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常温干燥环保型涂料印花粘合剂的研究 总被引:2,自引:1,他引:1
以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、丙烯酸(AA)、丙烯酸乙酯(EA)、苯乙烯(St)和常温交联单体等为主要原料,通过乳液聚合法制备常温干燥环保型涂料印花粘合剂。研究结果表明,将该粘合剂用于印花坯布,并经常温(18~25℃)干燥后,其干摩擦牢度达到4级、湿摩擦牢度达到3~4级且刷洗牢度达到3级;该常温干燥涂料印花粘合剂的综合性能优于其他同类产品。 相似文献
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PUA乳液的合成及在涂料印花中的应用 总被引:4,自引:0,他引:4
用乳液聚合方法制备了丙烯酸酯改性聚氨酯乳液(PUA),并对其合成过程的某些影响因素进行了讨论,确定了较佳工艺条件。该乳液作为粘合剂应用于涂料印花,织物的印花牢度及手感均较好。 相似文献
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近年来涂料印花又有新的发展,寻求成本低、牢度好的粘合剂仍是科研课题。我们合成了新型涂料印花粘合剂T-130,经用户使用各项牢度指标均达到国家规定的标准。T-13O是以丙烯酸酯类为主体经乳液聚合而成的粘合剂。软单体:丙烯酸丁酯、丙烯酸辛酯;硬单体:丙烯胞、甲基丙烯酸甲酯;自交联单体:羟甲基丙烯酸胺;自增稠单体:丙烯酸。小试在装有搅拌器、温度计、回流冷凝管、滴液漏斗的四口瓶中进行。先加入乳化剂、水和部分单体、引发剂,开启搅拌,升温至85℃乳液变蓝,开始反应后保持温度并滴加剩余单体和引发剂,一小时滴完,继续反… 相似文献
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环保型低温涂料印花粘合剂的研制和应用 总被引:1,自引:1,他引:0
采用自交联单体807-3取代N-羟甲基丙烯酰胺,以丙烯酸酯为基本原料,通过预乳化半连续乳液聚合的方法合成了一种环保型低温涂料印花粘合剂。探讨了复合乳化剂、功能性单体807-3、柔软剂和防粘剂对自制粘合剂乳液性能(粘度、吸水率、泛黄性、手感、牢度、抗粘连性等)的影响。研究结果表明,当复合乳化剂和807-3的用量分别为单体总质量的3%和1.5%时,粘合剂的各项性能达到设定的要求,且其印花织物上的游离甲醛释放量合格。并确定了合适的助剂以优化自制粘合剂。 相似文献
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本文综述了聚氨酯/聚丙烯酸酯互穿网络(IPN)涂料印花粘合剂。介绍了IPN粘合剂的制备方法及其不同配比时对拉伸强度、断裂伸长率、摩擦牢度性能的影响。IPN粘合剂可克服聚丙烯酸酯粘合剂的延伸性差、湿摩擦牢度低、易吸尘和粘搭性强的缺点,是改进聚丙烯酸酯类粘合剂性能十分有效的方法。 相似文献
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Xue Jiang Huilu Hu Yuci Bai Xiuzhi Tian Dan Huang Shugen Wang 《Journal of Adhesion Science and Technology》2013,27(2):154-164
Vinyl silicone oil (VSO) modified polyacrylate latex is synthesized by emulsion polymerization. The core-shell structure of the latex particle is observed on transmission electron microscopy. The chemical structure of the copolymer was characterized by infrared spectrum. The glass transition temperatures of core-layer and shell-layer of latex particle are determined by differential scanning calorimetry. The size of particle of the core-shell latex is measured on a nanoscale granularity analyzer. The good softening effect of VSO is proved by the application of the latex as a binder of pigment printing on textiles. The good fastness of the printed fabrics is obtained, which shows that the synthesized core-shell latex can be used as a binder in pigment printing of textiles. 相似文献
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核/壳型有机硅改性苯丙乳液印花粘合剂的合成及应用 总被引:1,自引:0,他引:1
以过硫酸钠(NaPS)为引发剂,苯乙烯(St)和丙烯酸丁酯(BA)为核单体,甲基丙烯酸甲酯(MMA)、丙烯酸异辛酯(EHA)、苯乙烯(St)、丙烯酸(AA)为壳单体,采用种子乳液聚合法,制备了硬壳软核型苯丙乳液,对其进行有机硅改性,得到核壳型有机硅改性苯丙乳液(简称硅丙乳液),将其用作涂料印花粘合剂。研究了核壳单体质量比、丙烯酸用量、乙烯基硅油用量对乳液性能及印花性能的影响;并用热失重分析仪和透射电镜进行了表征。较佳配方为:核/壳单体质量比为6∶4,AA质量分数为2.5%,乙烯基硅油质量分数为10%~15%。该乳液的理化性能较好,耐热性优于核/壳苯丙乳液,将其用于涂料印花,改善了堵网性,印花织物的干、湿摩擦牢度,皂洗牢度,手感以及表观得色量可以达到工业用华润粘合剂的水平。 相似文献
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The application of chitosan in pigment printing 总被引:1,自引:0,他引:1
The use of chitosan as a combined thickener and binder in pigment printing has been examined in comparison with a commercial printing system (Alcoprint). Printing pastes made up from mixtures of chitosan, pigment and acetic acid at the appropriate viscosity gave satisfactory prints on polyester and 67:33 polyester/cotton woven fabrics. Rheological data showed the chitosan pigment paste had a much lower yield point than commercial printing paste though no difficulties were found in its use. Curing of the chitosan print at 150°C for 6 min gave samples of comparable colour fastness to the commercial printed samples when subjected to the rubbing and washing tests. The only drawbacks noted in using chitosan in this way were a reduced colour yield and a much higher fabric stiffness. 相似文献
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A collection of printed fabrics for men’s shirts was designed and prepared using computer‐aided design/computer‐aided manufacturing technology. The colours for designs were ink‐jet printed on cotton fabrics with pigments and ultraviolet‐cured. These prints represented the target colours for subsequent flat‐screen printing, which was performed using pigment printing pastes and thermal curing. For an exact transfer of colours of the ink‐jet‐printed standard into the screen‐printing process, a computer recipe prediction method was used. A comparison of colorimetric parameters of fabrics printed with both printing techniques shows minimal and acceptable differences in the CIELab colour values. A comparison of colour fastness properties proves that very good colour fastness is achieved on the pigment‐printed fabrics produced with both printing techniques. The flat‐screen‐printed fabrics show better colour fastness to washing, perspiration and rubbing, while ink‐jet‐printed fabrics show better colour fastness to dry‐cleaning and light. The fabrics printed with both printing techniques have high rigidity and non‐elastic properties. The mechanical and physical parameters are strongly dependent upon the amount of the dry substance of the printing media applied on the cotton fabric surface, which is higher on screen‐printed fabrics. The ink‐jet‐printed fabrics show better air permeability than flat‐screen‐printed fabrics. 相似文献
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Cationic pretreatment of cotton fabric for anionic dye and pigment printing with better fastness properties 总被引:2,自引:0,他引:2
Improved printability with pigment and anionic dyes was obtained after simple cationisation of cotton fabrics with Solfix E. Different print paste formulations were used for printing cationised cotton fabrics with pigment, acid and direct dyes. Print pastes containing a synthetic thickener or a pigment emulsion showed good suitability for printing with pigment and pastes containing Meypro-gum as a thickener showed good printability with anionic dyes. The prints obtained on cationised cotton showed better overall fastness properties than prints obtained on untreated cotton. After repeated washings, the prints on cationised cotton showed a much smaller percentage colour loss than the prints on untreated cotton fabric. 相似文献
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以聚乙二醇(PEG)、异佛尔酮二异氰酸酯(IPDI)为原料,二羟甲基丙酸(DMPA)为亲水扩链剂,乙二胺为非亲水扩链剂,三乙胺(TEA)为中和剂,采用预聚体分散法合成水性聚氨酯涂料印花粘合剂。通过单因素分析法测试涂料印花织物牢度指标等性能,确定了最佳整理工艺为:焙烘温度为150℃,焙烘时间为3min,粘合剂用量25g,涂料用量Rg.交联剂用量0.8g,增稠剂用量2~4g。 相似文献