Pool boiling characteristics of low concentration nanofluids

The pool boiling behavior of low concentration nanofluids (?1 g/l) was experimentally studied over a flat heater at 1 atm. Boiling of nanofluids produces a thin nanoparticle film, on the heater surface, which in turn is believed to increase the critical heat flux. The present study also indicates that the nanoparticle deposition results in transient characteristics in the nucleate boiling heat transfer. Finally, this study investigates possible causes responsible for the deposition of nanoparticle on the heater surface. Experimental evidence shows that microlayer evaporation, during nanofluid boiling, is responsible for the nanoparticle coating formed on the heater surfaces.     

Boiling time effect on CHF enhancement in pool boiling of nanofluids

Using TiO₂–water nanofluids as the test liquid, pool boiling experiments were carried out to investigate the dependence of the nucleate boiling heat transfer, surface wettability and critical heat flux (CHF) on the boiling time in nanofluids. In the experiments performed at sufficiently high nanoparticle concentrations, the boiling heat transfer first degraded, then improved, and finally reached an equilibrium state. It was hence supposed that the present nanofluids had competing effects to deteriorate and enhance the nucleate boiling heat transfer. As for the surface wettability and CHF, the static contact angle asymptotically decreased whilst the CHF asymptotically increased with an increase in the boiling time. The maximum CHF enhancement measured in the present experiments was 91%, and strong correlation was found between the contact angle and the CHF. Although the boiling time needed to achieve the maximum CHF enhancement was less than a minute at high particle concentrations, a longer time of the order of 1 h was necessary at the lowest particle concentration tested in this work. This experimental result indicated that sufficient attention should be paid to the boiling time effect particularly in industrial applications of nanofluids to emergency cooling.     

Surface effects of ribbon heaters on critical heat flux in nanofluid pool boiling

This paper deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using Nichrome wires and ribbons. Previously the current authors and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions, cross-sectional shapes as well as surface modifications on pool boiling heat transfer characteristics of water and water-based nanofluids. Our data suggest that the CHF and BHF decrease as heater surface area increases. For concentrations from 0.1 vol% to 2 vol%, the deposition of the particles on the wire allows high heat transfer through inter-agglomerate pores, resulting in a nearly 3-fold increase in burnout heat flux at very low concentrations. The nanoparticle deposition plays a major role through variation in porosity. The CHF enhancement is non-monotonic with respect to concentration. As the concentration is increased, the CHF and BHF decrease prior to increasing again at higher concentrations. Results show a maximum of 270% CHF enhancement for ribbon-type heaters. The surface morphology of the heater was investigated using SEM and EDS analyses, and it was inferred that the 2 vol% concentration deposition coating had higher porosity and rate of deposition compared with 0.2 vol% case.     

Stabilizer effect on CHF and boiling heat transfer coefficient of alumina/water nanofluids

We measured the critical heat flux (CHF) and boiling heat transfer coefficient (BHTC) of water-based Al₂O₃ (alumina) nanofluids. To elucidate the stabilizer effect on CHF and BHTC of alumina/water nanofluids, a polyvinyl alcohol (PVA) was used as a stabilizer. The plate copper heater (10 × 10 mm²) is used as the boiling surface and the concentration of alumina nanoparticle varies 0–0.1 vol.%. The results show that the BHTC of the nanofluids becomes lower than that of the base fluid as the concentration of nanoparticles increases while CHF of it becomes higher. It is found that the increase of CHF is directly proportional to the effective boiling surface area and the reduction of BHTC is mainly attributed to the blocking of the active nucleation cavity and the increase of the conduction resistance by the nanoparticle deposition on the boiling surface.     

Effect of surface particle interactions during pool boiling of nanofluids

The pool boiling characteristics of nanofluids is affected by the relative magnitudes of the average surface roughness and the average particle diameter. In the present work, an attempt has been made to study the interactions between the nanoparticles and the heater surface. The experimental methodology accounts for the transient nature of the boiling phenomena. The boiling curves of electro-stabilized Al₂O₃ water-based nanofluids at different concentrations on smooth and rough heaters and the burn-out heat flux have been obtained experimentally. Extensive surface profile characterization has been done using non-intrusive optical measurements and atomic force microscopy. A measure of the surface wettability has been obtained by determining the advancing contact angle. These results give an insight into the relative magnitudes of dominance of the prevalent mechanisms under different experimental conditions. Boiling on nanoparticle coated heaters has been investigated and presented as an effective solution to counter the disadvantageous transient boiling behavior of nanofluids.     

Pool boiling characteristics of nanofluid on flat plate based on heater surface analysis

Nucleate pool boiling of Al₂O₃ based aqueous nanofluid on flat plate heater has been studied experimentally. For boiling of nanofluid (< 0.1 vol.%) on heating surface with ratio of average surface roughness to average diameter of particles much less than unity when boiling continue to CHF, the heat transfer coefficient of nanofluid boiling reduces while critical heat flux (CHF) increases. CHF enhancement increased with volume fraction of nanoparticles. Atomic force microscope (AFM) images from boiling surface showed that after boiling of nanofluid the surface roughness increases or decreases depending on initial condition of heater surface. Changes in boiling surface topology during different regions of boiling, wettability and thermal resistance of heater surface owing to nanoparticles deposition cause to variations in nanofluids boiling performance.     

Nucleate pool boiling heat transfer of TiO2–R141b nanofluids

Nucleate pool boiling heat transfer of a refrigerant-based-nanofluid was investigated at different nanoparticle concentrations and pressures. TiO₂ nanoparticles were mixed with the refrigerant HCFC 141b at 0.01, 0.03 and 0.05 vol%. The experiment was performed using a cylindrical copper tube as a boiling surface. Pool boiling experiments of nanofluid were conducted and compared with that of the base refrigerant. The results indicate that the nucleate pool boiling heat transfer deteriorated with increasing particle concentrations, especially at high heat fluxes. At 0.05 vol%, the boiling heat transfer curves were suppressed. At high pressures of 400 and 500 kPa, the boiling heat transfer coefficient at a specific excess temperature was almost the same.     

Preparation and pool boiling characteristics of copper nanofluids over a flat plate heater

The copper nanoparticles of average size of 10 nm have been prepared by the sputtering method and characterized through atomic force microscopy (AFM), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The pool boiling heat transfer characteristics of 0.25%, 0.5% and 1.0% by weight concentrations of copper nanoparticles has been studied. Different copper based nanofluids were prepared in both, distilled water and distilled water with 9.0 wt% of sodium lauryl sulphate anionic surfactant (SDS). The pool boiling heat transfer data were acquired for the boiling of nanofluids over a 30 mm square and 0.44 mm thick stainless steel plate heater. The experimental results show that for the critical heat flux of pure water is 80% higher than that of water–surfactant fluid. Also, it was found that the critical heat flux for 0.25%, 0.5% and 1.0% concentrations of copper nanoparticles in copper–water nanofluids are 25%, 40% and 48% higher than that of pure water. But in the case of copper–water with surfactant nanofluids comparing with pure water, the CHF decreases to 75%, 68%, and 62% for respective concentrations of copper nanoparticles. The heat transfer coefficient decreases with increase of nanoparticles concentration in both water–copper and water–copper with surfactant nanofluids.     

An Experimental Investigation of Nucleate Pool Boiling Heat Transfer of Nanofluids From a Hemispherical Surface

An experimental investigation of nucleate pool boiling heat transfer is carried out using SiO₂ nanofluid in atmospheric pressure and saturated conditions. The results show that the nucleate boiling heat transfer coefficient (HTC) of the nanofluids is lower than that of deionized water, especially in high heat fluxes. In addition, the experimental results indicate that the critical heat flux (CHF) improves up to 45% with the increase of the nanoparticle volume concentration. Atomic force microscopy images from the boiling surface reveal that the nanoparticles are deposited on the heating surface during the nanofluid pool boiling experiments. It is found that the boiling HTC deteriorates as a result of the reduction in active nucleation sites and the formation of extra thermal resistance due to blocked vapor in the porous structures near the heating surface. Furthermore, the improvement of the surface wettability causes an increase in CHF. Based on the experimental investigations, it can be concluded that the changes in the properties of the boiling surface are mainly responsible for the variations in nanofluids boiling performance.     

Enhancing the onset of pool boiling by wettability modification on nanometrically smooth surfaces

Pool boiling experiments are performed with degassed water on highly smooth surfaces of two different wettabilities: hydrophilic and hydrophobic cases. Boiling curves and visual observations on the boiling have been performed. The onset of nucleate boiling (ONB) has been measured and the influence of the wettability has been quantified. As the inherent mean roughness of the glass substrates was lower than one nanometer it was possible to show the sole effect of the wettability. No hysteresis in the boiling curve was observed for both cases. The ONB was observed after 3.5 °C superheat on the hydrophobic case and the heat transfer coefficient (HTC) changed suddenly from the one of a convection regime (1.5 kW/m² K) to the one of a nucleate boiling regime (4 kW/m² K). On the contrary for the hydrophilic case, despite superheat above 37 °C and presence of boiling, the HTC was kept as the one of the convection regime.     

Pool boiling characteristics of multiwalled carbon nanotube (CNT) based nanofluids over a flat plate heater

This paper is mainly concerned about the pool boiling heat transfer behavior of multi-walled carbon nanotubes (CNTs) suspension in pure water and water containing 9.0% by weight of sodium lauryl sulphate anionic surfactant (SDS). Three different concentrations of 0.25%, 0.5% and 1.0% by volume of CNT dispersed with water and water containing 9.0% by weight of sodium lauryl sulphate anionic surfactant (SDS) were prepared and boiling experiments were conducted over a stainless steel flat plate heater of size 30 mm² and 0.44 mm thickness. The test results exhibit that the addition of carbon nanotubes increases boiling heat transfer coefficients of the base fluids. At a given heat flux of 500 kW/m², the enhancement of heat transfer coefficient was found to be 1.5, 2.6 and 3.0 times of water corresponding to 0.25%, 0.5% and 1.0% concentration of CNT by volume in water, respectively. In water–CNT–surfactant nanofluid, it was found that 0.5% of CNT concentration gives the highest enhancement of 1.7 compared with water. In both water and water–surfactant base fluids, it was observed that the enhancement factor for 0.25% of CNT first increases up to the heat flux of 66 kW/m² and then decreases for higher heat fluxes. Further, the overall heat transfer coefficient enhancement in the water–CNT nanofluids is approximately two times higher than that in the water–CNT–surfactant nanofluids. With increasing heat flux, however, the enhancement was concealed due to vigorous bubble generation for both water–CNT and water–CNT–surfactant nanofluids. Foaming was also observed over the liquid-free surface in water–CNT–surfactant nanofluids during the investigation. No fouling over the test-section surface was observed after experimentation.     

Effect of nanoparticle size on nucleate pool boiling heat transfer of refrigerant/oil mixture with nanoparticles

Effect of nanoparticle size on nucleate pool boiling heat transfer of refrigerant/oil mixture with nanoparticles was investigated experimentally. For the preparation of the test fluid, refrigerant R113, ester oil VG68, and Cu nanoparticles with three different average diameters of 20, 50 and 80 nm were used. Experimental conditions include a saturation pressure of 101.3 kPa, heat fluxes from 10 to 80 kW m^?2, nanoparticle concentrations in the nanoparticles/oil suspension from 0 to 30 wt%, and nanoparticles/oil suspension concentrations from 0 to 5 wt%. The experimental results indicate that the nucleate pool boiling heat transfer coefficient of R113/oil mixture with Cu nanoparticles is enhanced by a maximum of 23.8% with the decrease of nanoparticle size from 80 to 20 nm under the present experimental conditions, and the enhancement increases with the decrease of nanoparticles/oil suspension concentration or the increase of nanoparticles concentrations in the nanoparticles/oil suspension. A general nucleate pool boiling heat transfer coefficient correlation for refrigerant/oil mixture with nanoparticles is proposed, and it agrees with 93% of the existing experimental data of refrigerant/oil mixture with nanoparticles within a deviation of ±20%.     

Sorption and agglutination phenomenon of nanofluids on a plain heating surface during pool boiling

The pool nucleate boiling heat transfer experiments of water (H₂O) based and alcohol (C₂H₅OH) based nanofluids and nanoparticles-suspensions on the plain heated copper surface were carried out. The study was focused on the sorption and agglutination phenomenon of nanofluids on a heated surface. The nanofluids consisted of the base liquid, the nanoparticles and the surfactant. The nanoparticles-suspensions consisted of the base liquid and nanoparticles. The both liquids of water and alcohol and both nanoparticles of CuO and SiO₂ were used. The surfactant was sodium dodecyl benzene sulphate (SDBS). The experimental results show that for nanofluids, the agglutination phenomenon occurred on the heated surface when the wall temperature was over 112 °C and steady nucleated boiling experiment could not be carried out. The reason was that an unsteady porous agglutination layer was formed on the heated surface. However, for nanoparticles-suspensions, no agglutination phenomenon occurred on the heating surface and the steady boiling could be carried out in the whole nucleate boiling region. For the both of alcohol based nanofluids and nano-suspensions, no agglutination phenomenon occurred on the heating surface and steady nucleate boiling experiment could be carried out in the whole nucleate boiling region whose wall temperature did not exceed 112 °C. The boiling heat transfer characteristics of the nanofluids and nanoparticles-suspensions are somewhat poor compared with that of the base fluids, since the decrease of the active nucleate cavities on the heating surface with a very thin nanoparticles sorption layer. The very thin nanoparticles sorption layer also caused a decrease in the solid–liquid contact angle on the heating surface which leaded to an increase of the critical heat flux (CHF).     

Boiling enhancement by TiO2 nanoparticle deposition

TiO₂ nanoparticle-coated nickel wires were produced by electrical heating in various nanofluid concentrations ranging from 0.01 to 1 wt.% with various processing heat fluxes from 0 to 1000 kW/m². The experimental results demonstrated up to 82.7% enhancement on critical heat flux (CHF) in condition of coated nickel wire (processed in 1 wt.% with 1000 kW/m²) boiling in pure water. The contact angle measurement revealed that the hydrophilic porous coating formed by vigorous vaporization of TiO₂ nanofluid in nucleate boiling regime enormously modified the wettability of heating surface consequently improving the CHF. Besides, it is evident that the coverage of nanoparticle deposition tended to become more complete as concentration and processing heat flux increased based on SEM and EDS analysis. The nanoparticles dispersed in base fluid exhibited little effect on CHF enhancement and could even hinder the percentage of CHF augmentation from boosting, which demonstrated that one could enhance CHF by using only small amount of nanoparticles just adequate to form surface coatings instead of preparing working fluid with great bulk. However, according to the boiling curves in all cases of coated nickel wires, it is supposed that the nucleate boiling heat transfer coefficient deteriorates as a result of thermal resistance resulted from the occurrence of nanoparticle deposition. In summary, the coated porous structure of nanoparticles leads to enhance CHF and to decrease boiling heat transfer coefficient.     

Temperature induced changes in ZnO–water nanofluid: Zeta potential,size distribution and viscosity profiles

Stable ZnO–water nanofluids with particle volume concentrations in the range of 0.25–2 vol% were prepared using probe ultrasonication and sodium hexametaphosphate for dispersion. The effect of temperature on hydrodynamic size distribution and zeta potential during heating and cooling cycle has been investigated to elucidate its role on dispersion characteristics. The study on influence of temperature on relative viscosity of ZnO–water nanofluids reveals temperature independency of relative viscosity upto a temperature of 35 °C and inverse temperature dependency in the temperature range of 35–55 °C. From the aspect of minimizing relative viscosity at a fixed nanoparticle concentration, excessive ultrasonication is unfavorable resulting in the formation of aggregates with lower fractal dimension.     

Pool boiling heat transfer on the microheater surface with and without nanoparticles by pulse heating

We study the pool boiling heat transfer on the microheater surface with and without nanoparticles by pulse heating. Nanofluids are the mixture of de-ionized water and Al₂O₃ particles with 0.1%, 0.2%, 0.5% and 1.0% weight concentrations. The microheater is a platinum surface by 50 × 20 μm. Three types of bubble dynamics were identified. The first type of bubble dynamics is for the boiling in pure water, referring to a sharp microheater temperature increase once a new pulse cycle begins, followed by a continuous temperature increase during the pulse duration stage. Large bubble is observed on the microheater surface and it does not disappear during the pulse off stage. The second type of bubble dynamics is for the nanofluids with 0.1% and 0.2% weight concentrations. The microheater surface temperature has a sharp increase at the start of a new pulse cycle, followed by a slight decrease during the pulse duration stage. Miniature bubble has oscillation movement along the microheater length direction, and it disappears during the pulse off stage. The third type of bubble dynamics occurs at the nanofluid weight concentration of 0.5% and 1.0%. The bubble behavior is similar to that in pure water, but the microheater temperatures are much lower than that in pure water. A structural disjoining pressure causes the smaller contact area between the dry vapor and the heater surface, decreasing the surface tension effect and resulting in the easy departure of miniature bubbles for the 0.1% and 0.2% nanofluid weight concentrations. For the 0.5% weight concentration of nanofluids, coalescence of nanoparticles to form larger particles is responsible for the large bubble formation on the heater surface. The microlayer evaporation heat transfer and the heat transfer mechanisms during the bubble departure process account for the higher heat transfer coefficients for the 0.1% and 0.2% nanofluid weight concentrations. The shortened dry area between the bubble and the heater surface, and the additional thin nanofluid liquid film evaporation heat transfer, account for the higher heat transfer coefficient for the 0.5% nanofluid weight concentration, compared with the pure water runs.     

Measurement of surface dryout near heating surface at high heat fluxes in subcooled pool boiling

The authors have conducted measurements of liquid–vapor behavior in the vicinity of a heating surface for saturated and subcooled pool boiling on an upward-facing copper surface by using a conductance probe method. A previous paper [A. Ono, H. Sakashita, Liquid–vapor structure near heating surface at high heat flux in subcooled pool boiling, Int. J. Heat Mass Transfer 50 (2007) 3481–3489] reported that thicknesses of a liquid rich layer (a so-called macrolayer) forming in subcooled boiling are comparable to or thicker than those formed near the critical heat flux (CHF) in saturated boiling. This paper examines the dryout behavior of the heating surface by utilizing the feature that a thin conductance probe placed very close to the heating surface can detect the formation and dryout of the macrolayer. It was found that the dryout of the macrolayer formed beneath a vapor mass occurs in the latter half of the hovering period of the vapor mass. Two-dimensional measurements conducted at 121 grid points in a 1-mm × 1-mm area at the center of the heating surface showed that the dryout commences at specific areas and spreads over the heating surface as the heat flux approaches the CHF. Furthermore, transient measurements of wall void fractions from nucleate boiling to transition boiling were conducted under the transient heating mode, showing that the wall void fraction has small values (<10%) in the nucleate boiling region, and then steeply increases in the transition boiling region. These findings strongly suggest that the macrolayer dryout model is the most appropriate model of the CHF for saturated and subcooled pool boiling of water on upward facing copper surfaces.     

Comparison study of liquid replenishing impacts on critical heat flux and heat transfer coefficient of nucleate pool boiling on multiscale modulated porous structures

The critical heat flux (CHF) and heat transfer coefficient of de-ionized (DI) water pool boiling have been experimentally studied on a plain surface, one uniform thick porous structure, two modulated porous structures and two hybrid modulated porous structures. The modulated porous structure design has a porous base of 0.55 mm thick with four 3 mm diameter porous pillars of 3.6 mm high on the top of the base. The microparticle size combinations of porous base and porous pillars are uniform 250 μm, uniform 400 μm, 250 μm for base and 400 μm for pillars, and 400 μm for base and 250 μm for pillars. Both the CHF and heat transfer coefficient are significantly improved by the modulated porous. The boiling curves for different kinds of porous structures and a plain surface are compared and analyzed. Hydrodynamic instability for the two-phase change heat transfer has been delayed by the porous pillars which dramatically enhances the CHF. The highest pool boiling heat flux occurring on the modulated porous structures has a value of 450 W/cm², over three times of the CHF on a plain surface. Additionally, the highest heat transfer coefficient also reaches a value of 20 W/cm² K, three times of that on a plain copper surface. The study also demonstrates that the horizontal liquid replenishing is equally important as the vertical liquid replenishing for the enhancement of heat transfer coefficient and CHF improvement in nucleate pool boiling.     

Pool boiling of nanofluids: Comprehensive review of existing data and limited new data

Nanofluid pool boiling experimental studies have shown mixed results. Recent literature is reviewed and compared here. It is demonstrated here that experiments can be fit to the traditional Rohsenow correlation by changing the surface constant, C_sf. Therefore, this study suggests surface conditions are responsible for varying results. Some limited new experimental data are reported for Al₂O₃/H₂O nanofluids using the hot wire method. Relative to the baseline of pure water, boiling incipience occurs 2–3 °C earlier, heat transfer is enhanced 25–40%, but sub-cooled boiling deteriorates. These results are essentially in agreement with most earlier studies showing enhancement [S.K. Das, N. Putra, W. Roetzel, Pool boiling of nanofluids on horizontal narrow tubes, Int. J. Multiphase Flow 29 (8) (2003) 1237–1247; D. Wen, Y. Ding, Experimental investigation into the pool boiling heat transfer of aqueous based c-alumina nanofluids, J. Nanoparticle Res. 7 (2005) 265–274; S. Witharana, Boiling of refrigerants on enhanced surfaces and boiling of nanofluids, Ph.D. thesis, The Royal Institute of Technology, 2003; S.M. You, J.H. Kim, K.H. Kim, Effect of nanoparticles on critical heat flux of water in pool boiling heat transfer, Appl. Phys. Lett. 83 (2003) 3374–3376].     

Boiling heat transfer on a high temperature silver sphere in nanofluid

To investigate boiling heat transfer characteristics of nanofluids, transient quenching experiments of a high temperature silver sphere in water-based nanofluids with Ag and TiO₂ nanoparticles were performed. A silver sphere with a diameter of 10 mm and an initial temperature of 700 °C was quenched in these nanofluids at a temperature of 90 °C. The results showed a considerable reduction in the quenching ability of nanofluids compared to that of pure water. The presence of nanoparticles in water caused the film boiling mode to vanish at lower temperatures depending on the mixture concentration. Calculated heat transfer rates in nanofluids were lower than those in pure water. In the quenching experiments with an unwashed heated sphere, the film boiling mode did not appear and the hot sphere quenched more rapidly through nucleate boiling. In this case the sphere surface was covered by a thin layer of nanoparticles. It was evident that nanoparticle deposition on the sphere surface prevented vapor film from forming around it and resulted in quick quenching of the hot sphere.