共查询到20条相似文献,搜索用时 15 毫秒
1.
通过熔融共混法制备了聚对苯二甲酸丙二酯/蒙脱土(PTT/MMT)复合材料。采用DSC法对其非等温结晶性能进行了研究,结果表明MMT在复合材料中起到了异相成核作用,随着MMT含量的增加,PTT/MMT复合材料的结晶峰温θp向高温方向移动;采用偏光显微镜观察PTT及PTT/MMT复合材料在190℃等温结晶的情况下的球晶形态,PTT/MMT复合材料的球晶尺寸比PTT球晶尺寸大大减小;采用电子万能试验机、邵氏硬度计和D JF-20动态冲击分析仪对PTT及PTT/MMT复合材料的综合力学性能进行了测试,结果表明当MMT的质量分数为2%时的PTT/MMT复合材料的综合力学性能最佳。 相似文献
2.
The kinetics of isothermal crystallization and crystal morphology of poly(trimethylene terephthalate)/short glass fibers (PTT/SGF) composites were investigated by using differential scanning calorimetry (DSC) and polarized optical microscopy (POM). DSC data was analyzed by the Avrami equation and Hoffman‐Lauritzen theory. The results show that SGF plays a role as the nucleating agent, which largely accelerates the crystallization rate of PTT. SGF below 20% will increase the crystallinity of the composites but 30% SGF will decrease the crystallinity, which is also verified by the crystallinity results calculated from the wide‐angle x‐ray diffraction (WAXD) experiments. The crystal morphology of the composites exhibits so much microcrystallites because of the fast crystallization rate and the strong interaction between SGF and polymers, which is consistent with the results analysized by the Avrami theory. The nuclei exponent Kg is increased sharply as the SGF added into polymer, and SGF makes PTT easier to crystallize during isothermal crystallization process. POLYM. COMPOS., 2010. © 2009 Society of Plastics Engineers 相似文献
3.
采用型内二次发泡工艺制备了马来酸酐接枝乙烯-1-辛烯共聚物(EOC-g-MAH)共混增韧短玻璃纤维(SGF)/聚丙烯(PP)泡沫复合材料,考察了EOC-g-MAH含量对复合材料的泡孔形貌、微观结构和力学性能的影响。结果表明,EOC-g-MAH的引入改善了泡沫体的发泡效果,平均孔径减小约35%,泡孔密度提高近4倍且分布均匀。SGF与基体间的界面结合得到显著增强,且EOC-g-MAH在SGF表面形成了颗粒黏附结构,大幅提高了SGF/PP泡沫复合材料的冲击韧度,并在质量分数为8%时达到最大值,增幅为77%。随着EOC-g-MAH质量分数的增加,SGF/PP泡沫复合材料的抗弯强度先增加后降低,而压缩强度则呈近似线性下降的变化趋势。 相似文献
4.
采用阳离子可染聚对苯二甲酸丙二醇酯(CDPTT)与聚对苯二甲酸丙二醇酯(PTT)共混,制备CDPTT/PTT纤维。通过纤维强度、声速取向、X射线衍射等方法对纤维的力学性能及结晶取向进行表征,测定了染色性能。结果表明:CDPTT/PTT中间苯二甲酸丙二醇酯-5-磺酸钠(SIPT)的引入,纤维的相对断裂强度、取向、结晶度均有所下降,而断裂伸长率、沸水收缩率均高于PTT纤维,使得CDPTT/PTT纤维力学性能更趋于中强中伸型或低强高伸型。CDPTT/PTT纤维的染色性能较PTT纤维明显得到提高。 相似文献
5.
6.
Hybrid composite samples composed of polypropylene as matrix, 20% short glass fibers (SGF) as reinforcement and varying amount of maleic anhydride (MA) grafted SEBS as compatibilizer and impact modifier were prepared by melt mixing in a modular twin screw extruder. The SEM examination performed on cryogenically fractured surfaces of hybrid samples showed a three‐phase type morphology in which SGF and rubber phase finely distributed in the PP matrix. SEM results also revealed that in the hybrid samples containing SEBS‐MA, the surface of the SGF are coated with a thin layer of SEBS‐MA, indicating a strong adhesion between SGF and matrix materials. The results of rheological studies showed nearly equal viscosity for compatible and incompatible hybrid samples. Tensile yield strength enhanced with increasing rubber content up to 10% above which it decreased and highest impact strength enhancement was obtained for sample containing 20% rubber. The impact strength of composites was found to be increased with increasing the SGF content. In final, it was shown that a good balance between stiffness and toughness could be achieved by adjusting the SGF and rubber content in this ternary system. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2704–2710, 2007 相似文献
7.
以精对苯二甲酸(PTA)和1,3-丙二醇为原料,在聚对苯二甲酸丙二醇酯(PTY)的缩聚阶段加入间苯二甲酸丙二醇酯-5-磺酸钠(SIPT),制备了阳离子可染聚对苯二甲酸丙二醇酯(CDPTT),探讨了SIPT的制备和添加工艺,研究了CDPTT的制备工艺及性能。结果表明:制备SIPT溶液时,1,3-丙二醇与间苯二甲酸- 5-磺酸钠的摩尔比以6:1为宜;制备CDPTT时,SIPT须在酯化反应结束后加入;随着SIPT的含量增加,CDPTT的特性粘数降低,上染率增大;SIPT的摩尔分数(相对PTA)大于2.0%,CDPTT的结晶度随着SIPT含量的增加而减小,SIPT的摩尔分数(相对PTA)小于2.0%时,CDPTT的结晶度则随其增加而增大。 相似文献
8.
采用不同相对分子质量的聚乙二醇(PEG)对聚对苯二甲酸乙二醇酯(PET)进行共聚改性制备得到改性共聚酯(PEGT),将PEGT与聚对苯二甲酸丙二醇酯(PTT)按50:50质量比,以"8"字形进行复合纺丝制得PEGT/PTT并列复合弹性纤维,研究了不同相对分子质量的PEG对PEGT及PEGT/PTT并列复合弹性纤维的性能的影响。结果表明:随着PEG相对分子质量增加,PEGT共聚酯的吸水率和吸湿率也随着增加,接触角和体积比电阻(ρ)则降低。其中,吸水率最高可达4.2%,吸湿率最高为1.7%,接触角最低为57.85°,ρ最低为7.94×109Ω·cm;随着PEG相对分子质量的增加,PEGT/PTT并列复合弹性纤维的回潮率(R)也随着增大,而ρ则下降,其中R最大可达0.91%,相对PET/PTT复合纤维提高了75%,ρ最小可达1.20×1010Ω·cm;PEGT/PTT并列复合弹性纤维相对PET/PTT复合纤维卷曲性能较高,其中卷曲率最高可达63%;PEGT/PTT并列复合弹性纤维可以实现常压沸染,其上染率最高达93.37%,比同一条件下PET/PT... 相似文献
9.
10.
对位芳纶短纤维/氢化丁腈橡胶复合材料的制备及其结构性能 总被引:1,自引:0,他引:1
采用综合性能优异的氢化丁腈橡胶(HNBR)和耐高温对位芳纶短纤维复合,制备了高强度、高模量和耐高温的复合材料,比较了芳纶短纤维类型、纤维用量等对复合材料力学性能和流变行为的影响。结果表明,芳纶浆粕(PPTA-pulp)比芳纶短切纤维(DCF)对橡胶有更佳的增强效果,二者都能明显提高HNBR的高温强度,但PPTA-pulp的效果更为明显。PPTA-pulp增强橡胶复合材料的挤出物外观性能也较DCF增强橡胶复合材料好。 相似文献
11.
为了充分了解不同比例的PET/PTT双组分弹性纤维在结构及热性能上存在的差异。采用FT-IR对纤维的大分子结构进行了表征,结果表明:与PET纤维相比,PET/PTT双组分弹性纤维的亚甲基个数增多,表现在2 964 cm~(-1)附近的特征峰吸收强度增强。利用TG-DSC对纤维的热性能进行了分析,结果表明:随着PTT含量增多,PET/PTT双组分弹性纤维的分解起始温度、最大失重速率温度、分解终止温度均降低,热裂解程度增大,但失重速率变缓。玻璃化转变温度、熔融温度和结晶温度均降低,但结晶速率增加。 相似文献
12.
Seyfullah Madakbaş Zeynep Çelik Fatih Dumludağ Memet Vezir Kahraman 《Polymer Bulletin》2014,71(6):1471-1481
We focused on polyacrylonitrile (PAN)/huntite composites to reinforce the polymer prepared by adding different percentages (wt%) of huntite to PAN. The composites were characterized using thermogravimetric analysis, differential scanning calorimetry, fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy techniques. It was clearly seen that the composites of PAN/huntite have better thermal stability than pure PAN. The effect of the huntite adding to Polyacrylonitrile (PAN) on dc conductivity and dielectric constant was also investigated. Dc conductivity values were increased with increasing temperature. Activation energy values were calculated depending on huntite contents in PAN. Relative dielectric constant values varied in the range of 16.5–21.2 at room temperature at 100 kHz frequency depending on huntite concentrations. All the electrical measurements were performed in dark and vacuum ambient between the temperatures of 295 and 523 K. Dielectric measurements were performed in the frequency range of 40 Hz–100 kHz. 相似文献
13.
以柚皮素为原料合成了新型柚皮环氧树脂,以埃洛石纳米管为改性剂、马来酸酐为固化剂采用浇注工艺制备了柚皮环氧树脂/埃洛石复合材料,考察了埃洛石纳米管用量对柚皮环氧树脂/埃洛石复合材料力学性能、动态力学性能、热稳定性的影响。结果表明:纯柚皮环氧树脂的冲击强度及玻璃化转变温度较双酚A型环氧树脂分别提高了3.05 kJ/m2,96℃;埃洛石纳米管能够显著提高柚皮环氧树脂/埃洛石复合材料的冲击强度,当埃洛石纳米管用量为0.8%(w)时,柚皮环氧树脂/埃洛石复合材料的冲击强度为5.50 kJ/m2,较纯柚皮环氧树脂提高了52.8%。 相似文献
14.
以水稻秸秆经碱解、酸解得到的微晶纤维素(MCC)作为聚乳酸(PLA)的改性材料,通过溶液共混、流延成膜制备了PLA/MCC复合膜,采用傅里叶变换红外光谱仪、差示扫描量热仪、扫描电子显微镜等对其性能进行了表征。结果表明:水稻秸秆中木质素、半纤维素等杂质大部分被有效除去,当NaOH质量分数为5%时,去除率最大,MCC成功制备;当MCC质量分数为8.3%时,可以最大程度改善PLA/MCC复合膜的拉伸性能,MCC与PLA结合最好,而MCC的加入会使复合膜的热稳定性有所降低。 相似文献
15.
16.
17.
以水滑石(LDH)和聚氨酯(PU)为原料,采用溶液流延法成膜,制备了一系列不同LDH含量的复合材料;借助广角X射线衍射和扫描电镜对PU/LDH复合材料的结构和形貌进行了表征,并对其热稳定性能和力学性能进行了测试。结果表明:LDH在PU基体中以插层结构为主,PU大分子链部分插入LDH层间;适量的LDH粒子能够均匀分散在PU基体中;LDH对PU材料的热分解无阻隔作用;适量的LDH粒子能有效提高PU材料的拉伸强度和断裂伸长率,当PU/LDH复合材料中LDH的质量分数为5%时,复合材料的拉伸强度和断裂伸长率达到最大,分别为15.9 MPa和443.8%。 相似文献
18.
19.