Low thermal conductivity for Sr1−xLaxTiO3

Abstract

N type thermoelectric materials Sr_1?xLa_xTiO₃ (x?=?0·02, 0·06 and 0·10) have been obtained by hydrothermal method and sintering at 900 and 1100°C. The thermoelectric properties have been measured, and all of the samples in the measured temperature range have been found to be insulating. Very low thermal conductivity κ?=?0·75 W m^?1 K^?1 is found at 500 K for Sr_0·9La_0·1TiO₃ after sintering at 900°C. With increasing doping level x, the thermal conductivity κ decreases. With increasing sintering temperature, the grain size of samples increases, and the thermal conductivity increases. This phenomenon is ascribed to the strong suppression of the electron and phonon conductivities due to scattering by the numerous grain boundary scattering.     

Miniature heat-pipe thermal performance prediction tool – software development

The software for flat miniature heat-pipe parameters (Q_max, R_hp, temperature field along the pipe surface, heat transfer coefficients in the evaporator and condenser zones h_e, h_c, etc.) prediction and numerical modeling was developed. The experimental data received for the flat miniature heat pipe (2.5–4 mm thickness, 50–250 mm length, 8–11 mm width) with a copper sintered powder wick saturated with water were compared with the data of numerical analysis and results showed that experimental verification testifies the validity of the software application.     

Performance evaluation of photovoltaic/thermal–HDH desalination system

The efficiency of photovoltaic (PV) panel drops with increase in cell temperature. The temperature of the PV panel can be controlled with various cooling techniques. In the proposed work the PV panel is cooled by circulating water and the recovered heat energy is used to run a humidification and dehumidification desalination to produce distilled water from sea water (or) brackish water. This work deals with a detailed analysis of performance of combined power and desalination (Photovoltaic/Thermal–Humidification and Dehumidification) system. A mathematical model of PV/thermal–humidification dehumidification plant was developed and simulations were carried out in MATLAB environment. The performance of photovoltaic/ thermal desalination (Photovoltaic/Thermal–Humidification and Dehumidification) system was investigated under various solar radiation levels (800–1000 W/m²). For each solar radiation level the effect of mass flow rate of coolant water (30–110 kg/h) on water outlet temperature, PV efficiency, PVT thermal efficiency, distilled water production, and plant efficiency was studied. Results show that under each solar radiation level increasing coolant flow rate increases efficiency of PV panel and reduces the plant efficiency. The highest PV efficiency (16.598%) was reached under 800 W/m² at mass flow rate of 110 kg/h and the highest plant efficiency (43.15%) was reached under 800 W/m² at a mass flow rate of 30 kg/h. The maximum amount of distilled water production rate (0.82 L/h) was reached under 1000 W/m² at water mass flow rate of 30 kg/h.     

Temperature-explicit formulation of energy equation for thermal–hydraulic analyses

A temperature equation which is derived from an enthalpy transport equation by using an assumption of a constant specific heat is very attractive for analyses of heat and fluid flows. It can be used for an analysis of a solid–fluid conjugate heat transfer, and it does not need a numerical method to obtain temperature from a temperature–enthalpy relation. But its application is limited because of the assumption. A new method is derived in this study, which is a temperature-explicit formulation of the energy equation. The enthalpy form of the energy equation is used in the method. But the final discrete form of the equation is expressed with temperature. The discretized equation from the temperature-explicit formulation can be used for a heat transfer analysis in a solid–fluid coupled region without any special treatment at the solid–fluid interface. And it can be applied for multiphase flows with a real gas effect. It is found by numerical tests in this study that the proposed method is very efficient and as accurate as the standard enthalpy formulation.     

Forced oscillation in diffusion flames near diffusive–thermal resonance

In this work, we carry out a systematic analysis of forced oscillation in planar diffusion flames under weak external forcing. The external forcing is introduced by independently imposing a flow field with small amplitude fluctuations. Employing the asymptotic theory of Cheatham and Matalon, the linear response is first examined. It is shown that when the Damköhler number Da is close to the critical value Da¹ corresponding to the marginal state of diffusive–thermal pulsating instability, the imposed velocity fluctuation may induce very large amplitude of flame oscillation as the frequency of velocity fluctuation c approaches c₀, the flame oscillation frequency at the onset of instability. This is a resonance phenomenon between the imposed flow oscillations and the intrinsic flame oscillations that are driven by the diffusive–thermal instability, and hence we refer to this as the diffusive–thermal resonance. The nonlinear near-resonant response is then examined with the Damköhler number Da chosen to be very close to the critical Damköhler number Da¹, and we derive an evolution equation for the amplitude of forced oscillation. Examination of the evolution equation reveals that in most situations, flames with larger Lewis number of fuel, smaller initial mixture strength, and smaller temperature difference between the oxidant and fuel stream are more responsive to the external forcing.     

Synthesis and thermal properties of poly(styrene-co-ally alcohol)-graft-stearic acid copolymers as novel solid–solid PCMs for thermal energy storage

A series of poly(styrene-co-allyalcohol)-graft-stearic acid copolymers were synthesized as novel polymeric solid–solid phase change materials (SSPCMs). The graft copolymerization reactions between poly(styrene-co-allyalcohol) and stearoyl chloride were verified by Fourier transform infrared (FT-IR) and Proton Nuclear Magnetic Resonance (¹H NMR) spectroscopy techniques. The crystal morphology of the SSPCMs was investigated using polarized optical microscopy (POM) technique. Thermal energy storage properties of the synthesized SSPCMs were measured using differential scanning calorimetry (DSC) analysis. The POM results showed that the crystalline phase of the copolymers transformed to amorphous phase above their phase transition temperatures. Thermal energy storage properties of the synthesized SSPCMs were investigated by differential scanning calorimetry (DSC) and found that they had typical solid–solid phase transition temperatures in the range of 27–30 °C and high latent heat enthalpy between 34 and 74 J/g. Especially, the copolymer with the mole ratio of 1/1 (poly(styrene-co-allyalcohol)/stearoyl chloride) is the most attractive one due to the highest latent heat storage capacity among them. The results of DSC and FT-IR analysis indicated that the synthesized SSPCMs had good thermal reliability and chemical stability after 5000 thermal cycles. Thermogravimetric (TG) analysis results suggested that the synthesized SSPCMs had high thermal resistance. In addition, thermal conductivity measurements signified that the synthesized PCMs had higher thermal conductivity compared to that of poly(styrene-co-allyalcohol). The synthesized copolymers as novel SSPCMs have considerable potential for thermal energy storage applications such as solar space heating and cooling in buildings and greenhouses.     

Numerical study of mixed convection within porous square cavities using Bejan’s heatlines: Effects of thermal aspect ratio and thermal boundary conditions

The present numerical study deals with mixed convection flows within square enclosures filled with porous media. The influence of various thermal boundary conditions on bottom and side walls based on thermal aspect ratio (A) is investigated for a wide range of parameters (1 ? Re ? 100, 0.015 ? Pr ? 7.2, 10^?5 ? Da ? 10^?3 and 10³ ? Gr ? 10⁵). A penalty finite element method with bi-quadratic elements has been used to investigate the results in terms of streamlines, isotherms and heatlines and average Nusselt numbers. Lid driven effect is dominant at low Darcy number (Da = 10^?5), whereas buoyancy driven effect is dominant at high Darcy numbers (Da = 10^?4 and Da = 10^?3) for Re = 1. Asymmetric pattern is observed in isotherms and heatlines for Re = 100. It is found that thermal gradient is high at the center of the bottom wall for A = 0.1 due to large dense heatlines at that zone and that is low for A = 0.9 irrespective of Re, Pr and Gr. Overall heat transfer rates are higher for A = 0.1 compared to other thermal aspect ratios (A = 0.5, A = 0.9) irrespective of Darcy number, Prandtl number and Reynolds number.     

Pressurized thermal shock screening criteria re-evaluation effort — US industry activities

A joint project is under way between the US nuclear power industry and the US Nuclear Regulatory Commission (NRC) to re-evaluate the pressurized thermal shock (PTS) screening criteria as presently defined in title 10 of the Code of Federal Regulations, 10 CFR 50.61. Advances in probabilistic risk assessment (PRA), probabilistic fracture mechanics (PFM), thermal hydraulics (TH), and overall plant risk assessment are being incorporated into a comprehensive program to establish a technical basis for revising the present screening criteria. US industry activities are being coordinated through the Reactor Pressure Vessel Integrity Issue Task Group (RPV Integrity ITG) of the EPRI Materials Reliability Project (MRP). The EPRI MRP was formed in 1998 to identify and address issues that could affect operability of major components in pressurized water reactor (PWR) plants. Major activities are coordinated with the nuclear steam supply system (NSSS) vendors, the vendor owner's groups, The Nuclear Energy Institute (NEI), and the NRC. The MRP provides for a unified industry approach to resolution of technical and regulatory issues related to PWR materials degradation. A major task under the Reactor Pressure Vessel Integrity Issue Task Group (RPV Integrity ITG) is to support industry activities associated with the pressurized PTS re-evaluation effort. This paper provides a brief overview of the EPRI MRP program, the RPV Integrity ITG, and industry activities associated with the PTS re-evaluation effort.     

Pulsating flow in circular pipes — the analysis of thermal stresses

Flow pulsation in externally heated pipes generates a pulsating temperature field, which, in turn results in oscillating thermal stresses across the pipe wall. In the present study, pulsating flow inside a circular pipe, which is externally heated, is considered. The flow and temperature fields are computed numerically using a control volume approach. The resulting thermal stresses across the pipe wall due to temperature variation in the transverse direction are computed. Pressure pulsation at the pipe inlet is employed to produce the flow pulsation. The simulations are extended to include different pipe lengths, pipe diameters and pipe thickness. It is found that pipe diameter has a significant effect on the effective stress levels; in which case, the amplitude of the oscillation in stress levels across the pipe wall reduces considerably with increasing pipe diameter. Moreover, the effect of Reynolds number is more pronounced at mid and outlet planes such that increasing Reynolds number amplifies the amplitude of stress levels in the pipe.     

KNO3/NaNO3 – Graphite materials for thermal energy storage at high temperature: Part I. – Elaboration methods and thermal properties

Composites graphite/salt for thermal energy storage at high temperature (～200 °C) have been developed and tested. As at low temperature in the past, graphite has been used to enhance the thermal conductivity of the eutectic system KNO₃/NaNO₃. A new elaboration method has been proposed as an alternative to graphite foams infiltration. It consists of cold-compression of a physical mixing of expanded natural graphite particles and salt powder. Two different compression routes have been investigated: uni-axial compression and isostatic compression. The first part of the paper has been devoted to the analysis of the thermal properties of these new graphite/salt composites. It is proven that cold-compression is a simple and efficient technique for improving the salt thermal conductivity. For instance, graphite amounts between 15 and 20%wt lead to apparent thermal conductivities close to 20 W/m/K (20 times greater than the thermal conductivity of the salt). Furthermore, some advantages in terms of cost and safety are expected because materials elaboration is carried out at room temperature. The second part of the paper is focused on the analyses of the phase transition properties of these graphite/salt composites materials.     

Interface thermal characteristics of flip chip packages – A numerical study

Flip chip ball grid array (FC-BGA) packages are commonly used for high inputs/outputs (I/O) ICs; they have been proven to provide good solutions for a variety of applications to maximize thermal and electrical performance. A fundamental limitation to such devices is the thermal resistance at the top of the package, which is characterized θ_JC parameter. The die-to-lid interface thermal resistance is identified as a critical issue for the thermal management of electronic packages. This paper focuses on the effect of the interface material property changes on the interface thermal resistance. The effect of package’s junction to case (Theta-JC or θ_JC) thermal performance is investigated for bare die, flat lid and cup lid packages using a validated thermal model. Thermal performance of a cup or flat lid attached and bare die packages were investigated for different interface materials. Improved Theta-JC performance was observed for the large die as compared to the smaller die. Several parametric studies were carried out to understand the effects of interface bond line thickness (BLT), different die sizes, the average void size during assembly and thermal conductivity of interface materials on package thermal resistance.     

Ultraviolet activation of thermal decomposition of α-alane

We investigated activation of thermal dehydriding of α-AlH₃ crystal by preliminary irradiation by ultraviolet light using thermal desorption spectroscopy, barometry, and cathode luminescence methods. It is shown that hydrogen vacancies appear due to irradiation; they serve as points where metal nuclei probably appear, so dehydriding becomes significantly faster. Possible explanation of transformation of hydrogen vacancies to metal phase nuclei is suggested: new vacancies are more likely to appear near the first one compared to remote places. Using density functional theory method we calculated the electronic structure of stoichiometric α-AlH₃ and α-AlH₃ with a hydrogen atom removed from a regular lattice site with a vacancy in place of it. It is suggested that an appearance of a new vacancy near the first vacancy needs less energy compared to the first one. From cathode luminescence data we see that appearance of vacancies can also be activated thermally. The model of hydrogen desorption from α-AlH₃ activated by UV light is suggested and kinetic parameters of desorption are evaluated.     

A critical review of photovoltaic–thermal solar collectors for air heating

Integrated photovoltaic–thermal solar collectors have become of great interest in the solar thermal and photovoltaic (PV) research communities. Solar thermal systems and solar PV systems have each advanced markedly, and combining the two technologies provides the opportunity for increased efficiency and expanded utilization of solar energy. In this article, the authors critically review photovoltaic–thermal solar collectors for air heating. Included is a review of photovoltaic thermal technology and recent advances, particularly as applied to air heaters. It is determined that the photovoltaic–thermal (PV/T) air heater is or may in the future be practicable for preheating air for many applications, including space heating and drying, and that integrated PV/T collectors deliver more useful energy per unit collector area than separate PV and thermal systems. Although PV/T collectors are promising, it is evident that further research is required to improve efficiency, reduce costs and resolve several technical design issues related to the collectors.     

Effects of thermal load on wheel–rail contacts: A review

This article presents a technical review on the effects of thermal loads evolved at the wheel–rail–brake contact interfaces. These dynamic contact interfaces develop heat transfer conditions of widely varied thermal level. Their modeling to identify the sources for a variety of defect formation, observable on wheel tread or rail surface, is very important. The railway system, in general, has to bear axle load, friction load, and thermal load arising from their contact conditions in addition to traction and dynamic loads. The defects arising from the interaction of thermal load and other loadings may be identified as hot spots, shelling, spalling, rolling contact fatigue (RCF), and corrugation. The mechanisms for the formation of such defects are pivoted over the existing thermal environment of dynamic interacting surfaces. This review summarizes the works of early investigations and recent advances in modeling the heat transfer conditions required to estimate the temperature distribution at the contact zone. The heat partitioning method for both drag and stop braking conditions, in the presence of rail chill effect, is emphasized. Thermal gradient, introduced by localized temperature rise in the contact zone, in the presence of variable friction coefficient, promotes the RCF process. These alter the residual stresses in the contact region to cause a structural shakedown, aggravate plastic flow and activates ratchetting phenomenon in rails. The evolution of thermomechanical surface and subsurface fatigue cracks are also discussed for the completeness of this article. The effect of all such defect formation, emerging from thermal loading condition, and their countermeasures for defect mitigation are presented in this review. This abridged technical documentation envisions attracting more research in the area to improve wheel–rail set design and performance standards to extend enhanced safety and comfort to rail transport operation. It is opined that the thermomechanical loading, their effects on promoting defect formation and propagation should be studied in combination instead of the current practice of treating them separately.     

Prediction of the thermal conductivity of metal hydrides – The inverse problem

With sustainability as an important and driving theme, not merely of research, but that of our existence itself, the effort in developing sustainable systems takes many directions. One of these directions is in the transport sector, particularly personal transport using hydrogen as fuel, which logically leads on to the problem of hydrogen storage. This paper deals with the prediction of the effective conductivity of beds of metal hydride for hydrogen storage. To enable modeling of the effective thermal conductivity of these systems, it is necessary to arrive at the functional dependence of the thermal conductivity of the solid hydride on its hydrogen concentration or content. This is the inverse problem in thermal conductivity of multiphase materials. Inverse methods in general are those where we start from known consequences in order to find unknown causes. Using published and known data of the effective thermal conductivity of the hydride–hydrogen assemblage, we arrive at the unknown hydride conductivity by analysis. Among the models available in the literature for determination of the effective conductivity of the bed from the properties of the constituent phases, the model of Raghavan and Martin is chosen for the analysis as it combines simplicity and physical rigor. The result is expected to be useful for predicting the thermal conductivity of hydride particles and determining the optimum heat transfer rates governing the absorption and desorption rates of hydrogen in the storage system.     

Packed-bed thermal storage for concentrated solar power – Pilot-scale demonstration and industrial-scale design

A thermal energy storage system, consisting of a packed bed of rocks as storing material and air as high-temperature heat transfer fluid, is analyzed for concentrated solar power (CSP) applications. A 6.5 MWh_th pilot-scale thermal storage unit immersed in the ground and of truncated conical shape is fabricated and experimentally demonstrated to generate thermoclines. A dynamic numerical heat transfer model is formulated for separate fluid and solid phases and variable thermo-physical properties in the range of 20–650 °C, and validated with experimental results. The validated model is further applied to design and simulate an array of two industrial-scale thermal storage units, each of 7.2 GWh_th capacity, for a 26 MW_el round-the-clock concentrated solar power plant during multiple 8 h-charging/16 h-discharging cycles, yielding 95% overall thermal efficiency.     

Optical efficiency of a PV–thermal hybrid CPC module for high latitudes

The advantage of PV–thermal hybrid systems is their high total efficiency. By using concentrating hybrid systems, the cost per energy produced is reduced due to simultaneous heat and electricity production and a reduced PV cell area. In this article, the optical efficiency of a water-cooled PV–thermal hybrid system with low concentrating aluminium compound parabolic concentrators is discussed. The system was built in 1999 in Älvkarleby, Sweden (60.5° N, 17.4° E) with a geometric concentration ratio of C=4 and 0.5 kW_p electric power. The yearly output is 250 kWh of electricity per square metre solar cell area and 800 kWh of heat at low temperatures per square metre solar cell area. By using numerical data from optical measurements of the components (glazing, reflectors, and PV cells) the optical efficiency, η_opt, of the PV–CPC system has been determined to be 0.71, which is in agreement with the optical efficiency as determined from thermal and electrical measurements. Calculations show that optimised antireflection-treated glazing and reflectors could further increase the electric power yield.     

Equilibrium of NH4SCNNH3 system for thermal energy storage

A solid-gas reaction of ammonium thiocyanate (NH₄SCN) and ammonia produces liquid ammoniate (NH₄SCN·nNH₃). The region of the liquid phase and the equilibrium properties of the ammoniate have been determined. Crystalization of the ammoniate was not observed, though the liquid was cooled to − 10°C. The enthalpy changes in the liquid phase were also estimated. Accordingly, this system has a wide range of liquid phase and offers a medium for thermal energy storage or a chemical heat pump system.     

Crystallization fouling of CaCO3 – Analysis of experimental thermal resistance and its uncertainty

Crystallization fouling occurs when dissolved salts precipitate from an aqueous solution. In the case of inversely soluble salts, like calcium carbonate (CaCO₃), this may lead to crystal growth on heated walls. Crystallization may also take place in the bulk solution either via homogeneous nucleation or heterogeneous nucleation on suspended material.In this paper, surface crystallization of CaCO₃ and crystallization in the bulk fluid and its effect on the fouling rate on a heated wall are studied. The fouling experiments are done in a laboratory scale set-up of a flat plate heat exchanger. Accuracy of the results is analyzed by uncertainty analysis. SEM and XRD are used to determine the morphology and the composition of the deposited material.The uncertainty analysis shows that the bias and precision uncertainties in the measured wall temperature are the largest source of uncertainty in the experiments. The total uncertainty in the fouling resistance in the studied case was found to be ±13.5% at the 95% confidence level, which is considered to be acceptable.Surface crystallization rate is found to be controlled by the wall temperature indicating that the surface integration dominates the fouling process. The flow velocity affects the fouling rate especially at high wall temperature by decreasing the fouling rate with increasing flow velocity. Crystallization to the bulk fluid is found to enhance significantly the fouling rate on the surface when compared to a case in which fouling is due to crystal growth on the surface.     

Energy and exergy analysis of photovoltaic–thermal collector with and without glass cover

In photovoltaic–thermal (PV/T) technology, the use of glass cover on the flat-plate hybrid solar collector is favorable to the photothermic process but not to the photovoltaic process. Because of the difference in the usefulness of electricity and thermal energy, there is often no straight forward answer on whether a glazed or unglazed collector system is more suitable for a specific application. This glazing issue was tackled in this paper from the viewpoint of thermodynamics. Based on experimental data and validated numerical models, a study of the appropriateness of glass cover on a thermosyphon-based water-heating PV/T system was carried out. The influences of six selected operating parameters were evaluated. From the first law point of view, a glazed PV/T system is found always suitable if we are to maximize the quantity of either the thermal or the overall energy output. From the exergy analysis point of view however, the increase of PV cell efficiency, packing factor, water mass to collector area ratio, and wind velocity are found favorable to go for an unglazed system, whereas the increase of on-site solar radiation and ambient temperature are favorable for a glazed system.