Thermo‐rheological and functional properties of gamma‐irradiated wholewheat flour

The effects of different doses (0, 0.5, 1, 2.5, 5 and 10 kGy) of gamma irradiation on the thermal, rheological and functional properties of the wholewheat flour were evaluated. Water and oil absorption capacity of the flour increased from 85.92% to 91.44% and 1.10 to 1.91 g g^?1 of flour, respectively, with increase in irradiation dose. The dough development time decreased with dose from 4.0 to 3.0 min. The transition temperatures (T_o, T_p and T_c) decreased as the dose increased; enthalpy of gelatinisation (?H) decreased from 5.18 to 4.27 J g^?1 with dose. The flow behaviour showed a shear‐thinning behaviour, and the hysteresis area decreased with dose. The structural recovery decreased with dose. FTIR did not show formation of any new chemical groups.     

Mechanical and barrier properties of sodium caseinate–anhydrous milk fat edible films

Edible films were cast from solutions of sodium caseinate (NaCAS) and from emulsions of this protein with anhydrous milk fat (AMF). The moisture sorption isotherms, mechanical properties [tensile strength (TS) and elongation] and water vapour and oxygen permeabilities were determined for films based on NaCAS as a function of AMF concentration. AMF concentration significantly affected TS (P < 0.001) and elongation (P < 0.05). The increase of lipid content led to a loss of mechanical efficiency, but had little influence on water vapour barrier properties. No significant difference (P > 0.05) occurred between oxygen permeability of films at each lipid concentration.     

Effect of surfactants and drying rate on barrier properties of emulsified edible films

The effects of globule size, nature and concentration of surfactant, and drying duration of water vapour transmission rate and tensile strength of emulsified edible barriers containing methylcellulose and paraffin wax, were measured. of the six surfactants tested, 0.6% purified glycerol monostearate (GMS) produced films with the lowest water vapour transmission rates and the highest mechanical resistance. Longer drying times of film-forming emulsions produced better barrier and mechanical properties. Control of the film forming emulsion stability allowed the reduction of the water vapour transfer rate by an order of magnitude.     

Effects of pH and salt concentration on functional properties of rambutan (Nephelium lappaceum L.) seed albumin concentrate

Searching new protein sources is essential due to an increase in protein demand. In this study, rambutan seed albumin concentrate (RSAC) with the protein content of 80.8% was isolated from defatted rambutan seed meal. The effects of pH and sodium chloride concentration on solubility and functional properties of RSAC were investigated. RSAC had minimum solubility at pH 4. Water absorption capacity at pH 7 and oil absorption capacity of RSAC were 0.79 and 6.13 mL g^?1, respectively. Both foaming and emulsifying capacities achieved maximal levels at pH 12. In sodium chloride solution, foaming capacity and stability achieved maximal levels at the concentration of 0.6 mol L^?1, while the highest emulsifying capacity and stability were noted at the concentration of 0.2 mol L^?1. The least gelation concentration of RSAC was 100 g L^?1 and this value decreased by five times as salt concentration in the protein solution was 0.6 mol L^?1. RSAC was a potential functional ingredient in food processing.     

提高多糖类可食性膜机械性能的研究进展

多糖类可食性膜的机械强度强于蛋白类可食性膜,但是还不足以应用到食品包装中。影响多糖类可食性膜机械性能的主要因素有成膜原料中各组分性质、制膜工艺以及贮藏条件等。可通过添加增塑剂、交联剂和改进成膜工艺,来提高多糖类可食性膜的机械性能。     

Antibacterial activity and mechanical properties of partially hydrolyzed sago starch-alginate edible film containing lemongrass oil

ABSTRACT:  Edible films were prepared from a mixture of partially hydrolyzed sago starch and alginate (SA). Lemongrass oil (0.1% to 0.4%, v/w) and glycerol (0% and 20%, w/w) were incorporated in the films to act as natural antimicrobial agent and plasticizer, respectively. The films were characterized for antimicrobial activity, water vapor permeability (WVP), tensile strength (TS), percent elongation at break (%E), and water solubility (WS). Fourier transform infrared (FTIR) spectroscopy was conducted to determine functional group interactions between the matrix and lemongrass oil. The zone of inhibition was increased significantly ( P < 0.05) by addition of lemongrass oil at all levels in the presence and the absence of glycerol. This indicates that the film containing lemongrass oil was effective against Escherichia coli O157:H7 at all levels. In the absence of glycerol, the tensile strength of film decreased as the oil content increased, but there was no significant ( P > 0.05) difference in percent elongation. The percent elongation at break and WVP values for film with 20% glycerol was found to be increased significantly ( P < 0.05) with an increase in lemongrass oil content. Addition of lemongrass oil did not have any interaction with the functional groups of films as measured by FTIR.     

Microbial inactivation and quality improvement of tomatoes treated by package film with allyl isothiocyanate vapour

In‐package sanitisation was developed using polylactic acid (PLA) films with allyl isothiocyanate (AIT) vapour. Tomatoes were artificially inoculated with Escherichia coli, Geotrichum candidum and Fusarium oxysporum and stored in clamshell boxes with the film fixed to the underside of the lid. The changes in bacterial and fungal populations and the quality of tomatoes during storage at 4 and 10 °C were evaluated. The results revealed that the film treatment (4 × 8 cm² film in 1 L box) reduced the populations of inoculated bacteria and fungi on tomatoes by 2–3 log CFU g^?1, and then significantly (P < 0.05) inhibited their growth during the 21‐day storage period at both temperatures. Tomatoes subject to film treatment had fewer changes in quality (colour, firmness, contents of total soluble solid, titratable acids and vitamin C) than the control samples during storage. The antimicrobial PLA film can be used for in‐package sanitisation to extend the shelf‐life of packaged tomatoes or similar perishable vegetables.     

Development of novel pea flour‐based nanofibres by electrospinning method

The aim of this study was to produce pea flour and hydroxypropyl methylcellulose (HPMC)‐based novel nanofibres using electrospinning method. The effects of pH, pea flour and HPMC concentration on apparent viscosity, electrical conductivity of electrospinning solutions and nanofibre characteristics were studied. Solutions were prepared at different pH values (7, 10, 12), with different pea flour concentrations (1%, 2% w/v) and HPMC concentrations (0.25%, 0.5%, 1.0% w/v). For all pea flour concentrations, k values increased significantly with increase in pH and HPMC concentration. It also increased with increase in pea flour concentration for basic solutions. Pea flour concentration increased diameter and water vapour permeability (WVP) values of nanofibres. This study showed that electrospinning was a promising method for fabrication of homogenous pea flour and HPMC‐based nanofibres to be used in packaging industry.     

Effect of temperature,pH and film thickness on nisin release from antimicrobial whey protein isolate edible films

BACKGROUND: An active packaging film based on whey protein isolate (WPI) was developed by incorporating nisin to promote microbial food safety. The effect of temperature and pH on the release of nisin from edible films of different thickness was investigated. The film mechanical properties and inhibitory effect were also evaluated. RESULTS: Nisin release was significantly favoured by low pH, with the highest release after 24 h (1325 IU), which was not significantly affected by temperature (5 or 10 °C). Thickness significantly affected film elongation, with thicker films showing the highest elongation (54.3 ± 2.7%). Water vapour permeability (0.15 ± 0.4 g mm m^?2 kPa^?1 h^?1) and elastic modulus were not significantly affected by thickness. The highest nisin effective diffusivity (5.88 × 10^?14 m² s^?1) was obtained using a solution at pH 4, 112 µm film thickness and a temperature of 5 °C. More than four log cycles of Brochotrix thermosphacta were reduced from the surface of a ham sample after 8 days of incubation at 4 °C by the active WPI film containing 473 IU cm^?2 nisin. CONCLUSION: Nisin diffusivity from WPI edible films was favoured at lower pH and film thickness. This active packaging film may be used to preserve the quality and safety of meat products. Copyright © 2009 Society of Chemical Industry     

甘油含量对大豆蛋白膜功能性质的影响

大豆蛋白膜是一种可降解、可食用和可再生的新型包装材料,但是其机械性能尚不能满足日常使用的需求。研究甘油含量对可食性大豆蛋白膜功能性质的影响,结果显示随着甘油含量的增加,大豆蛋白膜抗张强度下降,而断裂延伸率、水蒸气透过率和氧气透过率升高。当甘油添加量为大豆蛋白的30%时,大豆蛋白膜具有较好的机械性能。因此,甘油含量是影响大豆蛋白膜机械性能的主要因素之一。     

Physical properties of edible emulsified films based on pistachio globulin protein and fatty acids

Novel edible composite films were prepared from pistachio globulin protein (PGP), saturated fatty acids, and an emulsifier using the emulsification technique. The water vapor permeability (WVP) of the emulsified films was reduced by approximately 37–43% by fatty acid addition. The effect of fatty acid on the oxygen permeability (OP) of PGP films was indirectly determined as the oil peroxide value. The OPs of the emulsified films were lower than those of a PGP film without fatty acid, but the differences were not significant (P < 0.05). The mechanical properties of PGP films were also affected by fatty acid addition; the ultimate tensile strength (UTS) was diminished, and elongation at breaking (E) decreased considerably (35–70%). Furthermore, the incorporation of fatty acid increased the opacity of the films. Finally, differential scanning calorimetry showed that the glass transition temperature (T_g) of the PGP film was ∼127 °C and was not considerably affected by fatty acid addition.     

Hake proteins edible films incorporated with essential oils: Physical,mechanical, antioxidant and antibacterial properties

Physical, mechanical, antioxidant and antimicrobial properties of hake protein films incorporated with citronella, coriander, tarragon and thyme oils were investigated. Dried hake proteins were solubilized at pH 11.0 (protein concentration in film forming solution ca. 0.9%) and glycerol (59% w/w of protein) and 0.25 ml of each essential oil per gram of protein was added. Films obtained were homogeneous and transparent with a yellowish colour. The addition of the different essential oils reduced the water vapour permeability but increased the solubility of films in water. The amount of protein released from the films depended on the oil added. Among all essential oils incorporated-films the thyme oil films exhibited the lowest mechanical properties (puncture force and elongation at break). Conversely, films with thyme oil added presented the highest inhibition against Shewanella putrefaciens. Antioxidant activity of hake protein films generally increased with the incorporation of essential oils as indicated by DPPH radical scavenging activity and reducing power.     

Chemical composition and functional properties of Gleditsia triacanthos gum

The seeds of Gleditsia triacanthos (Fabaceae) are a source of galactomannans with a variable mannose:galactose (Man:Gal) ratio that depends on the isolation and purification methods. In this study, three processes were used: (1)—treatment with boiling water (M1); (2)—concentration with boiling 2 N NaOH (M2) and (3)—swelling with water and later manual removal of the endosperm (M3). The functional properties of the hydrocolloids obtained by the three isolating methods were compared with those exhibited by xanthan and guar gums, which are widely used as food additives. The product obtained by boiling water (M1) had the lowest yield, although that hydrocolloid showed high water absorption capacity and solubility, high emulsifying and foaming capacities, and imparted high stability to the dispersions (foams and emulsions). These properties could be influenced by its high Man:Gal ratio and protein content.     

Investigation on permeability and moisture management properties of different denim fabrics after repeated laundering

The physiological comfort determined by air permeability and moisture management properties of fabrics is influenced by various constructional parameters of the fabric which give woven fabric a porous structure. Evaporation of sweat during wear has the potential to cool the body besides restricting the additional weight of sweat being absorbed by the fabric. In this study, comfort characteristics of denim fabrics with different weft yarn of cotton, polyester and core spun Lycra have been discussed. Effect of enzyme washing and repeated laundering on air permeability, moisture management and drying rate has also been discussed. It was observed that air permeability and water vapour permeability of unwashed denim fabrics with cotton weft yarn are significantly higher than the fabric with polyester and Lycra cotton weft yarns. The wetting time is higher for cotton and Lycra cotton yarn fabrics. One-way transport index is highest for Lycra cotton weft fabrics and lowest for fabrics with polyester weft. Fabrics with polyester weft yarns show highest spreading rate, spreading radius and drying rate due to better wicking and hydrophobic nature of polyester fibres.     

A study on thermal properties of single-jersey knitted fabrics produced from ring and compact folded yarns

This paper presents a study on the thermal properties of single-jersey knitted fabrics manufactured using ring, compact and ring/compact folded yarns. The variations in thermal properties depending on the yarn twist and traveller weight of folded yarn single-jersey knits were discussed. It was found that the thermal resistance of knitted fabrics generally increases as the traveller weight decreases, and also water vapour permeability reduces as the traveller weight decreases. The water vapour permeability and air permeability of knitted fabrics increase as the twist increases. The thermal conductivity of knitted fabrics decreases as the twist increases. The air permeability and water vapour permeability values were higher for compact folded yarn fabrics as compared to those values of ring and ring/compact folded yarn fabrics. It is observed that yarn twist and traveller weight have affected different thermal properties of single-jersey folded yarn fabrics.     

Rheological properties and gel strength of Phaseolus lunatus protein/carboxymethylated flamboyant gum systems

The rheological behaviour and gel strength of hydrocolloid mixture systems (HMSs) of carboxymethylated flamboyant gum (CFG) with protein hydrolysates (PHs) of Phaseolus lunatus were examined to evaluate the influence of the protein/polysaccharide ratio (2:1 and 3:1), pH (3 and 9) and concentration of solids, according to a 2³ factorial design. The protein concentrate of P. lunatus was hydrolysed with pepsin–pancreatin enzymes. The flow curve results were fitted to the Ostwald–de Waele model. The flow behaviour index (0.66–0.78) for all conditions studied was indicative of the shear‐thinning behaviour. For the HMS, the consistency index (k) values ranged from 0.4 Pa sⁿ to 1.2 Pa sⁿ. The analyses of variance showed that the ratio of PH/CFG and pH were the main variables that had significant effect on k values (P < 0.05). Only PH system presented a weak gel‐like viscoelastic behaviour. Both functional properties were affected by the protein degree of hydrolysis (DH).     

包装袋阻隔性对腊肉储存期间品质的影响

为了研究包装材料阻隔性对腊肉储存期间品质的影响,本研究选取4种阻隔性不同的包装材料（普通袋PET/NY/PE、镀氧化铝袋PET/Al₂O₃/NY/PE、镀氧化硅袋PET/SiO₂/NY/PE和铝箔袋PET/AL/NY/PE）对腊肉进行真空包装,并对储存过程中水分含量、水分活度（Aw）、酸价（AV）、过氧化值（POV）、色泽、菌落总数和大肠菌群数及氨基酸含量进行测定。结果表明,普通袋的水分含量变化最大,铝箔袋水分变化最小（p<0.05）。四种包装袋的Aw前4个月增加,随后逐渐降低;普通袋包装的POV的变化显著高于镀氧化硅袋、镀氧化铝袋和铝箔袋（p<0.05）。铝箔袋的酸价增加最少,其余三种材料的酸价显著高于铝箔袋（p<0.05）。镀氧化铝袋和铝箔袋包装时色泽整体变化趋势较小。普通袋包装时菌落总数和大肠菌群增加量显著高于镀氧化铝袋、铝箔袋（p<0.05）。储存实验结束后,四种包装袋中的腊肉的各种氨基酸含量均显著增加,但两两之间无显著差异（p<0.05）。因此,铝箔袋可以有效的阻隔水分和氧气的进入,延缓腊肉储存期的品质下降,是良好的腊肉包装材料。      

Effect of beeswax content on hydroxypropyl methylcellulose-based edible film properties and postharvest quality of coated plums (Cv. Angeleno)

The effect of beeswax (BW) content of hydroxypropyl methylcellulose (HPMC)–BW edible coatings on stand-alone film properties and on postharvest quality of coated ‘Angeleno’ plums was studied. The coatings contained BW at 4 lipid content levels (0, 20, 40 and 60 g/100 g, dry basis). Coated and uncoated plums were stored 4 weeks at 1 °C and transferred to 20 °C for 1–3 weeks. Addition of BW to the HPMC film matrix reduced film mechanical resistance and oxygen barrier, and improved film moisture barrier. Film mechanical properties showed a good fit with an exponential and/or linear model that could provide a useful tool to predict mechanical properties with others HPMC–BW composition mixtures. Coatings with BW reduced plum weight loss compared to HPMC-based coatings with no BW. Plum weight loss decreased as BW content increased from 20 to 40 g/100 g, but above 40 g/100 g BW content, weight loss was not further reduced. Whereas, water vapor permeability of stand-alone films decreased significantly as BW content increased to 60 g/100 g. Coatings reduced plum softening and bleeding, with those with lower BW content being more effective, which could be related to the ability of coatings to create a modified atmosphere in the fruit. Flavor was not affected by coating application. Results indicate that HPMC–BW coatings with 20 g/100 g BW would provide the best compromise to extend shelf life of ‘Angeleno’ plums.     

Influence of hydrocolloid nature on the structure and functional properties of emulsified edible films

To investigate the influence of polymer behaviors on the structure and the functional properties of emulsified films, agar (AG) and cassava starch (CAS) were used as hydrocolloid continuous phases in which hydrogenated vegetable oil (VGB81) was dispersed. Different ratios of hydrophilic/hydrophobic materials (HB/HL) were also used in film formulations to study the evolution of film-emulsion structure. Microscopically observed, VGB–CAS emulsified films exhibit a similar bilayer structure. However, there was just a migration and an aggregation of lipid particles. There was no coalescence which could form a continuous “lipid layer” necessary for an effective barrier. Moreover, they could not be made with a HB/HL ratio greater than 0.7:1. Conversely, AG chains set into gel, which solidifies film-forming emulsion before drying, leading to a fixed macronetwork structure. Films made with a high HB/HL ratios lead to a film structure becoming like a multilayer system. The water vapor permeability of emulsified films is better found when HB/HL ≥ 1:1 when films are formed only with gelling polysaccharide (AG). In addition, there is no relationship between the moisture sorption and the moisture permeability of emulsified films. In contact with liquid water, brief sorption and swelling surface are observed for VGB–AG film surface and rapid absorption following a temporary hydrophobicity is found in the case of VGB–CAS films. While the mechanical properties of VGB–CAS films are strongly altered, those of VGB–AG films are considered to be sufficient for most of applications.