Alternative and low sulfur fuel options: boundary lubrication performance and potential problems

Studies of alternative fuels at Penn State include biodiesel, dimethyl ether (DME) and low sulfur diesel fuels. The fuel studies include bench tests, laboratory engine tests and vehicle tests. DME was evaluated in a campus shuttle bus operating on its regular campus route. A 25:75 vol% mixture of DME and diesel fuel was used. Laboratory engine tests of oxygenated fuels, including biodiesel, resulted in significant particulate reductions. However, some alternative fuels exhibit low lubricity. Bench tests comparing friction and wear characteristics of the fuels are described.     

Pretreatment methods to improve the kinematic viscosity of biodiesel for use in power tiller engines

Biodiesel is an environmentally friendly fuel that can replace diesel in compression ignition engines without changing the engine structure. Biodiesel is typically manufactured from vegetable oils and animal fats, which give the fuel its oxidation stability and cold-flow properties, respectively. However, the kinematic viscosity of biodiesel can cause engine performance problems such as incomplete combustion and sludge formation due to insufficient fuel atomization. To address these problems, in this study, a pretreatment technology that lowers the kinematic viscosity of biodiesel made from blended animal fat and vegetable oil was developed. The results of application of the pretreated fuel to a single-cylinder power tiller engine indicated that it produced 88.3–99.8 % of the brake power produced by conventional diesel. In addition, although the pretreated biodiesel exhaust included increased amounts of nitrogen oxides and carbon dioxide emissions, the proposed fuel also decreased the amounts of hydrocarbon and carbon monoxide emissions compared with conventional diesel emissions.

     

车用柴油机瞬态工况的排气颗粒数量

以一台轻型车用柴油机为样机,研究发动机定转速增转矩瞬态工况下的颗粒数量排放。所用燃料为纯柴油、纯生物柴油、B20和B50燃油。结果表明:瞬态工况期间,该机燃用柴油的核态颗粒数上升,且先缓后急;聚集态颗粒数由于瞬态工况初期进气滞后,呈先增后降的特点。总颗粒数整体上升,瞬态过程初期聚集态颗粒数起主要作用,而中后期核态颗粒数占主导地位。B20燃油的颗粒数动态变化特性与柴油类似;B50燃油和纯生物柴油的颗粒数动态特性与柴油差异较大,其中总颗粒数和核态颗粒数始终明显高于柴油,聚集态颗粒一直低于柴油,表明此时核态颗粒数在总颗粒数中的支配地位。纯生物柴油在该瞬态工况初期聚集态颗粒数就持续下降,而核态颗粒数快速上升并持续到工况过渡结束。     

Combustion characteristics of an agricultural diesel engine using biodiesel fuel

Biodiesel has great potential as an alternative fuel for diesel engines that would reduce air pollution. It is a domestically produced, renewable fuel that can be manufactured from fresh or used vegetable oils, or from animal fats. In this study, a biodiesel fuel derived from rice bran oil was tested as an alternative fuel for agricultural diesel engines. The emissions were characterized for both neat and blended biodiesel fuels, and for conventional diesel fuel. Since this biodiesel fuel contained 11% oxygen, it strongly influenced the combustion process. The use of biodiesel fuel resulted in lower carbon monoxide, carbon dioxide, and smoke emissions, without any increase in nitrous oxide emissions. The study demonstrated that biodiesel fuel could be effectively used as a renewable and environmentally innocuous fuel for agricultural diesel engines.     

Investigation of the effects of steam injection on the emissions and performance of a diesel engine using waste chicken oil methyl ester

The use of biodiesel-blended fuels in diesel engines improves the engine performance parameters and the partial recovery of incomplete combustion products, while also increasing the level of NOx emissions. In this study; biodiesel obtained through the transesterification of waste chicken frying oil was mixed with diesel fuel (90% diesel + 10% biodiesel-B10), and was then used as fuel in a direct injection diesel engine. To reduce the increased NOx emissions caused by the use of B10 fuel, the steam injection method (which is one of the NOx reduction methods) was applied. Steam was injected into the intake manifold at different ratios (5%-S5, 10%-S10 and 15%-S15) and at the time of the induction stroke with the aid of an electronically controlled system. Based on the study results, it was observed that steam injection into the engine using B10 fuel improved both the engine performance and the exhaust emission parameters. It was determined that the S15 steam injection ratio resulted in the best engine performance and emissions parameters. In comparison to STD fuel; the highest increase observed at the S15 steam injection ratio in the effective engine power was 2.2%, while the highest decrease in the specific fuel consumption was 3.4%, the highest increase in the effective efficiency was 3.5%, and the highest decrease in NOx emissions was 13.7%.

     

Investigation of combustion and emission characteristics of n-hexane and n-hexadecane additives in diesel fuel

One of the most important basic requirements of diesel-powered vehicles that they have lower pollutant emissions and fuel consumption. In diesel engines, combustion and engine performance are influenced by the physical and chemical properties of the used fuel. Engine design studies are not enough to increase engine performance and reduce exhaust emissions alone. By adding fuel additives in diesel fuel, the physical and chemical properties of the fuel can be improved. Fuel additives affect engine performance, combustion and emissions positively by exerting catalyst effect during combustion. In this study, n-hexane and n-hexadecane were added in diesel fuel (D0) by volume of 4, 12 % and 20 %. With respect to D0 fuel, in DHD20 and DHX20 fuels engine torque increased by 1.60 % and 1.32 %, respectively, while the brake specific fuel consumption decreased by 3.12 % and 1.98 %, respectively. Maximum cylinder pressures and heat release rate values of the ingredient added fuels increased. It was seen that NO_x emissions increased while HC, CO and soot emissions decreased with increasing contribution ratio.

     

The effect of biodiesel and ultra low sulfur diesel fuels on emissions in 11,000 CC heavy-duty diesel engine

It seems very difficult to comply with upcoming stringent emission standards in vehicles To develop low emission engines, better quality of automotive fuels must be achieved Since sulfur contents in diesel fuels are transformed to sulfate—laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied In general, flash point, distillation 90% and cetane index are improved but viscosity can be worse in the process of desulfunzation of diesel fuel Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio—diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels     

Study of performance and emission characteristics of IC engines by using diesel–water emulsion

Due to the shortage of petroleum products and its increasing cost, efforts are on to develop alternate fuels, especially diesel oil, for partial or full replacement. Also, internal combustion engines generate undesirable emissions during combustion process. The emissions exhausted in to the surroundings pollute the atmosphere and causes several problems. The emissions of concern are: unburnt hydrocarbons, oxides of carbon, and oxides of nitrogen (NO_X). Advanced diesel fuel formulations offer significant emission reductions to new and older in-use engines every time the fuel tank is filled. The addition of water to diesel fuel lowers particulate emissions by serving as diluents to the key combustion intermediates that lead to particulate formation. The incorporation of water also reduces NO_X emissions by lowering the peak combustion temperatures through high heat of vaporization. When using water blend diesel, the engine fuel system recognizes the liquid as diesel fuel because the water droplet is encapsulated within a diesel fuel. In this experiment, we have used single cylinder four-stroke engine and the water-blend diesel emulsion is used and the diesel emission test, emulsion emission test, and various gases has been analyzed; smoke meter test is also conducted for various rate of loads. The test results from the engine fuelled with water-blend diesel showed reduction in emissions as compared to that of engine fuelled with conventional diesel. The better emissions in the CI engine using water-blend diesel is due to the incorporation of water which reduces NO_X emissions by lowering the peak combustion temperatures. Water-blend fuel enhances fuel atomization by micro-explosion. The addition of water to diesel fuel lowers particulate emissions by serving as diluents to the key combustion intermediates that lead to particulate formation     

Performance and emission characteristics of conventional engine running on jatropha oil

A number of studies have recently been conducted to determine a suitable alternative fuel for conventional engine. The use of renewable fuels such as bio-ethanol, biogas, and biodiesel is thus investigated for this purpose. Performance tests were conducted on an indirect injection compression ignition engine by using diesel, unheated jatropha oil (JO), and preheated JO as fuels. The effects of fuel injection pressure and fuel inlet temperature on engine performance and emission for the different fuels were analyzed. Test results showed that the brake thermal efficiency of the engine with heated JO oil is superior to that with unheated JO, increasing from 28.4% with neat unheated JO to a maximum of 30.8%. The brake specific fuel consumption was reduced from 0.301 kg/kWh to 0.266 kg/kWh. Smoke opacity was also reduced relative to the neat unheated JO operation.     

Size distributions and number concentrations of particles from the DOC and CDPF

Particulate matters (PM) from diesel combustion comprise the major portion of harmful components of air in urban areas. In this study, the effects of DOC and/or CDPF on the size distributions and catalytic reactions of these nano-sized particles were investigated to clarify the exhaust mechanism and to minimize the emission of the nano-sized PM. Parameters of interest in the investigation included sulfur content of the fuels used, air-fuel equivalence ratio, fuel injection pressure, and the engine speed. The number concentration of the particles in diluted exhaust gas was measured by a SMPS in the diametric range of 10–385 nm. The number of nanometer-sized particles increased when the engine was operated at high equivalence ratio with diesel fuel that contained 500 ppm of sulfur. As the sulfur concentration in the fuel increased, the number of the particles smaller than 30 nm increased upon passing DOC and CDPF in the exhaust system of the common-rail diesel engine.     

发动机燃用生物柴油的颗粒可溶有机组分及多环芳烃排放

以一台车用柴油机为样机,研究发动机燃用生物柴油的常规排放,重点探讨其颗粒(Particulate matter,PM)、可溶有机组分(Soluble organic fraction,SOF)及多环芳烃(Polycyclic aromatic hydrocarbons,PAHs)的排放特性。所用燃油分别为柴油、生物柴油掺混配比为10%的B10燃油。结果表明,与柴油相比,该车用柴油机燃用B10燃油后颗粒、SOF和PAHs的质量排放均有所降低;NOx排放略有增加,HC和CO排放有所下降。B10燃油燃烧的颗粒SOF中醇类、酮类、醚类质量分数下降;脂类、酸类、醛类质量分数上升。在检测到的12种PAHs中,B10燃油有10种质量排放减少,尤其是苯并(a)芘等高环数致癌性的PAHs降幅明显,这表明发动机燃用生物柴油后,排气颗粒的化学成分毒性有所降低。     

GC-MS-SIM检测糕点中的防腐剂和抗氧化剂

利用气相色谱-离子阱质谱联用仪和选择离子监测（SIM）技术建立了同时检测糕点制品面包、蛋糕、月饼中7种防腐剂（山梨酸、苯甲酸、脱氢乙酸、对羟基苯甲酸甲酯、对羟基苯甲酸乙酯、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯）和3种抗氧化剂（叔丁基对苯二酚、叔丁基羟基茴香醚、2,6-二叔丁基对甲酚）的方法。优化了色谱、质谱仪器参数。根据10种添加剂的特征离子峰进行定性定量,方法学数据良好。10种添加剂的检出限分别为0.10、0.050、0.015、0.038、0.025、0.019、0.036、0.060、0.050、0.060mg/kg;精密度为2.2%～5.5%;回收率为81%～98%。将本法应用于糕点中食品添加剂的检测,效果良好,检测效率大大提高。     

A study on the usability of biodiesel fuel derived from rice bran oil as an alternative fuel for IDI diesel engine

The world is faced with a problem of air pollution due to the exhaust emissions from automobile. Recently, lots of researchers have been attracted to develope various alternative fuels and to use renewable fuels as a solution of these problems. There are many alternative fuels studied in place of diesel fuel made from petroleum. Biodiesel fuel (BDF) is a domestically produced, renewable fuel that can be manufactured from vegetable oils, used vegetable oils, or animal fats. In this study, the usability of BDF, one of the oxygenated fuels as an alternative fuel for diesel engines was investigated in an IDI diesel engine. Emissions were characterized with a neat BDF and with a blend of BDF and conventional diesel fuel. Since the BDF includes oxygen of about 11%, it could influence the combustion process strongly. Therefore, the use of BDF resulted in lower emissions of carbon monoxide and smoke emissions with some increase in emissions of oxides of nitrogen. It is concluded that BDF can be utilized effectively as a renewable fuel for IDI diesel engines.     

Comparison of the Effects of Biodiesel and Mineral Diesel Fuel Dilution on Aged Engine Oil Properties

Dilution of engine oil occurs when fuel is injected late in the combustion cycle to regenerate the diesel particulate filter used for trapping particulate emissions. Fuel dilution reduces oil viscosity and the concentration of engine oil additives, potentially compromising lubricant performance. Biodiesel usage may compound these issues due to its oxidative instability, and its higher boiling point compared to mineral diesel potentially causes it to concentrate more in the oil sump.

In this work, different amounts of mineral diesel and biodiesel (soy methyl ester, SME) were combined with 15W-40 CJ-4 diesel engine oil in laboratory oil aging experiments. Fuel was added and oil samples were withdrawn at periodic intervals. The oils were analyzed using typical oil analysis procedures to determine their condition, and wear evaluations under boundary lubricating conditions were determined using a high-frequency reciprocating rig (HFRR). Results showed that fuel dilution accelerated engine oil degradation, with biodiesel having a larger effect. However, friction remained unchanged with dilution, and wear actually decreased for fuel-diluted oils after 48 h of aging compared to aging without fuel dilution. Examination of the tribofilms by ultraviolet (UV) and visible Raman spectroscopy as well as Auger electron spectroscopy showed that additional carbon-containing components were present on tribofilms formed from fuel-diluted oils. These fuel-derived components may be responsible for the decreased wear observed.     

EFFECTS OF COOLED EXTERNAL EXHAUST GAS RECIRCULATION ON DIESEL HOMOGENEOUS CHARGE COMPRESSION IGNITION ENGINE

The effects of cooled external exhaust gas recirculation (EGR) on the combustion and emission performance of diesel fuel homogeneous charge compression ignition (HCCI) are studied. Homogeneous mixture is formed by injecting fuel in-cylinder in the negative valve overlap (NVO) period. So, the HCCI combustion which has low NOx and smoke emission is achieved. Cooled external EGR can delay the start of combustion effectively, which is very useful for high cetane fuel (diesel) HCCI, because these fuels can easily self-ignition, which makes the start of combustion more early. External EGR can avoid the knock combustion of HCCI at high load which means that the EGR can expand the high load limit. HCCI maintains low smoke emission at various EGR rate and various load compared with conventional diesel engine because there is no fuel-rich area in cylinder..     

不同甲醇预混合气引燃燃烧模式燃烧特性分析

针对甲醇、生物柴油和聚甲氧基二甲醚PODE的优势,为了改善经济性,在一台CY25柴油机上分析不同引燃燃料对甲醇预混合气引燃燃烧模式燃烧特性的影响。试验结果表明:PODE引燃模式的排放特性较差,CO浓度相较生物柴油模式可高达2-3倍。在大甲醇质量比下HC排放浓度可高达生物柴油的5倍。甲醇质量比较小时促进了NO_(X)生成,增大质量比可以降低NO_(X)浓度。生物柴油引燃模式的排放特性随甲醇质量比变化较平稳,PODE引燃模式则随甲醇质量比变化增长较快。     

An experimental study on the performance and emission characteristics of a CI engine fuelled with Jatropha biodiesel and its blends with diesel

The performance and emission characteristics of a compression ignition engine using mixture of jatropha biodiesel and mineral diesel have been experimentally investigated. It is observed that brake specific fuel consumption increases with higher percentage of biodiesel in the blends. Brake thermal efficiency decreases with the increased percentage of biodiesel in the blends. The maximum efficiency is found to be 29.6% with pure diesel and 21.2% with pure biodiesel. Carbon mono-oxide and hydrocarbon emissions are improved with the addition of biodiesel to diesel. NO_x emission is found to be increased with pure biodiesel by 24% compared to mineral diesel.     

Performance and combustion characteristics of a diesel engine with titanium oxide coated piston using Pongamia methyl ester

Owing to the increasing cost of petroleum products, fast depletion of fossil fuel, environmental consideration and stringent emission norms, it is necessary to search for alternative fuels for diesel engines. The alternative fuel can be produced from materials available within the country. Though the vegetable oils can be fuelled for diesel engines, their high viscosities and low volatilities have led to the investigation of its various derivatives such as monoesters, known as bio diesel. It is derived from triglycerides (vegetable oil and animal fates) by transesterification process. It is biodegradable and renewable in nature. Biodiesel can be used more efficiently in semi adiabatic engines (Semi LHR), in which the temperature of the combustion chamber is increased by thermal barrier coating on the piston crown. In this study, the piston crown was coated with ceramic material (TiO₂) of about 0.5 mm, by plasma spray method. In this present work, the experiments were carried out with of Pongamia oil methyl (PME) ester and diesel blends (B20 & B100) in a four stroke direct injection diesel engine with and without coated piston at different load conditions. The results revealed 100% bio diesel, an improvement in brake thermal efficiency (BTE) and the brake specific fuel consumption decreased by about 10 % at full load. The exhaust emissions like carbon monoxide (CO) and hydrocarbon (HC) were decreased and the nitrogen oxide (NO) emission increased by 15% with coated engine compared with the uncoated engine with diesel fuel. The peak pressure and heat release rate were increased for the coated engine compared with the standard engine.     

Influence of compression ratio on combustion characteristics of a VCR engine using Calophyllum inophyllum biodiesel and diesel blends

The standard configuration parameters of a Variable compression ratio (VCR) engine neglect to give specific execution with biodiesel from distinctive origins. Alongside, a bunch of exploration of diversified biodiesel over performance and emission analysis, extremely constrained work has been taken out on combustion analysis with VCR. This survey was performed to identify the impact of compression ratio on the combustion characteristics of a diesel engine fueled with Calophyllum inophyllum oil methyl ester (COME) and its blends with diesel. Experiments were conducted at a fixed speed of 1500 RPM, full load and at different compression ratios of 16:1, 17:1 and 18:1. Results, revealed that combustion duration of Calophyllum inophyllum oil was more, while the ignition delay period was shorter than that of diesel.     

Biodiesel production process optimization from Spirulina maxima microalgae and performance investigation in a diesel engine

Biodiesel is a renewable, easily biodegradable, eco-friendly and sustainable alternative energy source. In this investigation, crude oil was extracted from Spirulina maxima microalgae through biochemical conversion method with the help of soxhlet apparatus. Biodiesel production process parameters were optimized through base transesterification. Maximum biodiesel yield achieved was 87.75 % at optimal reaction condition after transesterification, when methanol to oil ratio was 6:1, catalyst loading was 1 % KOH (wt.%), temperature was 65 °C, and stirring speed was 600 rpm for a reaction time of 70 minutes. All the physicochemical properties of the produced biodiesel were determined and compared with the ASTM D6751 specification. Finally, performance and emission of an unmodified diesel engine was evaluated with 20 % and 40 % (v/v) biodiesel blends and compared the results with ordinary Diesel fuel (DF). Using biodiesel blends improves Hydrocarbon (HC) emission by 10-15 % and Carbon monoxide (CO) emission by 9.3-13.9 %. However, Brake specific fuel consumption (BSFC), Oxides of nitrogen (NOX), Carbon dioxide (CO₂) and smoke opacity were found to be slightly higher for biodiesel blends, and Brake thermal efficiency (BTE) was found slightly lower than DF. Thus, Spirulina maxima serves as a potential feedstock for biodiesel production and prospective fuel in diesel engine application.