撞击流反应制备CeO2超细粉体

以Ce(NO3)3·6H2O为原料,碳酸氢铵为沉淀剂,少量表面活性剂作分散剂,撞击流反应制备碳酸铈,经焙烧得到超细二氧化铈粉体.研究了加料方式、硝酸铈浓度、表面活性剂用量、搅拌速率、反应温度、反应时间、陈化时间及碳酸铈的焙烧温度和焙烧时间等因素对CeO2颗粒尺寸的影响,从而得出优化工艺条件.采用WJL激光粒度仪检测二氧化铈的粒径,并且通过TG、XRD和SEM等方法对合成产品进行表征,结果表明,合成的是立方晶系的球形二氧化铈超细粉体,晶粒尺寸为20.5nm.     

撞击流反应器制备氧化镧超细粉体

以La(NO3)3·6H2O为原料,碳酸氢铵为沉淀剂,表面活性剂PEG作分散剂,采用撞击流反应器制备碳酸镧,经焙烧得到超细氧化镧粉体.研究了分散剂种类、分散剂加入量、反应物摩尔比n(NH4HCO3)/n(LaO3)、反应温度、反应时间、搅拌速度、焙烧温度和焙烧时间等因素对La2O3粒径的影响,从而得出优化工艺条件.采用WJL激光粒度仪监测氧化镧的粒径,并且通过热重(TG)、红外(IR)、X射线衍射(XRD)和扫描电镜(SEM)等表征手段对产品进行表征,结果表明,所得氧化镧为纺锤形超细粉体,颗粒大小均匀,粒径分布较窄.     

撞击流反应制备钇稳定氧化锆超细粉体

以氧氯化锆和硝酸钇及碳酸氢铵为原料,PEG4000为分散剂,在撞击流反应器中制备钇稳定氧化锆前驱体,焙烧后得到钇稳定氧化锆(YSZ)粉体,考察PEG4000用量、搅拌速率、反应时间和焙烧时间对粉体粒径的影响,并对粉体进行表征。结果表明,优化工艺条件为:PEG4000用量1.4g/L,转速1 000r/min,反应时间65min,前驱粉体在1 460℃焙烧120min,可制得球形、粒度分布均匀、表观直径小于0.5μm的YSZ超细粉体。     

撞击流管式反应制备超细氧化锆粉体

我国氧化锆粉体产业目前基本上“精进粗出”，迫切需要开发氧化锆粉体备新工艺，特别是具有高附加值的纳米氧化锆粉体制备技术，液相反应沉淀法具有成本低，易于工业化等优点而成为研究的热点。本文采用撞击流管式反应新工艺，撞击流接触反应强化了过程的微观混合。实现了均匀成核，使得成核过程易于控制，而管式反应器的独特设计克服了返混，因而使得反应沉淀过程易于控制，粒子分布窄。用该工艺结合醇热处理表面改性制备的超细氧化锆粉体。平均粒径约为14nm，粒度分布窄并无硬团聚发生。该方法过程简单，易于工业化大生产。     

反溶剂重结晶法制备阿奇霉素超细粉体

采用反溶剂重结晶法进行了阿奇霉素微粉化实验研究.系统考察了药物溶液质量浓度、溶剂反溶剂比例、搅拌时间、干燥方式等因素对产品形貌和粒度的影响.得到较优的制备工艺条件为:药物溶液质量浓度0.2/mL、溶剂反溶剂体积比1:20及搅拌时间10min,可制备出平均粒径为270 nm的药物颗粒,经喷雾干燥可得粒径为2-5μm的阿奇霉素超细粉体.采用扫描电镜、比表面积测试、红外光谱分析和体外溶出实验对原料药及产品性质进行分析表征,分析结果表明,阿奇霉素超细粉体化学结构不变,且比表面积增大8倍,溶解速率明显提高.     

喷雾热分解法制备超细粉体材料的特点及应用

喷雾热分解法(Spray Pyrolysis,SP)是近年来发展起来的制备超细粉体材料的重要方法之一.采用该方法,原料可在溶液状态下混合,整个反应过程快速完成,产物组分分布均匀;颗粒一般呈规则的球形,而且少团聚,无需后续洗涤、研磨,纯度高,活性高;无过滤、洗涤、干燥、粉碎过程,一步即获得成品,操作简单方便,生产过程连续,生产效率高,因此,在薄膜材料、金属及其化合物粉体材料和复合粉体材料的制备方面具有重要的应用价值和广阔的市场前景.     

分步沉淀法制备氧化锌超细粉体的工艺研究

以ZnSO4为原料，采用氨水和NH4HCO3作为沉淀剂，首先ZnSO4和一定量氨水反应得到Zn(OH)2晶核，再与NH4HCO3反应包覆沉淀Zn5(OH)6(CO3)2,制得的复合前驱体经烘干，在450℃下煅烧90分钟得到超细ZnO粉体。利用正交实验方法优化得到较佳的沉淀工艺条件。     

超重力场反应器制备二氧化铈超细粉体

在超重力场反应器中,以硝酸铈为铈源,尿素为均匀沉淀剂,少量表面活性剂做分散剂,得到所需产品的前驱体,干燥后焙烧得到二氧化铈超细粉体.通过实验得出其优化工艺条件为:硝酸铈浓度 0.15mol·L-1,尿素浓度0.75mol·L-1,反应温度90℃,反应时间2h,分散剂浓度3g·L-1,旋转填充床转速1000r·min-1,在400℃下焙烧2h.所制得二氧化铈超细粉体经WJL激光粒度仪检测粒径,并通过XRD,SEM对产品进行表征,结果表明合成的二氧化铈属立方晶系,颗粒大小均匀,粒径分布较窄.     

亚微米碳化硅超细粉体的制备及破碎机理探讨

通过试验确定了一条使用搅拌球磨机粉碎碳化硅，使被加工物料一次达85％～95％的颗粒小于1μm的工艺路线，粉体质量达到国外同类产品水平。分析讨论了碳化硅的粉碎机理并对研磨粉碎曲线进行回归方程分析。得出两条曲线的回归方程，理论计算曲线与试验曲线吻合度很好。并探讨影响函数关系方程的因素，为实际生产提供了理论依据。     

一种新型超细粉体气力分级机

近年来，超细粉状物料的研究与应用在国内外日益受到重视，而分级又是生产超细粉料的关键，因为最终产品的粒度是由分级机控制的。本文介绍了一种国外最新研制成功并投入使用的一种新型、高效气力分级机。     

Optimal Conditions for Preparing Ultra-Fine CeO2 Powders in A Submerged Circulative Impinging Stream Reactor

Cerium carbonate powders were produced in a submerged circulation impinging stream reactor (SCISR) from Ce(NO3)3·6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted to produce ultra-fine cerium dioxide (CeO2) powders. The optimal conditions of such production process were obtained by orthogonal and one-factor experiments. The results showed that ultra-fine and narrowly distributed cerium carbonate powders were produced under the optimal flowing conditions. The concentrations of Ce(NO3)3 and NH4HCO3 solutions were 0.25 and 0.3 mol·L-1, respectively. The concentration of PEG4000 added in these two solutions was 4 g·L-1. The stirring ratio, reaction temperature, feeding time, solution pH, reaction time and digestion time were 900 r·min-1, 80 ℃, 20 min, 5～6, 5 min and 1 h, respectively. The final product, CeO2 powders, was obtained by roasting the produced cerium carbonate in air for 3 h at 500 ℃. The finally produced CeO2 powders were torispherical particles with a narrow size distribution of 0.8～2.5 μm. The crystal structure of CeO2 powders belonged to cubic crystal system and its space point group was O5H-FM3M. Under optimal conditions, powders produced by SCISR were finer and more narrowly distributed than that by Stirred Tank Reactor (STR).     

Optimal Conditions for Preparing Ultra-Fine CeO2 Powders in A Submelged Circulative Impinging Stream Reactor

Cerium carbonate powders were produced in a submerged circulation impinging stream reactor （SCISR） from Ce（NO3）3· 6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted to produce ultra-fine cerium dioxide （CeO2） powders. The optimal conditions of such production process were obtained by orthogonal and one-factor experiments. The results showed that ultra-fine and narrowly distributed cerium carbonate powders were produced under the optimal flowing conditions. The concentrations of Ce（NO3）3 and NH4HCO3 solutions were 02,5 and 0.3 mol · L^-1, respectively. The concentration of PEG4000 added in these two solutions was 4 g · L^-1. The stirring ratio, reaction temperature, feeding time, solution pH, reaction time and digestion time were 900 r · min^- 1,80 ℃, 20 min, 5 - 6, 5 min and 1 h, respectively. The final product, CeO2 powders, was obtained by roasting the produced cerium carbonate in air for 3 h at 500 ℃. The finally produced CeO2 powders were torispherical particles with a narrow size distribution of 0.8 -2.5 μm. The crystal structure of CeO2 powders belonged to cubic crystal system and its space point 5 group was OH^5-FM3M. Under optimal conditions, powders produced by SCISR were finer and more narrowly distributed than that by Stirred Tank Reactor （STR）.     

均匀沉淀法合成纳米Y2O3研究

以硝酸钇为原料,尿素为沉淀剂,低分子量聚丙烯酸钠为分散剂,研究了采用均匀沉淀法合成纳米Y2O3的工艺过程.制备条件为钇离子浓度0.3mol/L; 尿素与硝酸钇的摩尔比为41;分散剂聚丙烯酸钠的用量为1%(体积分数);反应时间4h,反应温度95℃;煅烧温度为850℃,煅烧时间3 h.制备得到粒径为32nm、无团聚、粒径均匀的纳米Y2O3.     

超细氧化铋制备研究

以硝酸铋和氨水为原料，通过液相沉淀法制得前驱体沉淀，再经灼烧获得超细氧化铋。经热重分析(TGA)和差热分析(DTA)表明：前驱体沉淀中Bi(OH)3的质量占99．44％，Bi2O3占0．56％，在560℃下完全分解成Bi2O3。经粒度分析、X-射线衍射和扫描电镜(SEM)表明：制备的氧化铋平均粒径为0．20μm，纯度高，晶型为单斜晶型，形貌为不规则颗粒。     

高性能阴极基体用超细钨粉的制备

采用反向滴加沉淀法、微乳法和溶胶-凝胶法3种液相方法合成超细WO3，然后将超细WO3在高纯氢气氛中还原成超细钨粉。XRD，SEM和数学统计分布软件结果分析表明，溶胶-凝胶法得到立方相钨粉，颗粒大小均匀且具有良好的球形度，平均粒径约为200nm，满足高性能阴极基体的要求。微乳法制备的钨粉形貌为片状，不适合作阴极基体的原始粉料。     

Preparation of Well Dispersed and Ultra-Fine Ce （Zr）O2 Mixed Oxide by Mechanochemical Processing

Ultra-fine CeO2-ZrO2 mixed oxide was successfully synthesized by wet-solid phase mechanochemical processing, Ce2(CO3)3·8H2O, ZrOCl2·xH2O and ammonia were used as reactants. It is found that the crystalline Ce2(CO3)3·8H2O and ZrOCl2·xH2O are changed to amorphous cerium and zirconium hydroxide precursor after milling with ammonia, and Ce0.15Zr0.85O2 mixed oxide with pure tetragonal phase structure and medium particle size(D50)less than 1μm is formed by calcining precursor over 673 K. The XRD patterns indicate that the crystal unite size increases with rising calcining temperature due to crystal growth. However, the particle size and BET surface area of the Ce(Zr)O2 mixed oxide decreases with rising calcining temperature, which may be attributed to the contract of particles and the vanish of holes inside grains.