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PET/蒙脱土纳米复合材料的制备及其性能研究 总被引:3,自引:0,他引:3
将十六烷基三甲基溴化铵/聚乙二醇混合物处理的蒙脱土与聚对苯二甲酸乙二醇酯在哈克流变仪上进行熔融复合,制备了聚对苯二甲酸乙二醇酯(PET)/蒙脱土纳米复合材料。X射线衍射以及透射电镜分析表明,蒙脱土层间距明显增大,部分剥离并分散于PET基体中。对其力学性能和热性能的分析发现,当有机化蒙脱土用量为5%(质量含量,下同)时,材料的热变形温度及弯曲模量分别达到154℃和3.335GPa。 相似文献
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采用熔融共混的方法制备了聚对苯二甲酸丙二醇酯/有机蒙脱土(PTT/MMT)纳米复合材料,通过DSC、热台偏光显微镜等研究了PTT/MMT纳米复合材料的结晶行为,测定了纳米复合材料的力学性能,并用熔体流变仪研究了PTT/MMT纳米复合材料熔体流变性能。结果表明:随着PTT/MMT纳米复合材料中蒙脱上含量的增加,PTT/MMT纳米复合材料的熔融结晶温度增高,纳米复合材料的力学性能有一定的提高;PTT-蒙脱土纳米复合材料熔体的流变性能随MMT含量的增加非牛顿性减弱,熔体的粘流活化能减小。 相似文献
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PE/MMT纳米复合材料的研究进展 总被引:1,自引:0,他引:1
介绍蒙脱土(MMT)及其纳米复合材料的结构、特点及聚乙烯(PE)/MMT纳米复合材料的制备原理和方法,并对PE/MMT纳米复合材料的国内外研究进展进行了综述,指出今后PE/MMT纳米复合材料的研究重点是先对PE进行改性,以增加PE与MMT片层的粘结力。 相似文献
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以聚对苯二甲酸乙二醇酯(PET)为基体,以三元乙丙橡胶(EPDM)为弹性体,用熔融共混的方法制备了不同比例的PET/EPDM/蒙脱土(MMT)复合体系。用原子力显微镜、扫描电子显微镜研究了复合材料的微观结构,并测试了力学性能。结果表明MMT含量较低时,用熔融共混的方法能制得PKT/EPDM/MMT纳米复合材料EPDM及增容剂的引入都较大程度地改善了复合材料的缺口冲击强度。 相似文献
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PET/PEN共混聚酯的结晶和热稳定性能研究 总被引:5,自引:0,他引:5
通过DSC、偏光显微镜、TG以及热变形测试等分析方法,研究了聚对苯二甲酸乙二醇酯(PET)/聚对萘二甲酸乙二醇酯(PEN)共混物的结晶特征以及热稳定性能。结果表明:PEN的结晶温度高,结晶历程长,快速降温会导致PEN结晶困难或不结晶。PET/PEN共混物结晶性能与PEN含量密切相关,含量低能结晶,含量达3a%时基本不结晶。PET/PEN共混物的热分解温度比PEN提高了4℃,总残留率比PET提高T5.57%,其中空吹塑容器的热收缩率随PEN含量的增加而降低,表明PET/PEN共混材料的热稳定性能好于纯PFT。 相似文献
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The crystalline size of polypropylene (PP) filled with montmorillonite (MMT) was studied by X-ray diffraction (XRD). The isothermal crystallization behavior of polypropylene was studied by means of differential scanning calorimetry (DSC). The Avrami equation was used to describe the isothermal crystalline kinetics of PP/MMT composites. The result showed that the addition of MMT decreased the crystalline size L hkl of the polymer. MMT was used as nucleating agent during isothermal crystallization process of polypropylene. The addition of montmorillonite decreased the crystallization time of the polypropylene and the melt point was raised. The value of Avrami exponent n was related with the crystallization temperature. The value of Avrami pre-index factor k of PP/MMT composite was decreased with increasing crystallization temperature. The value of half crystallization time t 1/2 of PP/MMT composite was less than that of PP at a given crystallization temperature, signifying that montmorillonite acted as nucleating agent, accelerated the overall crystallization process. 相似文献
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《国际聚合物材料杂志》2012,61(3-4):345-358
Abstract The crystallization of several blends of poly(ethylene terephthalate) (PET) and poly(ethylene 2,6 naphthalene dicarboxylate) (PEN) has been investigated by wide angle- (WAXS) and small angle X-ray scattering (SAXS) using synchrotron radiation. The role of transesterification reactions, giving rise to a fully amorphous non-crystal-lizable material (copolyester) is brought up. For the blends rich in PET, crystallization temperatures (Tc ) of 105 and 117°C were used. For blends rich in PEN, crystaffization was performed at Tc =150 and 165°C, respectively. The time variation of the degree of crystallinity was fitted into an Avrami equation considering the induction time prior to the beginning of crystallization. The Avrami parameters, the half times of crystallization, as well as the nanostructure development (SAXS invariant and long period) for the blends, are discussed in relation to blend composition and are compared to the parameters observed for the homopolymers PET and PEN. 相似文献
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Nanocomposites based on polycarbonate (PC) containing sodium montmorillonite (NaMMT) and maleic anhydride grafted styrene-ethylene/butylene-styrene (SEBS-g-MA) were prepared by melt compounding method followed by injection molding. X-ray diffraction (XRD) and transmission electron microscopy (TEM) results revealed the formation of intercalated nanocomposites. Incorporation of SEBS-g-MA into the PC/MMT nanocomposites enhanced ductility and impact strength but slightly reduced tensile strength and stiffness. The glass transition temperature (T g – detected from DMTA) and onset temperature (T onset – detected from TGA) of the PC nanocomposites was increased in the presence of SEBS-g-MA. For this PC/NaMMT system, SEBS-g-MA could act as an effective toughening agent. 相似文献
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Jungang Gao Dongshuan Hua Yonggang Du Xing Li 《Polymer-Plastics Technology and Engineering》2013,52(14):1429-1437
Polyhedral oligomeric silsesquioxane (POSS) is usually prepared from the hydrolytic condensation of organotrialkoxysilanes. The rheology, non-isothermal crystallization kinetics and mechanical properties of high density polyethylene (HDPE)/vinyl-containing POSS (V-POSS) nanocomposites were investigated. The results show that the molten HDPE/V-POSS belong to pseudoplastic fluid. The V-POSS can accelerate the nucleation of HDPE at starting stage of crystallization. However, it will decrease the crystallization ability of HDPE in the subsequent crystallization process. The modified Avrami analysis by Jeziorny can well explain the crystallization behaviour of HDPE/V-POSS. The yield strength and tensile modulus of nanocomposites both increase when V-POSS content is 6%. 相似文献