Self‐Propelled Activated Carbon Janus Micromotors for Efficient Water Purification

Self‐propelled activated carbon‐based Janus particle micromotors that display efficient locomotion in environmental matrices and offer effective ‘on‐the‐fly’ removal of wide range of organic and inorganic pollutants are described. The new bubble‐propelled activated carbon Janus micromotors rely on the asymmetric deposition of a catalytic Pt patch on the surface of activated carbon microspheres. The rough surface of the activated carbon microsphere substrate results in a microporous Pt structure to provide a highly catalytic layer, which leads to an effective bubble evolution and propulsion at remarkable speeds of over 500 μm/s. Such coupling of the high adsorption capacity of carbon nanoadsorbents with the rapid movement of these catalytic Janus micromotors, along with the corresponding fluid dynamics and mixing, results in a highly efficient moving adsorption platform and a greatly accelerated water purification. The adsorption kinetics and adsorption isotherms have been investigated. The remarkable decontamination efficiency of self‐propelled activated carbon‐based Janus micromotors is illustrated towards the rapid removal of heavy metals, nitroaromatic explosives, organophosphorous nerve agents and azo‐dye compounds, indicating considerable promise for diverse environmental, defense, and public health applications.     

Sperm‐Driven Micromotors Moving in Oviduct Fluid and Viscoelastic Media

Biohybrid micromotors propelled by motile cells are fascinating entities for autonomous biomedical operations on the microscale. Their operation under physiological conditions, including highly viscous environments, is an essential prerequisite to be translated to in vivo settings. In this work, a sperm‐driven microswimmer, referred to as a spermbot, is demonstrated to operate in oviduct fluid in vitro. The viscoelastic properties of bovine oviduct fluid (BOF), one of the fluids that sperm cells encounter on their way to the oocyte, are first characterized using passive microrheology. This allows to design an artificial oviduct fluid to match the rheological properties of oviduct fluid for further experiments. Sperm motion is analyzed and it is confirmed that kinetic parameters match in real and artificial oviduct fluids, respectively. It is demonstrated that sperm cells can efficiently couple to magnetic microtubes and propel them forward in media of different viscosities and in BOF. The flagellar beat pattern of coupled as well as of free sperm cells is investigated, revealing an alteration on the regular flagellar beat, presenting an on–off behavior caused by the additional load of the microtube. Finally, a new microcap design is proposed to improve the overall performance of the spermbot in complex biofluids.     

Architecting Graphene Oxide Rolled‐Up Micromotors: A Simple Paper‐Based Manufacturing Technology

A graphene oxide rolled‐up tube production process is reported using wax‐printed membranes for the fabrication of on‐demand engineered micromotors at different levels of oxidation, thickness, and lateral dimensions. The resultant graphene oxide rolled‐up tubes can show magnetic and catalytic movement within the addition of magnetic nanoparticles or sputtered platinum in the surface of graphene‐oxide‐modified wax‐printed membranes prior to the scrolling process. As a proof of concept, the as‐prepared catalytic graphene oxide rolled‐up micromotors are successfully exploited for oil removal from water. This micromotor production technology relies on an easy, operator‐friendly, fast, and cost‐efficient wax‐printed paper‐based method and may offer a myriad of hybrid devices and applications.     

Confined Catalytic Janus Swimmers in a Crowded Channel: Geometry‐Driven Rectification Transients and Directional Locking

Self‐propelled Janus particles, acting as microscopic vehicles, have the potential to perform complex tasks on a microscopic scale, suitable, e.g., for environmental applications, on‐chip chemical information processing, or in vivo drug delivery. Development of these smart nanodevices requires a better understanding of how synthetic swimmers move in crowded and confined environments that mimic actual biosystems, e.g., network of blood vessels. Here, the dynamics of self‐propelled Janus particles interacting with catalytically passive silica beads in a narrow channel is studied both experimentally and through numerical simulations. Upon varying the area density of the silica beads and the width of the channel, active transport reveals a number of intriguing properties, which range from distinct bulk and boundary‐free diffusivity at low densities, to directional “locking” and channel “unclogging” at higher densities, whereby a Janus swimmer is capable of transporting large clusters of passive particles.     

Magnetically Powered Shape‐Transformable Liquid Metal Micromotors

Shape‐transformable liquid metal (LM) micromachines have attracted the attention of the scientific community over the past 5 years, but the inconvenience of transfer routes and the use of corrosive fuels have limited their potential applications. In this work, a shape‐transformable LM micromotor that is fabricated by a simple, versatile ice‐assisted transfer printing method is demonstrated, in which an ice layer is employed as a “sacrificial” substrate that can enable the direct transfer of LM micromotors to arbitrary target substrates conveniently. The resulting LM microswimmers display efficient propulsion of over 60 µm s^?1 (≈3 bodylength s^?1) under elliptically polarized magnetic fields, comparable to that of the common magnetic micro/nanomotors with rigid bodies. Moreover, these LM micromotors can undergo dramatic morphological transformation in an aqueous environment under the irradiation of an alternating magnetic field. The ability to transform the shape and efficiently propel LM microswimmers holds great promise for chemical sensing, controlled cargo transport, materials science, and even artificial intelligence in ways that are not possible with rigid‐bodies microrobots.     

Mimicking Bubble Use in Nature: Propulsion of Janus Particles due to Hydrophobic‐Hydrophilic Interactions

Bubbles are widely used by animals in nature in order to fulfill important functions. They are used by animals in order to walk underwater or to stabilize themselves at the water/air interface. The main aim of this work is to imitate such phenomena, which is the essence of biomimetics. Here, bubbles are used to propel and to control the location of Janus particles in an aqueous medium. The synthesis of Janus SiO₂‐Ag and polystyrene‐Ag (PS‐Ag) particles through embedment in Parafilm is presented. The Janus particles, partially covered with catalytically active Ag nanoparticles, are redispersed in water and placed on a glass substrate. The active Ag sites are used for the splitting of H₂O₂ into water and oxygen. As a result, an oxygen bubble is formed on one side of the particle and promotes its propulsion. Once formed, the bubble‐particle complex is stable and therefore, can be manipulated by tuning hydrophilic‐hydrophobic interactions with the surface. In this way a transition between two‐ and three‐ dimensional motion is possible by changing the hydrophobicity of the substrate. Similar principles are used in nature.     

Quasi‐Static Single‐Component Hybrid Simulation of a Composite Structure with Multi‐Axis Control

This paper presents a quasi‐static hybrid simulation performed on a single component structure. Hybrid simulation is a substructural technique, where a structure is divided into two sections: a numerical section of the main structure and a physical experiment of the remainder. In previous cases, hybrid simulation has typically been applied to structures with a simple connection between the numerical model and physical test, e.g. civil engineering structures. In this paper, the method is applied to a composite structure, where the boundary is more complex i.e. 3 degrees of freedom. In order to evaluate the validity of the method, the results are compared to a test of the emulated structure – referred to here as the reference test. It was found that the error introduced by compliance in the load train was significant. Digital image correlation was for this reason implemented in the hybrid simulation communication loop to compensate for this source of error. Furthermore, the accuracy of the hybrid simulation was improved by compensating for communication delay. The test showed high correspondence between the hybrid simulation and the reference test in terms of overall deflection as well as displacements and rotation in the shared boundary.     

Multi‐precision Laplace transform inversion

For the numerical inversion of Laplace transforms we suggest to use multi‐precision computing with the level of precision determined by the algorithm. We present two such procedures. The Gaver–Wynn–Rho (GWR) algorithm is based on a special sequence acceleration of the Gaver functionals and requires the evaluation of the transform only on the real line. The fixed Talbot (FT) method is based on the deformation of the contour of the Bromwich inversion integral and requires complex arithmetic. Both GWR and FT have only one free parameter: M, which is the number of terms in the summation. Both algorithms provide increasing accuracy as M increases and can be realized in a few lines using current Computer Algebra Systems. Copyright © 2004 John Wiley & Sons, Ltd.     

Light‐Driven ZnO Brush‐Shaped Self‐Propelled Micromachines for Nitroaromatic Explosives Decomposition

Self‐propelled micromachines have recently attracted lots of attention for environmental remediation. Developing a large‐scale but template‐free fabrication of self‐propelled rod/tubular micro/nanomotors is very crucial but still challenging. Here, a new strategy based on vertically aligned ZnO arrays is employed for the large‐scale and template‐free fabrication of self‐propelled ZnO‐based micromotors with H₂O₂‐free light‐driven propulsion ability. Brush‐shaped ZnO‐based micromotors with different diameters and lengths are fully studied, which present a fast response to multicycles UV light on/off switches with different interval times (2/5 s) in pure water and slow directional motion in aqueous hydrogen peroxide solution in the absence of UV light. Light‐induced electrophoretic and self‐diffusiophoretic effects are responsible for these two different self‐motion behaviors under different conditions, respectively. In addition, the pH of the media and the presence of H₂O₂ show important effects on the motion behavior and microstructure of the ZnO‐based micromotors. Finally, these novel ZnO‐based brush‐shaped micromotors are demonstrated in a proof‐of‐concept study on nitroaromatic explosive degradation, i.e., picric acid. This work opens a completely new avenue for the template‐free fabrication of brush‐shaped light‐responsive micromotors on a large scale based on vertically aligned ZnO arrays.     

Multi‐scale methods

In this paper four multiple scale methods are proposed. The meshless hierarchical partition of unity is used as a multiple scale basis. The multiple scale analysis with the introduction of a dilation parameter to perform multiresolution analysis is discussed. The multiple field based on a 1‐D gradient plasticity theory with material length scale is also proposed to remove the mesh dependency difficulty in softening/localization problems. A non‐local (smoothing) particle integration procedure with its multiple scale analysis are then developed. These techniques are described in the context of the reproducing kernel particle method. Results are presented for elastic‐plastic one‐dimensional problems and 2‐D large deformation strain localization problems to illustrate the effectiveness of these methods. Copyright © 2000 John Wiley & Sons, Ltd.     

Ultrafast Growth and Locomotion of Dandelion‐Like Microswarms with Tubular Micromotors

Dynamic assembly and cooperation represent future frontiers for next generations of advanced micro/nano robots, but the required local interaction and communication cannot be directly translated from macroscale robots through the minimization because of tremendous technological challenges. Here, an ultrafast growth and locomotion methodology is presented for dandelion‐like microswarms assembled from catalytic tubular micromotors. With ultrasound oscillation of self‐generated bubbles, such microswarms could overcome the tremendous and chaotic drag force from extensive and disordered bubble generation in single units. Tubular MnO₂ micromotor individuals headed by self‐generated oxygen bubbles are ultrasonically driven to swim rapidly in surfactant‐free H₂O₂ solutions. A large bubble core fused from multiple microbubbles is excited to oscillate and the resultant local intensified acoustic field attracts the individual micromotors to school around it, leading to a simultaneous growth of dandelion‐like microswarms. The bubble‐carried micromotor groups driven by ultrasound could swarm at a zigzag pattern with an average speed of up to 50 mm s^?1, which is validated in low H₂O₂ concentrations. Additionally, such superfast locomotion could be ultrasonically modulated on demand. The ultrafast microswarm growth and locomotion strategy offers a new paradigm for constructing distinct dynamic assemblies and rapid transmission of artificial microrobots, paving the way to a myriad of promising applications.