttrium on microstructures and mechanical properties of Mg-Al alloy

The effect of yttrium and mischmetal(MMs)on the as-cast and solid solution treated structures of Mg-Al alloys with different Al-contents was investigated.The results show that the MMs in Mg-Al alloy existed in rod Al4(Ce,La)compound while Y in Mg-Al alloy in polygonal Al2Y compound.The amount of Mg17Al12 in Mg-Al alloy is decreased with increasing Y or MMs addition,and Mg17 Al12 intermetallic compound is changed from continuous network to discontinuous one.The Al4(Ce,La)and Al2Y compounds are not dissolved into Mg-Al alloy matrix during solid solution treatment so that their high heat stability can be exhibited.The experiment of mechanical properties indicate that elongation and impact toughness of the Mg-Al-Y alloy with polygonal Al2Y compound are higher than those of Mg-Al-MMs alloy with rod A4(Ce,La) compound.     

Al2O3f/Al-4%Cu合金复合材料界面偏析研究

利用挤压铸造制备了Ａｌ２Ｏ３ｆ／Ａｌ－４％Ｃｕ合金复合材料,研究了复合材料的界面偏析。研究结果表明,在复合材料的凝固末期,由于选择结晶,剩余液相中的溶质变化导致基体合金类型的改变,最张立生界面偏析。偏析对材料的组织结构和性能的影响可能是双重的。     

Effect of La and Nd on microstructures and mechanical properties of AZ61 wrought magnesium alloy

Effects of La and Nd addition on the microstructure and mechanical properties of the AZ61 alloy have been investigated. The results show that when La and Nd are added into the AZ61 alloy respectively, the β(Mg17-Al12) phase is refined and granulated, and new phases are formed in the form of small rod-like shape, which are verified as La3 Al12 and Nd3Al11 phase by X-ray diffraction and TEM observation. Microstructure observations show that the effective efficiency of La addition is higher than that of Nd addition, thus the sizes of β(Mg17 Al12) and La3Al11 phase are relatively smaller than those of β(Mg17 Al12 ) and Nd3 Al11 phases in both AZ61 alloy and Nd-containing alloy. The increase of the tensile strength and elongation of AZ61 alloy refers to the existence of small rod-like La3Al11 and Nd3Al11 phases, and fine granulated β(Mg17 Al12 ) phase.