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通过热重燃烧实验和煤岩镜质体反射率实验,研究了煤燃烧着火温度、峰值温度和燃尽温度与反映煤变质程度的干燥无灰基挥发分质量分数w(Vdaf)和碳质量分数w(Cdaf)的关系,探讨了燃烧速率峰的相对位置与变质程度的关系.结果表明:在程序升温条件下,煤着火温度随变质程度的加深呈现逐渐升高的趋势,而峰值温度、燃尽温度与着火温度均呈现较好的线性关系,相关系数R2分别为0.961 4和0.956 6;煤燃烧速率峰的相对位置较好地反映了变质程度的高低,变质程度高的煤,其燃烧失重曲线和燃烧速率峰相对位置均处于高温段,变质程度低的煤,其燃烧失重曲线和燃烧速率峰相对位置均位于低温段. 相似文献
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几种生物质的TG-DTG分析及其燃烧动力学特性研究 总被引:13,自引:1,他引:12
采用热重分析技术对木屑、麦秆、玉米秆和玉米芯4种生物质的燃烧特性进行了研究,考察了其着火、燃尽特性和综合燃烧特性,研究了升温速率对生物质燃烧特性的影响,同时在热天平上对其进行了动力学试验研究.研究表明:生物质燃烧过程大致可以分为3个阶段,即水分析出阶段、挥发分析出燃烧阶段、固定碳燃烧与燃尽阶段:生物质具有着火温度低、燃尽温度低、燃尽率高等优点;随着升温速率的提高,着火温度、各试样挥发分最大释放速率、燃尽温度均呈升高趋势,燃烧特性随升温速率的提高而变好.采用一级反应动力学模型和积分法对生物质燃烧动力学参数的研究表明,生物质具有较低的活化能,有利于点燃. 相似文献
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采用热重分析仪研究了不同煤粉在烟气气氛下的燃烧特性,考虑了升温速率和氧气浓度对燃烧特性的影响。研究结果表明:低氧条件、高升温速率下,煤粉的TG、DTG曲线均向高温区靠近,燃烧速率变慢,燃尽时间增长;改变氧气浓度和升温速率对煤的着火温度影响不大,在一定氧浓度(5%~15%)范围内,高水分低阶煤采用烟气干燥输送的制粉系统,能满足其安全性要求;氧气浓度和升温速率主要对煤的燃烧阶段产生影响,随着升温速率的升高和氧浓度的降低,燃尽温度明显升高,且氧浓度对燃烧特征参数的影响大于升温速率的影响。此外,采用Coats-Redfern积分法对煤粉在程序升温过程中的燃烧反应做了相应的动力学分析。结果表明:氧气浓度和升温速率的变化均对活化能产生影响,且随着氧气浓度的降低,煤阶对活化能的影响逐渐减弱。 相似文献
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为了研究分析陕西主要煤种的燃烧特性,采用德国NETZSCH STA-409PC型热重分析仪分析了样品质量、升温速率、粒径对煤粉燃烧特性的影响。实验结果表明,随着粒径的减小,神木烟煤的燃烧性能先增强后变弱,粒径75~90μm左右燃烧特性最好。升温速率、样品质量对煤粉的燃烧特性也有影响。随着升温速率的提高,煤粉的着火温度升高,最大失重速率增大,最大失重速率对应的温度升高;随着质量的增加,煤粉的着火温度略有降低,燃尽温度却逐渐增大,最大失重速率明显增大,放热效应的最大温度点逐渐增大,并且煤粉挥发分燃烧低温放热与固定碳燃烧高温放热有一定的分期。 相似文献
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灰煤混合燃料的燃烧动力学特性研究 总被引:1,自引:0,他引:1
利用TGA/SDTA851e型热重分析仪,对煤及不同灰煤比的混合燃料进行了热失重实验,获得了其热失重特性曲线。采用单个扫描速率的Coats-Redfern法、多重扫描速率的FWO(Flynn-Wall-Ozawa)法和Starink法三种典型的热分析方法求取了各样品的动力学参数。结果表明:随着灰煤比的升高,样品燃烧反应平均过程的活化能增高;灰煤比由0升高到0.15时,样品的活化能、着火温度和燃烬温度变化较大;灰煤比从0.15升高到0.45时,活化能、着火温度和燃烬温度变化较小。同时,通过对比几种分析方法的计算结果,认为采用多重升温速率法求取活化能时要谨慎,建议采用单重升温速率法和多重升温速率法相结合来分析燃料的热解及燃烧机理。 相似文献
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生物油热解及燃烧特性分析 总被引:2,自引:1,他引:1
对由木粉热解所得的生物油样品分别进行了氮气与氧气气氛下不同升温速率的热重分析试验.结果表明:生物油的热解分为两个阶段,第一阶段为生物油中低沸点有机物的挥发以及各组分间反应生成各类产物的过程,第二阶段为各种重组分的裂解过程;生物油的燃烧分为3个阶段,即前期的挥发与裂解和最后焦炭的燃烧过程.提高升温速率使氮气气氛中生物油样品的初始失重温度、失重峰值温度及对应的最大失重速率均有所增大,且在较高升温速率(20℃min)下,较少含炭残余物形成.随升温速率升高,生物油着火温度提高,最终失重率无变化.最后根据热重数据对热解与燃烧各段反应进行了动力学拟合. 相似文献
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《燃烧科学与技术》2017,(6)
通过热重和差示扫描量热(TG-DSC)同步热分析仪在空气气氛条件下研究不同煤阶煤粉的燃烧特性.将煤粉在挥发分燃烧及焦炭燃烧过程分为4个不同的反应区域.研究得出,煤粉低温氧化主要从150~200,℃区段开始显著发生,200,℃之前,不同加热速率下的煤粉低温氧化并无明显区别;随着煤阶的增加,吸氧增重量逐渐降低;煤粉在挥发分燃烧及焦炭燃烧区段内对应的最大热流量均随加热速率的增加而增加,且释热加速度也随之增加;相同加热速率下,煤阶增加导致释热加速度减小.煤粉在高温段氧化最大热流值对应的温度Tmax、着火温度Ti、强着火温度Tig及其他特征温度均随加热速率及煤阶的增加而增加. 相似文献
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《International Journal of Hydrogen Energy》2022,47(63):26789-26797
The issues related to the reliability of hydrogen engines of unmanned vehicles and increasing the efficiency of using hydrogen as fuel when using the method of its production during the decomposition of hydrogen-containing molecules of liquid-phase organic compounds in a plasma discharge under the action of intense ultrasonic exposure are considered. Experiments have shown that as a result of decomposition in the acoustoplasma discharge of liquid hydrocarbons, solid-phase carbon-containing products are formed, chemical transformations occur in the liquid phase and hydrogen-containing combustible gas is formed. Hydrogen-containing gas can be used as fuel immediately after synthesis, i.e. it does not require separation, since in addition to hydrogen it contains only impurities of CO2 and water vapor. The purpose of the study is to formalize the basic conditions for tightening the control of mutual compliance with the efficiency of hydrogen engines of the same series in the conditions of their mass production. Methods of mathematical statistics and hardware-software modeling were used in the study. The term “unerroric of quality mutual compliance control” is introduced to describe a set of hardware and software tools for such control. The principle of in-depth testing of the technical condition of such engines of one series is described in a multidimensional formulation of the quality control problem for three of their operating parameters at once. The conditions for increasing the mutual correspondence of the measured values of such parameters in the conditions of serial production of hydrogen engines are formalized. 相似文献
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基于《水工混凝土掺用氧化镁技术规范》中的Ⅰ型氧化镁(MgO),研究了该型MgO膨胀剂(MEA)细度对掺粉煤灰水泥浆体膨胀性能的影响。即采用X射线衍射分析(XRD)及同步热分析(TG DSC)分析了掺MEA水泥浆体中MgO的水化性。结果表明,养护温度相同时,MEA的细度对水泥浆体内MEA中MgO的水化和水泥浆体的膨胀无显著影响,产生的膨胀均能补偿水泥浆体的收缩;MEA的细度可从试验设计采用的45 μm筛筛余15%左右增加到30%左右,这将有利于MEA生产企业的节能降耗。 相似文献
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Linear and nonlinear analyses of the instabilities and distortion of liquid streams injected into a gaseous media are discussed. The various fundamental mechanisms and the predictive capabilities for the distortions are emphasized. Round jets, planar sheets, annular sheets, and conical sheets are discussed in detail. The balance between capillary and inertial forces is primarily examined. The method for simplifying the analyses in the case of thin liquid sheets is discussed. The capabilities for representing the droplet size distribution that follows the stream disintegration are outlined. 相似文献
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使用ANSYS8.0软件对高速列车车轮进行了三维有限元分析,计算出车轮在直线、曲线和道岔条件下牵引、制动共6种工况时孔边薄弱部位的应力,分别通过Mises等效平均应力方法、Sines平均主应力方法和应力分量中考虑平均应力方法计算出应力在极值位置时的等效应力幅、等效平均应力,从而进一步算出车轮的安全系数,对其疲劳强度进行评定,并对3种方法进行了比较研究。 相似文献
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M.R. Salimpour M. SharifhasanE. Shirani 《International Communications in Heat and Mass Transfer》2011,38(1):93-99
This paper documents the geometric optimization of an array of circular and non-circular ducts. The optimization was carried out numerically using finite volume method. As optimal dimensions were independent of the array configuration, the numerical simulation was performed on a unit cell. Numerical optimization for circular, square and isosceles right triangle cross-sections of channels was performed. Based on the results of this investigation, some correlations were proposed to predict the optimal hydraulic diameter and dimensionless heat transfer per unit volume. In addition to examining the effect of pressure drop on these parameters, it was showed that among the different geometries of this study, square cross-section has the most efficiency for a given volume. The numerical results of the present study were compared with approximate results reported in the literature which a good agreement was observed. 相似文献
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General expressions for the heat of vaporization of mixtures at constant pressure; at constant temperature; and at constant pressure, temperature, and composition are proposed. The last one is related to the liquid-vapor interface where steady vaporization or condensation is taking place. Numerical examples by the proposed expressions are shown for binary mixtures of HCFC22(R22) and (HCFC123(R123) © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(1): 12–24, 1996 相似文献
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本文对漫灰均温物体在常物性条件下对外辐射传热的Yong值计算建立了数学模型。通过与物体内能Yong公式的数值计算比较,得出了辐射能量的Yong值不大于内能Yong值的结论。从初步的热射Yong值计算公式发现。Yong与物体表面辐射率有关。 相似文献