Establishing physico-chemical reference conditions in Mediterranean streams according to the European Water Framework Directive

Type-specific physico-chemical reference conditions are required for the assessment of ecological status in the Water Framework Directive context, similarly to the biological and hydro-morphological elements. This directive emphasises that natural variability of quality elements in high status (reference condition) needs to be quantified. Mediterranean streams often present a marked seasonal pattern in hydrological, biological and geochemical processes which could affect physico-chemical reference conditions. This study establishes general physico-chemical reference conditions (oxygenation, nutrient, salinity and acidification conditions) for different Mediterranean stream types. 116 potential reference sites located in 23 Mediterranean catchments in Spain were sampled in spring, summer and autumn in 2003. All sites were subjected to a screening method for the selection of reference sites in Mediterranean streams (Mediterranean Reference Criteria) and classified using a pre-established stream typology that establishes five different stream types (temporary streams, evaporite-calcareous at medium altitude, siliceous headwaters, calcareous headwaters and large watercourses). Reference conditions (reference value and reference threshold equivalents to high-good class boundary) were calculated using two different methods according to the availability of reference sites: the reference site 75th percentile approach of all reference sites and the 25th percentile of the population approach. The majority of the studied potential reference sites (76 out of 116) were selected as reference sites. Regarding type-specific reference conditions, only siliceous headwaters could be considered different from the rest of stream types because lower conductivity and pH. All reference stream types presented seasonal differences as regards some parameters, except for temporary streams due to the high natural variation of this stream type. For those parameters which presented seasonal differences in a specific stream type, the least restrictive values were proposed as reference conditions.     

The social benefits of restoring water quality in the context of the Water Framework Directive: A comparison of willingness to pay and willingness to accept

The Water Framework Directive (WFD) is by far the most important piece of water legislation in Europe for the coming decades. Its main aim is to achieve “good ecological status” for all water resources by 2015. The economic valuation of the non-market benefits derived from improving water quality is an important input in assisting the design and implementation of efficient and effective water management policies. In this study, the contingent valuation method has been applied with a double purpose. On the one hand, we have estimated the value of a hypothetical improvement in water quality of a river asking individuals about their willingness to pay, and on the other hand, the issue of exemptions contemplated in the WFD has been addressed surveying people on their willingness to accept compensation if projected improvements were not carried out. Finally, a comparison of costs and benefits in a cost-benefit framework shows that the net present value of the water quality policy is positive both if we consider willingness to pay estimates as willingness to accept estimates, therefore this policy appears desirable from a social perspective.     

Use of numerical models for determination of best sampling locations for monitoring of large lakes

The implementation of the European Union Water Framework Directive (WFD) that requires all surface waters to achieve at least good status by year 2015 presents a challenge to local authorities responsible for the monitoring programmes. Obtaining a single representative value for each water quality parameter may be extremely difficult to achieve in the case of large lakes, which may be characterised by significant spatial and temporal variation of water quality parameters. The aim of this paper is to present a methodology, which can support the decision making as to the best locations for water quality sampling when developing monitoring systems of large lakes. The methodology is based on three-dimensional hydrodynamic and a conservative tracer transport numerical modelling and utilises the concept of flushing and residence time. The 3D numerical model of Lough Corrib located in the west of Ireland was created and used to calculate its residence time and flushing pathways. Based on the results it was possible to identify the areas in the lake that are characterised by the local residence time values close to the lake's average as well as by the values significantly lower and higher. Three water classes have been introduced and the authors recommend that sampling takes place in all three classes at various frequencies. Spatial distribution of the flushing pathways allows identifying the areas in the lake that best represent the lake's average conditions both in the long term and seasonally, where monitoring can be carried out at the required frequency; worst affected areas can also be identified. The methodology can be used to improve robustness of the monitoring programme and may also contribute towards the reduction of both sampling and analytical costs, both at the design and operational stages.     

Dynamics of water use in Scotland

This paper uses a variety of data sources and methodologies to construct business as usual (BAU) water‐use scenarios for the Water Framework Directive (WFD) characterisation report, a key preliminary benchmarking requirement for member states. The paper addresses the most significant water‐use sectors in Scotland over the period 2001–2015. In terms of volumetric use, our figures are dominated by the demands of electricity generation. The next highest demands come from fish farming/aquaculture, which is mostly direct abstraction. Various industrial uses are estimated to be associated with significant volumetric uses (specifically electrical and engineering, fibres and food and drink). Because of structural changes in farm support, agriculture is the only sector showing a decline. Household demand is also a highly significant use and we are able to specify the public/private breakdown of demand.     

Phosphate treatment to reduce plumbosolvency of drinking water also reduces discharges of copper into environmental surface waters

The majority of drinking water supply zones in the United Kingdom are currently dosed with phosphate in order to meet the drinking water quality standards for lead. Consequent reductions in other metals released from domestic plumbing might be expected. Lead, copper, zinc and nickel concentrations in the tap water of supply zones and in effluents from related sewage works were examined to assess reductions in the concentrations of these metals associated with the dosing of orthophosphate. This paper provides an analysis of the impact of phosphate dosing of drinking water on the metal concentrations in drinking water and sewage work effluents and the potential impacts in relation to the Water Framework Directive. Phosphate treatment the reduced average copper concentrations in drinking water by around 40% from 65 to 35 μg/L; the reduction is proportional to the phosphate dose. A corresponding 30% decrease in wastewater treatment work effluent concentrations is observed. No significant changes are evident in the zinc and nickel concentrations.     

Nitrate attenuation in groundwater: a review of biogeochemical controlling processes

Biogeochemical processes controlling nitrate attenuation in aquifers are critically reviewed. An understanding of the fate of nitrate in groundwater is vital for managing risks associated with nitrate pollution, and to safeguard groundwater supplies and groundwater-dependent surface waters. Denitrification is focused upon as the dominant nitrate attenuation process in groundwater. As denitrifying bacteria are essentially ubiquitous in the subsurface, the critical limiting factors are oxygen and electron donor concentration and availability. Variability in other environmental conditions such as nitrate concentration, nutrient availability, pH, temperature, presence of toxins and microbial acclimation appears to be less important, exerting only secondary influences on denitrification rates. Other nitrate depletion mechanisms such as dissimilatory nitrate reduction to ammonium and assimilation of nitrate into microbial biomass are unlikely to be important in most subsurface settings relative to denitrification. Further research is recommended to improve current understanding on the influence of organic carbon, sulphur and iron electron donors, physical restrictions on microbial activity in dual porosity aquifers, influences of environmental condition (e.g. pH in poorly buffered environments and salinity in coastal or salinized soil settings), co-contaminant influences (particularly the contrasting inhibitory and electron donor influences of pesticides) and improved quantification of denitrification rates in the laboratory and field.     

DIFFUSE POLLUTION ‐ WHAT IS THE NATURE OF THE PROBLEM?

This paper considers recent developments in the understanding of diffuse pollution, its generation, transport and impacts. The relative importance of diffuse sources to total pollutant loading must be identified in order to develop appropriate strategies for management.
Research has indicated that individual diffuse pollutants respond differently to changing flow conditions and that there is a widespread misconception that higher flows are associated with lower pollutant concentrations. Evidence is presented to highlight this discrepancy and a rationale for load assessment is presented. The implications of this for monitoring within the context of the EU Water Framework Directive are discussed as are the implications for the mitigation of diffuse pollution.     

Long term change of nutrient concentrations of rivers discharging in European seas

Cases of severe eutrophication are still observed in European surface waters even though tough regulation has been in place since the beginning of the 1990s to control nutrient losses and inputs in the environment. The purpose of this paper is to evaluate the evolution since 1991 of the quality of the water entering European seas in terms of the concentration of major nutrients (nitrogen and phosphorus), and to analyze the effectiveness of implemented national/international measures and EU legislation in reducing water nutrient pollution. Despite the reduction in large portions of the European territory of agricultural nutrient applications and nutrient point source emissions, the impact on water quality is limited. It is shown using two large river basins that this lack of response for nitrogen, and nitrate in particular, between the reduction of the nitrogen surplus and the recovery of water quality is partly explained by the lag time due to transfer of nitrates in the unsaturated and saturated zones and storage in the soils and aquifers. In order to monitor efficiently the impact of policy implementation on water quality, the Nitrates Directive and the Urban Waste Water Treatment Directive in particular, it is recommended to use long term permanent monitoring stations to be able to separate the impact of climate variability from that of policy implementation. It is also recommended to investigate and develop harmonized methodologies for estimating the lag time in order to come up with realistic estimates of response time of water bodies due to the implementation of measures.     

Occurrence and removal of priority pollutants by lamella clarification and biofiltration

This study investigates the occurrence of all priority substances (n = 41) listed in the Water Framework Directive and additional substances (n = 47) in raw sewage, as well as the removal performance of lamella clarification and biofiltration techniques. Once the efficiency of both types of techniques has been assessed for typical wastewater parameters, the differences in each technique's ability to remove pollutants becomes obvious; nevertheless, pollutant removal in quantitative terms still depends on the physico-chemical properties of the compounds used and operating conditions within the selected facility. For lamella clarification, the removal of organic chemicals was found to be primarily correlated with their sorption potential and, hence, strongly dependent upon log K_ow of the compound under study. Compounds with a strong hydrophobic character (log K_ow > 4.5) are removed to a significant extent (approx. 85%), while hydrophilic compounds (log K_ow < 3.5) are poorly removed (<20%). For biofiltration, the removal of chemicals appears to be compound-dependent, although this outcome involves several mechanisms, namely: i) physical filtration of total suspended solids, ii) volatilisation, iii) sorption, and iv) biotransformation of substances. Even if the complex processes within a biofilter system do not yield an accurate prediction of pollutant removal, two groups of chemicals can still be clearly identified: i) hydrophobic or volatile compounds, for which moderate to high removal rates are observed (from 50% to over 80%); and ii) hydrophilic, non-volatile and refractory compounds for which a low removal rate would be expected (<20%).     

STRATEGIC AND PROJECT LEVEL RIVER RESTORATION PROTOCOLS — KEY COMPONENTS FOR MEETING THE REQUIREMENTS OF THE WATER FRAMEWORK DIRECTIVE (WFD)

The number of river restoration projects undertaken in the UK has increased rapidly over the last five years. However, schemes are still largely undertaken on an ad-hoc basis rather than part of a co-ordinated, strategic, catchment restoration strategy. Additionally, project level restoration is rarely initiated through a systematic approach that involves all stages from baseline studies through to design, installation, monitoring and post-project appraisals. The need for both strategic and project levels to be undertaken effectively is necessary if the requirements of the Water Framework Directive (WFD) are to be met. This directive has the potential to significantly increase the number of schemes, as restoration of surface water bodies has become a key duty of member states. There exists, therefore, a need for a holistic catchment scale approach to restoration to be adopted to maximise benefit to the fluvial systems and ensure compliance. This paper outlines key components of strategic and project level protocols for river restoration from a UK perspective.     

Assessing remotely sensed chlorophyll-a for the implementation of the Water Framework Directive in European perialpine lakes

The lakes of the European perialpine region constitute a large water reservoir, which is threatened by the anthropogenic pressure altering water quality. The Water Framework Directive of the European Commission aims to protect water resources and monitoring is seen as an essential step for achieving this goal. Remote sensing can provide frequent data for large scale studies of water quality parameters such as chlorophyll-a (chl-a). In this work we use a dataset of maps of chl-a derived from over 200 MERIS (MEdium Resolution Imaging Spectrometer) satellite images for comparing water quality of 12 perialpine lakes in the period 2003-2009. Besides the different trophic levels of the lakes, results confirm that the seasonal variability of chl-a concentration is particularly pronounced during spring and autumn especially for the more eutrophic lakes. We show that relying on only one sample for the assessment of lake water quality during the season might lead to misleading results and erroneous assignments to quality classes. Time series MERIS data represents a suitable and cost-effective technology to fill this gap, depicting the dynamics of the surface waters of lakes in agreement with the evolution of natural phenomena.     

WATER, LIFE AND CULTURE: THE WATER FRAMEWORK DIRECTIVE

Although wetlands are referred to in the statement of purpose of the Water Framework Directive and in the objectives for groundwater status. there are few further references to Member States'obligations towards them in the body of the Directive or its annexes. This paper (a) describes wetlands and their functions, and argues that they play an essential role in aquatic systems, (b) explains the place of wetlands within the Directive, and (c) advocates approaches to implementation in the UK which will ensure maximum human and ecological benefit.     

Integrated Risk Assessment for WFD Ecological Status classification applied to Llobregat river basin (Spain). Part II - Evaluation process applied to five environmental Lines of Evidence

Many indicators and indices related to a variety of biological, physico-chemical, chemical, and hydromorphological water conditions have been recently developed or adapted by scientists in order to support water managers in the Water Framework Directive (WFD) implementation. In this context, the achievement of a comprehensive and reliable Ecological Status classification of water bodies across Europe is hampered by the lack of harmonised procedures for selecting an appropriate set of indicators and integrating heterogeneous information in a flexible way.To this purpose, an Integrated Risk Assessment (IRA)² methodology was developed based on the Weight of Evidence approach. This method analyses and combines a set of environmental indicators grouped into five Lines of Evidence (LoE), i.e. Biology, Chemistry, Ecotoxicology, Physico-chemistry and Hydromorphology. The whole IRA methodology has been implemented as a specific module into a freeware GIS (Geographic Information System)-based Decision Support System, named MODELKEY DSS. This paper focuses on the evaluation of the four supporting LoE (i.e. Chemistry, Ecotoxicology, Physico-chemistry and Hydromorphology), and includes a procedure for a comparison of each indicator with proper thresholds and a subsequent integration process to combine the obtained output with the LoE Biology results in order to provide a single score expressing the Ecological Status classification. The approach supports the identification of the most prominent stressors, which are responsible for the observed alterations in the river basin under investigation. The results provided by the preliminary testing of the IRA methodology through application of the MODELKEY DSS to the Llobregat case study are finally reported and discussed.     

Priority pollutants in wastewater and combined sewer overflow

Implementation of the European Water Framework Directive and its affiliated directives requires Member States to improve their understanding of priority pollutants (PPs) in urban areas and obviously within wastewater systems. As a direct consequence, this study is intended to furnish data on both PP occurrence and the significance of concentrations in wastewater during dry and wet periods within combined sewers. Various sampling sites within the Paris combined sewer network were selected; for each sample, a total of 66 determinants, including metals, polycyclic aromatic hydrocarbons (PAHs), pesticides, organotins, volatile organic compounds, chlorobenzenes, phthalates and alkylphenols, were analysed. A broad range of PPs was observed in wastewater during dry as well as wet weather periods. Of the 66 elements investigated, 33 and 40 priority substances could be observed in raw sewage and wet weather effluent, respectively. As expected, a majority of metals were present in all samples, reflecting their ubiquitous nature. For both periods, chlorobenzenes and most of the pesticides always remained below the limit of quantification, while the majority of other organic pollutants assessed were identified within the microg l(-1) range. As highlighted by the larger number of substances detected in wet weather samples and the significance of their concentrations, runoff via atmospheric inputs and/or surface leaching was found to induce a wider range of PPs (n=40) and lead to higher concentrations of certain metals, PAHs, pesticides and other individual compounds. The data generated during this survey, which constitutes one of the first studies conducted in Europe to report concentrations for a variety of priority substances in wastewater within combined sewers, may be used in the future to identify PPs of potential significance for dry and wet weather periods and targeted for further investigation.     

Monitoring,river restoration and the Water Framework Directive

Monitoring is an important aspect of any procedure that seeks to determine whether a technique has worked effectively. The river restoration process is no different. Unfortunately, monitoring is often not undertaken due to constraints on time and resources, as well as the commonly held belief that river restoration is inherently a good thing and, as a result, monitoring is unnecessary. There are many reasons to monitor projects and among the most important is the need to learn from experiences and for regulatory compliance. This paper examines the issues associated with the monitoring of river restoration schemes. In particular, it details monitoring selection models focusing on those associated with ecology and geomorphology. The paper also considers the requirements of monitoring schemes that will help deliver the goals of the Water Framework Directive (WFD).     

Predicting phosphorus concentrations in British rivers resulting from the introduction of improved phosphorus removal from sewage effluent

Phosphorus (P) concentration and flow data gathered during the 1990s for a range of British rivers were used to determine the relative contributions of point and diffuse inputs to the total P load, using the Load Apportionment Model (LAM). Heavily urbanised catchments were dominated by sewage inputs, but the majority of the study catchments received most of their annual phosphorus load from diffuse sources. Despite this, almost 80% of the study sites were dominated by point source inputs for the majority of the year, particularly during summer periods when eutrophication risk is greatest. This highlights the need to reduce sewage P inputs to improve the ecological status of British rivers. These modelled source apportionment estimates were validated against land-use data and boron load (a chemical marker for sewage).The LAM was applied to river flow data in subsequent years, to give predicted P concentrations (assuming no change in P source inputs), and these estimates were compared with observed concentration data. This showed that there had been significant reductions in P concentration in the River Thames, Aire and Ouse in the period 1999 to 2002, which were attributable to the introduction of P stripping at sewage treatment works (STW). The model was then used to forecast P concentrations resulting from the introduction of P removal at STW to a 2 or 1 mg l^− 1 consent limit. For the urbanised rivers in this study, the introduction of phosphorus stripping to a 1 mg l^− 1 consent level at all STW in the catchment would not reduce P concentrations in the rivers to potentially limiting concentrations. Therefore, further sewage P stripping will be required to comply with the Water Framework Directive. Diffuse P inputs may also need to be reduced before some of the highly nutrient-enriched rivers achieve good ecological status.     

Challenges to the Implementation of the Water Framework Directive in Scotland: A Personal View

The Water Framework Directive was implemented in December 2000 and has to be transposed into Scottish legislation by 2003. The Directive provides a major opportunity to enhance the water environment of Scotland and to improve its management through the implementation of river-basin management planning with stakeholder and public engagement and the delivery of a programme of environmental-improvement measures to deliver good ecological status. Whilst the Directive provides unparalleled opportunities, there are significant challenges to its successful implementation in Scotland, where a step-change in managing the water environment will be required. This paper explores some of the challenges which include technical aspects, scale and timing issues, and capacity limitations.     

Stakeholder involvement and public participation: a critique of Water Framework Directive arrangements in the United Kingdom

Expert consensus regarding public consultation and participation on environmental matters favours a multilevel approach: the process is much more likely to succeed when those consulted can relate to the boundaries, scale and the local nature of the issues. The Water Framework Directive requires those with the responsibility for river basin management planning to engage with stakeholders and the general public when such plans are being developed. Examination of the arrangements for public participation in the regions of the United Kingdom shows a marked variation in the interpretation of the Directive that may leave the general public residing in England and Wales at a significant disadvantage. In both Scotland and Northern Ireland involvement by the general public is planned at a much more local level through groups established specifically for that purpose. Arrangements at local level in England and Wales are focused on narrower existing liaison arrangements in place before the implementation of the Directive.     

Challenges in developing an integrated catchment management model

Directives and policies increasingly call for more integrated management of land and water. Frameworks such as integrated catchment management may address these calls, and yet their implementation requires decisions to be taken under conditions of extreme complexity and uncertainty. This paper summarises a participatory framework through which decision‐makers, experts and system modellers can collaboratively develop an integrated model to support such decisions. A feasibility study showed the potential of the framework. An operational version of the model, able to analyse the effects of 50 management options on 20 indicators, is estimated to require in the order of 225 man‐months from system modellers, alongside substantial inputs from stakeholders. The significant technical challenges confronting such an exercise may be overshadowed by the institutional challenges, including the fundamental question of whether organisations are truly committed. However, the reward for overcoming such challenges is the opportunity to achieve genuine improvements in the social, economic and environmental quality of our catchments.     

Predicting microbial pollution concentrations in UK rivers in response to land use change

The Water Framework Directive has caused a paradigm shift towards the integrated management of recreational water quality through the development of drainage basin-wide programmes of measures. This has increased the need for a cost-effective diagnostic tool capable of accurately predicting riverine faecal indicator organism (FIO) concentrations. This paper outlines the application of models developed to fulfil this need, which represent the first transferrable generic FIO models to be developed for the UK to incorporate direct measures of key FIO sources (namely human and livestock population data) as predictor variables.We apply a recently developed transfer methodology, which enables the quantification of geometric mean presumptive faecal coliforms and presumptive intestinal enterococci concentrations for base- and high-flow during the summer bathing season in unmonitored UK watercourses, to predict FIO concentrations in the Humber river basin district.Because the FIO models incorporate explanatory variables which allow the effects of policy measures which influence livestock stocking rates to be assessed, we carry out empirical analysis of the differential effects of seven land use management and policy instruments (fiscal constraint, production constraint, cost intervention, area intervention, demand-side constraint, input constraint, and micro-level land use management) all of which can be used to reduce riverine FIO concentrations.This research provides insights into FIO source apportionment, explores a selection of pollution remediation strategies and the spatial differentiation of land use policies which could be implemented to deliver river quality improvements.All of the policy tools we model reduce FIO concentrations in rivers but our research suggests that the installation of streamside fencing in intensive milk producing areas may be the single most effective land management strategy to reduce riverine microbial pollution.