A novel methodology for estimating space air change rates and occupant CO2 generation rates from measurements in mechanically-ventilated buildings

It is useful to know ventilation rates and carbon dioxide (CO₂) generation rates for evaluating indoor air quality and ventilation efficiency in mechanically-ventilated buildings. A strong limitation of the current models is either they focus solely on a whole building or they are too complicated for practical use in studies of individual spaces. This paper develops a new method for accurately quantifying ventilation rates (i.e. space air change rate) and CO₂ generation rates from measured CO₂ concentrations for individual spaces. The proposed method firstly determined space air change rate using Maximum Likelihood Estimation (MLE). Additionally, a novel coupled-method was initiated for further estimating CO₂ generation rates. Both simulated and experimental data were used to validate the model. Experiments were conducted in a school office by measuring indoor CO₂ concentrations and pressure differences between the return air vent and space. Excellent agreement was obtained. At least 0.998 R² values were obtained for fitting measured CO₂ concentrations when conducting MLE for estimating space air change rate, and the corresponding residual plots showed no pattern and trend. The estimated numbers of occupants were same as the actual ones. Furthermore, the predicted space air change rates showed great consistencies with those from CO₂ equilibrium analysis. The model is simple, handy and effective for practical use. Moreover, the model is also capable for dealing with time-varying space air change rates.     

Performance of a CO2 sorbent for indoor air cleaning applications: Effects of environmental conditions,sorbent aging,and adsorption of co-occurring formaldehyde

Indoor air cleaning systems that incorporate CO₂ sorbent materials enable HVAC load shifting and efficiency improvements. This study developed a bench-scale experimental system to evaluate the performance of a sorbent under controlled operation conditions. A thermostatic holder containing 3.15 g sorbent was connected to a manifold that delivered CO₂-enriched air at a known temperature and relative humidity (RH). The air stream was also enriched with 0.8-2.1 ppm formaldehyde. The CO₂ concentration was monitored in real-time upstream and downstream of the sorbent, and integrated formaldehyde samples were collected at different times using DNPH-coated silica cartridges. Sorbent regeneration was carried out by circulating clean air in countercurrent. Almost 200 loading/regeneration cycles were performed in the span of 17 months, from which 104 were carried out at reference test conditions defined by loading with air at 25°C, 38% RH, and 1000 ppm CO₂, and regenerating with air at 80°C, 3% RH and 400 ppm CO₂. The working capacity decreased slightly from 43-44 mg CO₂ per g sorbent to 39-40 mg per g over the 17 months. The capacity increased with lower loading temperature (in the range 15-35°C) and higher regeneration temperature, between 40 and 80°C. The CO₂ capacity was not sensitive to the moisture content in the range 6-9 g/m³, and decreased slightly when dry air was used. Loading isothermal breakthrough curves were fitted to three simple adsorption models, verifying that pseudo-first-order kinetics appropriately describes the adsorption process. The model predicted that equilibrium capacities decreased with increasing temperature from 15 to 35°C, while adsorption rate constants slightly increased. The formaldehyde adsorption efficiency was 80%-99% in different cycles, corresponding to an average capacity of 86 ± 36 µg/g. Formaldehyde was not quantitatively released during regeneration, but its accumulation on the sorbent did not affect CO₂ adsorption.     

Submicrometer particle removal indoors by a novel electrostatic precipitator with high clean air delivery rate,low ozone emissions,and carbon fiber ionizer

A novel positive‐polarity electrostatic precipitator (ESP) was developed using an ionization stage (0.4 × 0.4 × 0.14 m³) with 16 carbon fiber ionizers in each channel and a collection stage (0.4 × 0.4 × 0.21 m³) with parallel metallic plates. The single‐pass collection efficiency and clean air delivery rate (CADR) were measured by standard tests using KCl particles in 0.25–0.35 μm. Performance was determined using the Deutsch equation and established diffusion and field charging theories and also compared with the commercialized HEPA filter‐type air cleaner. Experimental results showed that the single‐pass collection efficiency of the ESP ranged from 50 to 95% and decreased with the flow rate (10–20 m³/min), but increased with the voltage applied to the ionizers (6 to 8 kV) and collection plates (?5 to ?7 kV). The ESP with 18 m³/min achieved a CADR of 12.1 m³/min with a voltage of 8 kV applied to the ionization stage and with a voltage of ?6 kV applied to the collection stage. The concentration of ozone in the test chamber (30.4 m³), a maximum value of 5.4 ppb over 12 h of continuous operation, was much lower than the current indoor regulation (50 ppb).     

Assessment of the decrease of CO2 emissions in the construction field through the selection of materials: Practical case study of three houses of low environmental impact

A great quantity of CO₂ is emitted to the atmosphere through the different phases of a building life cycle: in the production of materials and products, in the construction of the building itself, in the setting on site, in the exploitation, the renovations, the later rehabilitations, up to the final demolition. The present paper shows the possibility of reducing the CO₂ emissions up to 30% in the construction phase, through a careful selection of low environmental impact materials. The purpose of this study is to quantify the total amount of CO₂ emissions saved by the method presented in the particular phase of material selection within the life cycle of a building. This material selection, as well as the bioclimatic characteristics, must be defined from the early design project phase.     

Particle distribution analysis along the collection electrode of a ‘wire-to-cylinder’ electrostatic precipitator

This study determined the value distribution of the ‘charge/mass’ ratio of the particles charged by corona along a ‘wire-cylinder’ electrostatic precipitator (ESP). These particles are absorbed by suction from the openings on the collection electrode. The results enabled the analysis of the particle movement in the ESP. For moderate voltage values (8–12 kV), the constant ratio along the ESP suggests that the product is uniformly collected when the particles acquire a sufficient electric charge during their progression. Conversely, for higher voltages (14–16 kV), massive deposition occurs at the inlet as soon as the particles are sufficiently charged.     

Assessment of chemical and microbiological parameters of indoor swimming pool atmosphere using multiple comparisons

The aim of this study was to evaluate the air quality of an indoor swimming pool, analyzing diurnal and seasonal variations in microbiological counts and chemical parameters. The results indicated that yeast and bacteria counts, as well as carbon dioxide (CO₂), nitrogen oxides (NO_x) and O₃ concentrations, showed significant diurnal difference. On the other hand, temperature, relative humidity (R.H.), yeast counts and concentrations of CO₂, particles, O₃, toluene, and benzene showed seasonal differences. In addition, the relationship between indoor and outdoor air and the degree of correlation between the different parameters have been calculated, suggesting that CO₂, fine particles and NO_x would have indoor origin due to the human activity and secondary reactions favored by the chemical and environmental conditions of the swimming pool; while O₃, benzene and toluene, would come from outside, mainly. The overall results indicated that indoor air quality (IAQ) in the swimming pool building was deficient by the high levels of CO₂ and microorganisms, low temperatures, and high R.H., because frequently the limits established by the legislation were exceeded. This fact could be due to the poor ventilation and the inadequate operation of heating, ventilation, and air‐conditioning systems.     

Capture of CO2 from flue gas via multiwalled carbon nanotubes

Carbon nanotubes (CNTs) were modified by 3-aminopropyl-triethoxysilane (APTS) solution and were tested for its CO₂ adsorption potential at multiple temperatures (20-100 °C). The physicochemical properties of CNTs were changed after the modification, which makes CNTs adsorb more CO₂ gases. The adsorption capacities of CO₂ via CNTs and CNTs(APTS) decreased with temperature indicating the exothermic nature of adsorption process and increased with water content in air at 0-7%. The mechanism of CO₂ adsorption on CNTs and CNTs(APTS) appears mainly attributable to physical force regardless of temperature change, which makes regeneration of spent CNTs at a relatively low temperature become feasible. The CNTs(APTS) have good adsorption performance of CO₂ at 20 °C as compared to many types of modified carbon or silica adsorbents documented in the literature. This suggests that the CNTs(APTS) are promising low-temperature adsorbents for CO₂ capture from flue gas.     

Effect of green roof on ambient CO2 concentration

Plants can improve air quality by removing pollutants. The air purification capability of plants has been receiving increasing attention because of the rapid deterioration of the environment. However, research on evaluating quantitatively the effect of plants on the environmental pollutant concentrations is still scarce. This paper studies the effect of a green roof on the ambient CO₂ concentration as an example to assess the benefit of urban greening. The study comprises three parts: (1) Field measurement of the difference of CO₂ concentration at a location in the middle of the plants in a small plot of green roof and one in the surrounding area, (2) Experiments to measure the plant’s CO₂ absorption velocity and emission rate using a sealed glass chamber; and (3) Computer simulation of the CO₂ concentration distribution around a green roof using the measured CO₂ absorption velocity and emission rate to quantify the effects of the green roof on the ambient CO₂ concentration.     

Effect of temperature on carbon nanoparticle collection efficiency using photoelectric ESP

The electrostatic precipitator (ESP) technique is a promising method for enhancing the particulate matter (PM) emission reduction efficiency of diesel engines, and is much better than the diesel particulate filter (DPF) technique. However, the ESP's low efficiency in collecting PM with diameters less than several tens of nanometers remains a problem because the particle charging efficiency decreases as the size of the nanoparticles decreases. To improve the collection efficiency of nanosized PM, we used a photoelectric charger to increase the charging efficiency of nanoparticles ahead of the ESP system. Carbon nanoparticles produced using a spark discharge generator were used to evaluate the collection efficiency of the combined photoelectric charger and ESP system. The particle sizes were measured using a scanning mobility particle sizer system at various experimental temperatures similar to the temperature of DPF systems commonly used in diesel engines. We succeeded in obtaining improved collection efficiencies at increased inner temperatures of the photoelectric charging chamber. As the temperature increased from 694 °C to 839 °C at the inlet of the photoelectric chamber, the efficiency of PM collection improved significantly to 28.5% for a particle diameter of 18.4 nm.     

Plant crown traits and carbon sequestration capability by Platanus hybrida Brot. in Rome

Measurements of carbon dioxide (CO₂) concentration carried out in the city of Rome in the period January–December 2005 showed a mean yearly CO₂ concentration of 414 ± 45 ppm; polluted sites (P sites) had 21% higher CO₂ concentration than control sites (C sites). The significant (p < 0.01) correlation analysis between CO₂ concentration and traffic density measured during the study period at P sites showed that traffic density explained 51% of the CO₂ variation. The CO₂ trend during the traffic limitation days (provision imposed by ordinance of the City Council) did not show significant differences as regards regular traffic days, suggesting the ineffectiveness of this provision. Leaf area index (LAI) of Platanus hybrida Brot. was on an average 11% lower at P sites than at C ones associated with a lower total photosynthetic leaf surface area (SPT, 34% lower at P sites than at C ones). P. hybrida had a total carbon sequestration of 117 ± 13 kg year⁻¹ (mean value of P and C sites) playing an important role in sequestering CO₂. Thus, the choice of plant species for urban areas may be set out taking into account their own air amelioration capability. Plant traits of each species may be used for urban tree planting programs to ameliorate urban air pollution.     

Degradation of NO using photocatalytic coatings applied to different substrates

This article deals with the degradation of NO present in the air by means of a photocatalytic oxidation process based on TiO₂ nanoparticles incorporated in a polymer-matrix-based coating. The experimental set-up consisted of a flow type reactor adapted from the ISO 22197-1 standard. NO₂ in the gas phase, and nitrate ions adsorbed on the photocatalytic surface were detected as finals products. Various parameters influencing the NO degradation efficiency were studied: the coating composition, the substrate nature, the initial concentration of NO, the polluted air flow rate and the humidity. Compared to glass, the use of mortar as the substrate enhanced the photocatalytic performance of coatings by reducing the generation of gaseous NO₂ as a by-product.     

Methods to reduce the CO2 concentration of educational buildings utilizing internal ventilation by transferred air

The aim of this study is to develop internal ventilation by transferred air to achieve a good indoor climate with low energy consumption in educational buildings with constant air volume (CAV) ventilation. Both measurements of CO₂ concentration and a multi‐room calculation model are presented. The study analyzes how to use more efficiently the available spaces and the capacity of CAV ventilation systems in existing buildings and the impact this has on the indoor air quality and the energy consumption of the ventilation. The temperature differences can be used to create natural ventilation airflows between neighboring spaces. The behavior of temperature‐driven airflows between rooms was studied and included in the calculation model. The effect of openings between neighboring spaces, such as doors or large apertures in the walls, on the CO₂ concentration was studied in different classrooms. The air temperatures and CO₂ concentrations were measured using a wireless, internet‐based measurement system. The multi‐room calculation model predicted the CO₂ concentration in the rooms, which was then compared with the measured ones. Using transferred air between occupied and unoccupied spaces can noticeably reduce the total mechanical ventilation rates needed to keep a low CO₂ concentration.     

Forecasting future cooling demand in London

Cooling of buildings in the UK is responsible for around 15 TWh per year of energy demand, largely powered by electricity with highly related CO₂ emissions. The Greater London Authority wished to understand the potential impact of London's growing need for cooling on UK CO₂ emissions in the period up to 2030. This paper describes a model developed to analyse the cooling requirements for London's key building stock and assess how these would be affected by change in system mix, improvements in system efficiencies, and by varying degrees of climate change.The analysis showed that, if left unchecked, the growth in active cooling systems in London could lead to a doubling of CO₂ emissions from this source by 2030. This growth will be due to increase in building stock, increase in market share of cooling systems, and climate change. The last of these is difficult to predict, but by itself could add 260,000-360,000 tonnes of CO₂ emissions by 2030. This increase can be strongly mitigated, or even offset, by improvements in system efficiency. The difference between no efficiency improvements, and an assumed 1-3% annual efficiency improvement is around 340,000 tonnes by 2030.     

Combined use of an electrostatic precipitator and a high‐efficiency particulate air filter in building ventilation systems: Effects on cardiorespiratory health indicators in healthy adults

High‐efficiency particulate air (HEPA) filtration in combination with an electrostatic precipitator (ESP) can be a cost‐effective approach to reducing indoor particulate exposure, but ESPs produce ozone. The health effect of combined ESP‐HEPA filtration has not been examined. We conducted an intervention study in 89 volunteers. At baseline, the air‐handling units of offices and residences for all subjects were comprised of coarse, ESP, and HEPA filtration. During the 5‐week long intervention, the subjects were split into 2 groups, 1 with just the ESP removed and the other with both the ESP and HEPA removed. Each subject was measured for cardiopulmonary risk indicators once at baseline, twice during the intervention, and once 2 weeks after baseline conditions were restored. Measured indoor and outdoor PM_2.5 and ozone concentrations, coupled with time‐activity data, were used to calculate exposures. Removal of HEPA filters increased 24‐hour mean PM_2.5 exposure by 38 (95% CI: 31, 45) μg/m³. Removal of ESPs decreased 24‐hour mean ozone exposure by 2.2 (2.0, 2.5) ppb. No biomarkers were significantly associated with HEPA filter removal. In contrast, ESP removal was associated with a ?16.1% (?21.5%, ?10.4%) change in plasma‐soluble P‐selectin and a ?3.0% (?5.1%, ?0.8%) change in systolic blood pressure, suggesting reduced cardiovascular risks.     

Evaluation of four control strategies for building VAV air-conditioning systems

It is necessary to adopt appropriate control strategies to save energy and improve the indoor air quality (IAQ). On the validated TRNSYS simulation platform, four different control strategies are investigated to examine the indoor air temperature, energy consumption, CO₂ concentration and predicted mean vote (PMV) for the variable air volume (VAV) systems in an office building in Shanghai. As an original scheme, Strategy A using constant outdoor air intake fraction shows high energy consumption, low CO₂ concentration and acceptable thermal comfort. By using minimum outdoor air ventilation based on dynamic occupancy detection, Strategy B can provide more than 15% energy saving, acceptable PMV value but high CO₂ concentration in breathing zone. By using indoor air temperature reset, Strategy C presents the most energy savings beyond 20% reduction, low CO₂ concentration but poor thermal comfort. In mild seasons, combining enthalpy-based outdoor airflow economizer cycle with supply air temperature reset, Strategy D can achieve 9.4% energy savings and the lowest CO₂ concentration. Taken together, each strategy covers some strengths as well as some weaknesses. How to comprehensively assess a control strategy for all specific objectives should be considered in future studies.     

Variation in indoor particle number and PM2.5 concentrations in a radio station surrounded by busy roads before and after an upgrade of the HVAC system

Indoor particle number and PM_2.5 concentrations were investigated in a radio station surrounded by busy roads. Two extensive field measurement campaigns were conducted to determine the critical parameters affecting indoor air quality. The results indicated that indoor particle number and PM_2.5 concentrations were governed by outdoor air, and were significantly affected by the location of air intake and design of HVAC system. Prior to the upgrade of the HVAC system and relocation of the air intake, the indoor median particle number concentration was 7.4×10³ particles/cm³ and the median PM_2.5 concentration was 7 μg/m³. After the relocation of air intake and the redesign of the HVAC system, the indoor particle number concentration was between 2.3×10³ and 3.4×10³ particles/cm³, with a median value of 2.7×10³ particles/cm³, and the indoor PM_2.5 concentration was in the range of 3–5 μg/m³, with a median value of 4 μg/m³. By relocating the air intake of the HVAC, the outdoor particle number and PM_2.5 concentrations near the air intake were reduced by 35% and 55%, respectively. In addition, with the relocation of air intake and the redesign of the HVAC system, the particle number penetration rate was reduced from 42% to 14%, and the overall filtration efficiency of the HVAC system (relocation of air intake, pre-filter, AHU and particle losses in the air duct) increased from 58% to 86%. For PM_2.5, the penetration rate after the upgrade was approximately 18% and the overall filtration efficiency was 82%. This study demonstrates that by using a comprehensive approach, including the assessment of outdoor conditions and characterisation of ventilation and filtration parameters, satisfactory indoor air quality can be achieved, even for those indoor environments facing challenging outdoor air conditions.     

Indoor and outdoor PM2.5 and PM10 concentrations in the air during a dust storm

Asian dust storms (ADS) originating from the arid deserts of Mongolia and China are a well-known springtime meteorological phenomenon throughout East Asia. The ventilation systems in office utilize air from outside and therefore it is necessary to understand how these dust storms affect the concentrations of PM_2.5 and PM₁₀ in both the indoor and outdoor air. We measured dust storm pollution particles in an office building using a direct-reading instrument (PC-2 Quartz Crystal Microbalance, QCM) that measured particle size and concentration every 10 min for 1 h, three times a day. A three-fold increase in the concentrations of PM_2.5 and PM₁₀ in the indoor and outdoor air was recorded during the dust storms. After adjusting for other covariates, autoregression models indicated that PM_2.5 and PM₁₀ in the indoor air increased significantly (21.7 μg/m³ and 23.0 μg/m³ respectively) during dust storms. The ventilation systems in high-rise buildings utilize air from outside and therefore the indoor concentrations of fine and coarse particles in the air inside the buildings are significantly affected by outside air pollutants, especially during dust storms.     

Embodied and operational carbon dioxide emissions from housing: A case study on the effects of thermal mass and climate change

A 100-year lifecycle carbon dioxide (CO₂) emissions analysis is reported for a two-bedroom, 65 m² floor area, semi-detached house in south-east England. How the balance between the embodied (ECO₂) and operational CO₂ emissions of the building are affected by the inclusion of thermal mass and the impacts of climate change is quantified. Four ‘weights’ of thermal mass were considered, ranging from lightweight timber frame to very heavyweight concrete construction. For each case, total ECO₂ quantities were calculated and predictions for operational CO₂ emissions obtained from a 100-year dynamic thermal modelling simulation under a medium-high emissions climate change scenario for south-east England. At the start of the lifecycle, the dwellings were passively cooled in summer, but air conditioning was installed when overheating reached a certain threshold. The inclusion of thermal mass delayed the year in the lifecycle when this occurred, due to the better passive control of summertime overheating. Operational heating and cooling energy needs were also found to decrease with increasing thermal mass due to the beneficial effects of fabric energy storage. The calculated initial ECO₂ was higher in the heavier weight cases, by up to 15% (4.93 t) of the lightweight case value, but these difference were offset early in the lifecycle due to the savings in operational CO₂ emissions, with total savings of up to 17% (35.7 t) in lifecycle CO₂ found for the heaviest weight case.     

Energy conservation in honey storage building using Trombe wall

This paper investigates energy conservation, mitigation of CO₂ emissions and economics of retrofitting for a honey storage building with Trombe wall for winter heating application. The passive heating potential of Trombe wall for a honey storage building was estimated using TRNSYS building simulation software. This honey storage building is located at Gwalior (latitude: 26°14′N) in India. During winter months, the room air temperature of building falls below the required temperature range of 18–27 °C which is suitable for honey storage. So, the room air temperature range is maintained in the building using a 2.3 kW capacity electrical oil filled radiator (or room air heater) which accounts for the major energy consumption of the building on an annual basis. On account of which there are significant CO₂ emissions into the atmosphere from the honey storage building. Hence, this case study was conducted to recommend the passive heating concept to the stakeholders of the building so as to conserve the energy requirement for room air heating. The investigation showed that the room air temperature can be easily maintained in the range suitable for honey storage using a vented Trombe wall. The experimental work was carried out for the existing building on a typical clear day of harsh winter month of January to validate the results of TRNSYS model of the present building. The statistical error analysis showed a good agreement between model and experimental results. This investigation concludes that there is potential of energy conservation up to 3312 kWh/year and associated reduction in CO₂ emissions (∼33 tonne/year) using a Trombe wall. Also, the retrofitting of building is economically viable as the simple payback period is only about 7 months.